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By M. Kuyumcu

After German reunification the mining industry in former East Germany was profoundly restructured. Beside privatization of profitable companies the public sector took over responsibility for the mining operations to be shut down. Therefore state-owned companies cope with technical, ecological, and social challenges. The rehabilitation and reclamation has to rededicate former mining areas to new use and provided new jobs as well. In the lignite mining districts there are around 100,000 ha of mining area, a mining caused disturbance to the groundwater balance and to the system of surface water bodies of approx. 390,000 ha. They are called the largest landscape construction site in Europe. In addition to the results and diverse experience achieved over the past 23 years, a description will follow of our new challenges and of an outlook on remaining tasks. This article will describe the financing, as well as aspects of the jobcreation policy arising from lignite industry remediation.

Aug 1, 2013

By J. Trojacek

A large-scale development in exploration and production of uranium ores in the Czech Republic was done in the 2nd half of the 20th century. Many uranium deposits were discovered in the territory of the Czech Republic. Over a period of 50 years approximately, 110 000 tons of uranium in concentrate were produced. Different mining methods were developed and used. One of the most considerable deposits in the Czech Republic is the site Hamr na Jezere ? Straz pod Ralskem where both mining methods ? the underground mining and the acidic in-situ leaching ? were used. The extensive production of uranium led to widespread environmental impacts and contamination of groundwaters. Over the period of ?chemical? leaching of uranium (ca. 32 years), a total of more than 4 million tons of sulphuric acid and other chemicals have been injected into the ground. Most of the products (approximately 99.5 %) of the acids reactions with the rocks are located in the Cenomanian aquifer. The contamination of Cenomanian aquifer covers an area larger than 27 km2. The influenced volume of groundwater is more than 380 million m3. The total amount of dissolved SO4 2- is about 3.6 million tons. Approximately 0.5 % of the contamination is located in the Turonian aquifer. After 1990, a large-scale environmental program was established and the Czech government decided to liquidate the ISL Mine and start the remediation in 1996. The remediation consists of contaminated groundwater pumping, removing of the contaminants and discharging or reinjection of treated water. The objectives of the remedial activities are the followings : to restore the aquifer to a condition guaranteeing continuing usability of Turonian water of Northern Bohemia Cretaceous, to decommission boreholes and surface installations and to incorporate the surface of leaching fields into the ecosystems taking into account regional systems of ecological stability and urban plans. Nowadays four main remedial technological installations for reaching of these aims are used - the ?Station for Acid Solutions Liquidation No. One?, the ?Mother liquor reprocessing? station, the ?Neutralization and Decontamination Station NDS 6? and the ?Neutralization and Decontamination Station NDS 10?. Total capacity of this complex is sufficient to reach the target values of remedial parameters in 2037. The remediation action consists of: pumping of residual solution to the surface, separating uranium from the solution and reprocessing contaminants into commercially usable or ecologically storable products. It is expected that the amount of withdrawn contaminants will vary from 80 000 to 120 000 tons per year. Total costs of all remediation activities are expected to be in excess of 1.5 billion EUR.

Aug 1, 2013

By S. Xu, A. Ramesh, F El-dabbagh, Z. Fang, A. Sobhy, J. A. Kozinski

Waste remediation is a goal that will be driven forward by economic conditions. As the cost of waste disposal increases, new methods of waste reduction will become economically attractive, and will be implemented. It is difficult to imagine, however, a time when there will be no waste generation. For the foreseeable future, despite effective reduction practices, there will still be hundreds of millions of tons of waste that must be destroyed or controlled to protect the public health and the sanctity of the environment. To remain faithful to environmental covenants, the mineral and metallurgical industries will face these new challenges. This paper discusses novel waste remediation approaches and techniques focusing on hazardous wastes and thermal remediation. Aspects concerning technological and environmental importance are examined. Solutions for neutralization of environmentally hazardous compounds are proposed.

Jan 1, 2004

By C. W. K

This little sketch of the late Willet G. Miller, Provincial Geologist of Ontario, is intended to be neither a biography of his career nor a eulogy of his life. His biography has already been written in an incomparable manner by Mr. T. A. Rickard, his eulogy by Canon Cody. What more can be said of Dr. Miller than is summed up in the words of that great Canadian divine, Canon Cody, that he was "Big in body, big in heart, and, as we learned, big in brain." This article, then, will merely record a few personal reminiscences of the man himself, and while they are necessarily disjointed, they may at least serve to illustrate certain traits in his character which are not generally known or appreciated outside of the circle of his intimate friends. In the latter part of May in the year 1904, Willet G. Miller, with two? assistants, set out for the small village of Haileybury to begin his geological work in the area a few miles to the south which he was soon to name Cobalt. At that time the Timiskaming and Northern Ontario railway was not finished, although the right-of-way was cleared and partly graded. The nearest railway station was on the Canadian Pacific at the south end of lake Timiskaming, from which point the old steamer Meteor carried passengers and freight up the long, narrow and deep waters of lake Timiskaming, a very pleasant trip of some sixty miles. On this particular trip there was a fairly large crowd on board consisting of settlers going into the clay belt north of lake Timiskaming, of lumbermen, and of a few merchants and commercial travellers who were interested in the small business centres of Haileybury, New Liskeard and Ville Marie. Scarcely any attention was paid to the reports of the newly found silver deposits, although the daily papers had announced discoveries in the district six months before. As a matter of fact, the chief excitement on board was afforded by a moose, which, in swimming from the Ontario to the Quebec shore of the lake, crossed the bow of the boat, the captain steering to within a few yards of the terrified animal.

Jan 1, 1925

By Garston H. Blackwell

For ageing open pit mining operations where the economic viability of another pushback is questionable, mine life can be extended by increasing the wall slope. If the steepening is started where ore intersects the pit wall, the capital outlay for waste stripping is minimal. Such a venture must be conducted safely, and a basic requirement would include loading equipment capable of working remotely. In the application described, alternatives in the choice of loader included equipment available on site, or the purchase and assembly of used equipment. Only electric cable shovels were in use at the operation, and it was thought that these would be more capable of digging high muck piles at the productivity demanded by an increasingly efficient mill, and in a challenging environment less suited to a rubber tired loader or hydraulic front shovel. A decision was made to convert an older electric cable shovel to remote controlled operation and to include the application of semi-robotic control. The conversion was completed successfully and is described, along with methods developed for remote operation of a shovel, and the application of various sensors for semi-robotic operation. A plan of operations to mine out several completed double benches and make two quadruple benches with wide catchment berms is depicted. On completion of this task, the working benches developed would be wide enough to operate at near full production. Prior to moving the remote controlled shovel back into the pit, a large wall instability became active, eventually closing the operation. The instability could have been safely mined using the remote controlled shovel.

Aug 1, 2013

By S. Gaulocher

Gearless mill drives (GMDs) are the workhorse in the mineral processing industries, more specifically when it comes to grinding crushed ore and cement (in various production stages) in semiautogenous (SAG) mills and large ball mills. They are renowned for their excellent reliability and robustness, long lifespan, and little need for maintenance, and thus yield a low total cost of ownership (TCO). A GMD represents a major investment for a mineral processing plant, and its availability is pivotal for the grinding process. As a basic rule, shut-down periods are to be minimized, but even much more important is that unscheduled shut-downs be avoided. In this contribution, we will present a portfolio of innovative remote diagnostic that consist of the following three key components: 1. Trouble shooting is a form of corrective maintenance and is based on state-of-the art remote access technology, thus enabling highly skilled engineers to access the current sensor readings anytime and from anywhere in order to resolve urgent problems together with the GMD user. 2. Periodic maintenance reports are a form of preventive and predictive maintenance and aim at continuous improvement based on long-term historical records and analyses of multiple measured signals. These detailed reports highlight the health and operational status of the GMD and are periodically (e.g. 3 months) submitted to the customer. 3. Remote condition monitoring spans across preventive and predictive maintenance and is based on continuous recording and automatic analyses of relevant signals using advanced algorithms. The main issue is how to handle the enormous flood of data in an intelligent manner. The results of these analyses are made available to both the GMD user and supplier in real time in order to increase the availability and reliability of the GMD. In this paper, we consider various parts of the GMD, e.g. the cycloconverter, the ring motor, the auxiliary devices (e.g. cooling and lubrication systems), and also phenomena related to the mill itself (e.g. state and quantity of charge). The signal analysis techniques range from simple threshold-based analyses to complex time and frequency domain analyses. We will illustrate the benefits of the proposed approaches with some selected examples.

Jan 1, 2012

By J. Koponen, K. S. Stadler, A. Fuerst, S. Gaulocher, Th. von Hoff, R. Veldsman

"Gearless mill drives (GMDs) are the workhorse in the mineral processing industries, more specifically when it comes to grinding crushed ore and cement (in various production stages) in semiautogenous (SAG) mills and large ball mills. They are renowned for their excellent reliability and robustness, long lifespan, and little need for maintenance, and thus yield a low total cost of ownership (TCO).A GMD represents a major investment for a mineral processing plant, and its availability is pivotal for the grinding process. As a basic rule, shut-down periods are to be minimized, but even much more important is that unscheduled shut-downs be avoided. In this contribution, we will present a portfolio of innovative remote diagnostic that consist of the following three key components:1. Trouble shooting is a form of corrective maintenance and is based on state-of-the art remote access technology, thus enabling highly skilled engineers to access the current sensor readings anytime and from anywhere in order to resolve urgent problems together with the GMD user.2. Periodic maintenance reports are a form of preventive and predictive maintenance and aim at continuous improvement based on long-term historical records and analyses of multiple measured signals. These detailed reports highlight the health and operational status of the GMD and are periodically (e.g. 3 months) submitted to the customer.3. Remote condition monitoring spans across preventive and predictive maintenance and is based on continuous recording and automatic analyses of relevant signals using advanced algorithms. The main issue is how to handle the enormous flood of data in an intelligent manner. The results of these analyses are made available to both the GMD user and supplier in real time in order to increase the availability and reliability of the GMD.In this paper, we consider various parts of the GMD, e.g. the cycloconverter, the ring motor, the auxiliary devices (e.g. cooling and lubrication systems), and also phenomena related to the mill itself (e.g. state and quantity of charge). The signal analysis techniques range from simple threshold-based analyses to complex time and frequency domain analyses. We will illustrate the benefits of the proposed approaches with some selected examples."

Jan 1, 2012

By S. K. Schwartz

"This paper describes the general layout of the environmental monitoring scheme at Devco 's No. 26 Colliery, including wall face ventilation, fan performance and methane drainage, and then goes on to discuss the sensors, the outstation layout, the surf ace control room and the protection of the system.IntroductionCape Breton coal mines have been pioneers in the use of the latest technology in mining coal on this continent. To mention just one example, continuous methane monitoring at the coal face was started in 1976 and the idea of automatically stopping the face conveyor during high gas levels using the face signalling system was conceived and developed by CBDC engineers.With the introduction of remote environmental monitoring, No. 26 Colliery will be the first underground coal mine in Canada and possibly in North America to have computer-based comprehensive environmental monitoring.Traditionally, surveillance of the mine environment has been based mainly on periodic checks by portable or hand-held monitors. Although this method proved adequate, it has some limitations, namely:1) restricted 'number of observations and samples;2) relatively long time between taking measurements and availability of results for assessment.With remote monitoring, the above limitations are overcome because (a) monitoring is continuous and (b) monitored data are updated quickly (typically 5-7 sec.). Remote monitoring also provides a centralized 'information center' at the surface from where the entire mine environment can be monitored. Details of modes in which data can be displayed and features available at the location will be discussed later in the paper."

Jan 1, 1982

By A. Kowalski

Telvis Limited, manufacturer of an emergency communication dispatcher's broadcasting system, now introduces the possibility of a remote software upgrade to its devices. The paper presents methods, features and ways to accomplish this task. It describes the mechanisms used and the opportunities that arise from the use of this type of functionality. The mechanism software update presented applies to devices on the surface and in underground areas of mines. The electronics used currently allow the use of remote software updates, but the mining equipment makes little use of these methods. This paper aims to start the discussion on this topic and tries to lay the path of development by showing one of the first examples of the application.

Aug 1, 2013

By Gary Watters

PORTS AND ARCTIC CONDITIONS ?Large ice forces ?Standard designs fail in the arctic ?Specialized construction methods for ice PRESENTATION OUTLINE 4 Example Projects ? 2 Alternative Construction Methods ? Advantages & Disadvantages ?Controlling costs

Oct 1, 2010

By Joel T. Werner

Tire costs represent one of the highest controllable costs in open-pit mining, accounting for approximately 10% of mining costs. Tire monitoring technology has evolved rapidly in recent years and is emerging as a viable tool for extending tire life and reducing costs. The majority of the major tire manufacturers and several independent companies are in various stages of developing monitoring systems that capture and store vital tire data. Previously this information had only been accessible when the vehicle passed a fixed point in the mine, or when mine personnel manually downloaded the data. Integrating this technology with a mine management system enables remote collection and management of trend and alarm data. Mine personnel can now monitor a tire?s health parameters at any time, anywhere on site, regardless of the vehicle?s location. Anomalous tire conditions can be detected early and corrective actions taken. This information can then be integrated with other major onboard systems, operating conditions, and geographical information. Tire monitoring no longer exists as a stand-alone technology, but has evolved into an important integrated tool for mine operators. This paper will review the current status and benefits of integrating this emerging technology with a real-time mine management system.

May 1, 2002

By Fei Dai

Musculoskeletal disorders (MSDs) are a group of painful disorders that affect muscles, tendons, nerves, joints, cartilage, and ligaments. They are a serious problem among the workforce in the United States. In the construction industry, high physically demanding tasks expose construction workers to a number of well recognized MSDs risk factors such as repetitive motion, high force exertion, and awkward body posture. Finding ways to effectively identify and evaluate risks of MSDs can significantly alleviate this problem. To this end, this paper reviews state of practice and research in the assessment of risks of MSDs among construction workers, in which a number of biomechanical models have been developed to evaluate joint and tissue loading with the aid of state-of-the-art remote sensing technologies. Findings from the review reveal that despite the advances in tracking human motion and muscle activities, current remote sensing approaches still involve sophisticated instrumentation and expensive experiment setup. These factors greatly limited the applicability of such approaches in real construction settings. How can we detect and evaluate the construction worker?s MSDs risk in real work environments? In this paper, strategies by utilizing video surveillance systems are presented, to set the stage for addressing the above question and discussing future research in real-time, marker-less, and costeffective MSDs risk assessment.

Aug 1, 2013

By M. S. Millman

Close monitoring of performance at each process stage, from raw material through to finished product, is vital for operational consistency and the production of high quality steel. However, many of the integrated iron and steelmaking process route stages operate under such severe conditions of temperature, dust, water, thermal radiation, vibration, pressure, vacuum, extreme dynamic events, high material flows, corrosion, erosion, electrical-noise, electromagnetic-noise, or audio-noise that, in general, it is a very difficult challenge to obtain useful information for control. Thus, state-of-the-art non-contact and remote sensors are applied to help monitor and control specific process operations. Often, these sensor systems have been developed especially for the steel industry and they are based on four principal technologies: Laser, Microwave, Electro-Magnetics and Thermal Imaging with supporting technologies such as: X-ray Fluorescence, Audiometry, Digital Image Processing, Radio Telemetry, GPS and many others. These advanced sensor technologies are reviewed with respect to their application at various stages along the integrated process route.

Jan 1, 2004

By S. Kapusniak

Specialist Machine Developments (SMD) is a design and manufacturing company involved in the design of Remotely Operated Vehicles (ROV?s), ploughs, trenchers and mining machines for use in submerged environments. Established in 1971, the company has made over 500 vehicles for subsea use. These range in size from small remotely operated swimming vehicles with a weight of less than a tonne to heavy duty seabed crawling machines with a weight of up to 310 tonnes (in air). Primarily, these machines have been designed for offshore vessel-based applications, but the machines are equally suited to other submerged mining applications onshore. Many onshore deposits can technically and theoretically be mined using currently available submerged mining ROV technology. Similar equipment to that in use subsea could easily be fast-tracked into use to extend the life of opencast mines facing severe hydrological problems. It could also easily be used to mine vertical ore-bodies where the stripping ratio has become uneconomical due to increasing depth. In some cases mining ROVs could even be suitable for use as the primary extraction method for a new mine. Exploration and extraction techniques used in oil and gas gradually developed and moved from land to offshore in the middle of the last century. Are we about to witness a similar shift with other minerals? This paper describes the design concepts of submerged mining equipment, targetted subsea mineral deposits, the suitability of submerged mining ROVs for onshore deposits, limits to their application and parallel research and development activities which will help to accelerate the use of such equipment in the emerging submerged mining sector.

Aug 1, 2013

By P. A. Riveros, W. D. Gould, R. Molnar, D. W. Koren, P. Bédard

This paper reports the results of the field demonstration campaign of a new process for removing and destroying ammonia from mining/ metallurgical effluent solutions. The 50-day campaign was carried out at a uranium plant in Saskatchewan, Canada. The process was developed by adapting and integrating two well established technologies: zeolite adsorption/ elution to extract the ammonia from the effluent stream and to produce a concentrated ammonia eluate; and conversion of the ammonia in the eluate to innocuous nitrogen by applying bacterial nitrification-denitrification (NH3 = > NO3 - => N2). The data show that reasonable target criteria were met, under very challenging operating conditions. Problem areas and possible causes for poor performance are identified. Preliminary and generic cost estimates of the process are also presented.

Jan 1, 2003

By Kazutoshi Haga, Batnasan Altansukh, Atsushi Shibayama, Ryuji Oinuma

"Recently, the arsenic grade in copper ores has been increasing year by year. Arsenic bearing minerals (enargite (Cu3AsS4) and tennantite (Cu12As4S13)) coexist with typical copper minerals such as chalcopyrite (CuFeS2). The removal of arsenic from copper ores that contain relatively high arsenic content is essential due to its adverse impact on the environment and the resulting economic consequences. In this study, arsenic removal and dissolution behaviour of Cu and As from enargite (Cu3AsS4) were investigated using ferric sulphate (Fe2(SO4)3) solutions containing sodium chloride under high pressure oxidation conditions. The effects of numerous parameters including the concentration of Fe2(SO4)3 and NaCl, temperature, total pressure, leaching time and particle size were studied while other variables such as pulp density and stirring speed were fixed at 100 g/L and 750 rpm. The results showed that more than 60% of the copper was dissolved in a 0.1 M ferric sulphate solution under the high pressure oxidative conditions, whereas the leaching rate of arsenic was less than 20%. SEM observation revealed that elemental sulphur was deposited on the surface of enargite forming a passivation layer and the residue was agglomerated. Those phenomena may cause a decrease in the copper leaching rate. It was found that more than 80% of copper was dissolved in the ferric sulphate solution in the presence of 0.34 M sodium chloride under the conditions optimized, whereas the dissolution of arsenic in the mixture did not exceed 2%. XRD analysis of the solid residues from the leaching experiments used ferric sulphate and mixtures of ferric sulphate and sodium chloride showed arsenic to be present as scorodite (FeAsO4).INTRODUCTION In recent years, there has been an increase of the arsenic (As) content of copper ores due to the gradual depletion of high grade copper ores. In some copper deposits, arsenic occurs in the form of minerals such as enargite and tennantite. The removal of arsenic in ores containing copper is critical to the production of pure copper and the management of the environmental challenges caused by the smelting process. Due to the environmental risk caused by arsenic emission and the deteriorated quality of the copper product, smelting of enargite concentrates is not an effective method for the extraction of copper (Padilla et al., 2010; Safarzadeh et al., 2014; Long et al., 2012). Therefore, a number of studies have been carried out to develop arsenic removal technologies from copper ores using various methods such as hydrometallurgy (Curreli et al., 2009; Tongamp et al. 2010), pyrometallurgy (Dalewski., 1999; Padilla. et al, 2012) and bio-oxidation (Ehrlich, 1964; Sasaki et al., 2010). Several hydrometallurgical leaching processes like sulphuric acid, alkaline sodium sulphide and sodium sulphate and ferric sulphate leaching have been developed to treat enargite ores and concentrates. The alkaline sodium sulphide leaching process has been developed for the removal of arsenic from enargite (Anderson, & Twidwell, 2008; Parada et al., 2014). The mechanism of the dissolution of arsenic from enargite in sodium sulphite solution is"

Jan 1, 2016

Arsenic bearing minerals such as enargite (Cu3AsS4) and tennantite (Cu12As4S13), which may associate with major copper minerals such as chalcopyrite (CuFeS2), chalcocite (Cu2S) and bomite (Cu2FeS4), usually report to the copper concentrate in conventional flotation due to their similar flotation properties. Arsenic in a copper concentrate causes environmental problems and also problems in the subsequent pyrometallurgical process. Voltammetric studies were carried out to investigate the oxidation characteristics of enargite, tennantite, chalcopyrite, chalcocite and bomite. Contact angle measurements and micro-flotation tests were conducted to examine the flotation characteristics of enargite and chalcopyrite under controlled pulp potentials. Selective flotation of enargite from chalcopyrite under varied pulp potentials was conducted to investigate the feasibility of arsenic removal from a copper concentrate. The test results indicate that the non-arsenic bearing copper minerals ( chalcopyrite, chalcocite and bornite) were easier to oxidise than arsenic bearing minerals ( enargite and tennantite) in an alkaline solution. Enargite floated well at a potential as high as +0.45 V vs. SCE while chalcopyrite was completely depressed at a potential higher than +0.43 V vs. SCE. Selective flotation revealed that enargite can be successfully removed from chalcopyrite through controlling the pulp potential at +0.30 ~ +0.50 V vs. SCE.

Jan 1, 2007

By C. Feng, D. W. M. Arrigan

Arsenic is often associated with gold mining operations and poses a significant health and environmental hazard. While a number of technologies are available for removing arsenic, none of them is effective under all conditions. Although adsorption is a promising approach, most methods focus on the purification of water under neutral or acidic conditions and tend to be less effective in gold mining process waters, operating under alkaline conditions. In this study, the removal of As (III) and As (V) from both arsenic-only solutions and simulated process waters using composite magnetic nanoparticles was investigated. The nanoparticles consisted of magnetite (Fe3O4) or maghemite (?-Fe2O3) cores covered by various metal oxides with Langmuir adsorption capacities of As (III) and As (V) ranging from 31.4 to 79.1 mg/g and 10.2 to 25.5 mg/g, respectively, in arsenic-only solutions at pH 9. Their adsorption capacities were further recognised by the adsorption tests conducted in simulated process waters. The ability to remove As (III) is of particular importance as it is harder to remove it from alkaline solutions. The magnetic cores allow simple and efficient magnetic recovery of the As-loaded nanoparticles.

Jan 1, 2017

By K. Sawamukai, S. Ogasawara, D. Umenai, T. Tsuruta

"Removal of cobalt, strontium or cesium ion from the aqueous solution containing each metal ion only using microorganism was examined. Arthrobacter nicotianae which had a high ability to remove cationic metal ion was used for the removal of each metal. The removal of cobalt, strontium or cesium using A. nicotianae cells was affected by the solution pH, concentration of metal ion, and cell amount. The effects of above mentioned factors on the removal of each metal and time course of strontium from the solution containing each metal only using A. nicotianae cells were reported in this paper. INTRODUCTIONRadioactive elements, such as cesium, iodine, strontium, plutonium, barium, cobalt, lanthanum, yttrium, and tellurium, were detected around Fukushima Daiichi nuclear power plant, which was damaged by the magnitude 9.0 earthquake and the tsunami followed.The removal of radioactive elements from contaminated sources is a worthwhile subject to investigatein terms of environmental control. Research efforts have been especially concentrated on studying microorganisms that remove uranium including bacteria (Andres et al, 1993, Hu et al, 1996, Marques et al, 1991, Strandberg et al, 1981), actinomycetes (Byerley et al, 1987, Friiss and Myers-Keith, 1986, Golab et al, 1991), fungi (Byerley et al, 1987, Galun et al, 1983a, Galun et al, 1983b,Tsezos and Volesky, 1981, White and Gadds, 1990) and yeasts (Strandberg et al, 1981, Schmate II et al, 1978).We have investigated removal and recovery of uranium from aqueous systems using microorganisms isolated from uranium mines. We identified some strains of bacteria with extremely high uranium removing abilities (Sakaguchi et al, 1996), and thus, the microbial biomass may be considered as an adsorbing agent for the removal and recovery of uranium and heavy metals present in aqueous systems around Fukushima Daiichi nuclear power plant.In the present study, we screened various species and strains of bacteria, actinomycetes, fungi, and yeasts for their ability to adsorb uranium (Tsuruta, 2002). Basic features affecting uranium adsorption?co-existing cations and anions, cell amounts, pH, and the adsorption time course?by Arthrobacter nicotianae cells, which adsorbed the largest amount of uranium, were also investigated. In addition, we examined the removal of an other actinoid element, thorium ion, which may be present with uranium in refining effluents.In this paper, the removal of cobalt, strontium, or cesium from the solution containing each metal ion using A. nicotianae cells is discussed."

Jan 1, 2012

By E. Hardwick, K. C. Sole, Y. Jurrius

"The Luilu cobalt plant at Kolwezi, Democratic Republic of Congo, has been operating since the late 1950s, using a conventional precipitation flowsheet for removal of impurities from the cobalt process stream. Most impurities are, however, incompletely removed using this technology. Copper and zinc, both of which quantitatively deposit at the cathode in the cobalt electrowinning process, are two of the main impurities contaminating the cobalt metal product. Ion exchange offers a modern approach to removing these impurities from the cobalt advance electrolyte.Following a laboratory testwork programme to identify a suitable ion-exchange system, an on-site pilot-plant trial, treating 1500 to 3000 L/d of electrolyte, was operated for a period of six weeks to optimise the operating conditions and to determine full-scale design criteria. Copper removal was carried out using a fixed-bed lead-polish configuration with the Lanxess iminodiacetic acid resin, TP 207. Zinc removal was subsequently carried out in a similar configuration using the Lanxess aminophosphonic acid resin, TP 260. The optimised system proved capable of removing both copper and zinc from 20 to 30 mg/L to <1 mg/L from plant electrolyte containing ~20 g/L Co. Selective elution allows co-loaded cobalt to be returned to the main circuit and value to be obtained for the copper impurity. The process shows operational and economic advantages over the traditional flowsheet. Full-scale implementation of the developed process is in progress and some design considerations are discussed."

Jan 1, 2014