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By P. Clinton Milne

Uranium mines in Washington State include the producing Midnite and Sherwood mines and several mined-out deposits, the most productive of which was the Daybreak mine. The Midnite mine is generally classified as a hydrothermal deposit consisting of tabular orebodies in Precambrian pelitic and calcareous metasedimentary host rocks. The host rocks occur as roof pendants in a Cretaceous porphyritic quartz monzonite intrusive; the quartz monzonite averages 12 ppm U308 The uranium deposit appears to have undergone a complex genesis, involving a series of depositional and enrichment stages. The Sherwood uranium deposit, approximately 4 miles south of the Midnite mine, occurs near the bottom of a basal Late Cretaceous to Paleocene arkosic conglomerate. The conglomerate lies nonconformably on the porphyritic quartz monzonite that is associated with the Midnite deposit. The Sherwood and Midnite uranium deposits may have had a similar genetic history linked by a common uraniferous pluton source, ground-water action, and/or leaching of uranium-rich ash flows from now-eroded, overlying, Eocene volcanics. The Daybreak deposit, in northeastern Spokane County, consists entirely of secondary uranium mineralization (metaautunite) in a quartz monzonite pluton. Mineralization is confined to a low-angle fault zone and is most highly concentrated at the intersection of primary and secondary shears. Both hydrothermal and ground-water origins are feasible. Besides the Midnite-Sherwood area, 14 other areas in the western Okanogan Highlands physiographic province and Cascades region have favourable characteristics for uranium potential. Criteria include the existence of uranium occurrences, Tertiary basin sediments with intercalated volcanic and volcaniclastic rocks, favourable geochemical data, alkaline plutons associated with uranium occurrences or borders of Tertiary basins, and structural controls.

Jan 1, 1979

By Sergio Bustos

A significant expansion project is under way at KATCO?s Torkuduk In Situ Leaching (ISL) operation to increase uranium production up to about 4000 tU/year. Higher flows and lower uranium concentration are expected in the rich solutions coming from the well fields. Therefore, extra adsorption and elution columns and modified operating conditions are required to deal with the increased demand for uranium transfer from the ISL solutions to the eluate solution, which goes to the uranium precipitation section. Resin adsorption and elution performance have been interpreted and projected by using Mac Cabe-Thiele equilibrium diagrams. The resin load, the adsorption mass transfer coefficient, the adsorption zone height and the eluate concentration have been estimated for the expected changing operating conditions associated to the future mine plan. This information has allowed to improve the present operation results and to define the main process design criteria for the expansion project.

Aug 1, 2010

By Brian Lewis

"IntroductionThe leaching method selected for the dissolving of uranium ore depends in part on the physical characteristics of the ore, as well as the uranium mineralization. There are two main methods of leaching employed in uranium circuits in North America, one being ""Carbonate Leaching"" on sandstone, and pitchblende type ores, and ""Acid Leaching"", on quartzite type ores.This chapter deals with the acid leaching of uranium ores found in the Elliot Lake area, using sulphuric acid, for the leaching reagent, and ""pachucas"" for the contactor.The basic leaching process involves the pregrinding of the ore and the mixing of the ore with hot sulphuric acid, the mixture is air agitated, the air being used to oxidize the ore as well as produce agitation. The chemical reaction is as follows: Uranium Oxide + Sulphuric Acid = Uranyl SulphateThe following equations show the actual dissolution of the ""Hexavalent Uranium"", which show that more than one ion or complex of uranium is possible.Uranium DissolutionsI. UO, + 2H-(UOJ + H,O2. (UO,) + SO, = -UO, SO, (Uranyl Sulphate)3. UO, + SO,-(UO, (SO,),)=4. (UO, (SO,),)= -(UO, (SO,),)'Test work carried out in the laboratory as well as in the plants has determined the most efficient methods of extracting the uranium from the ore. A very important factor that has to be determined during initial test work are the amount of acid consumers in the ore. Within the Elliot Lake orebodies are minerals such as chlorite schist, diabase, and basement material, all very high acid consumers, consuming up to 1000 lbs. of acid per ton of ore. Of these minerals only the chlorite schist contain any uranium at all.The following are the operating parameters that have to be controlled in the plant:I. sulphuric acid concentration2. temperature of the mixture3. agitation4. liquid solid ratio5. reaction time6. particle size of ground ore"

Jan 1, 1989

By Bruce C. Fielder

"The concentration of uranium in orebodies discovered in the Athabasca Basin of northern Saskatchewan over the last 20 years has increased by a factor of 100. These high grade uranium orebodies are associated with high concentrations of radionuclides, complex mineralogy and an elemental makeup that includes base metals, arsenic, and molybdenum. Exploiting these high grade ores has required metallurgical advances in milling, tailings disposal and effluent treatment as well as changes in the design of uranium mills.This paper describes the most significant advances, including advances in dealing with the environmental issues which have become more prevalent in recent years. The milling processes of the Cluff Lake Mill, Key Lake Mill, Rabbit Lake Mill, and McClean Lake Mill are compared to illustrate both similarities and differences necessary for milling different orebodies.BackgroundUranium mining in Saskatchewan started in 1953 when the Beaverlodge Mine, owned by Eldorado Nuclear Limited (Eldorado), came into operation at Uranium City. Development in the Athabasca basin started in 1975 when the Rabbit Lake mine came into operation. This was followed by the start-up of the Cluff Lake mine in 1980 and the Key Lake mine in 1983. The McClean Lake mine is forecast to start up in the near future. The McArthur River mine recently received construction approval and the Cigar Lake Project and the Midwest Project are currently in the environmental approval process.The Beaverlodge operation ceased production in June 1982 after nearly 30 years of operation. The Rabbit Lake mill processed Rabbit Lake ore from 1975 until 1985, Collins Bay R-Zone ore from 1985 until 1993, and is currently processing ore from the Eagle Point mine (Bharadwaj, Jarvi and Lam, 1996). The Cluff Lake mill processed ore from the D- Orebody from 1980 until 1984. Since then the Claude orebody has been processed and the OP and DS orebodies are presently being milled (SRK. Senes and Melis, 1987; and Cogema Resources Inc. 1994 ). The Key Lake mill processed ore from the Gaertner ore body from 1983 until 1989 and Deilmann ore has been processed since (Cameco Corporation, 1992b and I 994a). Processing of McArthur River ore in the Key Lake mill is scheduled for 1999. The McClean Lake mill will be processing ore from the JLR, Sue and McClcan orebodies associated with the McClean Lake mine. In future ore from the Cigar Lake and Midwest projects will be processed in the McClean Lake mill. (Minatco Limited. 1991a)."

Jan 1, 1998

By Chuck Edwards

"Milling operations in northern Saskatchewan’s Athabasca Basin have produced uranium continuously since 1975. Over that period, the Athabasca Basin has been one of the world’s premier uranium camps, yielding more than 660 million lb of U3O8. In this paper, the author describes former and current milling operations and discusses why and how the milling process has changed and developed over the past 35 years. The author’s considerations for the future of uranium extraction in the Athabasca Basin close out the paper.INTRODUCTIONThe roughly oval Athabasca Basin in northern Saskatchewan occupies nearly one third of the surface area of the Saskatchewan Shield. Its sandstone-like deposits lie unconformably on the older basement. The basin hosts many high-grade unconformity-type uranium deposits(Saskatchewan Energy and Resources, 2010) for which the Athabasca Basin is world famous. Uranium production in the Athabasca Basin has come from four mills. In the order of startup these are Rabbit Lake, Cluff Lake, Key Lake and McClean Lake. General data (AREVA, 2010; Cameco, 2010; Denison 2010) for each mill are shown in Table 1."

Jan 1, 2011

By C. Edwards

ABSTRACT: Milling operations in northern Saskatchewan’s Athabasca Basin have produced uranium continuously since 1975. During that period, the Athabasca Basin has been one of the world’s premier uranium camps, yielding more than 660 million lb (299,370,964 kg) of U3O8. In this paper, the author describes former and current milling operations and discusses why and how the milling process has changed and developed over the past 35 years. The author’s considerations for the future of uranium extraction in the Athabasca Basin conclude the paper.

Jan 1, 2012

By G. F. Colborne, A. Thunaes

"When the Canadian uranium milling plants went into operation during the early 1950's, they utilized flowsheets developed at the Radioactivity Division of the Federal Mines Branch in Ottawa. Since then, numerous process improvements have been made by the Mines Branch, by the operating companies themselves and by other research organizations. This paper will consider uranium milling technology from the standpoint of a new mine operator charged with the responsibility for the design of an economic flowsheet, and will indicate the range of process elements available to him and the testwork required to enable an intelligent decision to be made."

Jan 1, 1968

By Peter Waggitt

Northern Australia has been home to uranium mining for over 70 years, more or less continuously. In the early days, post World War 2, there was little effort made to remediate workings at the end of operations. The three “campaigns” of uranium mining (1951-55; 1960-70; and 1979-present) are all now in various stages of remediation. This includes not only the large legacy site at Rum Jungle but also smaller fields like the South Alligator Valley, as well as contemporary works at Nabarlek and the ongoing closure at Ranger– Australia’s longest operating uranium mine. This paper briefly describes some of the past remediation activities before providing an update on the Ranger closure programme and future timetable.

Jan 1, 2020

By R. J. Munday

Although uranium deposits in northern Saskatchewan are clustered around the Athabasca basin, basement lithostructure determines their distribution. Basal Wollaston Group pelites are invariably graphitic and carry uraninite in felsic segregations and biotitic pegmatite. Where these intersect the Athabasca Formation, remobilized uranium concentrated as pitchblende. Uranium is also concentrated in silicified and hematized sandstone where the Athabasca Formation overlies post-orogenic faults. Presumably, pregnant solutions associated with the fault were stripped of their metals as they emerged into the contrasting physico-chemical environment of the sandstone basin. Both these types of mineralization correlate with a Grenvillian (-1,000 m.y.) heating event and associated diabase intrusions. However, the rich pitchblende veins at Uranium City appear to predate the Athabasca Formation, but display spatial correlation with the Martin Formation. They are tentatively associated with a syn- to post-D3 retrograde metamorphic event which thoroughly leached crystalline basement and generated uraniferous fluids which escaped, and precipitated metals, into fractures associated with faults that define the grabens in which the Martin Formation was deposited. Remobilization events allowed some of this uranium to move upward into fractures within Martin sediments.

Jan 1, 1979

By C. L. Belyk

There are fifteen accepted types of uranium ore deposits and at least forty subtypes readily identified around the world. Each deposit type has a unique geological model which may also have unique processing implications. Primary uranium production in the past decade has come from a handful of these deposit types: unconformity, sandstone, calcrete, intrusive, breccia complex and volcanic. Processing implications for each of the fifteen deposit types can vary widely between and within different geological models. Some key characteristics of uranium deposits that may have processing implications include: ore grade, uranium and gangue mineralogy ? including clay and carbonate species and content, hardness, porosity, uranium mineral morphology, and carbon content. Processing roadblocks may occur as a result of one or more of these characteristics for any of the fifteen deposit types. Future technological advances and innovative thinking around uranium ore processing could provide avenues for roadblock removal setting the stage for additional and economically-viable uranium production from traditional and non-traditional uranium ore deposits.

Aug 1, 2010

Cameco Corporation is in the process of revitalizing the Key Lake mill. As part of this process, the company is considering installing the Rabbit Lake style strong acid stripping in solvent extraction. This would lead to using hydrogen peroxide for uranium precipitation. The process currently employs ammonia stripping and ammonia precipitation. As part of the process evaluation, an indirect fired drier pilot plant test was conducted. This paper will discuss the results of that test work, including the relationships between the following: ? Drying temperature and product grade ? Drying temperature and product colour ? Drying temperature and product reactivity with water ? Drying temperature and energy input requirements ? Drying temperature and shipping costs

Aug 1, 2010

By B. Dyck, C. Rodgers

ABSTRACT Cameco Corporation is revitalizing its Key Lake Operation uranium mill in northern Saskatchewan. The mill currently uses ammonia stripping in solvent extraction (SX) and ammonia yellowcake precipitation. As part of the revitalization, the company considered installing strong acid stripping in solvent extraction (used at its Rabbit Lake Operation), which would lead to using hydrogen peroxide for uranium precipitation. As part of the process evaluation, tests were carried out to study how the drying temperature in indirect fired dryers would affect the uranium peroxide yellowcake precipitate properties. This paper discusses the test work results, including the relationships between drying temperature and product reactivity with water, product colour, product grade, and energy input requirements.

Jan 1, 2012

By K. D. Hester

"1.0 INTRODUCTIONThe uranium industry started in Canada with the reopening of the gravity concentrator at Eldorado's Port Radium mine in the North West Territories in 1942. In 1948, uranium exploration and processing was opened to the private sector, and the Federal government offered special pricing incentives to the industry. Eldorado explored the Lake Athabaska deposits in northern Saskatchewan, and in 1953 opened the Beaverlodge mine. Other mines in the area soon followed. In 1953 also, the deposits in the Blind River - Elliot Lake area and in the Bancroft area of Ontario were discovered. Mines and mills were quickly developed in these areas.Canadian uranium production peaked at 15,900 short tons of U3O8 in 1959. In that year, uranium exports at $300,000,000 exceeded those of all other minerals in value. On October 1, 1959, Canadian uranium operations employed 13,900 people.Up to 1956, it was a seller's market. By 1958, world production of uranium was far ahead of requirements. Accordingly, in November of 1959, the USAEC announced it would not renew it's options for continued delivery of uranium from Canadian mines. This led to the ""stretchout"" of existing uranium contracts, and many mines were shut down (see Table 1) .In the early 1970's, a commercial uranium market seemed to be developing. In Ontario, at Elliot Lake and Bancroft, mines reopened. But competition was coming from the Athabaska basin of Saskatchewan. Currently it is these high grade, open pit deposits of northern Saskatchewan which are in the forefront of Canadian uranium developments. Canadian developments since 1942 reflect the political and market forces, as well as metallurgical progress and changes in environmental standards. This paper attempts to show these process changes in broad perspective."

Jan 1, 1987

By A. B. Carino

Gulf Minerals (Canada) Limited's Rabbit Lake uranium operation is located in the northern portion of Saskatchewan, 198 miles southeast of Uranium City and /34 miles northwest of Lynn Lake, Manitoba. The paper follows the ore flow through crushing, grinding, sulphuric acid leaching, countercurrent decantation, solvent extraction, ammonium diuranate precipitation, thickening, drying and tailing neutralization.

Jan 1, 1979

By K. M. Sarkar

"In many plant trial s(1,2) it has been proven that very small amounts (10 to 20 ppm) of uranium dissolved in mine water can be effectively recovered by the use of ion exchange resins and this uranium recovery has many advantages. In this paper an economic analysis at different levels of uranium contamination and at different market prices of uranium are described.For this study an operating mine-mill complex with a sulphuric acid leach circuit, followed by solvent extraction (SX) process, is considered, where contaminated mine water is available in excess of process requirements. lt is further assumed that the sulphuric acid eluant containing uranium would be mixed with the mill pregnant liquor stream that proceeds to the SX plant for final uranium recovery.Recovery by Ion ExchangeMine water, in this study, is defined as the water coming from the underground mine, or mine pits, and the run-off water from stockpiles, mine shops, crushing plant , washdown areas, etc.In nature, uranium mainly occurs in two stages; reduced (tetravalent) and oxidized (hexavalent) . The oxidation of sulphides present in the orebody often causes the presence of S04- and acidity in mine water, and this acidic water readily dissolves U+6 part of the depo sit. The react ion between hexavalent uranium, which is dissolved in water as U02+ 2 cation and S04 producing uranyl sulph ate as,"

Jan 1, 1984

By M. Fainerman-Melnikova

The use of strong base ion exchange resins for the extraction of uranium was pioneered in the 1950?s. Ion exchange technology is applicable to dilute leach solutions such as those obtained from in-situ, heap leaching or in-plant processing of low grade ores. A further advantage of ion exchange processes is that fluidised bed technology allows for treatment of solutions with a relatively high concentration of suspended solids and resin-in-pulp technology can treat leach slurries. However, the extraction of uranium with strong base resins is severely affected by the presence of chloride ions in solution. In areas where high quality water is not readily available, the use of saline water as process water would extend the potential application for ion exchange in uranium processing. Our research program has studied the effectiveness of a wide range of commercially available ion exchangers in uranium extraction from saline solutions. In the present work, we examine the impact of salinity (ranging from chloride concentrations found in groundwater to those present in sea water), on the uranium extraction with weak base anionic resins (WBA). The effect of pH and the presence of the competing impurities are also discussed.

Aug 1, 2010

By A. Bhowmik

Uranium Refining is the process in which undesirable neutron absorbing elements such as Boron (B), Gadolinium (Gd), Cadmium (Cd), Europium (Eu), Samarium (Sm) and other heavy metals (Fe, Ni, Co, Ca, Mg etc.) are removed to make it nuclear pure. At present, Uranium refining is carried out by solvent extraction process by using organic based solvent e, g. TBP diluted with Kerosene. The above process generates lot of nitrate bearing liquid waste and degraded organic. In order to eliminate use of hazardous organic and ammonia for Uranium refining altogether, a new process has been developed. In the new process, Yellow Cake is dissolved in nitric acid and uranium peroxide hydrate is precipitated selectively from the solution leaving all the impurities in the solution by using commercial grade hydrogen peroxide at a pre-defined pH, U conc., temperature and stoichiometric quantity of hydrogen peroxide under mild agitation. The precipitate is filtered and washed with DM water to obtain nuclear pure product meeting purity standard as per ASTM C ? 753-99.The product is spray dried and calcined to obtain uranium oxide. The process eliminates use of organic, flammable, toxic chemicals, consumes less quantity of nitric acid and uses environfriendly chemical hydrogen peroxide. The process is simple and can be integrated in the mill. A patent application is entering national phase in several countries including CANADA and abstract/full paper is available in WIPO publication no: WO/2009/013759.

Aug 1, 2010

By Grazyna Zakrzewska-Trznadel

The paper outlines the main objectives of the project that concern the evaluation of the possibility of uranium production from indigenous resources since Poland enters the nuclear program. The best available technologies are considered for uranium extraction and obtaining the yellow cake - U3O8. Liquid-liquid extraction with novel extracting agents, as well as membrane processes for separation of by-products will be tested in course of the project. The technological part will be completed with techno-economical analysis. Acknowledgement The studies were supported by the POIG project, No 01.01.02-14-094-09-00 ?Analysis of the possibility of uranium supply from domestic resources?.

Aug 1, 2010

By Edward S. Bell, Frank Angebrandt

"Nuclear reactors must have very large heat outputs to compete with conventional sources and the only feasible applications are in the production of electric power or large quantities of process steam. This paper considers alternative fuels for electric power generation in Canada. In a publicly owned utility, nuclear stations are economic for base-load generation for unit sizes of 500 mega• watts or larger where competitive fossil fuel costs are higher than about 30 cents per million Btu. In British Columbia, Alberta and Saskatchewan, fossil fuels will continue to be in adequate supply at costs lower than 30 cents per million Btu and thus, except for the special case of Vancouver Island, power generation in Western Canada will continue to be the hydraulic and conventional thermal type. In Eastern Canada, fossil fuel prices are likely to be higher than 30 cents per million Btu and most utilities will be able to install units of 500 mw or larger, so that nuclear power plants will provide much of the base-load generation required. Base-load generation comprises about two-thirds of the energy generated by power utilities. By 1990, the total annual electrical energy load will be over 600 billion kwh, with two-thirds of this load in Eastern Canada. Allowing for additional hydraulic resources which may be developed in Quebec, British Columbia and Manitoba, hydraulic generation is forecast to provide a little more than a third of this electrical energy, nuclear generation a third and fossil-fuelled generation about a quarter."

Jan 1, 1969

By Louise Corriveau, Bronwyn Azar, Valerie A. Jackson, Luke Ootes, Jeff Harris

We use the results of new bedrock mapping, combined with geochemical point data and airborne radiometric data (in particular equivalent uranium concentrations) to help determine which geological units in the Paleoproterozoic Great Bear magmatic zone (GBmz) contain elevated uranium. The data collectively indicate that the highest primary uranium concentrations are in equigranular granites and subvolcanic/volcanic porphyries. Notably, these rocks host the majority of known uranium-bearing deposits and/or prospects in the GBmz. We speculate that the uranium in these deposits/prospects was derived from nearby, uranium-enriched rocks and was mobilized by much younger, circulating hydrothermal fluids. Sedimentary rocks of the Thelon and Dismal Lakes groups unconformably overlie the GBmz and are known to host unconformity-type and sandstone-hosted uranium prospects. Most likely, the uraniumenriched rocks of the GBmz acted as a uranium donor to these overlying sedimentary basins. The method of investigation employed in this study may be applicable to other ‘granitic’ terrains in order to identify regions with favourable rocks for uranium exploration.

Jan 1, 2013