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By Y. Mitsuda, Y. Kayanuma, T. H. Okabe, M. Miyake

A new process to recover platinum group metals (PGMs) from automotive catalyst scrap using metal vapor was developed. To improve the efficiency of the acid dissolution process of PGMs, metal vapor of reactive elements such as magnesium or calcium were contacted with spent automotive catalyst. It was expected that metal vapor would react with metal selectively and form intermetallic compounds. The specimen of the spent catalyst was treated at 1173 K for 3 h, and it was then dissolved in aqua regia for 1 h to recover PGMs. After the reactive metal treatment, 88% of Pt, 81% of Pd, and 72% of Rh in the catalyst scrap was dissolved, while only 77% of Pt, 69% of Pd, and 38% of Rh was dissolved from untreated scraps.

Jan 1, 2004

By B. Dubé, R. Friedman, J. Oliver, R. Aubertin, M. Burson, G. Panneton, M. Hamilton, J. Ayer

"Abstract — The Detour Lake gold deposit is located within the northwestern limit of the Archean Abitibi Subprovince of the Superior Province. Mineralized zones are hosted by a sequence of pillowed and massive flows, hyaloclastite units, and altered ultramafic rocks, and are commonly oriented parallel to a series of high-strain zones that are co-planar to the regional-scale Sunday Lake Deformation Zone. Early in its kinematic history, the Sunday Lake Deformation Zone placed older (2.72 Ga) volcanic rocks of the Detour Lake Formation over younger (2.70 Ga) sedimentary rocks of the Caopatina assemblage. Gold mineralization is also parallel to the position of a laterally persistent siliceous rock unit, the 2.725 Ga ‘Chert Marker Horizon.’ The Chert Marker Horizon coincides with the boundary between the mafic-dominated upper Detour Lake Formation and the ultramafic-dominated lower Detour Lake Formation. Stratigraphic and geochronological data suggest that the Chert Marker Horizon is a deformed felsic volcaniclastic unit. At a cut-off of 0.6 g/t Au, the Detour Lake deposit contains 17.26 million ounces of Au within 445.9 million tonnes of rock grading 1.20 g/t Au. Gold occurs in shear-hosted and extensional vein arrays within rocks of the upper and lower Detour Lake Formation and within the Chert Marker Horizon. The Detour Lake deposit has many of the characteristics of a greenstone-hosted, quartz-carbonate vein deposit; its very large size may be attributed to large-scale rheological controls resulting in the formation of dilatant sites in permissive rock units. © 2012 Canadian Institute of Mining, Metallurgy and Petroleum. All rights reserved."

Jan 1, 2012

By M. Oliazadeh, A. Vazirizadeh

"The inclusion of small amounts of silicon, phosphorus and sulphur in iron ores or concentrates can have a profound effect on the steel making process and thus on the final iron and steel products. In nature however, it is inevitable that iron deposits contain unwanted elements. Each element has its own distinct effect on the final steel product. The effect of high silicon is the formation of gray iron. Phosphorus mainly increases hardness and strength, lowers solidus temperature and increases fluidity and cold shortness. Finally sulphur contamination causes cracks in the iron texture when smelting and forms white iron when casting. Overall, the acceptable level of phosphorus, sulphur and silica in the iron concentrate should be less than 0.04%, 0.15 % and 1.5 % respectively.Scarcity of high grade iron ores necessitates using lower grade ores with higher amounts of impurities. The purpose of iron concentrators is to increase iron grades to an appropriate level suitable for steel making as well as removing impurities. Although many impurities can be traced in the ore, the most predominant impurities are limited to one or two elements. In this paper the beneficiation methods for removing SiO2, P and S are presented, including flotation, and the parameters that need to be considered in the design of beneficiation plants are discussed. Finally industrial cases are discussed along with their metallurgical performance.INTRODUCTIONIn metal sector, value of iron ores and concentrates is determined by iron percentage as well ascontent of:• Useful elements (Mn, Ni, Cr, V, Ti): natural alloying elements in steel• Deleterious impurities (S, P, As, Zn, Pb, K, Na): impair metal properties or complicate operational process in blast furnace• Fluxing components (Si, Ca, Mg,, Al)Sulphur and copper result in red-short, phosphorus is the cause of cold brittleness and arsenic and copper decrease welding characteristics. Sulphur should not exceed 0.15 in commercial ore. Acceptable sulphur content in ores and concentrates for producing sinter and pellets is 0.6%max, as sintering and heat hardening of pellets remove sulphur 60-90%. Phosphorous content in ores, sinter and pellets is limited to 0.07%-0.15%. 0.00.1% As max, 0.1-0.2% Zn max and up to 0.2% Cu are allowed in iron-ore part of the blast furnace burden for the production of standard conversion pig iron. Slag-forming components are divided into basic oxides (Ca, Mg) and acidic (Si, Al). Higher ratios of basic to acidic oxides are preferred since this reduces raw fluxing material."

Jan 1, 2016

By Kati Tschöpe

Cathode wear has become an increasing challenge in the aluminum industry due to the use of more graphitized materials. Today, there exist no standard laboratory methods for measuring cathode wear where different commercial materials can be ranked. The typical average wear rate in an electrolysis cell is quite small. The aim of this work was to design a test method where the wear could be accelerated compared to industrial cells. It was focused on polarized tests where the cathode is exposed to electrolyte, which gives higher aluminium carbide solubility. The cathode materials were characterized by microscopy and image analysis.

Jan 1, 2011

By Robert B. Parsons

"The tax reform process marches on. The December 16, 1987 measures tabled by Finance Minister Michael Wilson represent one more step toward the objective of total reform of Canada's income and sales taxes. While the income tax changes are taking shape, much work still needs to be done on the sales tax side of the coin.IntroductionOn December 16, 1987 Finance Minister Michael Wilson tabled measures to implement the changes to Canada's income tax system that were proposed in the June 18, 1987 White Paper on Tax Reform. The measures were set out in a Notice of Ways and Means Motion; draft legislation relating to preferred shares, research and development expenditures; and draft regulations regarding capital cost allowance, certified films, flow-through shares, and the resource sector. The reaction of the government to the recommendations made by the Finance and Economic Affairs Committee Report on Tax Reform (the Blenkarn Committee), the Report of the Standing Senate Committee on Banking, Trade and Commerce and through consultations with interested groups and organizations, business, labour and individual Canadians is set out in a booklet of supplementary information.The basic features of the reformed income tax system set out in the White Paper remain. However, a number of significant changes have been incorporated in the Notice of Ways and Means Motion and other material. The following comments address those area s where changes have been made to the original White Paper proposals."

Jan 1, 1988

By C. G. Anderson

As the global demand for copper and gold steadily increases and the need for environmentally sound processing also grows, successful hydrometallurgical treatment of enargite (Cu3AsS4) concentrates has come to the forefront. This type of concentrate contains considerable arsenic so that successful arsenic fixation, for example as scorodite, is of the essence. This paper outlines the successful application of low temperature and low pressure nitrogen species catalyzed (NSC) hydrometallurgical pressure oxidation of enargite concentrates. The successful stabilization of the arsenic as an iron arsenate compound is discussed. Also, the use of experimental design software is highlighted as a process application and optimization tool.

Jan 1, 2006

By P. Bacher, L. Dubourg, M. Jahazi, G. Dezaise

Effect of friction stir welding parameters and natural ageing on weld properties are reported. Using a Taguchi design of experiment, attempt is made to systematically examine the influences of the welding speed, tool rotation speed, forge force, tilt angle and pitch ratio on the weld size and ultimate tensile strength of FSWed joints. One millimetre thick plates of AA7075-T6 were welded in lap joint configuration. Samples were characterized by optical microscopy, hardness and tensile measurements. Trends suggested by the results and directions for further investigation are discussed.

Jan 1, 2006

By K. Svens, M. Lahtinen, L. Lehtinen

"Outotec's direct leaching process is an atmospheric leaching process for sulphidiczinc concentrates. The direct leaching process, based on special leaching reactors developed by Outokumpu and leaching know-how, is the most economical way to produce electrolytic zinc. The newest industrial-scale application of Outotec's direct leaching process will be started up in 2008 in China at Zhuzhou smelter. The process isintegrated to the existing production plant, replacing part of the old production facilities by modern technology and increasing the production capacity significantly. The process equipment supplied by Outotec includes also tailor-made reactors designed on the basisof the work and experience of Outotec Research Centre."

Jan 1, 2008

By F. Habashi

"Extractive metallurgy was divided into the three sectors pyro-, hydro-, and electrometallurgy in 1959 when Professor Joseph Newton at the Idaho School of Mines in Moscow mentioned this in his book Extractive Metallurgy. Pioneer hydrometallurgists who built this discipline can be traced to the alchemists in the ninth century. It is now a mature subject of great importance in which pressure plays a vital role. Short biographies of some hydrometallurgists and the processes they invented are briefly outlined.INTRODUCTIONHydrometallurgy is the use of aqueous solutions to recover metals from ores. It is a relatively new discipline when compared with pyrometallurgy the use of fire to melt ores and recover metals which was practiced in ancient times. Hydrometallurgy can be traced to the time of alchemists whose concern was the transmutation of base metals into gold. Although alchemists did not succeed in their venture yet they described many reagents that are useful today. For example, they prepared sulfuric acid by distillation of iron vitriol, muriatic acid by distillation of sulfuric acid with salt, and nitric acid by reaction of sulfuric acid by reaction of sulfuric acid with salpeter. Jabir Ibn Hayyan the Muslim alchemist who lived in the ninth century (Figure 1) described aqua regia a mixture of nitric and hydrochloric acid that can dissolve gold although either acid has no action on gold. THE MIDDLE AGESIn the Middle Ages, it was reported that copper was recovered at Rio Tinto in Spain by allowing copper-containing pyrite to be exposed in piles to the action of air and rain. Copper sulfate solution obtained was treated with pieces of iron to precipitate metallic copper—a process that was called cementation. Georgius Agricola (1494–1555) (Figure 2) a medical doctor in Saxony who used to visit mines and smelters to examine miners and metal workers, described in his book De Re Metallica the parting of gold, i.e., separating of silver from gold by acids."

Jan 1, 2016

By Xu Feng, Han Shufeng, Zhu Bin, Wang Mingming

Due to urban subway tunnels mostly built in the cities with highly density buildings, the geological and construction conditions is complex, especially certain sections of the subway tunnel will pass through from the foundation of the overpass, therefore the stability and surface deformation control of that section’s tunnel excavation is particularly important. Taking Xi'an Metro Line Three interval tunnel as a research object, we have used FLAC3D simulation to analyze the tunnel’s surrounding soil deformation and tunnel lining stress distribution under bridge foundation with shallow buried covered excavation method. Analysis results show: (1) After the excavation of the tunnel right line, due to the bias of the upper bridge foundation the right of the tunnel showed relatively large deformation. In order to ensure the construction safety, we recommended using the grouting anchor reinforcement on the right side wall to further control the deformation zone. (2) The maximum vertical displacement of the ground occurred in the right wall of the tunnel portion which was due to the intensity of soil outside the grouting range of the arch is low, as a result the deformation is larger; this position requires special attention, strengthening the monitoring measurements of this part is necessary to avoid the large deformation and other adverse effects of the upper portion of bridge foundation. (3) The maximum vertical force area of the initial lining of the tunnel is in the middle of the side wall, while the second lining in this part of forces is smaller, thus at the beginning of the construction of the liner, attention should be paid to this area. On-site grouting or steel bracing reinforce support may be used if necessary.

Jan 1, 2015

By Barun Gorain, Andy Stradling

"The traditional metallurgical scale-up techniques for flotation plants are based on lumped flotation rate constants, dimensionless hydrodynamic numbers and the use of safety factors. Once the plant has been designed, the flotation principles that govern scale-up play almost no role in the optimisation of the circuit to meet its metallurgical targets. This deficiency can potentially lead to a plant design incapable of meeting its targets, especially when circuits incorporate large flotation cells. This paper demonstrates the application of the k = PSbRf model in providing a suitable framework for flotation modelling, scale-up and circuit optimisation, thus presenting an integrated approach to the problem. Studies were conducted at Teck Cominco’s Red Dog concentrator to characterise cell hydrodynamics, gas dispersion properties, fioth flow behaviour, entrainment and ore floatability to obtain the key data necessary to develop a model for the flotation circuit. The findings of these studies are presented in this paper, which provide valuable insights into the modelling and optimisation of the Red Dog flotation circuit.INTRODUCTIONThe traditional methodology for flotation scale-up and plant design is based on the rule-of-thumb with safety factors, dimensionless hydrodynamic group similitude considerations, etc. With the recent trend towards larger flotation cells with volumes of 150 m3 and greater in concentrators, the problem of scale-up has become even more acute. The scale-up factors that may have been tolerated on smaller cells are not applicable to larger cells. The transportation of froth in these large cells adds further complexity to the problem. Arbiter et al. (1980) foresaw this problem and pointed out that if scale-up were attempted by rule-of-thumb and trial-and-error, then the probability of failure would increase with scale. This problem is confounded by the fact that the design and scale-up considerations used for a new flotation circuit play almost no role in optimisation of the circuit to meet its metallurgical target. This results in a plant design incapable of meeting its metallurgical targets. There have been several instances where new concentrators have required significant circuit modifications and additional capacity to achieve design targets."

Jan 1, 2002

By D. Milne

Laser profilometers exist for obtaining very accurate two and three dimensional profiles of joint surfaces. The application of this technology is not commonly applied to the collection of field data on discontinuity surface roughness. Rugged and portable field devices are not commonly used and the value of the possible field data that can be collected has not been well recognised. This paper reviews commonly used field techniques for assessing discontinuity roughness, discusses the value of this data and presents a new laser profilometer design for field application.

May 1, 2009

By Zhiwei Wang, Chunsheng Qiao

"Aiming at the problems of the existing calculation methods for the support pressures of shallow tunnels in layered jointed rock strata, by using OAT (orthogonal array testing strategy) and DEM (distinct element method), 12 influencing factors including the thickness of the weathered overburden, and the states of the rock joints were considered. Then, the classification of the loosening zone was analysized. On this basis, by using the DEA (data envelopment analysis) theory, quantitative analysis on the influencing factors was conducted. By analyzing the influence of the key factors, a prediction formula of the boundary of the ringent trumpet-shaped loosening zone was established. According to principles of stress transformation, the formula of support pressures of the loosening zone which could considering the key factors were deduced. Finally, a practical case was introduced and studied to verify the proposed method.INTRODUCTIONIn recent years, various urban subway tunnels are increasingly carried out through jointed rock strata in many cities. Rock masses are discontinuous mediums with fissures, fractures, joints, bedding planes, and faults. The frequency of joints, their orientation with respect to the engineering structures, and the roughness of the joint have a significant importance from the stability point of view. However, there is a lack of understanding about the influence of the joints on the stability of tunnels. Therefore, how to measure the degree of the joints’ influence is a problem that needs to be solved.For the calculation of the support pressures, until now, many research results were focused on soil ground (Bierbäumer 1913; Terzaghi, 1943; Peck, 1969; Sabatini et al., 1999). In terms of site tests and model indoor tests, by measuring strut loads and calculating earth pressure based on strut spacing, the results proposed by Peck (1969) and Tschebotarioff (1973) have been widely used in practice for designing excavation support systems under sand (drained) and clay (undrained) soil conditions. Note that, it is unclear whether these findings could be extended to rock strata. For numerical simulations, how to simulate the states of the rock joints is a key problem that needs to be solved."

Jan 1, 2015

By Ian Bruce

Tailings and water management facilities are essential and integral components of mine and mill operations. They must be managed for the long term in order to ensure that safe and environmentally responsible stewardship is achieved. Toward this end, in 1998, The Mining Association of Canada (MAC) published A Guide to the Management of Tailings Facilities, which recommended the implementation of a tailings management framework (Figure 1) to integrate environmental and safety considerations into each stage of the life cycle of a tailings facility, from initial site selection and design, through construction and operation, to eventual decommissioning and closure. By February 2000 it was becoming apparent that while mining companies were making significant progress toward implementing and documenting tailings management systems, and integrating them with overall environmental management systems, further effort was warranted in their application at the operational level. In particular, a need was identified for further guidance in preparing manuals that outline procedures for the safe operation, maintenance and surveillance (OMS) of tailings and water management facilities.

May 1, 2002

By Arash Habibi

The FMC Westvaco Trona Mine is located near Green River, Wyoming and has an annual production of 4.5 M tons. The underground mine has three active development panels and one longwall panel. The mining horizon is about 500 m below surface and strata liberate methane. Three surface-based blowing fans provide ventilation air. A ventilation survey and subsequent analysis was undertaken and a simulation model developed. Air heating during winter is essential to prevent freezing of pipelines and to lesser degree, for miner comfort. Air at all three intake shafts is heated using gas-fired heat exchangers. A strata heat study was conducted in one of the active panels to determine rock attributes. Tests included in-situ measurements of rock thermal conductivity and geothermal gradient. Continuously methane monitors have also been installed in an active development panel?s return drift. Ventsim ventilation software was used to aid the heat and contaminant simulation study. An exercise was also undertaken to gain some understanding of methane contaminant levels throughout the mine. It was further used to determine an adequate surface intake air heating rate and consequently the minimum natural gas consumption needed for winter intake air heating at the mine.

Aug 1, 2013

By Peter Raziszewski

"A ball charge dynamics model is presented. Simulation results are compared with observed data showing good correlation. Based on the charge dynamics models, a liner wear model is presented along with some wear simulation results. Using the charge dynamics model with the liner wear model, it is possible to envision the predictions of mill power consumption as a function of liner wear. Further work is needed to validate the liner wear model.IntroductionFrom a process control point of view, industrial systems can be considered stationary or non-stationary. For example, the physical properties, such as geometric and/or material, of a system considered stationary do not change with time. However, this is not true for non-stationary systems such as those found in the mining industry where process dynamics are often violent with wear being an intrinsic process phenomenon.In this paper, a model for ball charge dynamics will be presented along with a description for liner wear. Simulation results for power draft prediction using the charge model will be compared with observed data. Further, liner wear results will also be presented."

Jan 1, 1997

By Jim Excell, Jim Rothwell, Mike Rylati

"LocationThe Ekati Diamond mine is located at Lac de Gras, Northwest Territories.Brief Description of OperationBHP Diamonds Inc. has developed Canada's first diamond mine in the Northwest Territories (NWT), Canada. BHP Diamonds Inc. is part of the BHP World Minerals Division ofBHP Minerals. The project is a joint venture between manager and operator BHP (51%) and the Blackwater Group (49%). The Blackwater Group comprises Dia Met Minerals Limited, Charles Fipke and Stewart Blusson.Production at the NWT diamonds project began in October with the mine officially opened October 14, 1998. The project is situated on an 853 000 acre claim block located in the Lac de Gras region of the NWT. It is about 300 km northeast of Yellowknife and 100 km south of the Arctic Circle. The seasonal winter ice road to the Echo Bay Lupin mine passes along the eastern margin of the project area. This allows road access each year from mid-January to mid-April. For the remainder of the year, the project is accessible only by air.HistoryIn 1980, Charles Fipke traced indicator minerals east from the Mackenzie River area. He discovered indicator minerals in the Lac de Gras area and staked mineral claims in 1989. A joint venture was formed between BHP and Dia Met in 1990, and in 1991, the first diamonds in the NWT were discovered at Point Lake by BHP and Dia Met. This initiated the largest staking rush in Canadian history. The joint venture launched an aggressive exploration program.Koala, Fox, and Leslie were identified in 1992 as potentially economic pipes.As soon as the project's potential was established, it was recognized that an enormous amount of work had to be completed in several areas before a mine could be developed, namely: technical evaluation of the resources; environmental and socio-economic evaluation to procure the necessary permits for the development; and engineering design to optimize mining and processing of the resource and to comply with specific environmental requirements."

Jan 1, 2000

By R. W. Nice

"The Similkameen Mining Company property is situated about 9 1/2 miles south and west of Princeton B.C. Owned and operated by Newmont Mining Corporation, mining is presently taking place in the Ingerbelle pit. At 15,000 tpd of 0.50% Cu ore the Ingerbelle pit is sufficient for about 8 years. Another 8 years ore supply is available from the old Granby workings of the Copper Mountain property which operated from 1927 to 1957.The pit operations commenced in late 1970 with the concentrator starting in March 1972. Designed and built by Bechtel Corporation under the supervision of Newmont the concentrator's design was based on single-stage crushing and single-stage modified autogenous grinding. The modification was installation of a crusher to crush the critical size build-up. The description of the operation follows.CRUSHERThe primary crusher is an open pocket Allis-Chalmers. 54"" x 74"" gyratory. The basic closed side setting is 8"". The crusher is fed from one side with 100 ton Electra-haul trucks. The crusher pocket discharges to a 96"" wide conveyor belt, then to a 48"" conveyor system including a stacker belt. The crushed product is piled on a stockpile with a capacity of about 30,000 live tons. This stockpile feeds the concentrator."

Jan 1, 1975

By K. Miao, W. Mu, M. Sharma, A. Haas, N. Dogan

"The ever increasing demand for cleaner steels with low inclusion content has highlighted the limits of our current knowledge for controlling and predicting inclusion agglomeration and removal during liquid steel processing. Key knowledge gaps in this area result from the complex nature of the problems associated with measuring and visualizing the phenomena studied. Confocal scanning laser microscope (CSLM) allows for continuous in situ observation of micron-size samples in real time, at high resolution, under conditions relevant to the steelmaking process. This paper summarizes some of recent CSLM applications in our laboratory to illustrate the methods of analyzing transient behavior. The reaction between inclusions and slag is given as an example. The dissolution rate of calcium aluminate inclusions in CaO-SiO2-Al2O3 slags has been studied at elevated temperatures: 1500, 1550 and 1600°C as well as thermodynamic/kinetic analysis. It is found that total dissolution time decreased with increasing temperature. The rate limiting steps are discussed. It is shown that the diffusion through a product layer is responsible for dissolution at 1500°C. At higher temperature, dissolution is most likely controlled by both boundary layer diffusion and chemical reaction at the slag-inclusion interface. In this paper, the evidence for and against the theory will be critically examined and repercussions of the theory to steel refining processes will be discussed.INTRODUCTION Inclusion formation during liquid steel refining is an unavoidable consequence of current ladle steelmaking processes. The nature and quantity of the inclusions formed in steel is critical in steelmaking, as it affects both productivity through clogging, and downstream physical properties of the steel. It is therefore crucial to better understand and control the formation, agglomeration and dissolution behaviour of inclusions in a slag in order to improve the removability of inclusions from liquid steel. Most research (Sandhage & Yurek, 1988; Sandhage & Yurek, 1990a; Sandhuge & Yurek, 1990b; Sandhuge, 1991) relevant to the kinetics of inclusion removal has been obtained by using a technique where simulated inclusion material (ceramic rods) is dipped in slag and the dissolution rate is measured. While much has been learned using this approach, the difference in scale from bulk materials to inclusions is likely to have a significant bearing on the dissolution kinetics of inclusions in a slag and will certainly result in a very different influence of capillary effects. Further, the data obtained using an indirect (dip test) procedure relies on a comparison of the initial and final conditions of a sample rather than in-situ observation which can be achieved in a confocal microscope in real time."

Jan 1, 2017

By George A. Guess

The making of contracts for the purchase of ores is a business which the metallurgist usually understands better than the miner. Companies in the custom ore business often employ an ore buyer who is aware of the class of ore which the smelter needs, and is thoroughly conversant with the business. The miner on the other hand makes ore contracts but seldom, and it is often only after a settlement has been made that he realizes the meaning of the terms of the contract under which he has sold his ores. He has expectations usually greatly in excess of the amount 'net proceeds' shown at the bottom of the settlement sheet. Seldom does the occasional shipper really know his contract. A somewhat similar parallel is to be found in insurance policies. We all have insurance policies; we never know the conditions contained in them until after the fire. The clauses in the policy are for the protection of the Insurance Company. An Insurance Company has no friends.

Jan 1, 1926