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By O. J. Restrepo-Baena, L. Rojas-Mendoza

Gold losses must be controlled during extracting processes, especially during cyanidation. Otherwise recovery decreases and therefore the profitability of projects too. One of the phenomena that generate such losses is known as preg-robbing which occurs when some mineral constituent adsorbs aurocyanide complex from a cyanide solution. There are some laboratory methods to identify potential preg-robbing in gold ores, highlighting the PRP method, the BGMI test, and cyanidation tests by conventional agitation without activated carbon (BRP) and with activated carbon (CIL). For this study we performed an initial characterization of a sample from Antioquia - Colombia and then we carried out the methods described above in order to identify the presence of carbonaceous matter. We obtained a percentage of preg-robbing of 78.7% by applying the BGMI test; the preg-robbing potential by the PRP method was 97.9% with an extraction of 0.77% and an inferred recovery of 36.6% if preg-robbing did not occur. Finally we obtained under the BRT test a recovery of 0%, while for CIL test an extraction of 33.6% what confirmed the presence of preg-robbers agents in the gold ore. We conducted all tests in the Institute of Minerals - CIMEX at Universidad Nacional de Colombia - Medellin.

Jan 1, 2014

By J. -C. Sztuke, M. Cao

ABSTRACT Wash water and polyethylene oxide (PEO) were used in the flotation of quartz and coal. Wash water decreased entrainment of –15 µm quartz. The optimum superficial wash water rate was 0.05 cm/s. PEO also lowered entrainment. The combination of wash water and PEO led to a slight further reduction in entrainment. For 1:1 mixtures of –15 µm quartz and –300 µm oxidized coal, the combined use of wash water (0.05 cm/s) and PEO increased the separation efficiency from approximately 30% to > 70%, whereas wash water alone at 0.05 cm/s did not lead to a discernible increase.

Jan 1, 2014

By R. E. Baylis, M. R. Tolley, S. Singh, A. J. Murray, R. Boden, L. E. Macaskie, T. P. Hathway, D. Vavlekas

We report rare earth element (REE) recovery using immobilized Serratia biofilm depositing metal phosphate via a robust enzymatic mechanism. Activity was approximately halved at pH 3.5 and restored at pH 5.5. REE(III) was recovered selectively against Th(IV) but the method was non-selective between different REEs (La, Y, Eu, Nd). Biofilms were active for a year (half life of ~ 3 months). The activity of aged biofilm was enhanced by pre-nucleation (‘priming’) with NdPO4 prior to onset of flow-through conditions. The use of different ‘priming’ metals and bacteria via a combinatorial approach revealed some REE selectivity through the selective exclusion of specific REEs.

Jan 1, 2014

By J. M. Mwase

The platinum group metal (PGM) industry is currently reliant on the crush-mill-float-smelt-refine route to process PGM ores. However, there are many instances where this route would not be feasible. An alternative process route has been developed which involves heap bioleaching to extract base metals followed by heap reclamation and a water wash step, leading into heap cyanide leaching to extract precious metals. This process was evaluated through test work on samples of Platreef ore using laboratory scale columns. After 304 days 75% Ni and 93% Cu were extracted in the bioleach experiment at 65°C, and after 60 days 58% Pt, 99% Pd and 90% Au in the follow-up cyanide leach experiment at 50°C. A preliminary process flow sheet has been developed around this. Analysis via a mineral liberation analyser showed that the remaining Pt was in the form of the mineral sperrylite, which appeared to be slow leaching in cyanide in comparison to the other mineral types. Analysis of cyanide effluent solution showed high levels of thiocyanate, which present an environmental risk for disposal and high consumption of cyanide. Further studies to develop the process for commercial application in the South African PGM industry are outlined.

Jan 1, 2014

By Bian Xue, Wu Wenyuan

High quality, mono-dispersed, hollow CeO2 microspheres with high surface area were produced by a spray pyrolysis method at 700oC. CeCl3 was used as the raw material of the process rather than Ce(NO3)3 because the latter is relatively difficult to obtain in industrial quantities. X-ray diffraction and electron microscopy results confirm the high quality synthesis of hollow CeO2 microspheres with narrow size distribution, good mono-disperse, and good reproducibility. The process of the formation of mono-dispersive CeO2 microspheres was investigated by chemical dynamics and a possible mechanism is proposed. This simple method for synthesis of CeO2 microspheres is easily scaled up to fabricate other metal oxide nanostructured materials at industrial scale.

Jan 1, 2014

By J. W. Matousek

Tonnage oxygen plays a critical role in the primary production of two of the most important industrial metals - copper and iron - and minute quantities of oxygen play equally critical roles in determining the properties of the market products. For refined copper, oxygen in the final metal is balanced between maximizing electrical conductivity, neutralizing the effects of harmful impurities, and ensuring that the metal takes on the desired "set" during casting - the surface texture and physical properties required for subsequent rolling and drawing. For refined iron, oxygen must be removed to minimize reaction with carbon during cooling from the molten state with the generation of CO and CO2 - leading to a loss of carbon and the creation of "blow-holes" in the solid ingots and the potential for defects in rolled and forged products. This paper reviews the thermodynamics of oxygen in molten copper and iron at the levels of primary interest to production metallurgists.

Jan 1, 2014

By D. Wolfe, R. Cleminson

"The Aurora North mine has been operating for more than ten years, and is the source of over half of Syncrude’s bitumen production. The hydrotransport systems at Aurora experience high rates of wear, and mission lengths on current slurry pumps are nominally 1,500-2,000 hours. Recent work has enabled a better understanding of the significant adverse effect of large particle impingement damage to impeller vane leading edges - which is the known life determining issue for Aurora hydrotransport pumps. A new pump design has been developed and installed at Aurora, incorporating significantly increased impeller diameter and pumping vane lengths. The new pumps are expected to triple Aurora’s previous mission length for hydrotransport pumps. Part II of this paper will share actual hydraulic and wear performance observed in the first several months of operation, and draw comparisons relative to what was expected for these pumps in design / development.INTRODUCTION Slurry Pumps are Critical Equipment at Syncrude Slurry pumps are a key component in Syncrude’s operations. In a typical Aurora application, each 5000 HP pump stage helps move over 8,000 dry tonnes per hour of oil sand, plus an equal volume of process water that has been added to create the slurry. The average impeller life in oil sand hydrotransport service at Aurora has been nominally 1,500 to 2,000 hours, or 12 to 16 million tonnes of oil sand pumped. Generally, the slurry pump application at Aurora has proven very difficult to improve due to the unique combination of high sand abrasivity, 125 mm (5”) large particle top size (lumps), and high flow rate relative to basic pump size; a factor that results in unduly high impeller vane leading edge speeds for the service conditions."

Jan 1, 2014

By R. L. Bruening, N. E. Izatt, S. R. Izatt

The need for selective metal separations has increased as the mining industry encounters more complex ore bodies and demand for higher performance end products expands. The Molecular Recognition Technology (MRT) process uses highly selective SuperLig® resins to remove desired metals from a variety of solutions in the mining and metals processing and recovery industries. MRT separation processes efficiently produce high purity metal products. In this paper, applications of MRT to metal recovery at mg/L to multiple g/L concentration levels are presented and discussed. Specific examples in the precious metal, nickel, cobalt, zinc, copper, and rare earth industries are given.

Jan 1, 2014

By Alfred Guenkel, Kyle Marte, K. Nikolaisen

"The INCO SO2/air process was patented by INCO in 1985 (Borbely, Devuyst, Ettel, Mosoiu & Schitka, 1985). Well over 80 mining operations worldwide are using this process to oxidize cyanides to cyanates in the tailings from gold, silver and copper mining operations. Though it is possible to supply sulphur dioxide (SO2) in either gas or liquid form, the majority of these SO2/air operations use sulphite-based salts as the ‘SO2’ equivalent reducing agent. This is probably due to the lower capital cost, safety concerns with, and availability of liquid SO2. Sodium metabisulphite (SMBS) is commonly employed, and its cost is an order of magnitude higher than that of sulphur. The increased capital expenditures (CAPEX) for a sulphur-burning SO2 gas plant could have a pay-back of less than two years. In addition, a SO2 gas plant offers potential for significant heat recovery from the sulphur burning process. In terms of safety, the SO2 gas plant only requires the storage of relatively benign sulphur and the site inventory of SO2 will be limited to the plant gas inventory. Furthermore, a SO2 gas plant will not trigger the US Clean Air Act Section 112(r) accident prevention regulations, as may be the case for liquid SO2.Most existing mining operations using ‘SO2’ are gold operations, but in recent years there has been an increased interest in larger sulphur dioxide gas plants for hydrometallurgical facilities that employ leaching of cobalt/manganese minerals or precipitation of manganese/iron (e.g. Tenke Fungurume and Boleo).This paper discusses the different processes which require SO2 as a reducing agent and compares the capital and operational costs of a SO2 gas plant to conventional process alternatives using sulphite-based salts or liquid SO2.The heart of the SO2 gas plant is the sulphur furnace. The most economical way to produce SO2 is by combustion of sulphur in air producing up to 19.5 vol% SO2. Examples of large and small sulphur furnaces are discussed in terms of design, operation, and impacts on operational costs.The SO2 gas produced in a sulphur-burning plant has to be contacted with the liquor to be reduced. The choice of gas-liquid contacting device is important, and two contacting devices are discussed: 1) Gas sparging into the bottom of leach tanks (high, nearly constant, back pressure due to liquid head) and 2) absorption columns (low gas-side pressure drop)."

Jan 1, 2014

By A. R. House, G. W. Shepherd

Newmont USA Limited owns and operates the Phoenix Mine near Battle Mountain, Nevada, USA. The existing milling facility has operated since 2006 (House, 2010). Following the startup of the milling operation, and coupled with the upswing in the copper market, Newmont realized that Phoenix had no process option to treat transition and oxide copper ores. This meant that potentially revenue generating ore would be mined as waste. With no system in place to treat the transition and oxide copper, work began to determine the most feasible approach. After evaluating multiple options, the flow sheet was set for a runof- mine (ROM) heap leach pad and solvent extraction/ electrowinning plant (L-SX/EW). This paper will discuss the eight years of successes and challenges with developing the copper L-SX/EW plant and achieving commercial production of copper cathode.

Jan 1, 2014

By K. Esmaieli

ABSTRACT We conducted a series of numerical experiments to investigate the influence of rock mass foliation on impact-induced damage on ore pass walls. The 2D Particle Flow Code was used to simulate three distinct rock masses surrounding an ore pass, characterized by foliation angles of 60°, 90°, and 120° (clockwise from horizontal). Subsequently, we projected a rock fragment against the ore pass walls at a constant impact angle and velocity. The resulting damage increase

Jan 1, 2014

By Michel Ruel

"This paper describes how to make advanced control choices when difficult processes need improvement. The decision-making process involves choosing between a rules-based approach and a model-based approach as well as weighing benefits and drawbacks, complexity and simplicity, investment and results. This paper will present briefly each solution: basic control, advanced regulatory control, model predictive control, and expert systems such as fuzzy logic controllers and neural networks. The article then proposes a decision tree for selecting the most appropriate approach. A table will compare usage, development, commissioning, maintenance and lifecycle costs for each approach. Finally, conclusions and suggestions will summarize the methodology.INTRODUCTION Advanced process control (APC) is a popular topic. How can one decide whether advanced control should be added to an existing system? Advanced control is used to improve performance, stabilize production, handle constraints, protect equipment and manage grade changes. Most plants use feedback controllers, usually PID (proportional, integral, derivative) controllers. It is common to develop special control schemes to handle more complex processes. In classic PID process control, a controller brings a single value close to a set point using a single manipulated variable. On the other hand, APC brings several values close to optimal targets simultaneously using several manipulated variables. APC's four main strategies are advanced regulatory control, model predictive control (MPC), fuzzy logic and neural networks. Simple solutions are always preferred. Complexity will be increased if performances (production, quality, etc.) are below par. Profitability analyses should be conducted to validate project viability. Needs—not trends—should dictate choices! Before increasing complexity, it is important to define needs, goals, technical support, budget, etc. All these approaches entail strengths and weaknesses. Building a project based on technology rather than needs spells trouble."

Jan 1, 2014

By B. Dubreuil, J. -M. Lalancette, D. Lemieux

Arsenical bearing deposits are posing an increasing challenge for the mining industry. In particular, mineral processing of arsenical sulfidic ores for base and precious metals recovery tend to produce problematic arsenical tailings. This arsenic being present as sulphide or oxide, tends to dissolve, contaminating surface and underground waters. To meet the environmental regulations, it is often required to stabilize the arsenic in a more insoluble form. Dundee Sustainable Technologies has developed a new patented technology using vitrification of the arsenic oxide in an economical way, giving a stable solid, well below the environmental regulations upon leaching. This technology involves oxidation of As (III) to As (V), by using a low cost natural oxidizer and transformation of the produced arsenic oxide into calcium arsenate, which is not volatile at the melting temperature of the glass. This technology would be advantageously applied on most cases around the world where sulphide concentrates are oxidized in a fluidized bed or smelted.

Jan 1, 2014

By L. Chunpongtong

The mining limit in oil sands is regulated by the ratio of total mining volume (ore, interburden, and overburden) one has to mine per volume of bitumen in place (TV/BIP). This paper presents a mathematical solution for creating the most economical pit outline where the TV/BIP ratio upper limit is 12, by combining mining economic theory and the Lerchs-Grossmann (LG) algorithm.

Jan 1, 2014

By D. Sprott, P. A. Kirsch, J. Harris, D. Cliff

This paper details the work of RISKGATE, the largest Australian Coal Association Research Program (ACARP) occupational health and safety initiative to date. The program is an interactive online risk management system developed to maximize health and safety performance in the coal mining industry by implementing continuous improvement in managing major unwanted events. The comprehensive knowledge base covers tires, collisions, fires, isolation, strata control underground, ground control open cut, explosions, explosives, manual tasks, and slips/trips/falls. All major Australian coal mining companies contributed topic experts to this broad industry initiative: nine coal mining companies, more than 80 experts, and more than 400 days of individual time for knowledge-capture workshops.

Jan 1, 2014

By A. Galley, R. Tosdal, F. Robert

The Canada Mining Innovation Council (CMIC) Exploration Innovation Consortium developed a 10-year business case for developing new discovery criteria, exploration techniques, and better data management and analysis to improve exploration success in deep, remote, and covered terrains. Within this context, the CMIC devised a five-year project proposal to create improved multiparameter exploration tools to detect ore systems and more efficient vectoring toward high-grade mineralized cores. The Footprints project was approved March 2013. More than CAD$13 million funding was provided through the CMIC-led joint sponsorship from 30 companies and the Natural Sciences and Engineering Research Council. Consistent industry leadership and integration of dedicated industry and academic expertise has the project on track for reaching its well-defined objectives.

Jan 1, 2014

By B. R. Conard

Copper refining at Vale Canada (previously known as Inco) has been associated with Ni production. Because Cu and Ni carry risks for adverse health endpoints through inhalation exposure, it is critical that their aerosol levels, and the metallurgical processes through which they enter the air, are understood. Because certain Ni substances have been linked to respiratory cancers, it is also important to characterize the amounts and types of Ni compounds in occupational settings. This paper describes electrorefining and electrowinning operations near Sudbury, Ontario (1930–present), and gives aerosol measurements (1978–present).

Jan 1, 2014

By A. Sokolov, E. Hasikova, V. Gostilo, V. Titov

Introducing online X-ray fluorescence (XRF) analyzers in the mining and processing industries can lower costs and improve the representativeness and speed of analysis. The applicability of the CON-XTM industrial conveyor XRF analyzer for continuous measurement of potassium content in process materials was demonstrated at various stages of potassium muriate (MOP) production. The CON-X analyzer produced reliable and accurate results for sylvinite ore (27–36% KCl), MOP cake after flotation (88–97% KCl), and NaCl residue (1.5–5% KCl). Tests of the analyzer at an MOP-producing plant showed a < 0.5% difference between online and laboratory results.

Jan 1, 2014

By A. M. Ramadan

The composition of phosphate rocks, mainly used in manufacturing fertilizers, varies among deposits; therefore, phosphate rocks from different sources are expected to behave differently in acidulation processes. This paper examines the effect of preconcentration of phosphate ore from El-Sebaiya East, Egypt, using flotation on uranium leaching. A high-grade ore sample (27.3% P2O5, 168 mg/kg U) supplied by the Al-Nasr Mining Company, was subjected to reverse single-stage flotation to separate carbonate from the phosphate sample. Subsequently, P2O5 and U concentrations were 32.2% (92.1% recovery) and 225 mg/kg, respectively. After the leach process, the U concentration in the liquor was 319 mg/L.

Jan 1, 2014

By A. van As, J. McGaughey, M. J. Mol, R. Tosen

Geotechnical monitoring is a key element of the successful management of a block cave mine. The interrelationships between production and various monitoring datasets are often not realized due to a lack of data integration and appropriate 3D visualization. Timely delivery of information to ensure best cave management practices is only possible with an integrated cave management system. At Rio Tinto, a state-of-the-art cave management system (CaveCAD) has been designed and developed in cooperation with Mira Geoscience to integrate and analyze vast datasets and report this as instructive information regarding the current \u201cstatus\u201d of the cave.

Jan 1, 2014