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By Mahoney M

For gas content analysis in recent years, it has been standard procedure to report results on a 'dry ash free' (daf) basis, under the assumption that gas only adsorbs onto coaly material. In order to test the relationship between ash and sas content, samples of various rock types were taken from two drillholes in the Newcastle Coalfield. The results of this study confirmed the correlation between gas content and ash, providing an accurate means of relating gas contents for all carbonaceous rock types.

Jan 1, 1995

The introduction ofa submerged entry tundish nozzle incorporating a cylindrical internal space for argon distribution to its inner bore slab is described. In co-operation with the refractory supplier, four major phases of nozzle development have been undertaken. Problems as well as successes are outlined.Significant reduction in alumina clogging ofnozzles has been achieved along with a decrease in nozzle consumption, using resin bonded alumina graphite with up to 4 different materials "zoned" to give resistance to thermal shock, gas leakage, and erosion.

Jan 1, 1985

By Whang K, Choi H

A study of flocculation of ultra-fine coal particles by ultrasonic waves was investigated on a laboratory scale.The coal suspension was dilute, with low ionic strength, and at pH 6·2.When a stationary sonic wave is set up in a solution containing suspended coal particles, it is believed that high and low pressure regions are alternately established at the half wave-length of the sonic wave and this resultsin the migration of coal particles towards the low pressure regions.As expected the flocculation is more effective as to frequency and the power of the ultrasonic waves is increased.The shape and size of the test equipment are also important variables.

Jan 1, 1977

A description is given of the construction and operation of an automatic version of the coarse batch particle sizer which requires a minimum of operator supervision and which is capable of processing a sample every 4 min.

Jan 1, 1968

The design and operating characteristics of the hydraulic cyclone elutriator were described in detail by Kelsall and McAdam (1963), and the method of operation of the commercially available version, the Cyclosizer, is described in the manufacturer's pamphlet (Anon). Complete details of the operating procedure are given in the relevant operating manual (Anon, 1964).The cyclones which form the basis of the Cyclosizer (Fig. 1) under normal operating conditions produce typical cut sizes of 44, 33, 23, 15, and 10 µm for cyclones one to five respectively for material with a specific gravity of 2·7. At the end of the selected elutriation period each sized fraction is discharged and collected for subsequent assay or analysis but all material rejected by the fifth cyclone (e.g. minus 10 \lm quartz) normally passes to waste. When this material is needed for separate study, although its amount and average analyses can be calculated by difference, it may be necessary to collect more than 250 I. of very dilute suspension, flocculate the solids, allow to settle, and decant off the supernatant liquid.This procedure is cumbersome and inconvenient and the simple technique to be described may offer some advantages. The temperature of the water fed to the Cyclosizer is maintained at a constant value for added reproducibility.PROCEDUREThe present overall treatment of the subsieve material (minus 37 \lm) fed to the Cyclosizer incorporated several refinements compared with normal operation and these may be best illustrated by anactual example. Material to be cyclosized (25 to 100 g depending on size distributIOn and specific gravity) is completely dispersed in water at 23 QC by vigorous stirrmg, using suitable dispersants if necessary, in a...

Jan 1, 1974

KIeeman (1968) described practice in the Mount Hebbard dump concentrator, Broken Hill, N.S.W. The purpose of this note is to give data on flotation pulp chemistry in the plant for comparison with results of Woodcock and Jones (1970a, 1970b).Ten chemical parameters were measured at ten points in the circuit using the techniques of Woodcock and Jones (1970a, 1970b). Fig. 1 shows a condensed time plot of some continuous measurements in conditioner overflow and rougher feed. Fig. 2 shows average values of selected parameters at the start and end of each of the three rougher flotation stages.DISCUSSIONpH and redox potentiaIsFig. 1 shows that pH and Eh were relatively constant at the start of sulphide lead flotation. There was a fairly steady increase in pH throughout the circuit (Fig. 2), but flotation was always conducted in a slightly acid pulp in spite of the large amount of alkaline reagents added. Eh values became more positive as the pulp progressed through the circuit (Fig. 2) in accord with results elsewhere.

Jan 1, 1973

Zircon is extensively used as moulding sand in the production of steel and high-duty iron castings. To achieve a satisfactory grade of zircon concentrate, the zircon particles may need ,to have surface coatings removed, as such coatings can hinder electrostatic and magnetic separation of zircon from associated minerals. Xn addition the presence of surface coatings on the zircon. particles can cause sinterins and fusion of the zircon to the east metal resulting in "burnt-on" sand or fritting of the casting. "Burnon" necessitates cleaning of the casting by grinding or chipping, which is expensive and results in loss of definition on the casting face.Hudson (1966) has pointed out ,that some coatings on mineral sands are lightly-adhering clays which can be removed quite readily by agitating the sands in water for a few minutes-thus their removal constitutesno problem. However, the heavy gingery coloured coating which adheres strongly to the surface of the particles in some deposits, and which has generally been considered to be a form of iron oxide (Baker, 1962; Hudson, 1966), cannot be removed effectively by attrition cleaning in water (Hudson, 1966). Such coatings limit the usefulness of these concentrates in the foundry industry.An investigation of strongly-adhering coatings on "ginger zircon" concentrates from the Yoganup deposit of Westralian Sands Ltd has shown that the stain consists of a cemented mixtvre of hydrated iron and aluminium oxides and kaolin minerals, and that it can be removed by a relatively low cost treatment.IDENTIFICATION OF THE STAIN BY XRDX-ray powder diffraction (XRD) patterns were obtained from small samples of stain scraped, individually, from the surface of hand-picked zircon and ilmenite crystals. These scrapings were mounted on quartz fibres and exposed to CoKa radiation in a 57 mm Debye camera. To avoid heavy fogging of the x-ray films, a substantial amount of the iron oxides was preferentially leached from the scrapings (before mounting) with an ammonium oxalate-oxalic acid solution (Rooksby, 1961). The residual material gave a fairly well resolved powder pattern (Table 1). A...

Jan 1, 1975

It is suggested that if adequate knowledge is available about classifiers in closed grinding circuits, these units may be used as on-stream size analysers when equipped with suitable sensing devices. Research work which is at present in progress to enable a hydrocyclone to be used for this purpose is discussed.

Jan 1, 1967

By Rao P. K, Sahoo P. K

The main constituents of ferromanganese slags are silicates of Mn, Ca and AI. Factors affecting the recovery of manganese from a low manganese content ferromanganese slag (about 16 per cent MnO) during acid leaching were studied. These included time, temperature, agitation, sulphuric acid addition, solid:liquid ratio and particle size. Agitation rates greater than 300 rev/min. leaching periods greater than 30 min and temperatures above ambient were found to have no effect on Mn recovery. Dissolution of Mn was found to be highly dependent on the amount of acid added.About 90 per cent of the Mn was recovered when 5·5 times the stoichiometric amount of acid was used. About 28 per cent of the Mn was recovered when the stoichiometric quantity of acid (with respect to Mn alone) was used. However, the recovery increased to about 75 per cent when the total stoichiometric requirement of acid with respect to Ca, Al, Mg and Fe as well as Mn was used for leaching. The extent of Mn dissolution also depended on the particle size of the slag. The percentage of Mn recovery (using 5·5 times the stoichiometric amount of acid) increased from about 60 per cent to about 92 per cent when particle size decreased from -36 +52 to -150 +200 mesh (B.S.S.). When the results of this study were compared with those in a previous study involv,ing the leaching of a high manganese content slag (containing about 40 per cent MnO) results were similar except that there was a gr-eater consumption of acid in the present case (i.e. low manganese content slag).

Jan 1, 1979

By Giannini L. M

A method using dynamic programming for solving the optimum pit limit problem was presented in an earlier paper. A recent issue of this journal contained some contributed discussion on the implementation of this technique. In this paper we provide some additional ideas and possible options one can incorporate into the method. In particular, an efficient procedure for obtaining further optimum pit outlines on extensions of the original block model is described.

Jan 1, 1987

By Turner T. M

The problem of metering fine particulate material at low flowrate is often encountered in metallurgical experiment. This note describes a feeder which wa developed to provide metered flows of copper sulphide concentrate in the range of 0'1-0'7 g/min.It is believed that the present device is easier to operate than previously described feeders (e.g. Hamor and Smith, 1971). It may have applications in the field of analytical chemistry, as well as in metallurgical investigations.

Jan 1, 1978

About 11,000 tons of contaminated zinc flotation concentrate were available in the form of earth walls from dams used for atmospheric drying of the concentrate.Following successful laboratory tests this material was treated in a plant by crushing, grinding, and then flotation in a circuit consisting of roughing, scavenging, and two stages of cleaning. Reagents used were copper sulphate and a little butyl xanthate and frother. About 5,720 tons of zinc concentrate assaying 52· 3 per cent zinc were produced.

Jan 1, 1968

By Field R. V, Graieg O, George T. J

The design, construction and operation ofa laboratory scale rotary pot kiln are outlined. Charges ofup to 3 kg can be heated to temperatures up to 1200°C in a controlled atmosphere. Some examples of pyrometallurgical investigations carried out using the kiln are briefly described, including thermal reactivation ofcarbon using steam at 550-850°C, high temperature testing ofkiln liners for corrosion resistance to fluoride, and calcination oflimestone. Results obtained from these trials allow either direct scale-up to the Engineering Chemistry Laboratory's pilot-scale (50-100 kg/hr) rotary kiln or modifications to be made to commercial scale processes and/or equipment.

Jan 1, 1986

A mineral grain finder is described which is easily constructed to fit onto the stage of a standard reflected light ore microscope.The device is most useful in relocating particular grains or mineral associations on 30 mm diameter polished sections. The use of the grain finder in the teaching of ore microscopy is outlined.

Jan 1, 1988

This technical note describes a problem with WANG82, a ventilation network analysis programme. The problem was highlighted by Renison Ltd when using the programme on large, complex networks. Under certain circumstances the programme produced incorrect results or failed to converge to a solution.

Jan 1, 1986

By Poi G, Madgwick J. C, Davis P, Pannowitz D, Cho D, MacKay B, Chan S. M, Varga R. A, Chun U

Periodic dilute sulphuric acid treatment ofstill, batch-fed, molassesenriched, microaerobic, manganese-dioxide-Ieaching microbial cultures led to marked improvements over untreated cultures. Percentage Mn++ recoveries increased (7X), rate of Mn++ formation improved (3X) and yields of Mn++ per molasses use were more economical (5 X). The yield in terms of molasses used improved with decreasing sugar used (eg 1.17 g Mn++/gram molasses at 0.2 per cent molasses (w/v) feed and 24 per cent (w/v) pulp density MnO2 tailings). The most effective Mn++ leaching in terms ofpercentage recovery (97 per cent) and rate ofleaching (46 mg Mn++/day) was at 0.5 per cent molasses (w/v) and 14 per cent pulp density (w/v) MnO2 tailings.

Jan 1, 1986

By Pollard D, Meadows N

The presence of impurities which are electropositive to zinc in acid zinc electrolyte causes changes to deposit morphology and reduced current efficiency. Glue may be added to control some impurity effects, but assaying for animal glue concentration is difficult and seldom done. Measurement of the activation overpotential for zinc deposition by cyclic voltammetry is used in some plants to monitor electrolyte quality and control glue additions.The deposit morphology and current efficiency of zinc deposition from commercial electrolyte were investigated for various glue additions in the presence of increased levels of antimony. Cyclic voltammetry was investigated as a method of optimising glue additions in the presence of antimony.Scanning electron rnicroscopy showed deposits characteristic of the impurity element present and the glue addition rate. Cyclic voltarnmetry measurements showed some correlation between current efficiency and activation polarisation potential. The importance of using tankhouse electrolytes where results are to be related to tankhouse operation was noted.

Jan 1, 1988

By Botz R. W

Macroscopic and microscopic studies of the outburst-prone Gemini Coal (Bowen Basin) showed that outbursts were associated with a localized inertinite-rich ply. Previous studies of the Gemini Coal had shown a general relationship between desorption rate, regarded as a good measure of outburst proneness, and inertinite content of coal samples.Desorption rates increased with increasing inertinite content and were highest for inertodetrinite-rich samples. These results suggest that inertinite content and composition play a significant role in outbursting and may be useful in identifying outburst-prone coals, which could be confirmed by desorption measurements.Consequently outburst-prone areas in the Upper Permian coal measures ofthe Sydney, Gunnedah and Bowen Basins have been defined using a combination ofthe parameters, inertinite content, depth ofcover and coal rank. In the Upper Permian, inertinite-rich coals are confined mainly to the top of the coal measures, except in the Sydney and Gunnedah Basins where an inertinite-rich interval (Bayswater Coal and correlatives) is also present towards the base of these measures. Only a small area ofthe central Sydney Basin, butmuch ofthe north-eastern and north-central part of the exposed Bowen Basin is considered outburst prone on the basis of these parameters.The most outburst-prone inertodetrinite-rich lithologies have a patchy and unpredictable distribution in the top of the Upper Permian coal measures. They can be defined only by sampling and petrographic analysis at the subsection level.

Jan 1, 1986

The results from three quick methods for the determination of W03 in scheelite ore samples, mill products and concentrates were compared with gravimetric results and tested with standard samples to establish which was the most reliable. Summaries of the methods, two X-Ray fluorescence and one colorimetric, are given. The best method was X-Ray fluorescence, with samples cast as glass discs.

Jan 1, 1988

By Bruce See J

Oxidation of artificial Imperial Smelting Furnace lead bullion was performed during cooling between 1180 and 820°C in order to attempt to produce a tin-rich dross.The addition of sodium carbonate together with stirring increased the tin content of the dross when oxidation was carried out with air or PbO on zinc-free bullion.Zinc in the bullion during oxidation resulted in a decrease in tin concentration of the dross due to zinc oxidation and copper entering the dross.

Jan 1, 1987