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By Hassan El-Shall, Rosana M. Macedo Borges, Ponisseril Somasundaran, Regis Stana, José Renato B. Lima, Patrick Zhang

The phosphate fertilizer industry is a large activity in Brazil because the soil has a phosphorous deficiency. The phosphoric acid that is produced is extensively used in the production of fertilizer. It is produced by reacting phosphate carbonaceous rock with sulfuric acid, generating phosphogypsum as a by-product. In 1991, there were about 29 million tons of phosphogypsum stored in Brazil. This has increased to an estimated 280 million tons in 2001. While the phosphogypsum is used in the cement industry and also in agriculture, the quantity used is much less than the production rate, and the stockpiles are still increasing. The radioactivity of this waste may not allow its continued use as a construction material and some other uses. However, Brazilian phosphogypsum contains a smaller quantity of radioactive materials than is reported for phosphate rocks from other countries. One important reason is the geological origin of the Brazilian apatite. All the large deposits being currently mined are igneous, not sedimentary, as is the majority of the phosphate rock produced around the world. An extensive study is being conducted to characterize the phosphogypsum generated in two production facilities in Sao Paulo state to develop safe uses for this waste and determine the environmental impact caused by the present method of phosphogypsum disposal.

Jan 1, 2002

By Nader Shahcheraghi, Verya Nasri, Mehdi Bakhshi, Ali Haghighat

An accidental fire load is one of the major loads considered in design of segmental linings in transit tunnel. Typically, a two-dimensional coupled thermo-mechanical finite element analysis (FEA) is conducted. The conventional approach involves using standard fire curves (temperature-time curves) which can lead to a significant overestimation of fire load and tunnel lining thickness in metro tunnels. The focus of this paper is on the cutting-edge approach, using 3D computational fluid dynamics (CFD) analysis of real train fires in metro tunnels and coupled thermo-mechanical finite element analysis (FEA) to accurately and cost-effectively design fiber-reinforced concrete (FRC) segmental tunnel linings for large-scale metro projects.

Jun 23, 2024

By T. Tamagawa, I. Iwasaki, N. X. Fu, M. Kobayashi

A low-temperature-chlorination selective oxidation followed by aqueous chloride leaching and SX-EW for producing electrolytic copper, elemental sulfur and ferric oxide was investigated for hydrometallurgical processing of a chalcopyrite concentrate. In this article, the selective oxidation phase of the process is described. The selective oxidation requires a temperature well above the CuCl-FeCl3 eutectic points. The test procedure was developed with a batch reactor and then tested with a continuous reactor. The process was initiated by adding small amounts of chlorinated samples to a fluidizing bed of dead-roasted sulfide concentrate micropellets. The selectively oxidized samples thus prepared were shown to fully dissolve copper, while virtually all the iron remained undissolved.

Jan 1, 2000

By J. E. Gebhardt, S. Chander

Significant advances have occurred in the use of electrochemical techniques for sulfide mineral flotation research. The techniques have been used singly or jointly with other characterization methods. When used in combination with other methods, the electrochemical methods provide a means to control the state of oxidation of the surface. Various analytical methods are employed for characterization. The methods that have been used include wetting, x-ray photoelectron and fourier transform infrared spectroscopies. The electrochemical methods include voltammetry and transient electrochemical techniques of galvanostatic polarization and AC impedance spectroscopy. The challenge for the future lies in the utilization of this knowledge in plant operations so as to increase the overall efficiency of flotation separations.

Jan 1, 1989

By I. Iwasaki, K. A. Smith, X. Cheng

The reaction mechanism for the cathodic decomposition of pyrrhotite in deoxygenated solutions at natural, near neutral pH levels was studied using potential and cyclic voltammetric measurements. Reaction products on the pyrrhotite surfaces were examined by Auger Electron Spectroscopy (AES), by X-ray photoelectron spectroscopy (XPS) and by analyzing the voltammograms for the electron balance of the reactions. Surface properties of the pyrrhotite/solution interface were characterized using an ac impedance technique. The parameters of an equivalent circuit were determined by the nonlinear least-squares fit (NLLSF) technique. The effect of cathodic polarization on floatability was investigated by performing microflotation tests. Possible implications to the flotation separation of chalcopyrite-pyrrhotite ores are discussed.

Jan 1, 1995

By F. M. Doyle, K. Osseo-Asare, E. Peters

With the aid of molecular orbital theory, a discussion is presented of the relationship between the electronic structures of ions and molecules, and the elementary steps involved in homogeneous electron transfer reactions. An electronic theory of the reactivity of oxidants and the mechanism of action of oxidation catalysts is then presented, with emphasis on the oxidative decomposition of metal sulfides. For model oxidants, two molecular reagents: O2 and Cl2, and two ionic reagents: Fe3+ and CU2+ were selected; silver (1) was chosen as the model catalyst. The reactivities of these reagents are rationalized in terms of constraints on orbital overlap, the availability of unoccupied d orbitals, and the rearrangement of electronic configurations.

Jan 1, 1993

By S. W. Asihene, K. Osseo-Asare

The leaching and solution treatment operations used in the ammoniacal treatment of laterites depend on the ability to establish and maintain close stability relations between soluble metal ammine complexes and solid phases such as oxides, hydroxides, basic carbonates, sulfides and ammonium double salts. This paper presents a quantitative treatment of heterogeneous equilibria in ammonia/laterite hydrometallurgical systems, by means of several.types of hydrometallurgical phasedia- grams (e.g., Eh-pH, log [NH3 + NH4+] - pH, log [C02] - pH, log SO42-] - pH, log [Metal] - pH). Dissolution/precipitation phenomena associated with nickel and cobalt recovery and with magnesium scaling are discussed in the context of the phase diagrams.

Jan 1, 1979

By A. Röttger, W. Theisen, J. Küpferle, M. Alber

"Wear of TBM tools significantly affects tunneling advance rates. Wear-prediction models are based (amongst others) on the abrasivity of the present geology, which is determined via laboratory tests. To evaluate the results from such tests in context, this work considers the tribological system TBM tool from a materials technology perspective. In so doing, the microstructures of different application-oriented materials are presented and discussed in terms of their wear behavior and wear resistance. The significant influence of tool materials on the abrasivity of the geology and thus wear prediction models has already be identified. LCPC, Cerchar and nano-scratch experiments have been performed as confirmation. Material-dependent wear mechanisms and their correlation in terms of tunneling have shown that it is mandatory to consider the complete tribological system to estimate the wear of TBM tools. 1 INTRODUCTION Mechanized tunneling is vital to ensure necessary infrastructure development in megacities like Tokyo (Bay Tunnel), Istanbul (Eurasia Tunnel) and Mexico City (Tunnel Emisor Oriente). The use of Tunnel Boring Machines (TBMs) has been established for many years. In contrast to other methods such as boring and blasting or excavation using dredgers, tunneling with TBMs allows simultaneous excavation and removal of both the mineral and tunnel lining by tubbing segments or shotcrete. This makes tunneling more efficient, allowing for faster development of the tunnel in both hard rock and soil [1]. When budgeting such tunneling projects, precise planning and coordination in terms of tunneling technique choice (e.g. EPB or Slurry-shield), the relevant geology, and the associated penetration rates and tool wear are required. In particular, wear to TBM tools has a significant impact on tunneling progress. Due to wear, tools become dulled or lose their functionality because of brittle material behavior, thus reducing penetration rates and therefore tunneling efficiency [1]. As a result, additional tool changes are necessary, leading to higher overall costs due to down times and maintenance costs. Therefore, there is strong interest in a reliable and precise wear prediction model for TBMs. As already mentioned, the geology and associated wear of the tunneling tools define the maintenance times."

Jan 1, 2016

By L. G. Austin, R. C. Klimpel

Batch breakage kinetic tests were performed in a mill of 0.3 m diameter for a range of mill conditions. Accurate simulation required the measurement and use of factors which accelerated the specific rates of breakage of the top sizes as finer material accumulated in the slurry. These factors depended on the size distribution expressed relative to the top size, not the absolute size, suggesting that they are due to a packing effect not a rheological effect. The data simulated correctly a series of steady-state continuous tests in a mill of the same diameter providing values were corrected to the hold-up, ball load, slurry density, and size distribution measured in the continuous mill tests.

Jan 1, 1990

By Roberto Pimentel de Souza

Since 1976 CVRD is carrying out tests to develop a type of pellet made with organic binder. One binder that showed good possibility to be used in industrial plants is Peridur. An extensive framework of tests was run in CVRD's pilot plant. The results are presented in this paper. Finally, the decision was taken to carry out an industrial production of 50.000 t of pellets. It was scheduled for March '81. The results are shown in this pager. It was not observed any detrimental effect of the peridur neither in the process nor in the product quality.

Jan 1, 1981

By G. Vallebuona

Currently, empirical models are used for predicting the hydrocyclone performance in terms of capacity, cut size (d50,c), water split and partition curve. These models, for example those of Lynch and Plitt, have been developed and checked for hydro cyclones with diameters larger than four inches. For smaller diameter hydrocyclones little empirical modelling has been done. This paper reports extended experimental research on small hydrocyclones. For these cyclones, the suitability of existing empirical models has been checked and their accuracy compared. Modifications of the existing models equations are proposed, improving their predictive capability for the small cyclones performance.

Jan 1, 1994

By D. Constantinides

In 1981 a Zn-Ag-Pb deposit was discovered in the vicinity of Molai, Greece. Subsequently, it was determined to be of the Kuroko type. The geology of various areas in the southeast Peloponnesean Peninsula is similar to that of the Molai deposit. Since favorable geologic criteria are present, absent, or unknown in varying degrees in all areas, it was deemed necessary to classify and rank the prospective areas according to the level of information available. For each level of information, an ore discovery model based on pragmatic exploration criteria was developed, enabling the favorability of occurrence to be calculated for each area. A Monte Carlo simulation was used to calculate the probabilities, the input data consisting of quantitative and qualitative estimates of the geologic criteria for each area. Three levels of information were modeled : Level A consisted of 9 criteria, level B of 12 criteria, and level C of 20 criteria. The three levels of information were tested on the Molai area. The results exceeded expectations, showing the gen¬eral trends which control mineralization at the lowest level of information. With an increase in the level of information, geological trends become more evident and a differentiation can be made between areas containing Cu mineralization, exhibiting a low probability, and areas likely to contain Zn-Ag-Pb mineralization. The models were then applied to the neighboring areas - only level A and B were available.

Jan 1, 1986

By E. J. Hammer

In the crushing and grinding of metallics for beneficiation, the sizing is normally done to liberate the metals or sulphides for further processing to improve recoveries of the basic metals or minerals. The objective is to reduce the ore in size through various closely controlled stages to that degree of fineness which gives an economic liberation of valuable mineral, but which avoids as much as possible the production of sliming fractions. A different philosophy applies to the crushing and grinding of Gypsum. Our requirements normally demand controlled grinding and/or crushing of the material not only to a fineness suitable for further processing of the mineral into end products, but to produce various sizes of material which are them- selves saleable products. The majority of our tonnage ultimately ends up in stucco for Wallboard. Therefore, our mineral reduction is normally designed toward this end, but it is done in a manner that permits drawing off inter- mediate products to meet various Customer requirements. This forces us into compromises at times in our equipment installations, and our equipment must sometimes be more versatile and complex than we would like it to be. We try to process our basic rock, Gypsum, for the most efficient size reduction. We market 5 to 6 different sizes intermediate to the end product, which generally is the fineness of material to be used for stucco for Wallboard, and we do this with controlled crushing, grinding and sizing cycles of the material. To summarize, we use a different philosophy of crushing and grinding than the metallic field which uses comminution or crushing and grinding to improve recovery, whereas we choose our equipment to crush and grind primarily for product performance.

Jan 1, 1969

By R. W. Bartlett

Aeration curing, over- a long duration in wet- red stockpiles, shows promise as an affordable pretreatment method for oxidizing gold encapsulating sulfide minerals, and possibly organic matter, in low grade refractory ores. Following aeration pretreatment, the ore is reclaimed, neutralized, and cyanide leached by conventional practices. Large tonnages of subeconomic material, including mine stripping waste, may he converted into ore by this new technology. The results presented show that a successful application of this technology will likely require crushing to about -2 cm (-3/4 in.), followed by aeration in a wet stockpile for long periods, up m three years. Natural convection may he inadequate, hut forced air ventilation, at modest pressures and power consumption, is affordable.

Jan 1, 1991

By B. Denby, R. Hollands, S. Cooper

Augmented Reality (AR) is a technology that can be used to mix computer-generated images of data with views of the real world. The University of Nottingham is developing AR technology in a major research project which can be used to assist mining companies in visualising complex mine data whilst out in the field. The technology comprises of integrated GPS surveying technology and electronic orientation devices to provide location and viewing information, video capture via digital camera and portable computing hardware to overlay 3D models on views of the real world. The paper describes the concepts of the technology in some detail and concentrates on the possible applications of this in the surface mining and exploration industries.

Jan 1, 2002

By M. G. Ayat

Coal degradation is the breakage of coal particles to finer sizes due to the continuous forces of attrition and gravity to which coal is subjected during mining, handling and preparation. The objective of this paper is to determine the extent of degradation that a coal slurry experiences when transported through pumps and pipelines. The examination of degradation results for a number of different coal slurries have indicated that the extent of breakage is dependent upon the physical properties of coal and the time span of circulation. These results have also indicated that certain size fractions of coal are more susceptible to breakage than others.

Jan 1, 1986

By J. C. Franklin

The U.S. Department of the Interior, Bureau of Mines, has developed a data acquisition system to continuously monitor radon, working level, absolute pressure, temperature, relative humidity, and air velocity. Data have been taken in intake and exhaust drifts, working stopes, and sealed-off areas of positive and negative ventilated uranium mines. Radon emanation rates, ranging from 1.7- to 12.2 x 2 10-l4 Ci/cm /sec were determined in four mines. The ratios of short duration, primary fan shutdown time to radon normalization time were 1 to 2 and 1 to 4, respectively, for-negatively and positively ventilated mines. Blasting and slushing caused radon increases of 160 and 67 percent, respectively.

Jan 1, 1980

By Kalliat T. Valsaraj, Louis J. Thibodeaux

A mathematical model is described for the transfer of hydrophobic compounds from aqueous to an immiscible organic phase using fine bubble aeration; the process otherwise known as "solvent sublation" an adsorptive bubble separation process. The limitations of the model are explored by simulating experimental results both for a batch scale process and a continuous process. The qualitative predictions of the model with respect to the influence of the organic layer (mineral oil) are tested by performing experiments using chloroform and 2,3,6-trichloroanisole as hydrophobic compounds in the aqueous phase. The continuous process is seen to be limited by the requirements of fine bubble generation and the ratio of influent feed rate to air flow rate.

Jan 1, 1989

By R. Kahrger

This paper is written to convey the latest developments in compact bucket wheel excavators (BWE's) operating in medium-hard rock and will serve to indicate that BWE and compact machines in particular do in fact have application in materials other than loose sandy soils and soft rock. A recently run extensive three month field test in hard marl, which was previously considered too hard and difficult to be handled by a BWE, is used as an example to explain some of the design requirements and problems associated with digging harder materials.

Jan 1, 1990

By William R. Sharp

This paper describes a graphics station and graphics software designed specifically for use within the minerals industry. Through the graphics station, a user is able to recall maps for modification, display them on a color CRT, send the work to a plotter, and restore the work when finished. The engineer may use the system for the storing of data, per- forming engineering calculations, doing word processing, and performing general file maintenance. In addition, the system may be used to communicate with a mainframe computer for such purposes as: transmission of large data files, graphic 3-dimensional rotation of a mineral deposit or mine design, contouring of spacial data, and other data processing work.

Jan 1, 1982