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By H. G. Iverson

The purpose of this investigation was to beneficiate the Talladega gray iron ores by flotation. A component of the problem was the determination of the degree of beneficiation possible by flotation as well as the relative selectivity of certain reagents in promoting flotation of either the iron minerals or the siliceous gangue minerals. The scope of the present investigation involved only the use of small-scale laboratory equipment. Treatment by roasting and magnetic separation was not included in this study, inasmuch as a similar comprehensive investigation was completed and the results were published by the Bureau of Mines in 1927. The results of the work on Talladega iron ores are briefly summarized in this report. In the search for efficient and economic methods of beneficiating low-grade iron ores, the flotation process is among those that are receiving considerable attention. The Talladega ores are of particular interest for a flotation study, because they contain two iron minerals (magnetite and specular hematite) that are somewhat dissimilar in their flotative response.

Jan 1, 1949

By Edward M. Kawenski

Tests were made in the Bureau of Mines Experimental Coal Mine on stop-pings similar to those used in operating coal mines to obtain information on air leakage through the face and the rupture strength of a stopping subjected to a pressure differential. Block stoppings were made from cinder, slag, and gravel aggregates with and without mortared joints and coatings. Sheet stop-pings were uncoated brattice cloth and nylon or brattice cloth and expanded metal-lath coated with asphalt, latex, mortar, or rigid urethane foam. Limited data were obtained on air through stoppings subjected to simulated roof convergence and to shock forces created by the firing of an adjacent charge of explosive. The pressure differential required to rupture stoppings was determined. shows that coating the face of a stopping effectively reduces ail: leakage. Block stoppings, particularly those with mortared joints, are most resistant to pressure and shock forces than are sheet stop-pings. Where ground movement is a factor, sheet stoppings leak less air than block stoppings.

Jan 1, 1965

By John C. Machisak

THE INJURY data and experience at quarries and related plants of the United States are presented in this publication under the following general sections : (A) General injury experience: Tables 1 through 3: Contain current data on the number of injuries, injury-frequency rates, location, accident agency, degree of injury, and related employment data. (B) Injury experience at different kinds of quarries: Tables 4 and 5: Contain current data on number of injuries, injury- frequency rates, location, accident agency, degree of injury, and related employment data. (C) Injury experience by States: Tables 6 through 19: Contain current data on the number of injuries, injury-frequency rates, accident agency, degree of injury, and related employment data.

Jan 1, 1959

From 1886, the first year shipments were recorded, until 1939, the Leadville district produced over 3,500,000 long tons of manganiferous ore. Of this total, metallurgical-type ores comprised 27 percent and manganiferous iron ores suitable for fluxing in lead smelters made up 73 percent. In 1939, the Bureau of Mines, as part of the strategic minerals investigative program being conducted at the time, requested the Mineral Industries Survey Section of the Mining Division to make a comprehensive study of the manganese resources of the Leadville area. This investigation, owing to the caved and flooded condition of the underground mine workings, was necessarily confined to a study of old maps, production records, and geological reports, and the results were published as an Information Circular in July 1940.

Jan 1, 1949

By E. C. Lane

During the past 15 years the Bureau of Mines has made and published several hundred analyses of typical petroleums and has developed a system of interpreting the analyses and of classifying crude oils. In describing crude petroleum frequent reference is made to the "base" of the oil, a usage the petroleum industry has found convenient. As part of its general study of the characteristics of crude oils, therefore, the Bureau of Mines has developed a system of classifying them according to "base." This system as first published in 1927 was limited to four classes and in its original form is no longer considered adequate. Since the system was first published the Bureau has analyzed a large number of crude oil, including representative samples from nearly every important producing field in the world, and has found that the system of classification could be revised and amplified to advantage. The revised system is presented herein.

Jan 1, 1935

By H. W. St. Clair

This study was undertaken to provide a more adequate knowledge of the chemistry of the sulfide volatilization process for recovery of tin from low-grade Bolivian ores. The investigation was partly supported by the Department of State under its program for scientific cooperation with South American republics. The results of this investigation demonstrate the conditions under which cassiterite (Sn02) may be converted to stannous sulfide by reaction with pyrite or sulfur vapor, Quantitative data are given on the rate of sulfidization and on the vapor pressure of stannous sulfide.

Jan 1, 1954

Between 1985-1986, the Bureau of Mines reviewed the mining history and minerals information for areas in and near the San Isabel National Forest to appraise the mineral resources present and determine the types of deposits, and their location in the Forest, that could be mined economically if sufficient demand and metal prices existed. The two major metallic deposit-types that are of national mineral resource significance within the Forest are stockwork- molybdenum (with tungsten and tin) and carbonate-replacement zinc-lead-silver deposits. Historically, small gold placers, gold-quartz veins, silver-quartz veins, skarn iron and copper deposits, volcanogenic copper-zinc-precious metal deposits, and base- and precious-metal veins have been mined. Barite, carbonate rocks, gypsum, other non-metallic deposits, and pegmatites, have also been mined. Sand and gravel, present in large volumes, occurs along and has been mined outside the Forest along the upper Arkansas River valley. Turquoise and gemstones are present in small amounts and are of interest to collectors and jewelers. Geologically, sediment-hosted uranium and copper are present in small occurrences but no resources have been identified. Geothermal resources are related to the Rio Grande rift which parallels the central part of the Forest. Four hot spring areas are present - two of these are within the Forest. Because of the low power requirements of the region, and the presence of other generating facilities, these geothermal resources have had only limited local use. Evaluation of mine models that may be found in the region show that base-metal deposits require a high precious-metal component to be economic. Although molybdenum can be produced at economically competitive prices, there is little demand for the product. Capital costs to start new molybdenum mines would be very high and it is not likely that new mines will be put into production in the near future.

Jan 1, 1989

By D. D. Fischer

Recovery and separation of molybdenum and rhenium from a process solution was accomplished by a technique developed by the Federal Bureau of Mines involving a combined solvent extraction and activated carbon adsorption procedure. The processing sequence required treatment of the solution with S02 to reduce the chlorate ion and adjust the pR prior to solvent extraction of molybdenum and rhenium with a tertiary amine. Molybdenum and rhenium were stripped from the organic phase with an NH40H solution, and the strip solution was then passed through activated carbon to preferentially adsorb the rhenium. After washing entrained molybdenum from the column with a brine solution, rhenium was eluted with an MeOH-H20 mixture. The activated carbon was regenerated with water. Molybdenum was recovered as (NH4)6Mo7024 by evaporating the column effluent. Rhenium in the column eluate was reextracted with a tertiary amine, stripped from the organic phase with dilute NH40H, and recovered as NH4Re04 by evaporating the strip solution. The final (NR4)Re04 product contained < 80 ppm impurities. Sodium sulfate was crystallized from the first solvent-extraction raffinate by lowering the solution temperature to 0° C. Precious metals contained in the original process solution were adsorbed onto the activated carbon.

Jan 1, 1975

By K. E. Tame

As part of a Bureau of Mines survey of radioactive waste disposal , a laboratory investigation was made to study such problems in carbonate leaching mills . Because uranium concentrators employing carbonate leaching with caustic precipitation normally recycle barren solutions to the washing circuit , the disposal of liquid radioactive wastes is automatically controlled . However , it was deemed important to determine the actual radium 226 concentrations occurring in this type of milling so that the survey of the entire industry would be complete . The laboratory procedure consisted of leaching the ground ore at 85 ° to 90 ° C and 50 pct solids for 6 hours in a sodium carbonate - sodium bicarbonate solution . The pulp was filtered to obtain a pregnant solution that was reacted with sodium hydroxide to precipitate the uranium as sodium diuranate . Regeneration of the barren solution was accomplished by gassing with carbon dioxide . The solution then was reused by advancing the solution through the washing to the leaching operations . The radioactivity in the pregnant solution was unusually high , averaging 6,500 disintegrations per minute ( dpm ) of radium 226 per liter . However , over 95 pct of the radium was precipitated with the uranium . Consequently , no buildup of radium occurred upon reuse of the barren solutions for washing .

Jan 1, 1964

By Thomas E. Green

A combined solvent extract ion-spectrophotometric method for the determination of as little as 1 ppm of copper in tungsten metal or tungstic oxide has been developed and evaluated. Metallic samples are converted to tungstic oxide by treatment with hydrofluoric and nitric acids. The oxide is then dissolved in sodium hydroxide, and the copper is extracted as the colored neocuproine complex. Total elapsed time for the analysis is approximately 1-1/2 days; however, actual working time for a group of six or eight determinations is less than 4 hours. Precision at the 2-ppm level is better than 0.1 ppm.

Jan 1, 1963

By H. J. Lechtenberg

This Bureau of Mines report investigates solvent injection as a means of increasing oil production from low-gravity oilfields; thus, wells in two California oilfields that produce from reservoirs having low-gravity oil were injected with highly aromatic solvents to increase their oil recovery. The wells were either allowed to soak or the solvent was circulated for a period of time. In some of the wells, the solvent was followed by a slug of water. The post-stimulation production rate was considerably higher than the prestimulation rate of the wells. Wells in which the solvent was not followed by water showed an immediate increase in oil production, and essentially all of the solvent was recovered. The wells in which solvent was followed by water essentially showed a delay in the increase in oil production, thus indicating a temporary water block. The results show that the production rate is usually increased by the injection of solvent, and the method may prevent early abandonment of marginal producers. Cumulative post-stimulation oil production indicates that cyclic solvent injection treatment can be an economic success.

Jan 1, 1974

By Elaine Cullen, Launa Mallett, Mike Jenkins, C. M. K. Boldt, Thomas Camm

The material in this Information Circular was presented at the National Institute for Occupational Safety and Health’s (NIOSH) open-industry briefing held during the 2004 Northwest Mining Association conference in Spokane, WA. The open-industry briefing discussed results of recently completed and on-going mine safety- and health-related research conducted at NIOSH’s Spokane and Pittsburgh Research Laboratories on the human side of mining—the miner. The first paper sets the stage for what mining has achieved and what we mean by “getting to zero.” The second paper, “Help Experienced Miners Become Great On-the-Job Trainers,” distinguishes between experienced miners and trainers. This paper provides some key concepts for turning great miners into great trainers. “The Power of Story-Telling in Getting Through to Miners” explains the history and importance of stories in the culture and training of miners. Finally, “Understanding Self in Stressful Working Environments,” describes the personal and social aspects of the working environment, much of which parallels familial theories. The downward trend of deaths in U.S. mining has been remarkable. The number of miners killed or injured each year has decreased steadily over the past 100 years. Some charts show these trends overlain with important events such as World War II and the Mine Safety and Health Act. However, this downward trend in mining fatalities has flattened out. How can you get to zero accidents? Do you concentrate on technological advances and equipment maintenance to avoid malfunctions? Do you concentrate on developing work processes and organizational structures that minimize risk? Do you combine them and take a systems approach that links one to the other with an evaluative loop? Safety efforts in mining have used all of these approaches. What more can we do to get to zero? Getting to zero will require two objectives: A clear and unshakeable belief that it can be done and attention to the human side of mining. Getting to zero is not a new idea; it has been used by mine companies and safety professionals for years as the safety goal. But getting to zero is not so much a physical goal as it is a belief that there are no insurmountable barriers to achieving the goal.

Jan 3, 2006

By A. G. Starliper

Research was conducted by the Bureau of Mines to determine feasible roasting methods for the removal and the recovery of germanium, cadmium, and lead as enriched fractions from sphalerite concentrates. The two types of roasting processes studied were: (1) Batch, with a stationary bed, and (2) continuous, with a suspended bed, Results indicated that either method gave satisfactory metallurgical recoveries} but the continuous process is recommended because of inherent advantages. Final products were enriched fractions that could be treated by conventional methods for production of metallic germanium, cadmium, and lead. In the batch process, the concentrates were placed in a large tube furnace and heated at 1,080° C, an average of 3 hours. During the heating period, inert, reducing} or sulfur-laden gases were passed over the stationary charge to convey the sublimed metal sulfides from the hot portion of the tube to a lower temperature condensing zone at the end of the tube, where the metal sulfides were collected on baffles and recovered. In the batch and fluidizing roasting processes alike, the gases passed over or through the charge and served only as carriers for the sublimates and as suspension media in fluidization roasting. Since both processes depended on the volatilization, at relatively high vapor pressures, of the sulfides of germanium, cadmium, and lead, it was imperative that very little oxygen come in contact with the charge to alter the sulfide minerals. Germanium has a high affinity for oxygen, but in this instance it was buffered by being in solid solution in zinc sulfide.

Jan 1, 1961

By Martin H. Rogoff

The presence of antibiotic materials extractable with polar organic solvents was demonstrated in coals of various ranks. Since these antibiotics occur in low concentrations, 200 pounds of a high-volatile C coal was extracted with acetone at room temperature to obtain sufficient material for detailed study. The biologically active materials in the extract were concentrated by extracting with aqueous sodium hydroxide. The fractions soluble in sodium hydroxide inhibited bacterial cultures when present in concentrations comparable to those at which other antibiotics are active (5 µg/ml). Steam distillation of the extracts did not yield highly active materials, contrary to the finds of other investigators. Mass spectrometry of the extract indicated, mainly, the presence of 6-ring compounds in the region of mass 324 to 392. The predominance of 3-ring aromatic systems found by ultraviolet analysis suggests compounds such as biphenanthryl or similar structures. The activity of the hydroxide- soluble material decreased markedly when the phenolic hydroxyl groups were transformed into trimethylsilyl ethers. Hydrolysis of the ethers yielded a product having the same activity as the original material, which indicates that phenolic compounds are largely responsible for the antibiotic activity observed.

Jan 1, 1963

By A. W. Fahrenwald

Coarse sand flotation, both alone and in conjunction with gravity concentration, is a subject of research at the U. S. Bureau of Mines Field Office, Moscow, Idaho. One of the most important results of this work which is being carried out in cooperation with the University of Idaho, has been the development of a concentration process embodying flotation, classification, and tabling, in the order named. The flow sheet of the process is given in Figure 1. The type of feed desired for this process is coarser than is common in present "all flotation" practice, and is about the size of table feed.

Jan 1, 1929

By Benjamin Petkof

Production quarry blasts in three rock types were photographed with a high-speed camera. Analysis of the films showed that step increases sometimes occur in the horizontal velocity of the broken rock. These step velocity increases were observed only in the first foot or so of rock movement. This observation indicates that the gaseous products of the explosion do additional work on the rock after it is crushed and cracked by the initial compressive-stress pulse and the reflected tensile-stress pulse. The observed initial fly-rock velocity is compared with the calculated fly-rock velocity for reflection spalling. A mechanism possibly causing the velocity increases is discussed. INTRODUCTION When a small concentrated charge of explosive is detonated at the bottom of a drill hole near a free surface, two modes of rock failure have been observed; both are associated with the stress pulse generated in the rock by the detonating explosive. The first mode of failure is the crushing and radial tensile cracking associated with the initial passage of the compressive-stress pulse as it propagates outward from the explosion. This type of rock failure is usually confined to the immediate vicinity of the charge hole. The second mode of failure is the tangential and radial tensile cracking associated with the tensile-stress pulse that is reflected from the free surface. This mode of failure is commonly called scabbing or spalling and has been shown to be a primary cause of rock failure in crater formation at one free surface. (3).4

Jan 1, 1961

By B. F. Naylor

"INTRODUCTION Investigation of the physical properties of electrolytic manganese and its alloys has constituted a part of the program of the Bureau of Mines for several years, and already extensive data have been reported. 3-14/ Heat-content measurements above 25° C. of pure manganese 15/ were completed recently at the Pacific Experiment Station of the Bureau, and the results obtained removed many of the inconsistencies in previously reported data. This paper reports heat-content data of seven manganese-copper alloys, varying in composition from 25 to 90 percent man-ganese. The alloys, obtained from the Salt Lake City Station, 16/ had been quenched from 850° C, and cold-worked. Without further heat treatment, heat-content measurements of each of these alloys were made at 100° or less temperature intervals from 450° to 850º C., as it was considered likely that any abnormal behavior of the specific heat would be found in this temperature range. Also, a portion of each alloy was heat-aged at given temperatures for periods of time thought sufficient to reach phase-equilibrium; then the heat-contents above 25° C. were determined at the aging temperatures. (Heat-aging was done at approximately 450°, 550°, 650°, 750°, and 850° C.)METHOD AND MATERIALSThe heat contents were determined by the ""drop"" method in a previously described apparatus. 17/ The calorimeter was cali-brated with electrical energy, measured in international joules, and the results were converted to the conventional thermochemical calorie by the relation, 1 cal. = 4.1833 int. joules."

Jan 1, 1946

By H. S. Caldwell

Molten zinc, condensed from zinc vapor, was used by the Federal Bureau of Mines to leach aluminum from an aluminum-silicon alloy made by carbothermic reduction of silicious aluminum ores. Zinc requirements were minimized by re-fluxing condensed zinc in a low-pressure, Soxhlet-type distillation unit. The minimum ratio of zinc used to aluminum in the crude alloy was approximately 2:1. When the system pressure was reduced from atmospheric pressure to 100 microns or less, the rate of aluminum extraction increased by a factor of 20. Leaching rates were much higher when the zinc vapor was condensed directly on the crude alloy than when molten zinc was passed over the alloy in the absence of appreciable zinc vapors. Observations indicated higher extraction efficiencies from crude alloys containing greater amounts of iron. Complete extraction was obtained with negligible loss of zinc. Assuming complete removal of zinc, the aluminum products will contain 1 to 6 percent silicon and about 0.5 percent iron plus titanium. The leached crude-alloy residue is a highly friable spongelike material containing about 80 percent silicon, several percent iron and titanium, with the remainder aluminum. This extraction method has been patented (Patent 2,810,637) and assigned to the Government. Research and development investigations are continuing at the College Park Metallurgy Research Center.

Jan 1, 1961

By Manuel Gomez

The Bureau of Mines used data from 31 core samples to develop prediction equations for evaluating chemical and carbonization properties of six seam units in a lignite deposit approximately 2 miles wide and 8 miles long in the Wilcox Formation of central Texas. Statistical response surfaces, based on core analyses, were computed for 14 parameters indicative of lignite quality. These computed surfaces, and their mathematical equations, can be used to predict values of the selected properties of the lignite seams at any desired surface coordinate position between core hole locations. The wide range of application shown by this study indicates that the methods of statistical regression analysis may be useful to evaluate large deposits of lignite or higher rank coal.

Jan 1, 1969

Reduce rockfall fatalities and injuries by using innovative blasting practices to reduce damage to the rock at the excavation limits with little or no increase in cost. The Problem Falls of highwall have been a leading cause of fatalities, injuries, and equipment damage in the surface mining industry. Although the number of highwall falls is not great, when such an incident does occur it is about 14 times more likely to be fatal or result in severe injury and damage to equipment than other types of surface mine accidents. Overbreak or damage to the rock from poor or improper blasting practices is a major factor contributing to rock falls. Presplitting or cushion blasting is the technique most often recommended for improved wall control. This type of blasting however, adds to drilling and blasting costs and is not universally accepted by the industry. Air gap presplitting techniques, also called air decks, are currently being used in some mines as a less costly alternative to conventional presplitting. Approach Blasting can cause highwall damage, but proper blasting techniques have been shown to reduce the magnitude of rockfall problems. In preventing rock falls, it is important to maintain the natural strength of the rock structure to the greatest extent possible. Improved blasting practices have three main advantages: 1) they are preventive rather than corrective in nature; 2) they are cost effective; and 3) they have a very low impact on the mining operation when properly implemented. New ways of evaluating highwall integrity, such as seismic refraction tomography, were investigated.

Jan 1, 1991