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By A. Ghahremaninezhad, E. Jorjani, A. Riahi, Islamic Azad University, B. Nazari, H. Hani, Z. Manafi

The presence of a high iron concentration, 9.1 g/L, in the raffinate of the Sarcheshmeh copper heap bioleach process led to the formation of various types of jarosite, (K,Na,NH4,H3O)Fe3(SO4)2(OH)6, on the heap mineral surfaces. This study probes iron removal from the raffinate using a bio-oxidation process based on A. ferrooxidans bacteria in the presence and absence of jarosite seed. The jarosite seed was biologically synthesized using A. ferrooxidans bacteria. The effect of solution pH (1.5 to 2.5) and jarosite seed dosage (0 to 15 wt.%) on iron removal was examined. It was demonstrated that the concentration of iron ions present in the raffinate decreased from 9.1 g/L to 2.5 g/L with the addition of 10 wt.% jarosite seed at pH 2 and 130 rpm mixing rate at 32°C. Three different types of raffinate including (1) native raffinate containing 9.1, 3.4, 5.7 g/L of total, ferric and ferrous iron, respectively, (2) bio-oxidized raffinate in the absence of the jarosite seed containing 8.5 g/L total iron (mainly ferric with negligible ferrous), (3) bio-oxidized raffinate in the presence of jarosite seed containing 2.55 g/L total iron (mainly ferric with negligible ferrous) were used in mesophilic, moderate thermophilic and thermophilic bioleaching processes. The results of the flask tests showed that the highest copper bioleaching recoveries of 9.4, 49.4 and 90.8 % were achieved using raffinate (3) with mesophilic, moderate thermophilic and thermophilic bioleaching processes, respectively.

Jan 1, 2016

By Sepulvedam Jaime E., Levi Guzmán Rivera

"Grinding media consumption rates and their dependence on key operating conditions in semiautogenous grinding mills is analyzed on the basis of a detailed mathematical model recently developed by Moly-Cop´s specialists which describes and takes into account the three primary media consumption mechanisms, namely: abrasion/corrosion, surface spalling and impact ball breakage. The influence of key mill operating conditions – such as ball filling, discharge grate opening, mill speed, lifter profile, and ball quality – on their corresponding grinding media consumption rates is explored via a variety of model simulations, discussing in every case the independent contribution of each of the indicated consumption mechanisms to the estimated total ball consumption rate.INTRODUCTIONA thorough understanding of the independent contribution of each grinding media wear mechanism is extremely important, especially in semi-autogenous grinding (SAG) operations where macrowear (spalling) and ball breakage cannot be ignored or neglected. The high impact conditions imposed in modern SAG milling environments has created serious challenges for grinding media manufacturers since their products must be able to perform with minimal breakage and surface spalling.GRINDING MEDIA WEAR MECHANISMFor SAG milling operations, at least 3 different mechanisms have been identified as the main contributors to the observed overall grinding media consumption, here referred to as: abrasion / corrosion, ball breakage and surface spalling.Wear by Abrasion/CorrosionThe abrasive/corrosive wear mechanism has been discussed in depth in previous publications (Benavente Hector, 2007; Guzman Levi, 2014; Sepulveda and Morrow, 2014). The most widely accepted approach to mathematically characterize the consumption (wear) kinetics of grinding media in rotary tumbling mills is known as the Linear Wear Theory (Prentice, 1943; Norquist, 1950; Sepulveda, 2004) which claims that—at each instant 't' after a grinding body enters the mill load—the rate at which the body loses weight is directly proportional to its surface area exposed."

Jan 1, 2016

By A. A. Nourbakhsha

During the last few years, low cement castable refractories found more application in industry, because of good low and high temperature mechanical properties.In the case of alumina based castables ,usually fume silica or reactive alumina are used as superfines in the matrix to form mullite at high temperature which depends to source of alumina . Mullite network formation improves the hot mechanical properties and thermal shock resistance of bodies. The mullitisation of andalusite (so called primary mullite) also produces a certain amount of rich silica glass, part of it being expelled out of the grain. This phenomenon restrict the application of andalusite low cement castable in pig iron ladle. In this research, firstly 8 pig iron ladles from ESC(esfahan Steel company) with different conditions selected and monitored during usage to determine of main factors affecting on corrosion of refractories. Results showed that tap to tap time and undischarged pig iron are the main ones.Therefore monolithic refractories such as castables which increase thermal shock resistance could be substituted. Regarding to ternary phase diagram of Al2O3-SiO2-CaO ,fumed silica was selected as fine particle.After optimization of particle size distribution by using of modified andreasen equation and rehological properties ,different mixture were composed with andalusite ,fume silica, reactive alumina,secar 71 ,SiC and kyanite.All aggregates system components were mixed dry for 1 min in hobart mixer .After water addition wet mixing was continued until getting flowing about 4 min.The ready mixes were poured in the moulds of of 25mm X 25mm X 140mm with vibrations .After demoulding the samples were cured for 24 hrs and dried at 110OC/18hrsand then fired at 1100-1500OC. Physical ,mechanical ,phase analysis(XRD) and microstructure studies (SEM)were carried out according to ASTM standards. Results showed that by addition of kyanite ,more mullite phase formed through the matrix but,because of expansion occured during this phase transformoration, some cracks formed and mechanical properties decreased.By SiC addition the silica film on the surface of SiC lead to improvement of mechanical properties at high temperature

Oct 1, 2011

By E. Ghali, W. Zhang, C. Su, N. Sorour, G. Houlachi

"Zinc electrowinning process is sensitive to the presence of metallic impurities such as lead ions that could substantially and negatively affect the power consumption and surface morphology. Effect of various concentrations of manganese ions and traces of lead ions up to 2.5 mg L-1 added to the electrolyte during electrowinning have been investigated by electrochemical polarization techniques such as galvanostatic, cyclic voltammetry and potentiodynamic. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) were applied to examine the surface morphology and crystallographic orientation, respectively. Microwave plasma-atomic emission spectrometry has been used to determine the lead content in the deposit and in the electrolyte after electrodeposition. It was found that lead ions added to the zinc electrolyte led to the increase of cathodic overpotential and current efficiencies of zinc deposit. However, addition of Mn2+ into the zinc electrolyte resulted in the decrease of cathodic potential and current efficiency of zinc deposit. It can be stated as example that galvanostatic polarisation at 40?C and 52.5 mA cm-2 in presence of lead up to 0.1-0.2 mg L-1 in the electrolyte and 8-12 g L-1 Mn could be better considered as practical working parameters for electrowinning process.INTRODUCTIONApproximately 85% of the global production of zinc metal is produced by electrolytic process (Sinclair, 2005). The main goal of the zinc plant is to obtain pure zinc deposits with high current efficiencies. Smooth and pure deposits with high current efficiency (CE) are always obtained from pure electrolytes (Alfantazi & Dreisinger, 2001). The presence of metallic impurities in the zinc sulphate electrolyte is a major problem for the zinc electrowinning industry, since decreases in current efficiency, changes in deposit morphology and cathodic polarization are observed for electrolytes containing small concentrations of impurities (Ault & Frazer, 1988; Muresan, Maurin, Oniciu & Gaga, 1996). Low level concentrations as parts per million of these impurities are reported to influence negatively the zinc electrodeposition (Beshore, Flori, Schade & O'Keefe, 1987)."

Jan 1, 2016

By Mark Sherman, M. Dennis, Raj Rajamani

"The two Alumbrera 36ft (10.97m)dia. SAG mills were sized, using the FDW ""Grindpower 'I program, to treat an average of 1852 tph each. This paper describes how modelling of the shell lifter design, using the Millsoft program, identified milling inefficiencies caused by poor charge motion. This explained the ""as built"" circuit's inability to achieve the throughput rates predcted by the circuit's designer. Use of the Millsoft program to design a new, dramatically different lifter configuration, in conjunction with a different approach to variable speed drive utilization, has resulted in an improved charge motion and a 30% increase in hard ore milling rates. The new lifter design has allowed the designer's predicted average throughput rates to be achieved.IntroductionThe Alumbrera project grinding circuit consists of two 36ft dia. X 17ft EGL, 13 500 kW, variable speed, gearless drive SAG mills coupled to four 20ft dia. X 30ft EGL, 6 000 kW fixed speed, gear driven, ball mills. The circuit is configured as two identical grinding aisles, each consisting of one SAG mill and two ball mills. No pebble crushing circuit was installed due to the expected absence of a critical size fraction in the first years of production. However, the grinding circuit layout does incorporate space for a pebble crushing retrofit. At present, only about 5% - 10% of the new mill feed reports as trommel oversize and is recycled back to each SAG mill using a water cannon.The circuit was designed to be ball mill limited and to treat the four major Alumbrera ore types at rates varying between 68 000 tpd, and 89 750 tpd, depending on ore hardness. Average throughput rate, and hence nominal design rate, for the grinding circuit was 80 000 tpd (1 852tph per line at 90% availability)."

Jan 1, 1999

By Yan Qun, Chen Xiao-ming, Ma Pei-long, Luo Xian-ping, Luo Cai-gui, Feng Bo

The effect of leach promoting reagent LPF on the leaching process of a weathered crust elution-deposited rare earth ore has been investigated and the mechanism is discussed. The result shows that the leach promoting reagent LPF can enhance the leaching extraction of rare earth ore effectively. With the addition of LPF to the lixiviant at a concentration of 0.1%, the leaching extraction increased by more than 8%, the ammonium sulfate concentration could be decreased by 25%, and the leaching liquid/solid ratio reduced by 34%. The mechanism analysis shows that LPF can react with rare earth ions and form soluble coordination compounds, thus reducing the activity of the leached rare earth ions, increasing the concentration difference for ion diffusion, and promoting the rare earth leaching process. These results will hopefully help point to a new approach to making the leaching process of low-grade weathered crust elution-deposited rare earth ore more efficient and with lower lixiviant consumption.

Jan 1, 2014

By D. Wolfe, K. Reid, T. Nunn

"The Aurora North mine has been operating for more than ten years, and is the source of over half of Syncrude’s bitumen production. In order to minimize front-end rejects, and to allow for high throughput, the ore top size at Aurora has been set at a nominal 125 mm. These relatively large lumps have a significant effect on both pump performance and pipeline pressure gradient. Current design methods underestimate the solids de-rating effect of lumpy slurries in pumps, and do not accurately describe the distribution or magnitude of the lump effect on pipeline pressure gradient. Data from the Aurora hydrotransport systems has been compiled, to quantify the effect of lumps on the pump head ratio and pipeline pressure gradient, and how this effect changes as lump ablation occurs along the length of the pipeline. A model has been built, using a logarithmic curve, which predicts the effect of 125 mm lumps on pipeline pressure gradient as a function of velocity and the distance from the start of a hydrotransport pipeline. This model is applicable only to Aurora hydrotransport operation, but similar models could be developed for other operations using the same methods. Using accurate pipeline pressure gradients and pump head ratios when designing future hydrotransport pipeline systems will help improve their reliability and operability."

Jan 1, 2014

By P. R. G. Brandão, E. E. Ferreira

The presence of metallic cations in solution will affect the aggregation or dispersion of the fine hematite particles, depending on the type of cation adsorption: either specific or non specific adsorption. In this work, the zeta potential measurements were carried out on a sample of pure hematite as a function of pH and metallic cations concentration (Ca2, Mg2+, Mn2+, K+, Na+ and Al3+). The objective of these studies was to clarify the effect of these metallic cations on the surface chemical properties of pure hematite. The cations K+ and Na+ adsorbed as non-specific species and caused only the reduction on the values of zeta potential (in terms of absolute value) over the entire range of pH values tested. For the Al3+ cation, in the acidic pH range it adsorbed as a specific species and increased the zeta potential values. The cations Ca2+, Mg2+ and Mn2+, adsorbed as a non specific species at pH levels less than 6.0 and caused the reduction of zeta potential due to the compression of the electrical double layer. However, for pH values greater than 6.0, these cations adsorbed as a specific species causing the zeta potential to increase and became more positive as the pH value increased (alkaline). This effect could be due to the adsorption of some hidroxy complex species of these cations, which contributed to the positive charge. The effect of metallic cations (Ca2+, Mg2+ and Al3+ concentration, at pH 4.0, 7.0 and 10, showed the following results: a) at pH 4.0, increasing the concentrations of Ca2+ and Mg2+ resulted in on a small reduction in the value of the zeta potential. At this pH, increasing the concentration of A131 cations caused the zeta potential to increase due to specific adsorption of a negatively charged Al3+ hydroxy complex b) at pH 7 and 10, increasing the concentrations of Ca2+ and Mg2+ caused the zeta potential to change its charge from negative to positive.

Jan 1, 2004

By Liang Zhen, Jian-Tang Jiang, Guo-Ai Li, Xiao-Ya Wang

"Deformation behavior of 2A97 aluminum alloy containing coarse secondary phases was studied using uniaxial hot compression (HC, 340–490°C, 0.4001–1 s-1). The flow stress could be described by a Zener-Hollomon parameter in hyperbolic sine function with the hot deformation activation energy of 237 kJ/mol. Based on the experimental data and dynamic materials model, processing maps were generated to demonstrate the hot workability of the alloy. The coarse secondary phases experienced dissolution by varying degree under different deformation temperature, which producing different effects on the microstructure evolution. When deformed at relatively low temperatures, a mass of fine grains shaped up in the original grains and grain boundaries, and the dominating deformation mechanism was believed to be dynamic recrystallization. As the deformation temperature rising to 490°C, most secondary phases disappeared and few recrystallized grains were observed, indicating that the secondary phases dissolved sufficiently along with dynamic recovery occurred during the hot deformation. Particle stimulated nucleation related to the coarse secondary phases was believed to promote the recrystallization and the recrystallization behavior was sensitive to deformation temperature.INTRODUCTION Al-Li alloys has received much attention as new promising structural materials in the aircraft and aerospace industries, due to their lower density, higher elastic modulus and improved fatigue crack growth resistance in comparison with the conventional commercial aluminum alloys (Ou Ling, 2015). 2A97 alloy is one of the 3rd generation Al-Li alloys targeting at comprehensive improvement of aviation aluminum alloy and applications for wing spars and ribs to other internal structures for transport aircraft. Al-Li alloys are usually formed by hot deformation, either by rolling or extruding. The deformation behavior and resulted microstructure evolution during the forming process mainly dominates the formability of the alloy and the serving performances as well. Therefore, the deformation behavior and microstructure evolution at elevated temperature need be made clear for optimizing the hot processing parameters and controlling microstructure evolution."

Jan 1, 2018

By D. A. Beattie

Three novel dextrin polymers of varying functional group chemistry but similar molecular weight have been used to depress talc in single and mixed mineral studies. The mixed mineral system was a model sulphide ore consisting of talc, pentlandite, and chalcopyrite. Adsorption isotherms for the three polymers on both valuable and gangue mineral phases were determined to give initial clues as to the ability of the polymers to depress talc. Flotation testing revealed a distinct hierarchy of effectiveness of the polymers in the depression of talc in the single mineral system (MP Dextrin > CM Dextrin > Dextrin TYM), reflecting the observed adsorption affinity and adsorbed amount of the polymers on talc. However, a different order of effectiveness was observed for talc depression in the mixed mineral system (CM Dextrin > MP Dextrin > Dextrin TYM). Competition between the valuable and gangue mineral phases for uptake of MP Dextrin is responsible for its observed decrease in efficiency in mixed mineral flotation. All three polymers were found to be reasonably selective in their action, although at high dosages the polymers began to affect the flotation of the valuable minerals.

Jan 1, 2006

By E. Kordzadeh, M. Reza Bateni, M. Karaminezhaad, A. Moeini

A series of austenitic heat resistant Fe-Ni-Cr-Al alloys with different nickel contents have been investigated at 1100 ° C and 25, 50, 50,100 hours in S/0 bearing atmospheres. Before sulphidation test, the specimens were annealed in argon at 1250 °C for 8 hrs. Weight changes were measured using an automatic thermo gravimetric analyzer and corrosion products were analyzed by scanning electro microscope (SEM), energy dispersive X-ray spectrometry (EDAX), X-ray diffraction and optical microscope. The results showed that sulphidation resistance decreased with increasing nickel content. Internal sulphidation controlled by gaseous transport through cracks and pores and the formation of internal sulphide increased when liquid sulphides formed on the surface.

Jan 1, 2004

By Mingxia Liu, Hao Li, Qi Liu

"Laboratory batch flotation tests were carried out on fine (-20 µm) hematite to investigate the non-polar oil’s influences when sodium oleate, octyl hydroxamic acid, or oleyl hydroxamic acid were used as a collector. Batch flotation tests were performed with artificial mixed minerals (hematite:quartz = 1:1) under natural pH condition and kerosene was utilized as the model oil. The experimental results showed that kerosene emulsion behaved differently when used in conjunction with the three collectors. Kerosene helped improve the flotation when sodium oleate or oleyl hydroxamic acid was used as a collector. Nevertheless, it reduced concentrate weight yield, grade and recovery to a noticeable extent when octyl hydroxamic acid was used as a collector, especially at low dosages. In addition, single hematite batch flotation kinetics tests coupled with water recovery measurement were carried out to study the role of kerosene at different collector dosages. It was observed that water drainage and the resulting froth destabilization by kerosene was dominant at low collector dosages, especially in the flotation using octyl hydroxamic acid. At higher collector dosages, the water drainage and froth destabilization effect by kerosene was possibly counter-balanced by the higher hematite hydrophobicity and bubble surface tension gradient, which led to more stable froth layer.INTRODUCTION The minerals industry is facing a steady decline in ore grade, compounded by increasing complexity of mineral dissemination. As a result, the ore has to be ground sufficiently fine to have a suitable degree of mineral liberation, which produces large percentages of fine and ultrafine particles outside of optimal size range for ore dressing. Due to the unique characteristics of fine particles, i.e., small mass, high specific surface area, and problems such as increased solubility of complex minerals (Finkelstein, 1997; Finkelstein & Allison, 1976; Fornasiero & Ralston, 2005), high reagent consumption, fast surface oxidation in the case of sulfides (Collins & Read, 1971; Klassen & Mokrousov, 1963), severe particle entrainment (Subrahmanyam & Forssberg, 1988; Warren, 1984), low flotation rates (Glembotsky, 1953; Philippoff, 1952; Ye & Miller, 1988), slime coating (T. K. Mitchell et al., 2005; Parsonage, 1984), etc., flotation performance of these finely ground ores is very poor in terms of low concentrate grade and recovery."

Jan 1, 2017

By Karl Houseley, Dr. Robert J. Chapman

"A gravity concentration process has been applied to ores from the Clogau Mine, north Wales, the Tyndrum deposit, central Scotland and an alluvial ore from Leadhills area of Scotland. In the case of the Welsh ore and the alluvial deposit the gold grains in the concentrate and tailings streams have been characterised in terms of their three dimensions.In the case of Welsh ore, the thickness of a gold grain has been shown to be the single most important factor in determining behaviour in a gravity concentration operation. Six indices were used to quantify the overall geometry of the gold grains and those which incorporate a thickness term have proven to be effective in predicting the destination of gold particles within the concentration circuit. It is proposed that the most simple of these, the Heywoods flakiness ratio, has potential for the control of milling operations as an alternative to the established practice of characterising the size of the mill discharge.The effect of grain geometry on the recovery of fine gold has been studied using Tyndrum ore. The recovery of gold by gravity concentration increased from 20% to 70% when the criteria used to design the milling operation was the prevention of over grinding of gold grains.The destination of alluvial grains in the concentration circuit did not show such dependence on shape, and this has been attributed to the effective classification of all the gold grains in the sample by fluvial action producing a population of similar geometric characteristics."

Jan 1, 1996

By Jessica Egan, Daniel Hodouin, Claude Bazin

"The recovery of gold by leaching is influenced by the size of the gold carrier particles and the chemical environment. Using the relationships between the leaching rate, infinite recovery and particle size for a given set of chemical conditions, it is possible to simulate gold recovery for various feed size distributions. However the use of these particle size relationships is only valid if the leaching of gold from a given size class is independent of the production history of this size class. For instance, to use these relationships it is necessary to verify that gold recovery from the leaching of the 200-270 mesh size class remains the same if the size fraction is taken from a coarse or finely ground ore sample. Several laboratory tests were carried out to answer that question. Results of the tests show that within the large error margin associated to gold content measurements, the history of the production of a size class does not affect the gold leaching from that size class. Emphasis of the discussion is put on the difficulty associated with the processing of data containing significant measurement errors as it is the case for gold assays of leaching tests.INTRODUCTIONMore than 75% of the gold produced in the world is extracted by cyanide leaching of gold ores. The ore is ground to expose the gold carriers and the ground material is reacted in an oxygenated cyanide solution that dissolves gold, leaving solids gangue minerals that are disposed to tailings ponds or returned in underground mines as paste fill. The gold contained in the solution is recovered by either the carbon in pulp process or by cementation onto zinc powder, before being melted and casted into a brick (Marsden and House, 2006)."

Jan 1, 2009

By B. McFadzean, I. Achaye, T. Chidzanira, J. Wiese

"Froth stability has an overriding effect on metallurgical recovery and grade for many ore types. Froth recoveries of less than 10% are common for low stability froths such as those in sparsely mineralized ores or in cells at the back end of flotation circuits. It is well known that, aside from chemical factors such as frothers and electrolytes, the mineral particles themselves have the dominant influence on froth stability. The particle properties of size and hydrophobicity are expected to have the greatest effects on froth stability. The aim of this study was to understand the effects of particle size on froth stability and to quantify these relationships.The study compared a synthetic ore of pyrite and quartz, with carefully controlled size ranges and hydrophobicity, with conventionally milled platinum-bearing UG2 ore and the bulk reverse flotation of hematite ore. A novel bench-scale continuous column flotation cell and continuous mechanical hybrid cell with large relative froth volumes, as well as a three-phase froth stability column were used to characterize the froths.It was found that froth stability could be related to the concentrate particle surface area by a Langmuir-type relationship. This is indicative that the mechanism by which particles stabilize the thin films in froths is similar to the mechanism by which surfactants lower surface tension. Different froth stabilities were found for different ores and this was thought to be the result of different particle sizes and distributions, which resulted in different packing densities in the thin films and Plateau borders. Interestingly, there was a clear relationship between the feed particle size and the froth stability even though froth stability was dependent on the concentrate particle surface area. It seems that the feed particle size is a good predictor of the surface area of particles in the concentrate. Concentrate particle size did not show a clear relationship with froth stability since it was already shown that it is both the size and the amount of the particles in the froth that contribute to the stability.INTRODUCTIONThe stability of the froth in froth flotation is important to the recovery and grade of the valuable mineral. Too stable a froth and the grade is reduced; not stable enough and the recovery may be compromised. Platinum-bearing ores with fragile, poorly mineralised froths are known to have froth recoveries that are routinely less than 10% (Crosbie et al, 2009). There are a number of chemical, physical and operating parameters that can affect froth stability, including reagent dosages, air flow rate, pulp density and particle properties. Arguably, the largest contribution to froth stability is from the particles that stabilise (or destabilise) the thin films in froths. Particle size, hydrophobicity and shape all affect froth stability to some extent."

Jan 1, 2016

By Primak. George J.

"In the development of a new product as well as during its introduction on the market, it is very important to give due consideration to problems involving patents, licenses and trade marks. At the very beginning of the research and development program, it is obviously essential to ascertain, through a suitable patent search, that the product in question will not infringe any patents which are still in force. Then, a possibility of achieving one's own patent or proprietary position on the product or the process of its manufacture should be carefully explored. Licensing arrangements that one may reach with respect to patents and know-how covering such new product may, in the final analysis, determine its over-all success or failure. If one can count on licensing revenues or some favourable cross-licensing arrangements with respect to a newly developed product, this may go a long way to achieving profitability and success. The selection of a good trade mark is probably one of the most important acts that one has to perform once the product is developed, as customers will identify the new product by such a trade mark. In many instances, successful marketing and widespread acceptance of a product are largely due to its appealing name or trade mark, accompanied by proper promotion and advertising. Once the trade mark has been adopted, it should be registered in the Trade Marks Office to provide the protection afforded by federal statute. If the product is to be manufactured, sold or licensed in some other countries, similar considerations should be made with regard to each such country."

Jan 1, 1973

By J. Lu, J. B. Wiskel, D. G. Ivey, E. Niemi, H. Henein

Simulated TMCP using a Gleeble was undertaken to evaluate the effect of the austenite to ferrite cooling rate, coiling temperatures of either 400°C or 500°C and the magnitude of plastic deformation at the coiling temperature on the hardness of a Grade 483 (X70) steel. For comparable apparent cooling rates and deformation conditions, the hardness of the samples were independent of coiling temperature The application of a minimum compressive deformation > 8% was required to increase hardness at both simulated coiling temperatures of 400°C and 500°C. An increase in hardness was also observed with increased cooling times between 800°C and 500°C (i.e., slower cooling rates).

Jan 1, 2005

By P. Burke, V. Vuaroqueaux, A. Doyle, C. Petit, Kipouros. G. J.

Magnesium and its alloys are attractive for use in automotive and aerospace applications because of their low density and good mechanical properties. However, difficulty in forming magnesium and the limited number of available commercial alloys limit their use. The present work reviews the efforts to improve the attractiveness of magnesium through non-traditional processing, and presents results of current work on producing magnesium alloys via powder metallurgy (P/M). P/M can be used to alleviate the formability problem through near-net-shape processing, and also allows unique chemical compositions that can lead to new alloys with novel properties. The surface layer formed on the Mg powders during processing acts as a barrier to diffusion and sintering is problematic. The layer contains oxides, hydroxides and carbonates of magnesium, formed by reactions with the atmosphere. There are several means to possibly overcome this barrier. Alloying additions have been identified that may promote surface layer disruption during sintering. Processing variables such as sintering atmosphere may reduce the layer or allow the formation of less detrimental compounds. Post-sintering processes such as hot working may disrupt the layer and improve density. The experimental effect of all these processing parameters is presented in this paper.

Jan 1, 2010

By R. Simon, A. Khosravi

"Tensile strength of rock samples is measured by direct and indirect tensile tests in accordance with standard guidelines. Due to the difficulties in performing direct tensile test, the indirect tensile (Brazilian) test is conventionally carried out to obtain the ultimate tensile strength. A limited number of studies have been conducted to investigate the role of sample size (length to diameter ratio = L/D) in the stress distribution of the Brazilian test using numerical and analytical methods. These investigations showed that the tensile stress distribution along the loading diameter is not uniform. They also indicated that the difference between the tensile stress at the middle part and at the sides of the sample with higher L/D ratio is greater than that in the other samples.The objective of this study is to show the effect of tensile stress distribution on the fracture surface created by the Brazilian test from a morphological point of view on the samples with different L/D ratio. Hence, a series of fracture surfaces created using the Brazilian tests on the rock samples with L/D of 0.5, 0.75, 1, 1.25 and 1.5 were investigated.In this study, all fracture surfaces were scanned by a 3D laser profilommeter. A number of roughness profiles parallel and perpendicular to loading axis have been selected from the samples with different L/D ratio and spacing of 1 mm. The results show that the roughness of the profiles perpendicular to the loading axis increases with an increase of L/D ratio, while the roughness of the profiles parallel to the loading axis decreases. Furthermore, some roughness profiles parallel to the loading axis were chosen and divided into three segments. The results revealed that the segment in adjacent to the upper loading platen possesses higher roughness than the other segments."

Jan 1, 2015

By R. M. Bustin

"Extensive deposits of tectonically sheared coal of the Mist Mountain Formation occur in the south eastern Canadian Cordillera. The quality of the coal varies markedly; it is commonly partially oxidized and poor washability characteristics.Oxidation of the sheared coal has been promoted by its fine grain-size and by fractures in adjacent rocks which have facilitated penetration of atmospheric oxygen and circulation of oxygenated waters. Oxidation has resulted in a loss of coking power, a decrease in vitrinite reflectance, and an Increase In oxygen and decrease in carbon content.The relatively low clean coal yields of the sheared coal are primarily the result of the greater volume of mineral matter present, which in turn reflects both the greater susceptibility to shearing of coal with abundant rock partings and the shearing and dissemination throughout the coal of formerly discrete rock partings. The high ash content of some sheared coal seams may be artificial, resulting from the difficulty in distinguishing and separating sheared roof rock and floor strata from the coal seam during mining. There is little variation between the quality of the washed sheared and unsheared coal, with the exception of the somewhat higher ash content of the clean sheared coal compared to clean unsheared coal. This poorer separation of the ash from the organic fraction of the sheared coal is considered to be a product of the large amount of fines present as well as the local formation of aggregates of organic material and ash resulting from plastic flowage of the vitrite and clarite during shearing.IntroductionIn the southeastern Canadian Cordillera, coal seams of the Lower Cretaceous Mist Mountain Formation (Gibson, 1979 were in part sheared and comminuted during Late Cretaceous and Tertiary tectonism . Extensive deposits of sheared coal exist, and even in areas of mild deformation the coal may be locally sheared (Bustin, 1979). The quality of the sheared coal varies notably; it is commonly oxidized even far from the present weathering horizon, and locally has a disproportionately large amount of ash and poor washability characteristics even far from the present weathering horizon and locally has a disproportionately large amount of ash and poor washability characteristics."

Jan 1, 1982