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By C. R. Edwards

"Since the first commercial extraction of uranium in the early 1940s, the range of feasible process alternatives has greatly increased. This paper reviews process options to reduce extraction costs, improve efficiencies, effect safer operations, and lessen environmental impacts. Equipment and processes used in the past, in use now, and that could be considered for future use are described.BackgroundTwo billion years ago life on earth consisted solely of single celled creatures of the simplest design (Gould 1989). Incredible as it may seem, uranium fission reactors were operating then also. In what is now western Africa, a series of natural reactors were fueled by rich uranium deposits in contact with underground rivers. Water from the rivers provided the moderator necessary to sustain the nuclear fission chain reaction. These primordial reactors ran down after about 600 000 years (Ontario Hydro 1989).Because it is ubiquitous in the earth's crust, humans have always been in contact with uranium. Mining of uranium, albeit not intentional, is ancient ; uranium minerals were embedded in ore veins mined for metals such as silver and copper.Uranium was discovered in 1789 in Berlin by an apothecary, Martin Heinrich Klaproth, who named the element after the recently discovered planet Uranus. The metallic element uranium, as opposed to its compounds, was extracted in 1841 by the French chemist Eugene-Melchior Peligot. The atomic mass of uranium was calculated to be 120, but the Russian genius Dmitri Ivanovich Mendeleev (famous and welcome everywhere except in Russia, where his liberal politics were detested by the Tsar), found this did not fit into his periodic table, and submitted a value of 240. Mendeleev was close; the exact atomic mass is 238.029.Henri Becquerel's detection of the radioactivity of uranium in 1896excited scientific study of the metal, but virtually no practical use was found for uranium outside of a minimal consumption as a colouring agent for glass and ceramics. Scientific interest intensified in the 19305. In 1933 Leo Szilard patented the concept of the nuclear chain reaction. While walking to work on a fine fall London morning and mulling over the problem of how to release atomic energy, he was stopped by a red light. He stood in thought and conceived the notion of the neutron-activated chain reaction before the light turned green. The patent was filed in 1934, and Szilard assigned it to the British Admiralty in order to keep it secret, in an honourable but ultimately futile effort to prevent the misuse of science (Bronowski 1973)."

Jan 1, 1992

By L. A. Homeniuk, R. Bonnar

"The Athabasca Basin has been the scene of an intense exploration effort since the late 1960s, resulting in the establishment of this area as one of the major uranium districts in the world.The A thabasca Group is of Helikian age and unconformably overlies metamorphic rocks of Aphebian and Archean age. Most of the known uranium deposits have a close spatial relationship with the unconformity, graphitic meta-sediments, major northeast-trending structures and the basin edge. It should be noted that, in regard to the latter, some of the Cluff Lake deposits are exceptions.The pre-Helikian rocks underlying the Athabasca Group have been divided into six Iithostructural domains. The known uranium deposits are concentrated in the Wollaston and Mudjatik domains in the southeastern portion of the basin.The orebodies typically have a narrow high-grade portion below the unconformity and a broader, lower-grade disseminated zone in the overlying sandstone. Over-all grades average over 1% U3O8 and our estimate of known reserves totals more than 400 million pounds of contained U3O8. Some of the deposits have high concentrations of other metals, including nickel, arsenic, cobalt and gold. Ubiquitous chlorite and clay alteration is characteristic of the orebodies.Other Proterozoic basins in Canada of similar ages and having analogous geological settings to the Athabasca have received far less attention. Although little of the known uranium mineralization in these basins is related to the Helikian unconformity, there may be an exploration potential for deposits similar to those of the Athabasca basin.IntroductionThe Athabasca sedimentary basin is located within the Churchill Structural Province of the Canadian Shield in Northern Saskatchewan. The basin is elliptically shaped and is approximately 800,000 square kilometres in area.The objective of this paper is to summarize the various elements in the genesis of the unconformity-type uranium deposits of the Athabasca Basin and to evaluate the comparative potential of other Proterozoic basins to host similar unconformity-type deposits."

Jan 1, 1982

By R. R. Culbert

Several thousand parts per billion of uranium are present in some alkaline lake and ground waters of the Okanagan region, British Columbia. To a major extent the uranium content of these highly anomalous waters is controlled by their levels of dissolved bicarbonate. In lakes, dissolved bicarbonate and the organic content of the sediment largely control the partitioning of uranium between sediment and water. This relationship is found to a lesser extent in alkaline creeks, and transported geochemical anomalies in soils appear where uranium-bearing alkaline ground waters have encountered organic materials. There is a possibility that young, near-surface deposits (with very low radioactivity) are forming from these uraniferous waters.

Jan 1, 1978

By L. López

Argentina reported about 40,000 tonnes of uranium (tU) as reasonably assured resources and inferred resources for the production cost category <130 US$/kgU in the OECD-NEA/IAEA classification scheme. These resources belong to the following projects: Sierra Pintada, Cerro Solo, Don Otto, Laguna Colorada, Laguna Salada, Meseta Central and Amarillo Grande. With three heavy water reactors in operation and an approximate installed capacity of 1.7 GWe, the current natural uranium requirements are about 220–250 tU per year. Based on various nuclear growth scenarios, it is estimated that by 2030 there will be a generation capacity of some 3,092 GWe for the reference case, with raw material needs of some 486 tU per year. Currently, there are no perspectives for local uranium production in the short term, and it is thought that uranium projects with identified resources must complete resource delineation and advance in technical pre-feasibility studies for the recovery of uranium. It is expected that Argentina continue meeting the uranium demand with imports in the next following years. In the Latin America region, both Brazil and Paraguay could be considered as potential uranium suppliers. In conclusion, despite the apparent growth prospects for the use of nuclear energy to generate electricity in Argentina, there are no immediate prospects for the provision of uranium oxide concentrates from domestic deposits for fuel fabrication. This has implications for supply and energy security.

Jan 1, 2020

By A. H. Lang

"IntroductionMUCH PROSPECTING, exploration, and development work was done for uranium in Canada in 1952, chiefly in northern Saskatchewan and in the Great Bear Lake region of the northwest Territories. The outstanding feature of the year was the great amount of work done in preparing for production at the Ace mine of Eldorado Mining and Refining, Limited, in the Goldfields region . of Saskatchewan. Many private companies and prospectors were also active in this region. Most of the other parts of Canada where uranium has been found received less attention than during the last few years, partly because so much interest was taken in the Goldfields region.In presenting this short summary of the year's activities now, the writer is handicapped because the season is not yet over; some discoveries have probably not yet been announced, and there has not yet been time to digest the numerous reports that have been sent in by companies and prospectors. In any case it would be impossible to give details for most of the discoveries and properties, because that would require a long report, and because that information is classed as confidential until released by the discoverers and companies concerned. It is only possible, therefore, to give a few generalizations, a brief out-line of the activities in northern Saskatchewan, even briefer ,accounts of the work in other parts of the country, and a few details that property owners have informed the writer he may publish or that have already been published by the owners."

Jan 1, 1953

By Charlie Jefferson

Main Goal: Resource Assessment 1. Incorporate existing data & results, old process. 2. NEW Quantitative Analysis (Chung and Chen) 3. Try mass balance of U and geochemical tracers 4. Use holistic process approach ?with key foci ?Targeted basin / belt assessments ?Is there as much in the Athabascaas they say? ?Athabasca reference for other basins (Thelon, etc) ?Compare sandstone & volcanic with USA, Kazakhstan etc: do their models apply here? ?Which IOCG systems are prospective for uranium? 5.Consider Groundwater, Environment; 6.Communicate

May 1, 2006

By Sunil S. Gandhi

"Uranium occurrences are widely distributed in tuffaceous-argillaceous beds and abundant rhyolitic volcanic rocks of the upper Aillik group, which is more than 3 km thick and over 125 km by 40 km in areal extent. They include partially developed Kitts and Michelin deposits, containing 1560 and 7366 t U respectively.Uranium occurs mainly as disseminated fine pitchblende grains in beds and lenticular stratabound zones, and rarely as coarse pitchblende aggregates and thin veinlets. The Kitts deposit and ten other occurrences are in the argillaceous-tuffaceous beds within a steeply dipping stratigraphic zone, less than 50 m thick and over 20 km long, at the base of the upper Aillik group. The occurrences hosted by the rhyolitic rocks, numbering over fifty and including the Michelin deposit, are in elongate structural-stratigraphic belts or zones, and are characterized by a pronounced enrichment of soda and depletion of potash associated with mineralization. The mineralized zones are affected to a varying degree by Hudsonian deformation, metamorphism and granitic intrusions.The uranium mineralization is interpreted as genetically related to the felsic volcanism, involving syngenetic deposition in argillaceous-tuffaceous beds and epigenetic emplacement in rhyolites. The volcanic activity occurred 1855 ± 5 Ma ago according to a preliminary U-Pb zircon date on porphyritic rhyolite. Pitchblendesfrom the Kitts and Michelin deposits and a few other occurrences in rhyolites have yielded nearly concordant dates in 1810 to 1730 Ma range. They reflect resetting of isotopic equilibrium at the time of Hudsonian deformation. Other isotopic data on pitchblendes and galena from veins and aggregates .in the south near the 'Grenville Front' indicate local redistribution of uranium and radiogenic lead at the time of Grenville Orogeny approximately 1100 Ma ago."

Jan 1, 1986

By Philippe Portella

Current Ownership : AREVA NC-France & affiliates (63.4%), ONAREM-Niger (36.6%)Related Mines : Ariège, Artois, Arlette(initial Somaïrlease) and Tamou, Taza, Takriza, Tamgak(SMTT lease)Mining Method : Open Pits Reserves : about 14 000 tU Average grade : 0.3 % UEnvironmental Management : Certified ISO 14001 since November 2002Key figures :2003 output : 1126 tU number of employees at year end : 565 Current Ownership : AREVA NC-France & affiliates (34%), ONAREM-Niger (31%), OURD-Japan (25%), ENUSA-Spain (10%) Related Mines : the Akouta mine provides access to several adjacent orebodies(Akola, Akouta, and coming Afasto with Ebba North / South)Mining Method : Underground ?mainly room & pillars Reserves : about 29 000 tU Average grade : 0.40 to 0.50 % U3O8Environmental Management : Certified ISO 14001 since January 2003Key figures :2003 output : 2017 tU number of employees at year end: 1070

May 1, 2006

By R Thomson

The use of uranium metal in non-ferrous metallurgical practice is dis-cussed with reference to its alloying behaviour and chemical activity. It is suggested that the more promising applications are in the treatment of molten metals to combine with impurities. Mines Branch work along these lines is described for copper, zinc, magnesium, aluminum and nickel alloys. It is shown that a cop-per-uranium master alloy (25 per cent U) successfully deoxidizes molten copper without detriment to the electrical or mechanical properties of the product at residual uranium levels of up to 0.8 wt. per cent. Additions of uranium to alpha brass in amounts greater than the lead impurity content were found to remove the deleterious effect of lead on hot-workability. Similar deoxidizing and malleableizing effects were found with uranium additions to nickel. It is thought that uranium forms stable intermetallic compounds with many impurity elements. A significant malleableizing effect can therefore be expected in the presence of other elements besides lead.

Jan 1, 1963

By P. Clinton Milne

Uranium mines in Washington State include the producing Midnite and Sherwood mines and several mined-out deposits, the most productive of which was the Daybreak mine. The Midnite mine is generally classified as a hydrothermal deposit consisting of tabular orebodies in Precambrian pelitic and calcareous metasedimentary host rocks. The host rocks occur as roof pendants in a Cretaceous porphyritic quartz monzonite intrusive; the quartz monzonite averages 12 ppm U308 The uranium deposit appears to have undergone a complex genesis, involving a series of depositional and enrichment stages. The Sherwood uranium deposit, approximately 4 miles south of the Midnite mine, occurs near the bottom of a basal Late Cretaceous to Paleocene arkosic conglomerate. The conglomerate lies nonconformably on the porphyritic quartz monzonite that is associated with the Midnite deposit. The Sherwood and Midnite uranium deposits may have had a similar genetic history linked by a common uraniferous pluton source, ground-water action, and/or leaching of uranium-rich ash flows from now-eroded, overlying, Eocene volcanics. The Daybreak deposit, in northeastern Spokane County, consists entirely of secondary uranium mineralization (metaautunite) in a quartz monzonite pluton. Mineralization is confined to a low-angle fault zone and is most highly concentrated at the intersection of primary and secondary shears. Both hydrothermal and ground-water origins are feasible. Besides the Midnite-Sherwood area, 14 other areas in the western Okanogan Highlands physiographic province and Cascades region have favourable characteristics for uranium potential. Criteria include the existence of uranium occurrences, Tertiary basin sediments with intercalated volcanic and volcaniclastic rocks, favourable geochemical data, alkaline plutons associated with uranium occurrences or borders of Tertiary basins, and structural controls.

Jan 1, 1979

By Sergio Bustos

A significant expansion project is under way at KATCO?s Torkuduk In Situ Leaching (ISL) operation to increase uranium production up to about 4000 tU/year. Higher flows and lower uranium concentration are expected in the rich solutions coming from the well fields. Therefore, extra adsorption and elution columns and modified operating conditions are required to deal with the increased demand for uranium transfer from the ISL solutions to the eluate solution, which goes to the uranium precipitation section. Resin adsorption and elution performance have been interpreted and projected by using Mac Cabe-Thiele equilibrium diagrams. The resin load, the adsorption mass transfer coefficient, the adsorption zone height and the eluate concentration have been estimated for the expected changing operating conditions associated to the future mine plan. This information has allowed to improve the present operation results and to define the main process design criteria for the expansion project.

Aug 1, 2010

By Brian Lewis

"IntroductionThe leaching method selected for the dissolving of uranium ore depends in part on the physical characteristics of the ore, as well as the uranium mineralization. There are two main methods of leaching employed in uranium circuits in North America, one being ""Carbonate Leaching"" on sandstone, and pitchblende type ores, and ""Acid Leaching"", on quartzite type ores.This chapter deals with the acid leaching of uranium ores found in the Elliot Lake area, using sulphuric acid, for the leaching reagent, and ""pachucas"" for the contactor.The basic leaching process involves the pregrinding of the ore and the mixing of the ore with hot sulphuric acid, the mixture is air agitated, the air being used to oxidize the ore as well as produce agitation. The chemical reaction is as follows: Uranium Oxide + Sulphuric Acid = Uranyl SulphateThe following equations show the actual dissolution of the ""Hexavalent Uranium"", which show that more than one ion or complex of uranium is possible.Uranium DissolutionsI. UO, + 2H-(UOJ + H,O2. (UO,) + SO, = -UO, SO, (Uranyl Sulphate)3. UO, + SO,-(UO, (SO,),)=4. (UO, (SO,),)= -(UO, (SO,),)'Test work carried out in the laboratory as well as in the plants has determined the most efficient methods of extracting the uranium from the ore. A very important factor that has to be determined during initial test work are the amount of acid consumers in the ore. Within the Elliot Lake orebodies are minerals such as chlorite schist, diabase, and basement material, all very high acid consumers, consuming up to 1000 lbs. of acid per ton of ore. Of these minerals only the chlorite schist contain any uranium at all.The following are the operating parameters that have to be controlled in the plant:I. sulphuric acid concentration2. temperature of the mixture3. agitation4. liquid solid ratio5. reaction time6. particle size of ground ore"

Jan 1, 1989

By Bruce C. Fielder

"The concentration of uranium in orebodies discovered in the Athabasca Basin of northern Saskatchewan over the last 20 years has increased by a factor of 100. These high grade uranium orebodies are associated with high concentrations of radionuclides, complex mineralogy and an elemental makeup that includes base metals, arsenic, and molybdenum. Exploiting these high grade ores has required metallurgical advances in milling, tailings disposal and effluent treatment as well as changes in the design of uranium mills.This paper describes the most significant advances, including advances in dealing with the environmental issues which have become more prevalent in recent years. The milling processes of the Cluff Lake Mill, Key Lake Mill, Rabbit Lake Mill, and McClean Lake Mill are compared to illustrate both similarities and differences necessary for milling different orebodies.BackgroundUranium mining in Saskatchewan started in 1953 when the Beaverlodge Mine, owned by Eldorado Nuclear Limited (Eldorado), came into operation at Uranium City. Development in the Athabasca basin started in 1975 when the Rabbit Lake mine came into operation. This was followed by the start-up of the Cluff Lake mine in 1980 and the Key Lake mine in 1983. The McClean Lake mine is forecast to start up in the near future. The McArthur River mine recently received construction approval and the Cigar Lake Project and the Midwest Project are currently in the environmental approval process.The Beaverlodge operation ceased production in June 1982 after nearly 30 years of operation. The Rabbit Lake mill processed Rabbit Lake ore from 1975 until 1985, Collins Bay R-Zone ore from 1985 until 1993, and is currently processing ore from the Eagle Point mine (Bharadwaj, Jarvi and Lam, 1996). The Cluff Lake mill processed ore from the D- Orebody from 1980 until 1984. Since then the Claude orebody has been processed and the OP and DS orebodies are presently being milled (SRK. Senes and Melis, 1987; and Cogema Resources Inc. 1994 ). The Key Lake mill processed ore from the Gaertner ore body from 1983 until 1989 and Deilmann ore has been processed since (Cameco Corporation, 1992b and I 994a). Processing of McArthur River ore in the Key Lake mill is scheduled for 1999. The McClean Lake mill will be processing ore from the JLR, Sue and McClcan orebodies associated with the McClean Lake mine. In future ore from the Cigar Lake and Midwest projects will be processed in the McClean Lake mill. (Minatco Limited. 1991a)."

Jan 1, 1998

By Chuck Edwards

"Milling operations in northern Saskatchewan’s Athabasca Basin have produced uranium continuously since 1975. Over that period, the Athabasca Basin has been one of the world’s premier uranium camps, yielding more than 660 million lb of U3O8. In this paper, the author describes former and current milling operations and discusses why and how the milling process has changed and developed over the past 35 years. The author’s considerations for the future of uranium extraction in the Athabasca Basin close out the paper.INTRODUCTIONThe roughly oval Athabasca Basin in northern Saskatchewan occupies nearly one third of the surface area of the Saskatchewan Shield. Its sandstone-like deposits lie unconformably on the older basement. The basin hosts many high-grade unconformity-type uranium deposits(Saskatchewan Energy and Resources, 2010) for which the Athabasca Basin is world famous. Uranium production in the Athabasca Basin has come from four mills. In the order of startup these are Rabbit Lake, Cluff Lake, Key Lake and McClean Lake. General data (AREVA, 2010; Cameco, 2010; Denison 2010) for each mill are shown in Table 1."

Jan 1, 2011

By C. Edwards

ABSTRACT: Milling operations in northern Saskatchewan’s Athabasca Basin have produced uranium continuously since 1975. During that period, the Athabasca Basin has been one of the world’s premier uranium camps, yielding more than 660 million lb (299,370,964 kg) of U3O8. In this paper, the author describes former and current milling operations and discusses why and how the milling process has changed and developed over the past 35 years. The author’s considerations for the future of uranium extraction in the Athabasca Basin conclude the paper.

Jan 1, 2012

By G. F. Colborne, A. Thunaes

"When the Canadian uranium milling plants went into operation during the early 1950's, they utilized flowsheets developed at the Radioactivity Division of the Federal Mines Branch in Ottawa. Since then, numerous process improvements have been made by the Mines Branch, by the operating companies themselves and by other research organizations. This paper will consider uranium milling technology from the standpoint of a new mine operator charged with the responsibility for the design of an economic flowsheet, and will indicate the range of process elements available to him and the testwork required to enable an intelligent decision to be made."

Jan 1, 1968

By Peter Waggitt

Northern Australia has been home to uranium mining for over 70 years, more or less continuously. In the early days, post World War 2, there was little effort made to remediate workings at the end of operations. The three “campaigns” of uranium mining (1951-55; 1960-70; and 1979-present) are all now in various stages of remediation. This includes not only the large legacy site at Rum Jungle but also smaller fields like the South Alligator Valley, as well as contemporary works at Nabarlek and the ongoing closure at Ranger– Australia’s longest operating uranium mine. This paper briefly describes some of the past remediation activities before providing an update on the Ranger closure programme and future timetable.

Jan 1, 2020

By R. J. Munday

Although uranium deposits in northern Saskatchewan are clustered around the Athabasca basin, basement lithostructure determines their distribution. Basal Wollaston Group pelites are invariably graphitic and carry uraninite in felsic segregations and biotitic pegmatite. Where these intersect the Athabasca Formation, remobilized uranium concentrated as pitchblende. Uranium is also concentrated in silicified and hematized sandstone where the Athabasca Formation overlies post-orogenic faults. Presumably, pregnant solutions associated with the fault were stripped of their metals as they emerged into the contrasting physico-chemical environment of the sandstone basin. Both these types of mineralization correlate with a Grenvillian (-1,000 m.y.) heating event and associated diabase intrusions. However, the rich pitchblende veins at Uranium City appear to predate the Athabasca Formation, but display spatial correlation with the Martin Formation. They are tentatively associated with a syn- to post-D3 retrograde metamorphic event which thoroughly leached crystalline basement and generated uraniferous fluids which escaped, and precipitated metals, into fractures associated with faults that define the grabens in which the Martin Formation was deposited. Remobilization events allowed some of this uranium to move upward into fractures within Martin sediments.

Jan 1, 1979

By C. L. Belyk

There are fifteen accepted types of uranium ore deposits and at least forty subtypes readily identified around the world. Each deposit type has a unique geological model which may also have unique processing implications. Primary uranium production in the past decade has come from a handful of these deposit types: unconformity, sandstone, calcrete, intrusive, breccia complex and volcanic. Processing implications for each of the fifteen deposit types can vary widely between and within different geological models. Some key characteristics of uranium deposits that may have processing implications include: ore grade, uranium and gangue mineralogy ? including clay and carbonate species and content, hardness, porosity, uranium mineral morphology, and carbon content. Processing roadblocks may occur as a result of one or more of these characteristics for any of the fifteen deposit types. Future technological advances and innovative thinking around uranium ore processing could provide avenues for roadblock removal setting the stage for additional and economically-viable uranium production from traditional and non-traditional uranium ore deposits.

Aug 1, 2010

Cameco Corporation is in the process of revitalizing the Key Lake mill. As part of this process, the company is considering installing the Rabbit Lake style strong acid stripping in solvent extraction. This would lead to using hydrogen peroxide for uranium precipitation. The process currently employs ammonia stripping and ammonia precipitation. As part of the process evaluation, an indirect fired drier pilot plant test was conducted. This paper will discuss the results of that test work, including the relationships between the following: ? Drying temperature and product grade ? Drying temperature and product colour ? Drying temperature and product reactivity with water ? Drying temperature and energy input requirements ? Drying temperature and shipping costs

Aug 1, 2010