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By Lawson F

The leaching behaviour of BHAS copper matte in oxygenated acidic sulphate chloride solutions at 85¦C has been studied using samples containing 34% copper, 41% lead and 12% sulphur. Copper sulphide in the matte, essentially Cu2S was found to leach in two distinct stages. Similar to the behaviour of pure chalcocite, copper dissolution in the first stage was affected by the availability of oxygen in solution. The presence of chloride ions in the leachant was essential if there was to be any leaching in the second stage (which usually commenced after about 40% of the copper had been taken into solution). Lead sulphide in the matte was oxidised to lead sulphate and formed a shell around the partially leached matte particles. Electrochemical studies showed that this lead sulphate and/or sulphur produced during leaching can form a passivating layer around the copper sulphide. However, this layer was disrupted when chloride ions were present. A Plackett-Burman analysis was used to determine the species in the recycled leach solution that affect the leaching of copper. Under the experimental conditions used, in the first stage the rate of copper dissolution was influenced by the concentrations of sulphuric acid, Zn(II), Cu(II), Fe(III) and Cd(II). In the second stage, the rate was futher modified by the concentrations of Cl(I) and As(V) ions. In solutions of low acidity and high As(V) concentration, insoluble copper arsenate formed which coated the partially leached matte particles and acted as a barrier to futher reaction.

Jan 1, 1989

The results of a systematic geochemical survey of rare elements are applied to elucidate genetic relations in a suite of rocks and to predict the probability of mineralization. The geology, radioactivity, major element geochemistry and classification of the main intrusives are described. The distribution of a group of rare elements, their concentration trends and the bearing these have on the emplacement sequence of the rocks are considered in some detail. The guides for exploration in the Pilanesberg that emerge are listed and some areas which substantiate predictions are described briefly. It is concluded that a study of rare element trends can make a considerable contribution as an exploration tool and for clarifying relations between the members of rock suites.

Jan 1, 1986

By R Castedo, P Segarra, I del Castillo, L M. López, J A. Sanchidrián

This work investigates some suggested methods for blast vibration monitoring on a hard surface based on 53 tests on a vibration exciter. Errors in the measurement attributable to coupling have been described as function of frequency by the rock-to-mount (or coupling) transmissibility, ie ratio of the velocity of the vibration sensor mount to the velocity of the rock motion. Transmissibility has been measured from 2 to 200 Hz, at two vibration levels (5 and 20 mm/s), in four seismographs. Attachment methods with an anchor, thermal adhesive and gypsum plaster allow stiff rock-to-mount coupling. They ensure accurate measurements (errors below 0.3 dB) for frequencies commonly found in blasting (below 100 Hz) irrespective of the mount characteristics and the vibration level. Free laid mounts and sandbagged vibration sensors lead generally to a poor, weak coupling. Errors are non-linear errors with the input velocity, ie the operating frequency window narrows as the velocity of the ground increases. Free mounts follow ground motion acceptably well (error up to 0.4 dB) at both vibration levels and frequencies below 15 Hz. At higher frequencies, free mounts lead to the largest distortions with expected errors ranging from 0.8 to 6.6 dB. Sandbagging limits the expected errors below 1.3 dB, but it does not prevent large errors that can be up to 4.5 dB. Both frequency and velocity should be considered together to assess the measurement errors instead of the expected accelerations, as it is currently made.CITATION:Segarra, P, Sanchidrián, J A, Castedo, R, López, L M and del Castillo, I, 2015. Effect of vibration sensor mounting method on the quality of vibration measurements, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 545–552 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By Mills JC, Belcher CB

X-ray fluorescence spectrometry is used videly for routine quality control of the mining, )lending and agglomeration of iron ores. Most )f the procedures used, cannot tolerate significant changes in matrix composition or be Lpplied to a wide range of elements. Accord- ngly, a graphite briquette technique which is Lpplicable to some fifty elements in widely Tarying iron ore matrices is described. The ignificant advantages are suitability of the ame preparation for both optical emission and -ray spectrometry, a complete elemental overage for the range 5bcg/g to 100%, and the recision and accuracy of the methods are om.parable with the standard chemical.methods hich have been superseded in the authors' boratories. The proposed methods become ore attractive and economical as more prehensive information is sought.

Jan 1, 1975

By R Dunne, S Hart, G Levay

While water represents a major proportion of the mineral pulp processed in flotation circuits, relatively little research effort has been committed to understanding and controlling the influence of water quality on this process. Historically, this probably stems from the perception of water as an inert transport medium. However, the changing attitude towards water as a valuable resource, has given impetus to increasing requirements to use relatively impure make-up water supplies such as treated effluents and a high proportion of internally recycled water. In turn, this has resulted in the need for a more detailed focus on process water quality and its control to minimise adverse effects on sulfide flotation. Along these lines, prior to commissioning of a new concentrator at their Cadia Hill Gold Mine, Newcrest Mining was proactive in examining potential water sources and the influence of water quality on flotation of their copper/gold bearing ore. An extensive water quality survey of all major potential water supplies to the concentrator was undertaken. The flotation performance of the Cadia ore in each of these waters was investigated on a laboratory scale. The results of these studies identified that water quality could indeed have a significant influence on the flotation process. Since operations at the Cadia Hill concentrator began, water quality surveys of both make-up water sources and recycled flotation circuit waters have been carried out on a regular basis. By doing this, a database of water quality has been established which can be compared with plant performance. In parallel with the water quality surveys, a series of laboratory flotation tests have been conducted using a standard ore and waters from various streams to monitor changes in flotation performance as a function of water quality. These tests have indicated that certain water types may have a significant influence on plant performance. More research is required to better understand the impact of water quality on sulfide flotation. This understanding will help operators to minimise adverse effects, while maintaining the best utilisation of available water resources.

Jan 1, 2003

This paper presents the results of studying the influence of catastrophic failures arising in mines, on the behaviour of mine ventilation systems. It is very important to take account of this influence for the stable operation of the system and to ensure mine safety when mining underground coal and ore deposits.

Jan 1, 2003

Level measurement of underground orepasses is important. Orepasses are not only utilised to funnel ore to the shaft skip loading station but also as silos for storing of ore in order to smooth out ore flow in a shaft system. Safety and operational efficiency are also improved as proper orepass level measurement could prevent overfilling of tipping areas. A study was therefore commenced to determine alternative technologies available as well as identifying practical installations across the Anglo American plc Group. From an instrumentation perspective an orepass system is an extremely difficult environment to take measurements in. Factors like dust, vapour, interference, bridging, wear and physical installation have to be taken into account. The study discusses time-of-flight (ultrasonics, radar and laser) measurement techniques followed by other possible solutions. These solutions included strain gauge measurement, the æjumping monkeyÆ technique, radiotomography, fibre optics and very long baseline interferometry (VLBI). Finally, various South African suppliers have been approached in order to determine instrumentation that is available for orepass level measurement in the marketplace. These recommendations were verified, where possible, by visiting the claimed installations.

Jan 1, 2005

By Baker G

The exposures resulting from development work, following on the discovery of a new shoot of hIgh grade ore at the north end of the Sardine tin mine, during 1952, have provided an unusual opportunity to study the oxidation of a stannite-rich ore. Through the kindness of C. C. Morton, Chief Government Geologist of Queensland, an exactly located suite of specimens representative of the exposures was supplied by J. and W. Reddie. This was later supplemented by a number of specimens culled from a parcel ofrepresentative ore submitted to the Melbourne Ore Dressing Laboratory for testing.The Sardine tin mine, near Ewan, Queensland, has been the outstanding producer of the Kangaroo Hills Mineral Field. Since its discovery in 1918, up to 1952 it has yielded about 1,500 tons of cassiterite concentrates, and about 85 tons of stannite concentrates. The outcrop ore averaged 35% tin oxide, but the grade declined with increasing depth, and by 1930 had fallen to 7% tin oxide. In the northern section of the mine the ore shoots show a downward passage to complex primary s.ulphide ore, containing cassiterite and abundant stannite.The orebodies occur in a series of fissures in a crushed zone about 50 ft. wide in slates and quartzites that have been intruded by granite (Connah, 1952). A quartz porphyry dyke forms the footwall of the original main lode in its southern part, being traced' from the surface to' the No. 4 level (173 ft. vertical depth), and two narrow dolerite dykes were encountered in the workings north of the main...

Jan 1, 1954

Attempt has been made to determine the nature of charge on activated carbon surface by studying the electro-kinetic properties of the carbon in the presence of cations, anions and aurocyanide solutions. The zeta-potential measurements were made in the presence of individual ions and also in combinations. The cations and anions chosen were those commonly associated with gold bearing ores in Kalgoorlie area. It was found that the iso-electric point of Norit Carbon was at pH 4.45; below this pH the charge was positive, while above, it was negative. In the absence of gold cyanide solutions and in the presence of individual cations the i.e.p. shifted to the alkaline range (pH 7.2-8.5) while in the presence of anions the i.e.p. was shifted to less than pH 3.5. In the presence of aurocyanide solutions, the iso-electric point was still in the acid region irrespective of whether anions or cations were present. The probable mechanism for such a behaviour has been attempted after measuring the specific conductivities of solutions before and after gold adsorption, by studies using the electron- probe-mirco-analyser, and S.E.M. on the carbon surface.

Jan 1, 1982

At the outset I want to thank you for inviting a representative of the Chamber of Mines of South Africa to address you on the subject of mining and its future at this, the 13th Congress of the Council of Mining and Metallurgical Institutions. It is indeed a pleasure and an honour to be here. As many of you will recall, four years ago I, as the then President of the South African Institute of Mining and Metallurgy, had the privilege of hosting and welcoming you to the 12th Congress, the third such congress hosted by South Africa. The late Sir Ernest Oppenheimer, President of the 1930 Congress - the first to be held in South Africa - in his opening address foresaw the mining industry as "the most potent factor in spreading the benefits of civilisation over the sub-continent." We have come a long way since those halcyon days but, as I noted four years ago, it still remains true that mines have been, and will continue to be, the missionaries of development in many, if not most, of the Third World countries. I have been asked to address you on the subject of "mining" and to let my imagination roam widely so that delegates can leave the congress with a broader vision than they brought on arrival. It is a tall order and in my attempt to fulfil it I ask you to cast your minds back 120 years to a sultry, rustic day when the first diamond was discovered in South Africa at the now famous town of Kimberley. At that time the South African economy, predominantly pastoral, was still at subsistence level. Almost overnight the ensuing diamond rush turned the then British- owned northern Cape Colony's semi-desert scene into a hive of mining activity, every prospector bent on making his instant fortune. It was very little different, I am sure, to the gold rushes that hit California in 18+8, Australia in 1851, New Zealand in the 1860s. and the Yukon in the 1890s.

Jan 1, 1986

By N Dube, K L. Sandvik, C Mutevhe

Trojan Nickel Mine is the largest producer of Ni, Cu and Co in Zimbabwe. The mine has operated a nickel flotation concentrator and base metal refinery continuously since 1969, creating 28 million tonnes of sulfide bearing tailings, five million tonnes of permanent waste rock and about seven million tonnes of smelter slag. Exposure of the sulfide bearing minerals renders them susceptible to oxidation in the presence of water and oxygen, resulting in acidic solutions with elevated concentrations of total dissolved solids, sulfate, metals and residual flotation chemicals in various waters draining from the mine site. These pollutants pose a direct threat to the environment and human health, and understanding their deportment and behaviour in the various waste streams is essential in the mineÆs environmental objectives to prevent or minimise adverse impacts arising from its operations. A geochemical assessment of the pollutants was carried out to compute a mass balance between the major sources of pollution and the distribution and fate of pollutants in waste streams from the mine site. Waste rock, tailings, surface water, ground water and sediments were sampled, tested and analysed. Mineral composition and water chemistry data show that geochemical reactions are responsible for the release of pollutants from waste rock, tailings and plant spills. Drainage from the mine area is near neutral due to buffering by magnesium carbonates in the fine fraction of the tailings. The natural wetlands that exist downstream of the waste rock and tailings dams are effective in reducing metal loadings to water courses. However, solutes and heavy metals are occasionally released to surface and ground water, when their concentrations peak during the dry season. The results demonstrate the necessity to understand the natural chemical processes that characterise the distribution of pollutants in nature and how such knowledge can be used to develop cost effective methods to remediate pollution in the natural environment.

Jan 1, 2006

By K M. Brodie, D I. K McLeod, J Ruddock

Environmental incidents involving mine tailings and waste rock inevitably become highly publicised and serve to damage the credibility of the entire industry. The recent serious incident involving a spill from a Romanian mine, was blamed for triggering æone of the worst environmental catastrophes in Eastern EuropeÆ. It is important to clearly demonstrate to the general public that these incidents are not representative of the industry as a whole. Where such incidents have occurred, the causes are generally related to poor design and/or construction, inadequate supervision and/or monitoring and maintenance, lack of independent expertise, inadequate risk identification and treatment and no provision to ensure that rehabilitation and long term management of the site occurs. Many people are unaware that these issues have been considered and provided for at the Martha Mine. Despite the fact that the first tailings storage facility has performed very well over fifteen years of operation, the long term safety and security of the tailings storage facilities continues to be questioned and debated by the public. The best way to address this is to provide quality information to enable a better understanding amongst the general public.

Jan 1, 2002

By Parsons AE, Lewis IE

Selenium is a minor constituent of the raw materials processed by the Cockle Creek smelter of Sulphide Corporation Pty. Limited. Certain proposed raw materials contain higher levels of selenium, and these will create a problem with regard to the composition of liquid effluent discharged from the smelter. A method has been developed for removing selenium from the smelter circuit by the sulphation of the fume collected in the Acid Plant electrostatic-precipitators. It is planned that by treating 10-20% of the total dust arisings there will be a substantial reduction in the levels of selenium reporting in effluents when treating selenium-bearing raw materials. The selenium is recovered in elemental form.

Jan 1, 1978

Raw materials account for over 60 per cent of the cost of hot metal production in classical blast furnaces and the principal cost component is cost of coke. Dependence on coke is a traditional weakness of blast furnace ironmaking and while efforts have been made to evolve alternative ironmaking technologies which do not use coke, such as direct reduction, smelting reduction, and the more recent method of making iron carbide, blast furnaces continue to be the most efficient means of producing bulk hot metal even today. Coal injection, to the extent of 150 - 200 kg/t of hot metal, has been one of the major innovations made in blast furnaces to decrease cost and to reduce the dependence on coke. This has, however, given rise to more stringent coke property requirements (which often means more expensive coke) - a `tail spin' of Sorts!

Jan 1, 1999

By C Li, K McDonald an, T Nicholson, C Brown

The relative reactivities of chars prepared from different coal samples at temperatures in the range 500 to 1150¦C were determined by measuring the rates of metallisation of a standard ilmenite concentrate. The results have been interpreted in relation to different measured physical and chemical properties of the chars. Char reactivities were found to correlate with the maximum specific surface area (SSA) of the chars, obtained from plots of SSA versus temperature. Weathering of coal samples gave higher reactivities which correlated with higher SSAs. Experiments using recycled chars showed that the high internal SSAs developed during earlier reduction reactions provide no benefit in terms of increased metallisations. The important role of char hydrogen contents in controlling low temperature metallisation rates was demonstrated. Chars prepared from different rank coals had the same hydrogen content when prepared at the same temperature. Ilmenite metallisation rates had a linear dependence on the hydrogen content of the chars. Large differences in the slopes of the metallisation versus H2 content curves for different chars were interpreted in terms of SSA variations and catalysis of the gas reactions by dispersed metallic iron particles in the chars. A simple test based on magnetic separation of the char was shown to give an indication of enhanced reactivity due to contained metallic iron.

Jan 1, 2001

By Fookes R. A, Bunch K, Gravitis V. L, Watt J. S

The combustible volatile matter in coal mine roadway dusts (CVM) has been determined using x-ray backscatter techniques. The correlation between x-ray and chemical techniques is reasonably good for the 92 samples from collieries on the Bulli seam, and the maximum error expected at the maximum level of 11· 5 weight per cent CVM permitted in the N.S.W. Coal Mines Regulation Act, 1912, as amended, is about ± 2·5 weight per cent. This x-ray technique can be used only when the combustible volatile content of the coal matter (cvm) varies within a limited range, and a separate calibration is required for each coal seam.Portable equipment based on a radioisotope x-ray source ahd digital ratemeter makes possible simple and rapid analysis, and with adaptation to use in coal mines should lead to much more comprehensive testing- ofroadways and hence improved overall prevention of coal dust explosions.

Jan 1, 1977

By V Seedwell, P H. McGuckin

The Broken Hill Proprietary Company Limited (BHP), started as a silver-lead- zinc mining company in Broken Hill, New South Wales, Australia in the 1880s. Since then it has diversified into the resource industries of steel, iron ore, coal, petroleum and copper. BHP World Minerals, is a Business Group of BHP which is one of the worldÆs largest and most diverse mineral resource enterprises. BHP supplies raw materials for steelmaking, copper concentrate and other mineral commodities to customers in more than 45 countries. BHP World Minerals has operations throughout the world - in Australia, the United States, Brazil, Zimbabwe and Canada. Commodities produced by BHP World Minerals currently include silver, lead, zinc, titanium minerals, platinum group metals and coal. The challenges in the improving performances in safety arena are common to our industry and BHP operations. This paper outlines the vision and values that have been fundamental in assisting BHP Cannington search for and implement a safety system addressing behavioural matters.

Jan 1, 1998

By Matters, R T, Coldham, Slee, J C, R J, Wallman

The Committee desires to thank the managers of the various mines along the line of lode for their hearty co-operation in its labours. It would also extend thanks to Messrs J C Moulden, Howchin, Twelvetrees, and the West Australian Geological Surveyfor various information; to Messrs J G Dreyer, S Pope, T Read, P Moncrieff, R Williams, and W J Rose for analyses; and to a number of local gentlemen for advice and help. Professor Skeats, of Melbourne University, gave much valued assistance in petrology, and Mr Herbert Lavers kindly undertook the study of the garnets.INTRODUCTIONThe famous Broken Hill lode is situated in a low range of hills, the Barrier Ranges, near the western border of New South Wales. It has been worked since 1884-fust for silver, then for silver and lead, and at present for lead, silver, and zinc...

Jan 1, 1910

By R A. Binns, S Murao

The PACMANUS and Jade deposits are two active hydrothermal fields that are forming massive sulphide deposits at the Pacific rim margin. Both are associated with felsic submarine volcanic rocks and both occur in back-arc settings. However, PACMANUS is associated with almost sediment-free dacites and lies on the crest of a volcanic ridge, whereas Jade occurs in a heavily-sedimented tectonic depression associated with a basement of pumiceous rhyolite. The PACMANUS deposit is richer in Cu and Au, and Jade in Pb. Zinc, Ag, As and Sb contents are similar. Sulfide textures at PACMANUS suggest formation of Cu and Zn sulfides by simultaneous double-diffusion involving inwards-moving seawater mixing with outwards-moving hydrothermal fluid. By contrast, at Jade there is a more complex history of formation where initial growth of barite on the sediment surface, probably associated with microbial activity, formed an impervious cap which trapped higher temperature hydrothermal solutions.  

Jan 1, 1995

By D J. Hill

"Mining companies routinely invest in improvements to their processing operations, but often these enhancements do not work to full effect.Improvements can be ineffectual because underlying process problems are not identified or prioritised for correction or repair.This is frequently because ‘black box’ solutions deployed to implement process control improvements typically rely on instrumentation to provide data for algorithms to work effectively, and these solutions are often ineffective or disabled at mineral processing sites.There are three key reasons they can fail to deliver: vital instrumentation is not calibrated or functioning as required basic process control and loop tuning was not implemented correctly or is in need of tuning there is an inability to support the ‘black box’ solutions on-site.Many of these problems can be overcome by implementing operational analytics that identify where problems are occurring and prioritise where improvements need to be made.Incorporating operational analytics into process improvement is not a new methodology. It is more a back-to-basics approach to make more efficient use of capital and systems already deployed.Data collection systems, such as the OSIsoft PI System, provide real-time and historical process information for process control experts to analyse and identify areas for improvement. However, most systems are not used effectively. With some simple enabling, data collection systems can provide evidence for prioritising investments in improvements and determining an investment’s effectiveness.MIPAC advocates that the initial step, with analytical evidence, is that clients review the control strategies and implement small influential instrument repairs/calibrations and operator training. This can significantly boost process productivity without the need to spend large sums of money on new capital or employing expensive, difficult to maintain ‘black box’ solutions.A simple Stage-Gate®-style approach ensures that small investments in evidence-based process improvements deliver significant benefits to mining operations.CITATION:Hill, D J, 2014. How to prioritise process improvements, in Proceedings 12th AusIMM Mill Operators’ Conference 2014, pp 307–314 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Sep 1, 2014