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By B. Dyck, C. Rodgers

ABSTRACT Cameco Corporation is revitalizing its Key Lake Operation uranium mill in northern Saskatchewan. The mill currently uses ammonia stripping in solvent extraction (SX) and ammonia yellowcake precipitation. As part of the revitalization, the company considered installing strong acid stripping in solvent extraction (used at its Rabbit Lake Operation), which would lead to using hydrogen peroxide for uranium precipitation. As part of the process evaluation, tests were carried out to study how the drying temperature in indirect fired dryers would affect the uranium peroxide yellowcake precipitate properties. This paper discusses the test work results, including the relationships between drying temperature and product reactivity with water, product colour, product grade, and energy input requirements.

Jan 1, 2012

By K. D. Hester

"1.0 INTRODUCTIONThe uranium industry started in Canada with the reopening of the gravity concentrator at Eldorado's Port Radium mine in the North West Territories in 1942. In 1948, uranium exploration and processing was opened to the private sector, and the Federal government offered special pricing incentives to the industry. Eldorado explored the Lake Athabaska deposits in northern Saskatchewan, and in 1953 opened the Beaverlodge mine. Other mines in the area soon followed. In 1953 also, the deposits in the Blind River - Elliot Lake area and in the Bancroft area of Ontario were discovered. Mines and mills were quickly developed in these areas.Canadian uranium production peaked at 15,900 short tons of U3O8 in 1959. In that year, uranium exports at $300,000,000 exceeded those of all other minerals in value. On October 1, 1959, Canadian uranium operations employed 13,900 people.Up to 1956, it was a seller's market. By 1958, world production of uranium was far ahead of requirements. Accordingly, in November of 1959, the USAEC announced it would not renew it's options for continued delivery of uranium from Canadian mines. This led to the ""stretchout"" of existing uranium contracts, and many mines were shut down (see Table 1) .In the early 1970's, a commercial uranium market seemed to be developing. In Ontario, at Elliot Lake and Bancroft, mines reopened. But competition was coming from the Athabaska basin of Saskatchewan. Currently it is these high grade, open pit deposits of northern Saskatchewan which are in the forefront of Canadian uranium developments. Canadian developments since 1942 reflect the political and market forces, as well as metallurgical progress and changes in environmental standards. This paper attempts to show these process changes in broad perspective."

Jan 1, 1987

By A. B. Carino

Gulf Minerals (Canada) Limited's Rabbit Lake uranium operation is located in the northern portion of Saskatchewan, 198 miles southeast of Uranium City and /34 miles northwest of Lynn Lake, Manitoba. The paper follows the ore flow through crushing, grinding, sulphuric acid leaching, countercurrent decantation, solvent extraction, ammonium diuranate precipitation, thickening, drying and tailing neutralization.

Jan 1, 1979

By K. M. Sarkar

"In many plant trial s(1,2) it has been proven that very small amounts (10 to 20 ppm) of uranium dissolved in mine water can be effectively recovered by the use of ion exchange resins and this uranium recovery has many advantages. In this paper an economic analysis at different levels of uranium contamination and at different market prices of uranium are described.For this study an operating mine-mill complex with a sulphuric acid leach circuit, followed by solvent extraction (SX) process, is considered, where contaminated mine water is available in excess of process requirements. lt is further assumed that the sulphuric acid eluant containing uranium would be mixed with the mill pregnant liquor stream that proceeds to the SX plant for final uranium recovery.Recovery by Ion ExchangeMine water, in this study, is defined as the water coming from the underground mine, or mine pits, and the run-off water from stockpiles, mine shops, crushing plant , washdown areas, etc.In nature, uranium mainly occurs in two stages; reduced (tetravalent) and oxidized (hexavalent) . The oxidation of sulphides present in the orebody often causes the presence of S04- and acidity in mine water, and this acidic water readily dissolves U+6 part of the depo sit. The react ion between hexavalent uranium, which is dissolved in water as U02+ 2 cation and S04 producing uranyl sulph ate as,"

Jan 1, 1984

By M. Fainerman-Melnikova

The use of strong base ion exchange resins for the extraction of uranium was pioneered in the 1950?s. Ion exchange technology is applicable to dilute leach solutions such as those obtained from in-situ, heap leaching or in-plant processing of low grade ores. A further advantage of ion exchange processes is that fluidised bed technology allows for treatment of solutions with a relatively high concentration of suspended solids and resin-in-pulp technology can treat leach slurries. However, the extraction of uranium with strong base resins is severely affected by the presence of chloride ions in solution. In areas where high quality water is not readily available, the use of saline water as process water would extend the potential application for ion exchange in uranium processing. Our research program has studied the effectiveness of a wide range of commercially available ion exchangers in uranium extraction from saline solutions. In the present work, we examine the impact of salinity (ranging from chloride concentrations found in groundwater to those present in sea water), on the uranium extraction with weak base anionic resins (WBA). The effect of pH and the presence of the competing impurities are also discussed.

Aug 1, 2010

By A. Bhowmik

Uranium Refining is the process in which undesirable neutron absorbing elements such as Boron (B), Gadolinium (Gd), Cadmium (Cd), Europium (Eu), Samarium (Sm) and other heavy metals (Fe, Ni, Co, Ca, Mg etc.) are removed to make it nuclear pure. At present, Uranium refining is carried out by solvent extraction process by using organic based solvent e, g. TBP diluted with Kerosene. The above process generates lot of nitrate bearing liquid waste and degraded organic. In order to eliminate use of hazardous organic and ammonia for Uranium refining altogether, a new process has been developed. In the new process, Yellow Cake is dissolved in nitric acid and uranium peroxide hydrate is precipitated selectively from the solution leaving all the impurities in the solution by using commercial grade hydrogen peroxide at a pre-defined pH, U conc., temperature and stoichiometric quantity of hydrogen peroxide under mild agitation. The precipitate is filtered and washed with DM water to obtain nuclear pure product meeting purity standard as per ASTM C ? 753-99.The product is spray dried and calcined to obtain uranium oxide. The process eliminates use of organic, flammable, toxic chemicals, consumes less quantity of nitric acid and uses environfriendly chemical hydrogen peroxide. The process is simple and can be integrated in the mill. A patent application is entering national phase in several countries including CANADA and abstract/full paper is available in WIPO publication no: WO/2009/013759.

Aug 1, 2010

By Grazyna Zakrzewska-Trznadel

The paper outlines the main objectives of the project that concern the evaluation of the possibility of uranium production from indigenous resources since Poland enters the nuclear program. The best available technologies are considered for uranium extraction and obtaining the yellow cake - U3O8. Liquid-liquid extraction with novel extracting agents, as well as membrane processes for separation of by-products will be tested in course of the project. The technological part will be completed with techno-economical analysis. Acknowledgement The studies were supported by the POIG project, No 01.01.02-14-094-09-00 ?Analysis of the possibility of uranium supply from domestic resources?.

Aug 1, 2010

By Edward S. Bell, Frank Angebrandt

"Nuclear reactors must have very large heat outputs to compete with conventional sources and the only feasible applications are in the production of electric power or large quantities of process steam. This paper considers alternative fuels for electric power generation in Canada. In a publicly owned utility, nuclear stations are economic for base-load generation for unit sizes of 500 mega• watts or larger where competitive fossil fuel costs are higher than about 30 cents per million Btu. In British Columbia, Alberta and Saskatchewan, fossil fuels will continue to be in adequate supply at costs lower than 30 cents per million Btu and thus, except for the special case of Vancouver Island, power generation in Western Canada will continue to be the hydraulic and conventional thermal type. In Eastern Canada, fossil fuel prices are likely to be higher than 30 cents per million Btu and most utilities will be able to install units of 500 mw or larger, so that nuclear power plants will provide much of the base-load generation required. Base-load generation comprises about two-thirds of the energy generated by power utilities. By 1990, the total annual electrical energy load will be over 600 billion kwh, with two-thirds of this load in Eastern Canada. Allowing for additional hydraulic resources which may be developed in Quebec, British Columbia and Manitoba, hydraulic generation is forecast to provide a little more than a third of this electrical energy, nuclear generation a third and fossil-fuelled generation about a quarter."

Jan 1, 1969

By Louise Corriveau, Bronwyn Azar, Valerie A. Jackson, Luke Ootes, Jeff Harris

We use the results of new bedrock mapping, combined with geochemical point data and airborne radiometric data (in particular equivalent uranium concentrations) to help determine which geological units in the Paleoproterozoic Great Bear magmatic zone (GBmz) contain elevated uranium. The data collectively indicate that the highest primary uranium concentrations are in equigranular granites and subvolcanic/volcanic porphyries. Notably, these rocks host the majority of known uranium-bearing deposits and/or prospects in the GBmz. We speculate that the uranium in these deposits/prospects was derived from nearby, uranium-enriched rocks and was mobilized by much younger, circulating hydrothermal fluids. Sedimentary rocks of the Thelon and Dismal Lakes groups unconformably overlie the GBmz and are known to host unconformity-type and sandstone-hosted uranium prospects. Most likely, the uraniumenriched rocks of the GBmz acted as a uranium donor to these overlying sedimentary basins. The method of investigation employed in this study may be applicable to other ‘granitic’ terrains in order to identify regions with favourable rocks for uranium exploration.

Jan 1, 2013

By G. R. Guillet

THE LATE Dr. D. F. Hewitt, Ontario's foremost authority on industrial minerals, was the first to point out the importance of urban minerals when he produced figures (Hewitt 1968) to prove that the Toronto-Hamilton area was Ontario's second largest mining camp in 1966 (Fig . 1). In that year, the value of mineral production within a 60-mile radius of downtown Toronto exceeded individually that of Steep Rock, Kirkland Lake, Timmins, Manitouwadge and Elliott Lake. Only the nickel and precious-metal production of Sudbury .surpassed in value that of Toronto's pits and quarries. Although that position was unchanged for some years during the early sixties, it was admittedly an unusual situation: gold was still pegged at an artificially low value; uranium was stagnant; and Texasgulf had not entered the scene. However, the point had dramatically been made. The combined value of production from hundreds of sand and gravel pits and dozens of limestone and shale quarries was of formidable proportions. The mining industry of the urban fringe could not be denied. Construction aggregates, cement, building stone and bricks were fueling an apparently insatiable appetite for urban expansion and redevelopment.

Jan 1, 1978

By J. A. McCamley

Gypsum scrap generated from wallboard manufacturing, construction and deconstruction activities in North America, Europe and Japan is a recognized environmental problem. Landfill disposal of this gypsum scrap is problematic, with deposits often creating hydrogen sulphide emissions and metallic sulphide groundwater leachates. Of these regions, Europe is the most advanced in dealing with the issue having enacted legislation, which will come into effect in July 2005 that will strongly encourage gypsum recycling throughout the EU. An estimated 10% to 17% of all gypsum used in the wallboard industry becomes recyclable scrap, which represents approximately 1% of the total waste stream in North America. In the United States, 2.5 to 4.5 Mt of gypsum scrap is generated each year; the volume is similar in Europe (the percentage of total tonnage is less because of the higher use of brick and concrete). The Greater Vancouver region of British Columbia has banned gypsum from its landfills, and as a result, all gypsum scrap is now recycled. New West Gypsum Recycling, a Canadian firm, uses its proprietary technology to process large quantities of gypsum scrap that is reincorporated into new wallboard, at percentages ranging up to 25%. The operation of New West Gypsum Recycling Inc. of Langley, Vancouver is examined as a case study and recommendations are provided as to how other urban regions can implement similar gypsum scrap recycling programs.

Jan 1, 2004

By Murray D. Fredlund

The consolidation of soil material is central to many types of engineering analysis. Problems such as the building of highway structures, landfills, or buildings over saturated soft clays require application of such theory. It has been found in industry that the application of consolidation theory has lagged significantly behind the theory which has been developed some time ago. The application of small-strain saturated consolidation theory was first proposed in a 1D form by Terzaghi. Although this theory has been available for some time it?s implementation into software packages in 2D and 3D forms has been slow due to inherent complexities in the coupling equations. The flow and stress equations are also inherently somewhat unstable and this further complicates software implementation. Of particular interest in the mining industry is the consolidation of uranium tailings. One such disposal method that has been utilized is the subaqueous deposition of uranium tailings in large pit structures. When performing such deposition the calculation of consolidation rates is central to determining final pit capacity and expected life. Consolidation software can be successfully used in such cases in order to determine pit filling rates. The primary complexity, however, is that tailings are typically deposited in slurry form and therefore the potential deformations are large. Large-strain consolidation theory is therefore required in order to properly solve the deformations over time. This paper presents the use of a large-strain consolidation analysis in order to predict long-term filling rates in a uranium tailings pit.

Aug 1, 2010

By P. Plante

Contaminated neutral drainage (CND) is characterized by the presence of metal concentrations above regulatory requirements at circumneutral pH in mine drainage. The generation of CND by tailings and waste rocks is a growing concern for the mining industry due to increasingly restrictive regulatory requirements. Difficulties in CND prediction arise from the low oxidation rates of sulfide minerals and from the metal retention potential within the wastes. In fact, sorption phenomena may induce an important delay in the development of CND. For now, it is not possible to adequately consider this delay using the prediction tools developed for acid-mine drainage, such as humidity cells, columns and lysimeters. This work aims to present the new approaches currently under study for CND prediction, particularly the use of a chelating agent in kinetic tests. The main challenge of CND prediction is to quantify the metal retention potential of mine wastes, especially when sorption phenomena are involved in metal retention. Three approaches are currently used to overcome this difficulty. Firstly, the sorption potential is estimated using batch sorption studies. The second approach consists of artificially saturating the sorption potential of the mine waste by contact with a contaminated leachate in sorption-enabling conditions until saturation of the retention potential. These approaches both require that the possible metals involved in CND are known (as well as their chemical speciation) prior to the tests, which require an exhaustive material characterization. Although the two methods enable a qualitative estimation of the retention potential of mine wastes, their results are difficult to scale up from the laboratory to the field since some important parameters are not taken into account. A third proposed approach consists of inhibiting metal sorption at the source using chelating agents. The hypothesis is that chelating the metals immediately upon their release from the oxidation of sulfide minerals will inhibit all geochemical interactions (sorption, complexation, secondary mineral precipitation, ion exchange, etc.) between the metal and its environment. The ideal chelating agent will inhibit geochemical interactions after metal release in the drainage waters without having any impact on the sulfide oxidation and acid neutralisation rates. These approaches were tested over a waste rock sample that is known to naturally generate CND after a few decades of weathering. Results show that kinetic testing (weathering cell, ± 70 g samples) using a chelating agent (EDTA) in the leaching water renders higher metal concentrations in the leachates than a control sample without EDTA, suggesting that sorption (and possibly other geochemical interactions) is inhibited. These results suggest that the combination of these approaches can be efficiently used for more precise CND prediction from mine wastes. Future work will be done using the chelating agent approach over larger scale tests such as columns (± 80 kg samples) and field cells (± 100 tons) in order to propose an integrated approach for CND prediction.

Aug 1, 2013

By V. Gangrade

Recirculation is the major concern associated with the utilization of booster fans. In controlled recirculation, a portion of the return air is purposely mixed with the intake air and the mixture is directed towards a working district, while the air quantity and gas concentrations in the air are closely monitored and managed. The objectives of this study were to determine the gas concentration in intake and return airways during controlled recirculation, and to determine the recirculation fraction for multiple headings. Experiments were conducted in a laboratory model to determine the effect of controlled recirculation on the quality of air circulated through the working faces. Preliminary results showed that recirculation is beneficial to ventilation planning because it reduces the build-up of air contaminants at the working faces and reduces the overall power consumptions. The experimental results were used to quantify the recirculation fraction and to calibrate ventilation models of the laboratory model. These models are used to simulate the controlled recirculation and to predict the gas concentrations in multiple headings.

Aug 1, 2013

By A. Kapoor, L. Morin, S. Mortazavi, P. Béedard, Gould. W. D., A. Kuiper

The degradation of thiocyanate in a simulated gold mill effluent was studied using a laboratory scale rotating biological contactor (RBC). Complete SCN- removal was obtained at temperatures of 8 and 12°C, and a hydraulic retention time of approximately 3.3 h. The NH4+ produced by thiocyanate hydrolysis was oxidized by nitrifying bacteria to NO2 and NO3-. The HS- produced by thiocyanate hydrolysis was chemically and biologically oxidized to elemental S, which was subsequently biologically oxidized to sulfate. Incomplete sulfur oxidation occurred in the RBC, particularly at 8°C and elemental sulfur deposition was observed on the RBC disks. The RBC feed exhibited toxicity to rainbow trout but the RBC was effective in removing the acute toxicity of thiocyanate.

Jan 1, 2005

By B. S. A. Tatone

The surface roughness of unfilled rock discontinuities has a major influence on the deformational and hydraulic behaviour of discontinuous rock masses. Although it is widely recognized that surface roughness is comprised of a large-scale (waviness) and small-scale (unevenness) components, most investigations of surface roughness have been restricted to small fracture surfaces (< 1m2). Hence, the influences of the large-scale components of roughness are often neglected. Furthermore, these investigations typically focus on analyzing roughness in terms of two-dimensional profiles rather than the complete three-dimensional geometry, which can lead to potentially biased estimates of roughness. This contribution demonstrates the use of a new optical digital measurement system, based on the principle of triangulation, to digitize a large-scale natural rock discontinuity surface at both outcrop-scale (~6m x 2m) and lab-scale (~100mm x 100mm). Subsequently, the digitized surfaces are systematically analyzed using the three-dimensional roughness methodology proposed by Grasselli to investigate the dependency of roughness on sample window size and measurement resolution.

May 1, 2009

By P. A. Mingione

"AEROPHINE@ 3418A is a unique sulfide mineral promoter produced by Cyanamid, based on phosphine (PH3) chemistry. It has proven effective as a collector for the sulfide minerals of copper and particularly lead (galena), as well as for secondary gold and silver values. AEROPHINE 3418A has widest application as a Cu and/or Pb collector for complex ores of Cu-Zn and Pb-Zn, which frequently have significant quantities of associated precious metal values. Advantages shown in the use of AEROPHINE 3418A are improved selectivities against Zn- and Fe-sulfides, increased precious metals recoveries, reduced total collector consumptions for Cu and/or Pb flotation, and increased flotation kinetics leading to higher recoveries of these values. Operating plant, pilot plant and laboratory test data from treating different ores are presented, demonstrating the advantages in use and preferred application of AEROPHINE 3418A.INTRODUCTIONCyanamid operates the only phosphine and phosphine derivatives plant in North America, located in Niagara Falls, Ontario. Specialty chemicals manufactured at this facility are used in many diverse applications, including solvent extraction reagents and textile flame retardants. A unique phosphine-based sulfide mineral promoter, AEROPHINE 3418A, is also produced. The origins of AEROPHINE 3418A promoter date back to the 1960's, when it was established that sulfide mineral collectors based on phosphine chemistry demonstrated efficacy. This new collector chemistry was found to provide flotation performance differing significantly from those of more traditional thiol collector chemistries such as xanthates, dithiophosphates, mercaptobenzothiazoles, thionocarbamates and those with xanthogen groups. Some of the advantages ultimately demonstrated by AEROPHINE 3418A promoter compared to these traditional collectors include:"

Jan 1, 1990

By R. W. Culley

"In many areas of Saskatchewan, known gravel deposits have been depleted or are diminishing rapidly; in other areas, particularly in the north, demands for all-weather highways and access roads are far exceeding the supply of gravel sources with which to surface them. These two problems have made conventional methods of air-photo and ground surveys insufficient for gravel location. In the first case, hauling costs on construction now warrant searching for buried deposits and for smaller, less obvious surficial deposits that may be closer to the project. In the second case, search and access conditions are so difficult and costly that the ratio of successes to failures must be kept very high. The Department of Highways has long been aware of the oncoming scarcity of quality gravel deposits and is continually investigating ways of forestalling it. One of these ways is the use of airborne geophysical methods that permit rapid coverage of large areas and that sense and discriminate between earth properties to a significant depth below ground surface. In 1967, the Department began an investigation of an airborne conductivity survey method called INPUT*, or ""Induced Pulse Transient'', leading to a trial in 1968 and data analysis in 1969. The results of this trial initiated• modifications to the technique to improve its sensitivity for mapping shallow deposits. Part way through this modification in 1970, a decision was made to change to an airborne resistivity survey method called EPHASE*. Trials with this technique were conducted and analysed in 1971. This paper is an explanation of the E-PHASE system and a summary of the results from one of three areas mapped in 1971."

Jan 1, 1973

By Charles G. Kemsley

IN view of the truly remarkable development of special steels for special purposes, the mining industry has for years looked forward to a time when steel makers would come forward with a product which would be an improvement over the straight carbon steel which has always held the field for drilling rock. In order to avoid making changes in conventional shop practice, the industry has perhaps been too insistent upon obtaining a water hardening steel which could be handled in the blacksmith shop by long established methods. As early as 1932 or 1933, an oil-hardening tool-steel of the one per cent carbon, plus chrome, plus molybdenum type was applied to hollow drill steel. It was known as a hard as well as a tough steel, and one that, theoretically, should give a good account of itself as a rock drill, if properly heat-treated; and so it has proved in actual trials. There were numerous deterrents which retarded adoption of this steel. For several years there has been a constant improvement in the drilling qualities of the straight carbon steel, and, considering the higher unit price ? of the alloy, there has been considerable doubt in the minds of some mining? men as to what advantage there might be in the use of alloy over straight carbon for hollow drill steel. The alloy being an oil-hardening steel, its adoption meant having two kinds of steel in the mine, for a time, and that spelled trouble, unless some positive means of identification was adopted. The hardening and forging ranges of alloy steel being narrow also made necessary much closer control over these operations if poor results were to be avoided. These thoughts undoubtedly prevented its use becoming wide-spread, for, as a matter of actual record, less than fifteen per cent of all the hollow drill steel used in Canada today is alloy.

Jan 1, 1942

By Charles G. Kemsley

MR. C. R. WHITTEMORE: It is interesting to note that the mining industry is making increased use of alloy steels for drilling. They will undoubtedly lead to greater footage at lesser cost. Mr. Kemsley states that, for use in hard ground, the shanks are brought to a hardness of 435 to 440 Brinell by heating them to approximately l,800°F. It seems to me that this temperature is excessively high-it is considerably above the critical point of the steel. The only effect of such a high temperature is to lessen considerably the impact resistance of the steel. The possibilities of an oil quench, followed by a tempering draw which does not lessen the hardness of the steel too much but increases its toughness, might well repay further study; also the temperature control, a factor which depends on the composition of the steel. However, service results are undoubtedly the best criterion of practice. MR. KEMSLEY: I would like to point out that the steel is not quenched at 1,800°F. After heating to this temperature, it is laid aside to cool gradually; this high temperature is necessary to produce the required hardness by simple normalizing-cooling in still air. We all know that ideal conditions for hardening steel demand salt baths and furnaces with automatic temperature control, but for most companies the cost of such equipment having sufficient output capacity is prohibitive. The end we are trying to attain is to make good drills at a cost that will be within the means of any mine.

Jan 1, 1942