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By S. B. Mishra

Ni-20Cr metallic coating was deposited on a Ni-based Superalloy (3Fe-19.5Cr¬0.3Ti-Balance Ni) by a shrouded plasma spray process; NiCrA1Y was used as a bond coat. Erosion studies were conducted on uncoated and plasma-spray coated superalloy specimens using an air-jet erosion test rig at a velocity of 40 m/s and impingement angles of 30° and 90°. The coating has been characterized for porosity, microhardness and microstructure and X-Ray Diffraction (XRD). An electron probe micro analyzer (EPMA) was used to obtain X-ray elemental mappings of the coating along the cross-section. Scanning electron microscope (SEM) with EDAX attachment was used to analyze the eroded surfaces.

Jan 1, 2005

By F. N. Smith

The carbon steel casings of Heat Recovery Steam Generators (HRSGs) in a co¬generation plant were found to have developed cracks that originated on the inside surfaces. The HRSGs receive hot exhaust gases from the primary Gas Turbines (GTs), which are fuelled with pipeline natural gas. The GTs was initially operating without any suppression of nitrogen oxides (NOx). After being in service for about two years, some of the cracks were found to have penetrated right through the 1/4 in. thick casings. The casings are fitted with insulation on the inside (hot gas side). Examination of steel samples cut from the casing walls revealed (i) fine cracks propagating through the steel from the inside surfaces, and (ii) the presence of relatively large amounts of nitrate ion on the inside surfaces. It was concluded that the nitrate ions originated from nitric acid that was condensing on the relatively cool walls of the casings behind the insulation. Nitric acid was formed in the GT exhaust gases by the combination of water vapour (formed from combustion of the hydrocarbon fuel and from moisture in the combustion air) and nitrogen oxides (formed from nitrogen and oxygen in the combustion air).

Jan 1, 2005

By D. Sammut, F. Houllis, J-L. Huens, J. Moyes

The Intec Gold Process has been developed as a halide-based alternative for the recovery of gold from refractory sulphide deposits. The halide medium allows sulphide oxidation and gold extraction to be performed concurrently at moderate temperature and atmospheric pressure sourcing oxygen from direct air injection. The dissolved gold is loaded onto activated carbon and stripped in a conventional Zadra circuit. High gold extractions have been achieved from a range of refractory gold concentrates at laboratory scale, which has led to a continuous locked-cycle pilot plant program. The pilot plant operated at >99% availability, with a maximum of 96.5% gold extraction from a concentrate containing 58.6 g/t gold. >99% of the dissolved gold was loaded onto carbon at up to 1% w/w, with no loss of carbon activity detected over five loading/washing/elution cycles. This paper describes the process and presents both laboratory and pilot plant results as well as economic data from two costing studies.

Jan 1, 2005

When selecting a method for monitoring crack growth in pipeline steel, the sensitivity or crack-size resolution plays a dominant role. Even though there are several visual and non-visual methods, the direct current potential drop (DCPD) method is very effective for monitoring crack growth because of its resolution. This method has been used for the past few decades and has gained increasingly wide acceptance in fracture research as one of the most accurate and efficient methods for monitoring the propagation of cracks. Furthermore, most R&D experience has proven that the electrical potential method can be used in most "aggressive" environments. For these reasons, the DCPD method was selected to design a testing machine to monitor corrosion fatigue crack growth. The use of finite-element modelling is shown to facilitate the application of the DCPD method for monitoring crack growth in steels. The 2D model calibration provided a good description of the test data and proved more accurate than the analytic Johnson's formula.

Jan 1, 2005

By S. Kariyawasam, R. McNealy

Pipelines are subject to multiple threats often requiring quantification of pipeline risk and engineering evaluation of in-line inspection and other data to effect discovery of conditions defined by the regulation. Public concern and pressure from regulatory bodies are accelerating the need for pipeline operators to formalize and intensify their approach to integrity management. Most operators need a phased approach to progressively adopt the most relevant and needed assessments. The organized and relevant assessment steps need to be introduced according to data available and maturity of the integrity management program. Each refinement to the quantification offers distinct advantages to the user. In this paper, the progressive integrity assessment solutions using quantitative methods are presented. Methodologies for engineering evaluation of integrity in-line inspection data for immediate and future integrity are summarized. Corrosion is used as an example, but the approach is applicable to any time-dependent defect based hazard. Strategies for pipeline integrity management are discussed.

Jan 1, 2005

By J. J. Jonas

The categories of interpass time encountered in hot rolling are characterized. These are shown to fall into three broad categories: short (in rod rolling); intermediate (in strip processing); and long (in plate schedules). The effects of interpass time on recrystallization and carbonitride precipitation are described, and particularly on the interaction between these two mechanisms. The interactions, in turn, determine the final microstructure produced as well as the mechanical properties.

Jan 1, 2005

By Y. Feng

Perovskite structured oxide 15% Y-doped BaCeO3 (BCY15) has been evaluated for use as proton conducting electrolyte in SOFC with propane as the fuel and Pt as both electrodes. Under the fuel cell conditions, BCY15 exhibited high proton conductivity and good cell performances. Propylene was detected as product at the anode outlet, and the product distribution suggests that propane dehydrogenation underwent competition with cracking to lighter hydrocarbons. Stability during cell performance tests showed that there was no obvious degradation for BCY15 electrolyte during operation of C3H8-O2 fuel cell.

Jan 1, 2005

By S. A. Jacob

Magnesium sheet is notoriously difficult to form at low temperatures without initiating failure, In the present work cold rolling and annealing conditions are varied to produce samples of AZ3lB sheet with a range of grain sizes. The formability of these samples is investigated using tensile testing and forming limit diagrams (FLD's), The results are discussed in terms of twin types and frequencies.

Jan 1, 2005

By A. Plumtree

The morphology of environmentally assisted cracks in stressed pipeline steel has been investigated. For a dilute and neutral solution (NS4) simulating ground water in contact with the steel, semi-elliptical cracks grow faster on the surface (2c) than in the depth (a), hence, the aspect ratio (a/c) decreases. This is explained using a deterministic concept since corrosion is dominant and the primary constraint is the conservation of charge. By contrast, when mechanistic conditions prevail, significant growth occurs in the depth. When underloads are imposed in the loading history, temporary accelerations in crack growth occur because corrosion rather than mechanical effects become dominant.

Jan 1, 2005

By B. Andreaus

In spite of tremendous efforts in research and development of polymer electrolyte fuel cells (PEFCs), essential properties of the actual catalyst material, supported Pt or Pt-alloy nanoparticles, are not yet well understood. Fundamental understanding of the catalyst structure and the prevailing kinetic mechanisms is, however, of utmost importance for further progress. In the present study, we investigate catalyst activity for CO oxidation from a theoretical point of view. Electrochemical CO oxidation serves as an important test reaction for the study of the fundamental properties of supported Pt nanoparticles. Recent experiments have revealed strong effects of catalyst particle size and supporting material on catalytic activity. It was found, that the activity towards CO oxidation decreases significantly when the particle diameter drops below 2.5 nm. We perform kinetic Monte Carlo simulations of CO oxidation on supported catalyst particles to elucidate this particle-size effect. The simulations are based on the active site concept, highlighting the role of active site formation and finite surface mobility of adsorbed electroactive species for catalyst activity. For comparison with experimental results, potential step experiments were simulated. The Monte Carlo simulations consistently reproduce effects of particle size and electrode potential found experimentally. In comparison with our simulations, analytical mean field models and nucleation and growth models exhibit inferior agreement with experimental data. In summary, our findings support an oxidation mechanism via active site formation. The reason for the slow reaction kinetics on catalyst particles with diameters below 2.5 nm is a rather low CO surface diffusivity. The rates of active site formation, diffusion and CO oxidation via recombination with adsorbed OH can be determined from the simulations.

Jan 1, 2005

By K-A. Adamson

If fuel cells and hydrogen are to become a mass market reality a substantial amount of further research and development needs to be undertaken. Work in hydrogen storage, production, the economics of all aspects of fuel cells and hydrogen, materials balances, and product integration are just a few of the areas that are under focus. Setting R&D targets, and providing R&D funding are therefore areas that are central to the long term development of the market, and areas in which a number of governments worldwide are highly active. Some governments, such as Japan and Korea, have set a number of very ambitious, highly focused, long term targets and are backing this up with substantial funding, others such as the EU are working on a more integrated approach, wrapping some fairly fundamental R&D into large integrated projects which run in combination with a number of other market aspects, such as public acceptance and roadmapping. The US is slightly different, in that although is has a number of long term programmes and targets, FreedomCar and SuperGen being just two, the levels of funding are set annually with the passing of each years Fiscal Budget. This paper takes three high profile regions and analyses the R&D targets and funding levels for fuel cells and hydrogen. Criteria that will be looked at include: Time frame of target(s), level of ambition, funding issues, including: Funding windows, levels available, funding barriers, overall programme goals. The added value to this paper is that it will provide a clearer picture of where each region is heading, what are its strengths and weaknesses, in terms of R&D and where there may be areas for potential international collaboration.

Jan 1, 2005

By V. Prodanovic, M. Militzer

Production of advanced linepipe steels with strength levels of 685MPa (100ksi) and higher requires excellent control of runout table cooling to produce the desired final fine-grained microstructures, which may include acicular ferrite. Cooling is exerted on the runout table by applying water jets onto the hot surface of the strip and heat is removed from the steel by forced convective boiling. The associated boiling mechanisms are complex and include film, transition and nucleate boiling. A pilot-scale runout table test rig has been built to systematically study boiling heat transfer from a moving steel plate by employing industrial scale headers. Experiments were conducted using test plates moving at speeds between 0.3 m/s and 1.4 m/s. The plates were cooled down from 850°C to temperatures below saturation by a single water jet supplied through an industrial size circular nozzle. Based on these experiments heat fluxes were determined and further used to develop improved runout table cooling models.

Jan 1, 2005

By C. Caners

One of the main uses of fossil fuels is in the transportation sector, leading to environmental consequences such as climate change. In order to move towards a more sustainable energy infrastructure, a transition must begin from fossil fuels to renewable fuels, derived from e.g. biomass. One means of facilitating this transition is to develop reforming technology that can extract hydrogen from a suitable fuel that is either fossil fuel or renewable in origin. The hydrogen would be feed to a 'fuel cell' engine that would power the car, truck or bus. One reforming technology that is attractive for automotive applications is autothermal reforming (ATR). Autothermal reforming is the combination of steam reforming and partial oxidation, whereby a portion of the fuel is combusted using a sub-stoichiometric amount of air, and the resulting thermal energy drives the more desirable steam reforming reaction. ATR is attractive for fast start-up, rapid load following and ease of control. ATR also has the benefit of smaller volume and fewer peripheral requirements as compared to other reforming technologies. Recently, a bench-scale gasoline autothermal reformer (ATR) was constructed and tested. This ATR employs a novel design, consisting of three concentric annuli in order to promote heat transfer from the partial oxidation reaction to the steam reforming reaction. Concurrently, a CFD based model (FLUENT) of the ATR that considers the geometric complexity of the reformer was validated. In spite of the use of simplified kinetics, the model predicted well the observed trends in temperature and overall performance. This paper will discuss the use of the model to improve the design of the ATR. The impact of various system parameters upon performance will be investigated along with alterations in the geometry of the ATR. The various tradeoffs in performance and system volume/size will be highlighted in the context of a fuel cell power system.

Jan 1, 2005

By U. Olsson, M. Ramström

"The IREDES1 Special Interest Group (SIG) for drill rigs has been active since its launch during MineExpo 2000 in Las Vegas, Nevada, United States. SIG for drill rigs is responsible for the development of an IREDES drill rig profile, including the exchange of production planning, performance, and quality reporting data between various kinds of drill rigs and the databases used by the operating mine. During 2001, a first draft of the drill rigs profile was jointly prepared by drill rig suppliers, mining companies, and third-party suppliers and reviewed during several SIG meetings. The profile for prototyping projects was released in mid-2002; the first official IREDES release was based on feedback received from these projects.In 2002, LKAB and Atlas Copco decided to carry out an IREDES prototyping project using the Simba L6C production drill rig. The goal was to verify the drill rig profile and identify potential problems prior to the official release. This was done by implementing the IREDES prototype version into LKAB’s production planning and Simba rig control systems. The Simba rig control system was designed to handle drill plan and logging information coming from the mine planning system. In parallel to this, the mine production system was adapted for drill plan export and logging data import in IREDES format.This paper presents the most recent results of the IREDES prototyping project. Results from late 2002 show that the basic architecture of the drill rig profile works and that a common language for data exchange, IREDES, will be a central requirement for future mine automation.As a result of the IREDES prototyping project, the IREDES standard was approved at the IREDES board meeting held at the 2003 CIM Annual Conference and Exhibition. Soon thereafter, IREDES compliant products, including drill rigs and mine production planning systems, were put on the market."

Jan 1, 2005

By G. T. Lapidus, J. Trejo-Gallardo

A phenomenological model is presented for leaching silver from silver sulfide contained in mineral particles with ammoniacal thiosulfate solutions of copper in stirred reactors. Experimental results were used to adjust the kinetic parameters of the model, such as the reaction order and velocity. The incorporation of the cuprous sulfide-silver sulfide equilibrium at the reaction interface allowed the prediction of the conversion limits for different reagent concentrations. The information obtained from the reactor model was later integrated into a heap leaching simulation, whose results adequately describe tendencies observed in column tests, with respect to variations in copper and thiosulfate concentrations. Comp

Jan 1, 2005

By D. Fleury

"This paper describes the challenges of mining a sill pillar under various types of paste backfill quality. From 1994 to 2002, Louvicourt mine produced approximately 12,600,000 t grading 3.5% Cu, 1.5% Zn, 27 g/mt Ag, and 0.85 g/mt Au. The mining method is transverse blasthole stoping, mining primary and secondary stopes. The production of this 4,300 t/d operation was accomplished using two mining horizons; from the 655 m level to the 415 m level and from the 860 m level to the 680 m level. The main sill pillar is between the 680 m level and the 655 m level. The second sill pillar is between the 885 m level and the 860 m level representing a quarter of the main sill pillar in size. Since 2002, production has gradually decreased and mining activities are expected to end in mid-2005. The sill pillar production will represent almost 25% of the total mine production. The overall recovery of the sill pillars stopes will be discussed in this paper. To recover the sill pillars, more than 1,500 m of development was planned in or under paste backfill. The first sill pillar stopes under paste backfill were mined out in 2002 with excellent results."

Jan 1, 2005

By H. R. Oliveira, C. R. Aragonez de Vasconcellos

Pipeline operation and maintenance necessarily involves geotechnical studies at points and areas with deflagrated instabilities or still to map and monitor areas prone to geotechnical problems. Landslides, erosions and debris flows are some examples of natural hazards, that not rarely, can bring high consequences to pipelines, sometimes leading them to high stresses levels and ruptures. Bolivia-Brazil Natural Gas Pipeline has 2.593 kilometers since Rio Grande City in Bolivia until Canoas City, in south Brazil. The pipeline crosses a lot of types of geological fields and difficult topography. The south spread of the pipeline has the most prone areas to geotechnical hazards because of its hard topography combined with the variety of geological materials, such as, colluvium deposits and debris flow areas. The aim of this paper is to present the right-of-way geotechnical risks that affect pipelines, presenting some practical remedial works done by TBG at Bolivia-Brazil Natural Gas Pipeline as well as the integrity plan and the adopted actions in way to prevent geotechnical accidents.

Jan 1, 2005

By K. Ski

Three series of membranes were prepared by blending polyvinylidene difluoride (PVDF) or poly(vinylidene difluoride-co-hexafluoropropylene) [P(VDF/HFP)] with sulfonated poly(ether ether ketone) (S-PEEK), sulfonated polysulfone (SPU), or sulfonated polystyrene, in order to develop novel PEM membranes suitable for melt processing. By means of incorporating fluorine-containing block copolymer into the blended system, acceptable proton conductivity and low water containing PEM materials were prepared. The effect of sulfonated poly([vinylidene difluoride-co¬hexafluoropropylene]-b-styrene) block copolymers as compatiblizers was investigated: conductivity was enhanced for S-PEEK/fluoropolymer blends. Microstructures for the blends were examined by transmission electron microscope (TEM) and scanning electron microscope (SEM).

Jan 1, 2005

By P. Ashtari

Influence of Sr and Mn single and combined additions on the modification of the Fe-containing intermetallic compounds and mechanical properties of Fe-rich AA319 aluminum alloys have been investigated, The microstructural features e,g, morphology of the Fe compounds and eutectic Si has been correlated to the mechanical properties, It was demonstrated that modification of the Fe compounds from the platelet ß-Al5FeSi to the Chinese script a-Al8Fe2Si compound improves the UTS and elongation of the alloys by 10.3% and 83.9%, respectively. Moreover, the simultaneous modification of the Fe compounds and eutectic Si increases the UTS and elongation of the alloys by 15,3% and 116,1%, respectively.

Jan 1, 2005

By T. Navessin

Recent research activities in proton exchange membrane fuel cell (PEMFC) have significantly improved the performance per unit cost and its lifetime. These activities narrow the technology gaps, and thus, enable commercialization in some applications. One particular focus is in the development and understanding of proton conducting membrane materials. Many novel membranes are being developed which provide control and systematic understanding of complex relationships between chemical structure, morphology, physicochemical properties, and electrochemical kinetics. In this study, different classes of proton conducting membranes suitable for portable and automotive applications were evaluated in an operating PEMFC at the Institute for Fuel Cell Innovation, National Research Council. Analysis of these results may provide constructive feedbacks to the material researchers.

Jan 1, 2005