Search Documents

By A. S. H. Kabir, I-H. Jung, J. Su, S. Yue, M. Sanjari

The final mechanical properties of wrought magnesium alloys are mostly controlled by microstructure and crystallographic orientation or texture. In common magnesium alloys, grain coarsening occurs during annealing process and formation of undesirable basal texture cannot be changed markedly. The aim of this work is to investigate the effect of static precipitation on microstructure and texture evolution during annealing at 250 °C after warm rolling of Mg-Al-Sn alloy. Mg-3Al-3Sn (wt. %) alloy has been designed using thermodynamic modeling software, FactSageTM, based on forming target stable and incoherent Mg2Sn precipitate within the industrial deformation temperature range. Microstructures and precipitation were investigated by optical and scanning electron microscopes and macro-texture was measured by X-ray diffraction (XRD) techniques. It was found that static precipitates form in a large scale at the recrystallized grain boundaries and retards the grain growth during annealing. Slight weakening in basal texture was also observed during annealing.

Jan 1, 2014

By T. Gerritsen, R. MacRosty, R. Pula

For several years Hatch has been installing fibre optic temperature sensors on the copper cooling elements of smelting furnaces to improve monitoring capabilities in critical locations. The metal/matte tapblock is a key area to monitor in the furnace as it undergoes severe wear from the molten material repeatedly drained through it. The high wear rate around the tapblock means downtime is necessary to perform refractory repairs. A good understanding of the tapblock condition allows the operation to maximize safety and production; consequently the metal/matte tapblocks have been the focus of this study. Fibre optic technology allows the installation of numerous sensors in locations that are very sensitive to refractory thickness, thereby providing information previously unavailable with traditional measurements. The transient nature of the thermal response to tapping and the three-dimensional geometry of the tapblock confound the interpretation of refractory thickness from temperature measurements. This paper focuses on the analysis of both plant data and thermal modelling simulations and details the progress made in relating the temperature measurements to the refractory thickness in front of the copper tapblock.

Jan 1, 2014

By Michael Nicol

A quantitative description of hydrometallurgical operations depends primarily on an understanding of the kinetics of the chemical and physical processes that take place in such operations. This paper will review the current status of kinetics in hydrometallurgy in terms primarily of the author’s experience in diverse unit operations. A distinction will be made between the popular use of models based on limited kinetic data and mechanisms which reflect the actual elementary chemical or physical steps involved in an overall process. Several examples will be used to illustrate this distinction. The proliferation of published papers of declining quality has resulted in the bequest to later researchers of outdated and often incorrect conclusions by a process that is often difficult to reverse. Some examples of these mysterious concepts will be examined and hopefully reversed. Finally, several examples will be given that identify significant gaps in our understanding of the kinetics of important processes that remain unresolved.

Jan 1, 2014

By Collin Bartlett, H. Storch

"Modern metallurgical processes operating with oxygen enriched air, such as the Outotec Flash Smelter and Flash Converter, generate very concentrated SO2 off-gas, which in combination with Outotec sulphuric acid plant technology allows the production of high pressure steam to be used for power generation. Outotec combines well proven technology of sulphur burning plants for this purpose with metallurgical plants.The application of Outotec’s proven LURECTM process enables processing of SO2 gas of up to 25 vol.-%. This process maximizes the energy recovery from the SO2 oxidation at a suitable high temperature level which can be turned into high pressure steam. The application of the Outotec HEROSTM heat recovery system enables the generation of low pressure steam from the absorption energy released at the intermediate absorption step. Additionally, energy is also recovered in the acid coolers for boiler feedwater pre-heating.The concept of integration of high and low pressure steam in combination with the pressurized operation of the boiler feedwater deaerator, thus heating up the boiler feed water to temperatures around 160…170°C, enables indirect transfer of low pressure steam (for deaerator operation) into more valuable high pressure steam, which improves the degree of heat recovery. This is the characteristic of Outotec’s HEROS+TM process.The increased generation of high pressure steam will in turn enable the generation of more electricity when compared to a standard traditional sulphuric acid process."

Jan 1, 2014

By Zhigao Xu, Ruan Chi, Zhenyue Zhang, Yaoyang Ruan, Zhengyan He

Weathered crust elution-deposited rare earth ore is a specific rare earth resource in China that is rich in middle and heavy rare earths. From surface to bottom, the weathered crust elution-deposit rare earth ores can be divided into humic layer, completely weathered layer, partly weathered layer, and bedrock. The exchangeable rare earth ions mainly exist in the completely weathered layer and partly weathered layer, and the exchangeable aluminum ions mainly exist in the humic layer. A novel solution injection method for use in the in-situ leaching technology of weathered crust elution-deposit rare earth ores was put forward based on the different distributions of RE3+ and Al3+ in the four layers. Avoiding the humic layer, only the completely weathered layer and partly weathered layer were leached by controlling the height of the leaching solution liquid level. In this way aluminum, the primary impurity in the RE leaching solution, can be decreased and the purity of the RE product can be improved. Meanwhile, the choices of available leaching reagents were broadened and the possibility of landslide disasters could be reduced.

Jan 1, 2014

By F. Parada L

Two copper concentrate with medium and high enargite content were leached in a 3 L autoclave reactor under conditions based on the CESL process. Copper, arsenic, sulfur and iron were checked in all the experiments and antimony, zinc and molybdenum were evaluated in selected tests. The 98% of the obtained copper extraction is agree with others authors, but the behavior of arsenic, iron an sulfur have some differences. The solid residue was characterized by chemical analysis, DRX and QEMSCAN®. Finally a comparative analysis with neutral roasting as an option for the treatment of this concentrate is done.

Jan 1, 2014

Research on alternative lixiviants for gold is ongoing; however few people have looked at complete flowsheets. Alternative lixiviants are typically applied at concentrations 50 to 100 times those required for cyanidation. The higher concentrations make lixiviant recycle a vital part of the process. In addition it is no longer feasible to rely on lixiviant destruction to produce lixiviant free clean water for recycle to the comminution circuit. Ausenco has worked with Barrick to integrate reverse osmosis into the thiosulfate RIL processing flowsheet that forms the basis of the plant upgrade currently being constructed at Barrick’s Goldstrike autoclave facility.

Jan 1, 2014

By R. I. Iacobescu, Y. W. Chiang, A. Van Audenaerde, R. M. Santos, T. Van Gerven, P. Knops

In this work, we explore a novel mineral processing approach using carbon dioxide to promote mineral alterations that lead to improved extractability of nickel from olivine ((Mg,Fe)2SiO4). The precept is that by altering the morphology and the mineralogy of the ore via mineral carbonation, the comminution requirements and the acid consumption during hydrometallurgical processing can be reduced. Furthermore, carbonation pre-treatment can lead to mineral liberation and concentration of metals in physically separable phases. In a first processing step, olivine is fully carbonated at high CO2 partial pressures (35 bar) and optimal temperature (200 °C) with the addition of pH buffering agents. This leads to a powdery product containing high carbonate content. The main products of the carbonation reaction include amorphous colloidal silica, chromium-rich metallic particles, and iron-substituted magnesite ((Mg1- x,Fex)CO3). Carbonated olivine was subsequently leached using an array of inorganic and organic acids to test their leaching efficiency. Compared to leaching from untreated olivine, the percentage of nickel extracted from carbonated olivine by acid leaching was significantly increased. It is anticipated that the mineral carbonation pre-treatment approach may also be applicable to other ultrabasic and lateritic ores.

Jan 1, 2014

By Tuomas van der Meer, Jukka Tanninen, Annukka E. Mäkinen, Mika Martikainen, Laura M. Nevatalo

The mining industry consumes huge water volumes and the waste streams typically contain sulfate, which has caused problems to many operations around the world. Discharge of sulfate to fresh waters is being restricted as the sulfate load increases salinity and causes problems when sulfate is reduced to toxic H2S by natural bacteria. To reduce fresh water consumption, internal water recycling had become a necessity in metallurgical processes. However, the recycling causes accumulation of sulfate and other components in water, causing problems to process performance and increases scaling in piping and equipment. Few technically feasible water treatment processes exist in the market that can be applied to decrease sulfate concentration below gypsum saturation level: biological sulfate reduction, membrane separation, ion exchange, evaporation and chemical precipitation. Some of these technologies are effective for treating wastewater, but there is typically a highly concentrated sulfate fraction left requiring still further treatment. Outotec has developed a sulfate removal solution, Outotec Ettringite process, which allows flexible control of residual sulfate concentration, thereby opening doors for increased water recycle within processes and control of the sulfate in discharged waters. In this article the results and benefits of this novel process along with examples of operating costs are presented.

Jan 1, 2014

By Y. Miyabayashi, K. Nishikawa, H. Nagai

JX Nippon Mining & Metals Group recovers valuable metals from end-of-life electronic products in an economical and environmentally-benign way, based on technologies that have been acquired in mining, smelting, and refining operations over time. End-of-life electronic products contain halogens and hydrocarbons. When such materials are treated in the copper smelting process, corrosion of equipment and discoloration of sulfuric acid occur. As a countermeasure to these problems, we have developed pretreatment processes that include an incinerator, exhaust gas washing towers, and a defluorination facility. By implementing these improvements, we have been able to treat a large volume of end-of-life electronic products efficiently in the copper smelting process.

Jan 1, 2014

By Tomoya Kawasaki, Tatsuya Motomura, Yutaka Yasuda

Saganoseki Smelter, one of the largest copper producers in Japan, currently operates a single flash smelting furnace to produce 450,000 tons of new copper annually. The smelter used to employ two flash furnaces, and integrated the two into one in 1996. Since then, various improvements to its facilities and technologies have been made to increase productivity. To upgrade the operation efficiency, "stability" was considered a key issue, and the measures were taken to increase the operation and facility reliability. Currently, the furnace is running at a feed rate of 215 DMT/h, while the furnace utilization has been maintained at 97%. This paper outlines recent improvements that have made to increase furnace productivity and efficiency.

Jan 1, 2014

By D. Rahal, I. Shah, B. Hines, S. Reddick

"The development of stirred milling technology has proven to be an enabling technology in fine grained metallic deposits. The increased grinding efficiency allows for the economic size reduction required to produce saleable concentrates. This improvement has opened the door to retreatment projects such as reprocessing of historic gold mine tailings. Recently a VXP2500 stirred mill was installed at Casmyn Mining Zimbabwe Turk mine to allow the reprocessing of historic mine tailings. After commissioning, an extensive joint research project between Casmyn and FLSmidth Minerals was conducted to optimize the performance of the mill. This paper outlines the challenges encountered in the optimization program and the outcomes from the joint research project.INTRODUCTION The development of stirred mills has opened up many new opportunities to recover valuable minerals from refractory ores. Stirred mills have already been reported as an enabling technology for the processing of fine grained ores in lead/zinc applications (Pease, Young and Curry, 2005). Historically, conventional ball mills were unable to economically grind material fine enough to produce the required recovery or concentrate grade. This often resulted in the loss of valuable materials to the final plant tailings. The advent of stirred milling has now provided an opportunity which has both economic and environmental benefits, the reprocessing of historic mine tailings. Many tailings stockpiles now contain economic concentrations of gold because of the ability of stirred mills to efficiently and economically grind the tailings to liberation sizes. The primary advantage of reprocessing historic tailings is very low cost processing. Recovering the tailings is usually as simple as pumping the material into the reprocessing circuit. The disadvantage of reprocessing tailings is the low feed grade and greater difficulty in recovery valuable minerals at the same size distribution. The material has already been previously processed so fresh surface area or an increase in metal exposure is required. These are both provided by regrinding the tailings material."

Jan 1, 2014

By Zhibao Li, Lanmu Zeng

The behavior of dicalcium silicate in NaOH-NaAl(OH)4-Na2CO3 solution is of significance for controlling the silica level in the production of alumina via the sintering process. Dicalcium silicate samples were obtained through a twostep approach: coprecipitation of calcium and silicate from CaCl2-Na2SiO3-NaOH solutions; and calcination of the hydrated precursor at 1200°C for 4 hours. The optimization of the synthesis parameters including temperature, solution concentrations and aging time was also investigated. Xray diffraction (XRD) and chemical analysis show that the calcined solids include dicalcium silicate with trace amounts of wollastonite. The solubility of the synthesized dicalcium silicate in HCl, NaOH, mixed NaOH-NaAl(OH)4 and NaOH-NaAl(OH)4-Na2CO3 solutions was determined. It was found that the solubility increases with increasing HCl and NaOH concentration. The effect of temperature on the solubility in HCl solutions is limited, but the solubility decreases with increasing temperature in NaOH solutions. The solubility of dicalcium silicate in NaOH-NaAl(OH)4 and NaOH-NaAl(OH)4-Na2CO3 solutions was shown to increase with increased temperature, Al(OH)3 and Na2CO3 concentration. The BromleyZemaitis model for the aqueous electrolyte system was selected to predict the solubility of dicalcium silicate. The model’s predictions yielded certain success compared with experimental solubility data.

Jan 1, 2014

The dissolution of chalcopyrite has received a significant amount of attention. The predominant paradigm of investigation is that its rate of dissolution is limited or passivated by a surface coating or film of material. The common candidates for such a passivating coating are numerous: polysulfide coating, metal deficient layers, copper sulfide coating, bornite layers, jarosite precipitates, and elemental sulfur films. While this line of explanation, that is, the explanation based on passivation, seems to have won some form of consensus with researchers, there is another explanation for the results that can account for all the results observed. Crundwell (1988) proposed that the solid state properties of chalcopyrite, in particular, the semiconducting properties, are responsible for the observed behaviour of chalcopyrite. The purpose of this paper is to outline the semiconductor mechanism of dissolution, and to show how this mechanism accounts for all the observed phenomena recently reported in the literature. The paper outlines the semiconductor mechanism of dissolution, shows how this mechanism accounts for the dissolution

Jan 1, 2014

By K. Morin

"Silver and gold leaching by cyanidation is a well-known process used around the world. This reaction is often accompanied by the leaching of other species throughtout the cyanidation circuit that causes the diversion of cyanide towards non valuable by-products (SCN-, Cu(CN)x, Fe(CN)x, etc.). One of the detrimental impacts of the formation of these by-products is the precipitation of silver-cyanide complexes that occurs when cyanide concentration is too low. Without any extra-addition of free cyanide, the precipitated silver is lost and cannot be recovered causing an important economic loss. To overcome silver precipitation, cyanidation circuits are often operated at higher cyanide concentrations. Recently, COREM’s research team has been working on a technology to measure and control silver precipitation during the cyanidation process. Moreover, a methodology has been elaborated in order to evaluate threshold cyanide level which corresponds to the cyanide concentration at which silver starts to precipitate. This technology has been tested on site on a real cyanidation circuit at Agnico Eagle’s LaRonde mine."

Jan 1, 2014

By S. Esfahani, M. Barati, K. Danaei

"Substituting Portland cement with slag cement is one of the most economically attractive uses of slags. For this application, high cooling rates are required to form an amorphous structure. However, this is counteracted by the need to use small coolant flowrate to allow recovery of slag thermal energy as high quality heat to the coolant fluid. Therefore, a relationship between cooling rate of slag and its structure is essential to recover the heat effectively while making an amorphous slag.A modified Single Hot Thermocouple Technique (SHTT) was employed to investigate the crystallization behavior of slags by plotting their TTT (Time-Temperature, Transformation) diagrams. Seven different slag compositions containing CaO, SiO2, Al2O3, MgO were prepared at varying basicity (CaO/SiO2 =0.5-1.4).The results indicate that with increasing basicity, the TTT curves of glassy to crystalline transformation shift to the left which means higher crystallization tendency. This agrees with the fact that with the increase of basicity, the Si-O bonds are weakened, which in turn facilitates the re-ordering and crystallization of the silicate structure."

Jan 1, 2014

By G. Szilvay, P. Kinnunen, J. Salminen, V. Miettinen, O. Salmi, J. Mäkinen

This paper demonstrates experimental studies on bioprocessing of different waste streams. In Part I of this paper three tailings from mining industry were bioleached with mixed acidophilic culture in order to solubilize valuable metals, like copper, nickel, zinc and manganese to leaching liquor. Bioleaching resulted in > 70 %, > 85 %, 100 % and > 70 % leaching yields for Cu, Ni, Zn and Mn, respectively. However, contaminants like arsenic and chromium were not leached efficiently and they will cause challenges in residual solids and sometimes also in metal recovery from leaching liquor. Bioleaching resulted in 99 % leaching yield for copper. Part II demonstrates mine water treatment and also gold recovery from process liquids with biosorption method. The novelty of biosorption was finding that certain fungal species were able to be cultivated to self-immobilized systems, which are easier to operate than traditional suspended biomass methods. Biosorption resulted in more than 90 % removal for all contaminants, but was also seen to be gold selective.

Jan 1, 2014

By Curtis Rempel, John Bartlett, Alex Holtzapple

METSIM is a powerful program capable of modelling and simulating every known metallurgical and inorganic chemical process. METSIM is used by companies throughout the world to design, simulate and control operations from mine to tailings and everything in between. At its absolute simplest, METSIM can be used to create a process flowsheet. METSIM modules and built-in unit operations cover mass and energy balances for either steady-state or dynamic simulations of mine, stockpile, heap leach, material handling, comminution, beneficiation, hydrometallurgy, pyrometallurgy, gas and steam handling, and tailings management processes. Data for the material being processed can include mineralogy, particle size analysis, grade by size or multicomponent size analysis, washability data, mechanical, physical and thermodynamic properties. METSIM is written in APL (A Programming Language). Unlike C++, APL is simple and easy to learn, allowing the user to program whatever they can imagine, without first obtaining a degree in computer science. METSIM can also interface with EXCEL and other software through dynamic data exchange (DDE), allowing data to be imported and exported for viewing, analyzing and controlling. METSIM can answer simple or complex metallurgical and process questions allowing the user to predict and engineer without the issues of clumsy and tortuous spreadsheets.

Jan 1, 2014

By K. V. Phani Prabhakar, G. Padmanabham1, L. Subashini

Laser-arc Hybrid Welding (LAHW) is a relatively recent concept which effectively combines the advantages of laser welding such as the high depth of penetration, low heat input, high welding speed and the positive aspects of arc welding such as better edge bridging and possibility to add filler. For example, steel sections upto 12 mm thickness have been successfully welded in a single pass at a welding speed of 1 m/minute using a 3.5 kW CO2 laser in combination with a MIG arc. Maraging steel of grade M250 is widely used in the aerospace industry in thicknesses upto 10 mm. Conventionally, it is possible to MIG weld such thicknesses in 3-5 passes employing V-Groove joint preparation. However, this multi-pass welding results in formation of reverted austenite in the weld zone after post weld aging; and the high heat input widens the reverted austenite containing heat affected zone which is popularly known as the dark zone/eyebrow zone. Both these zones are detrimental to strength of the welded joint, specifically the fracture toughness. The width of the dark band is an important factor because, thinner the band, it is supported more effectively by the surrounding material. Therefore, in order to avoid multi-pass welding and reduce the overall heat input, single-pass laser-MIG hybrid welding was attempted on 10 mm thick maraging steel M 250 plates using a hybrid laser arc welding system comprising a 3.5 kW CO2 slab laser and a MIG welding system. Simultaneously, multi-pass MIG welds also are produced. Both the laser-MIG hybrid and MIG welds are characterized microstructurally and subjected to mechanical tests such as tensile and fracture toughness in as-welded and post weld aged condition. The amount and distribution of reverted austenite in the fusion zone and width of the dark band was found to be different. Hybrid welds showed a narrow dark band zone and improved mechanical properties. Laser-hybrid and MIG welding investigations carried out on thick section maraging steel M 250 will be presented in detail, including microstructure, tensile properties and fracture toughness of the welds. To the best of the knowledge of the authors there are no reports on laser-MIG hybrid welding of maraging steels.

Jan 1, 2014

By S. Ghafarnejad Parto, Å. Rasmuson, A. Fredriksson, M. Mohammadi, K. M. Forsberg, J. Martinez De La Cruz

The present study aims at recovering rare earth elements (REE) in conjunction with the production of fertilizers from an apatite concentrate. Apatite is one of the REE rich minerals ending up in the tailings pond when Luossarvaara-Kiirunavaara AB (LKAB) in Sweden processes Malmberget’s iron ore deposit. Leaching with nitric acid, hydrochloric acid, and sulphuric acid respectively have been studied. The nitric acid route was chosen for further investigations and the optimum acid concentration for leaching of the REE were determined. The leached REE are recovered by solvent extraction using di-(2-ethylhexyl) phosphoric acid (D2EHPA) and 2-ethylhexylphosphonic acid-mono-2-ethylhexyl ester (EHEHPA).

Jan 1, 2014