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By H. H. Schrenk

Much has been written and said concerning tables of permissible or maximum allowable concentrations of various toxic substances in air, but not enough attention has been given to their limitations and how to use them intelligently . There is a tendency to place too much reliance on figures , with little or no consideration of their real meaning . The repeated publication of a figure often adds significance to it far beyond that intended by the original author or publisher . How are these figures referred to as "maximum allowable concentrations " established? What is their real meaning? To answer these questions it is necessary first to define maximum allowable concentration . The usual definition is somewhat as follows : "The average concentration to which an industrial worker can be exposed for 8- hours daily for an indefinite period without injury or occupational disease . This definition is made up of the following items : ( 1 ) Average concentration, ( 2 ) 8 - hour day , ( 3 ) indefinite exposure period , and ( 4 ) lack of injury or occupational disease . There is some controversy regarding item ( 1 ) , items ( 2 ) and ( 3 ) are usually though not invariably accepted , and there is definite disagreement regarding the interpretation of item ( 4 ) . . To reach a more satisfactory interpretation of maximum allowable concentration , attention is directed to ( 1 ) the development of tables of maximum allowable concentrations , ( 2 ) criteria on which limits are based , and (3 ) methods used to obtain data on which limits are based .

May 1, 1948

By A. Soderberg

This paper describing the mining practice at the Utah Copper Co., Bingham Canyon, Utah, is one of a series being prepared by the Bureau of Mines on mining practices, methods, and costs in the various mining districts of the United States. The Utah Copper Co. operates the low-grade open-out copper mine at Bingham Canyon, Utah, which is 30 miles in a southwesterly direction from Salt Lake City. In addition to the mine the company operates two flotation concentrators, the Magma plant and the Arthur plant, which have a combined capacity at maximum metallurgical efficiency of 60,000 tons daily. The concentrators are at Magna, about 18 miles from the mine. The company operates its own standard-gage railway, known as the Bingham and Garfield Railway, between the mine and the mills (fig. 1). Concentrates are smelted at the Garfield smelter of the American Smelting and Refining Co., situated 4 miles from the mills.

Jan 1, 1930

By Glen C. Ware

The Bureau of Mines determined the factors involved in the corrosion of starting sheets used in the production of electrolytic zinc with the ultimate purpose of adapting zinc starting sheets to commercial practice . Under present practice , zinc is electrodeposited on aluminum cathodes and subsequently stripped for melting . The use of zinc instead of aluminum would eliminate the need to strip the deposit , thereby reducing the cost of handling and melting it , but zinc has not been suitable because it was too vulnerable to the corrosive attack of the electrolyte . Serious attack was found to be limited to the areas of the cathodes situated immediately above the surface of the electrolyte and to re - entrant corners . It was possible to avoid solution - level corrosion by immersing the starting sheets completely , exposing only a relatively heavy suspension member to solution - level attack . Zinc starting sheets could be made as reliable as aluminum and could be continued in residence for periods up to 39 days . Periods as long as a week were feasible under conditions similar to those found in commercial practice . A test of zirconium as a starting - sheet material showed that it promoted corrosion of the deposit to a lesser extent than aluminum and that the deposit adhered less tenaciously . These two properties lend themselves to the development of ways to strip deposits mechanically from zirconium starting sheets . Titanium was unsuitable for use as a starting - sheet material .

Jan 1, 1963

By T. F. Anstett

The Bureau of Mines estimated the potential availability of rare-earth oxides (EtEO), including yttrium, and thorium, which is also contained in the rare-earth bearing minerals monazite and bastnasite, from 38 'properties in market economy countries (MEC's). Only nine of the properties evaluated produce or would produce REO as the primary product; the others contain REO as a byproduct, chiefly from mineral sands operations recovering rutile, ilmenite, and zircon. Nearly 77% (2,578,000 mt) of the total 3,355,000 mt of recoverable RE0 evaluated is from producing properties. It is estimated that 21% (705,000 mt) of this total is from properties that could not realize a positive rate of return at the January 1984 market prices for the recovered commodities. At production capacities assumed for this evaluation, the amount of RE0 potentially available from producers ranges from an estimated 46,500 mt in 1986, to a peak of 50,900 mt in 1992, to 49,900 mt by the year 2000. Total MEG production in 1984 was estimated at 40,700 mt. Assuming demand does not increase sharply, producing properties can continue to fulfill overall REO demand through at least the end of this century.

Jan 1, 1986

By Liane L. M. Kacinuck

This U.S. Bureau of Mines publication is intended to provide mining industry representatives and regulatory authorities with a reference package dealing with studies on hydrology and underground mine subsidence. An annotated bibliography and a list of additional sources are given and represent references published prior to June 1993. Ninety-two references ware identified and 72 obtained for assessment. Annotating the references included evaluating the study methodology and summarizing the basic results. The references are also compiled based on geographic location to aid the user in identifying articles of particular interest.

Jan 1, 1994

By Edward F. Divers

This Bureau of Mines report describes a new type of scrubber (dust collector) and ventilation system built into the auger support frame (boom) of a Jeffrey 120L continuous mining machine. With this twin scrubber arrangement, one scrubber is mounted into each side of the boom. Each scrubber includes a 2,500-cfm fan, a flooded fibrous-bed scrubber panel, and a water droplet eliminator. The system was designed for minimum size and adds only a few inches to machine height. Exhaust duct design allows flexibility with various airflow configurations to suit both blowing and exhaust fare ventilation systems and brattice distances ranging up to 20 feet. Full-scale tests with exhaust ventilation were conducted at a Mine Safety and Health Administration surface facility at Bruceton, Pa., to determine the scrubbers' methane dilution capability. Several configurations of the twin scrubber-ventilation system produced striking improvements in face methane dilution when compared with conventional systems.

Jan 1, 1981

By S. M. Shelton, W. A. Calhoun

"INTRODUCTION Discovery and development of a southwestern Arkansas quicksilver district are recent history. In July 1930 4/, a specimen was discovered near the Little Missouri River in sec. 1, T. 7S. R. 26 W., which was identified as cinnabar. In the summer of 1931, Leo Yount began prospecting for cinnabar near the Little Missouri River. In the fall of that year he operated a small three-tube retort near the present Parker Hill mines and produced several flasks of quicksilver. Yount optioned a considerable block of ground containing the best showings in the Little Missouri River area, and on February 19, 1932, he and W. C. McBride, Inc., of St. Louis, Mo., formed the Southwestern Quicksilver Co., which was the largest producer in the district until operations ceased in September 1934.The Southwestern Quicksilver Co. installed a rotary furnace on Parker Hill in April 1932, which treated ore from the three principal mines Gap Ridge, Parker Hill, and Parnell Hill. In 1934 production was entirely from the Gap Ridge and Parker Hill mines. Nothing was done at Parnell Hill except a little small-scale work on a share basis.Mercury Producers, Inc., later took an option on the holdings of the Southwestern Quicksilver Co. and in June 1935 began operations. The company produced considerable quicksilver before the lease and option were surrendered in the summer of 1936. Most of the work of Mercury Producers, Inc., was on Parnell Hill, but some work was done on Parker Hill and at the Bell prospect on ground not controlled by the Southwestern Quicksilver Co."

Mar 1, 1942

By Gregory J. Chekan

The U.S. Bureau of Mines is investigating longwall panel and gate road layouts to increase coal recovery and reduce multiple-seam interactive problems. This report presents design practices for longwall mining multiple seams to provide mine planners and operators with practical guidelines for designing productive longwall mines. Key aspects of mine design that control longwall interactions are examined, including sequencing of seams, design of gate road pillars, and orientation of gate roads and longwall panels. Theories that describe stress transfer between multiple scams and the mechanics of interaction are addressed in relation to geology. Common longwall designs were further investigated using a boundary element model, MULSIM/NL. The model provided insight into relative stress transfer and distribution that occurs between longwall operations in multiple seams. Findings from the model show that (1) a longwall panel should be mined from the gob to the solid coal of an overlying mine, because the stress concentrations are lower; the approach angle should be kept under 30°; and (2) when mining in descending order, superpositioning gate roads usually produces the worst stress condition. To prevent this, the overlying isolated gate roads should be positioned from the centerline toward the headgate side of the underlying panel.

Jan 1, 1993

By Carroll W. DeKock

Thermodynamic data for selected metal sulfates were critically evaluated and compiled as part of the Bureau of Mines program to provide a scientific base for use in developing new technology and predicting the feasibility of new processes. Values for Cp°, S°, H° - H°298, -(G° - H°298)/T, ?Hf°, ?Gf°, and log Kf as a function of temperature are given in tabular form. Thermodynamic data were compiled for VOSO4, Cr2(SO4)3, MnSO4, FeSO4, Fe2(SO4)3, CoSO4, NiSO4, Cu2SO4, CuSO4, CuO-CuSO4, ZnSO4, and ZnO-2ZnSO4, together with their stable hydrates.

Jan 1, 1982

By E. K. Kleespies

The Bureau of Mines demonstrated a technique for electrowinning titanium from titanium nitride and titanium dioxide. Titanium-nickel-copper metal solutions containing 26 to 61 weight-percent titanium were prepared by electrolyzing titanium nitride in molten mixtures of potassium fluotitanate) and sodium chloride or barium chloride and depositing titanium on nickel-copper cathodes. A titanium-nickel alloy was prepared by electrolyzing titanium dioxide in an electrolyte of potassium fluotitanate) sodium fluoride) and calcium fluoride and depositing titanium on solid nickel cathodes. This alloy contained 21 weight-percent titanium and had a combined oxygen-carbon content of less than 0.1 weight-percent. A compartmented cell confined the oxide feed near the anode and inhibited oxygen contamination of the metal.

Jan 1, 1966

By E. J. Kloos

One phase of the work of the Bureau of Mines in health and safety is promoting the use of safe, satisfactory, and reliable respiratory-protective devices. To insure that such devices will be available, the Bureau has established schedules of minimum-performance requirements for the approval of self-contained breathing apparatus (1),4/ gas masks (2), supplied-air respirators (hose masks, air-line respirators, and abrasive-blasting helmets, hoods, or masks) (3), dispersoid (dust, fume, and mist) respirators (4), and nonemergency gas respirators (chemical-cartridge respirators) (5). Approval tests of self-contained breathing apparatus are conducted by Health and Safety District B; approval tests of other types of respiratory-protective devices are conducted by the Branch of Health Research. Manufacturers of respiratory-protective devices may submit their equipment to the Bureau of Mines for approval under the requirements of these schedules. If the device, when tested by the Bureau, meets the schedule requirements, a certificate of approval will be granted, which not only states that the equipment has passed the schedule requirements but also gives information about the limitations of the device. If it is found at any time that approved devices do not meet the requirements of the pertinent schedule, the Bureau may rescind approval.

Jan 1, 1959

By A. A. Berk

In the course of a study of the formation of external deposits on tubes in water-tube boilers it became desirable to determine the sulfur dioxide (SO2) and sulfur trioxide (SO3) in the Due gases. Determinations made by the A.S.M.E. method for SO2 and SO3 in gaseous products of combustion did not give accurate results. It was found that minute quantities of copper, present in the flue gases from the coal in use, caused oxidation of sulfite in the absorption bottle and that the carbon dioxide (CO2) in the flue gases caused high values for SO2. The A.S.M.E. test procedure was revised to prevent oxidation of sulfite in the absorption bottle and to allow for the effect of CO2; subsequent analyses of flue gases produced reliable results. The revised procedure is described.

Jan 1, 1950

By W. W. Adams

Because of insufficient funds for printing, the Bureau of Mines was unable to publish its annual bulletin covering accidents at metal mines in the United States for the year 1933. A brief mimeographed summary of the principal statistical data for that year was released to the public late in 1934. Since then reports for 1934 have been received from the mining companies, and in order to avoid further delay in releasing this information to the mining industry and others interested in the prevention of accidents in mining, statistics for both years are presented in this publication with a minimum of interpretation and comment. The fatal-accident rate for the metal and nonmetallic mines (excluding coal mines) of the United States was more favorable in 1933 than in any previous year since 1911, the first year for which the Bureau of Mines obtained reports from the operators. Further progress was made in 1934, when the fatality rate was even lower than that of 1933. On the other hand, the nonfatal-accident rate, which had reached its lowest level in 1932, increased in 1933 and increased further in 1934, although not to such an extent as to prevent the rate for either of those 2 years from being better than that for any year previous to r1931.

Jan 1, 1936

By G. E. McElory

"INTRODUCTION The subject of mine and tunnel ventilation has two broad aspects - (1) what atmospheric conditions to obtain in underground openings and (2) how to maintain the desired conditions efficiently. The first relates primarily to quantity requirements of ventilating systems, whereas the second relates more particularly to pressure requirements. Both, therefore, determine power requirements, which is the deciding factor in any system of mine or tunnel ventilation.Both divisions of the subject have received considerable attention from the Bureau of Mines since its inception in 1910 in the form of research, service, and correlation and dissemination of information. Numerous papers on various Phases of the subject have been published, of which a selected list, numbered and arranged in chronological order by type of publication, will be found at the end of this Paper. One of these, Technical Paper 705 (25) 2/ gives a complete bibliography of Bureau of Mines publications dealing with health and safety. As indicated by the selected list of publications accompanying this paper, the health and safety aspects have received most of the attention devoted to this work, chiefly because these have been dominant factors in Bureau policy, but partly because these aspects lend themselves to laboratory research and small-scale field studies. Although considerable attention has also been devoted to the engineering aspects of mine and tunnel ventilation, there has been, in the opinion of the author, who has been engaged on this phase almost continuously for the last 30 years, only sporadic recognition of the vital effect this phase of the work could have on improving health and safety conditions. As a matter of fact, ventilation activities have constituted but a very minor part of the total work of the Bureau of Mines, as, except for a few years in the nineteen twenties, there have been only a few short intervals when more than two or three men were engaged in field work and a similar number in laboratory research directly related to mine gases or mine air."

Mar 1, 1950

By Edmund S. Leaver

The selection of a process for treating a gold ore is governed primarily by the characteristics of the ore under consideration. The form in which the gold occurs, its mode of association with other minerals, and the size and surface condition of the gold particles are important factors which influence materially the choice of procedure for recovering gold. A knowledge of these characteristics may be obtained by microscopic and chemical methods combined with experimental testing. Cyanidation and amalgamation, either alone or in conjunction with flotation and gravity methods, are peculiarly adapted to the treatment of gold ores, especially those of relatively low grade. Gold alloys readily with mercury provided both present clean surfaces. The presence of oils and grease, antimony and arsenic minerals, or soluble sulphides have a harmful effect. Very small, flaky particles of gold frequently are lost in amalgamation because of noncontact with the mercury. Fine gold in pyrite, or gold having rusty or contaminated surfaces, is often lost for the same reason. Grinding or some form of abrasion sometimes removes surface films of iron oxide or substances of a similar nature, and alkalies or other chemicals are used to remove grease. Gold is readily soluble in cyanide solution, and this method of treatment is particularly effective in the recovery of gold from the tailings resulting from other types of concen¬tration procedure. Cyanide solutions must contact the gold to insure recovery, and the porosity of the ore treated and the fineness of grinding required are important governing factors. The use of lime in cyanidation is necessary to protect the cyanide, to precipitate undesirable substances, and to settle slimes. Certain substances in ores are harmful in cyanidation; chief among them are those that combine with cyanide, forming cyanides, and carbon which precipitates gold from solution. Arsenic and antimony are also harmful if present in sufficient quantity. These and other difficulties encountered in cyaniding certain ores often are overcome by roasting prior to leaching. Zinc dust is used almost universally for precipitating precious metals from cyanide solutions. The refining and melting of the product may be accomplished by oxidizing the zinc before melting it in graphite pots with fluxes, although sulphuric acid is now used largely to remove the zinc before melting. Straight cyanidaticn practice is being replaced by flotation as a major process, followed by cyanide leaching of the tailings, but amalgamation is still needed as a primary process for the recovery of coarse gold before either flotation or cyanidation.

Jan 1, 1935

By Edmund S. Leaver

The selection of a process for treating a gold ore is governed primarily by the characteristics of the ore under consideration. The form in which the gold occurs, its mode of association with other minerals, and the size and surface condition of the gold particles are important factors which influence materially the choice of procedure for recovering gold. A knowledge of these characteristics may be obtained by microscopic and chemical methods combined with experimental testing. Cyanidation and amalgamation, either alone or in conjunction with flotation and gravity methods, are peculiarly adapted to the treatment of gold ores, especially those of relatively low grade. Gold alloys readily with mercury provided both present clean surfaces. The presence of oils and grease, antimony and arsenic minerals, or soluble sulphides have a harmful effect. Very small, flaky particles of gold frequently are lost in amalgamation because of noncontact with the mercury. Fine gold in pyrite, or gold having rusty or contaminated surfaces, is often lost for the same reason. Grinding or some form of abrasion sometimes removes surface films of iron oxide or substances of a similar nature, and alkalies or other chemicals are used to remove grease. Gold is readily soluble in cyanide solution, and this method of treatment is particularly effective in the recovery of gold from the tailings resulting from other types of concentration procedure. Cyanide solutions must contact the gold to insure recovery, and the porosity of the ore treated and the fineness of grinding required are important governing factors. The use of lime in cyanidation is necessary to protect the cyanide, to precipitate undesirable substances, and to settle slimes. Certain substances in ores are harmful in cyanidation; chief among them are those that combine with cyanide, forming cyanides, and carbon which precipitates gold from solution. Arsenic and antimony are also harmful if present in sufficient quantity. These and other difficulties encountered in cyaniding certain ores often are overcome by roasting prior to leaching. Zinc dust is used almost universally for precipitating precious metals from cyanide solutions. The refining and melting of the product may be accomplished by oxidizing the zinc before melting it in graphite pots with fluxes, although sulphuric acid is now used largely to remove the zinc before melting. Straight cyanidation practice is being replaced by flotation as a major process, followed by cyanide leaching of the tailings, but amalgamation is still needed as a primary process for the recovery of coarse gold before either flotation or cyanidation.

Jan 1, 1935

By J. J. Shields

The Bureau of Mines observed two different types of longwall mining; the advancing longwall method and the retreating longwall method at seven bituminous coal mines located in five of the coal producing states. In two mines using the advancing face method, the coal faces were abandoned because of roof failures and poor production. In the other five mines using the retreating method, roof control was good as was production. The success of longwall mining depends on good roof control and good production. The use of self-advancing hydraulic roof supports, such as Westfalia, Dowty, and Wanheim props along with Westfalia coal planers and the Anderton and Eickhoff shearer-loaders have been a factor in recent successes.

Jan 1, 1967

This publication summarizes the research (in-house and contract projects) programmed by the Bureau of Mines for fiscal year 1984 (October 1, 1983-September 30, 1984) under its Health and Safety Technology Program. The objective of these projects is to provide an ordered and sequenced advance toward the Bureau's overall goal of providing the systems technology required to create a more healthful and safer working environment for the Nation's mining and minerals processing workers.

Jan 1, 1983

By E. G. Davis, H. P. LeVan, L. S. Smith

Leaching of a Georgia umber ore when using both ferrous sulfate and pickle liquor was studied in the laboratory . The ferrous sulfate content of the leach solution was the major factor affecting the extraction of manganese from the ore . Time , temperature , and the sulfuric acid content of the leach solutions had relatively little effect on leaching of manganese from the ore ; however , these factors did affect the amount of iron extracted from the umber and/or precipitated from solution . Simulated countercurrent leaching of the ore with pickle liquor containing 130 gpl (grams per liter ) ferrous sulfate ( 48 gpl ferrous iron ) produced a pregnant solution having 16 gpl manganese and 41 gpl iron . Filtration tests of the leach slurries indicated that separating the leach solution and solids by vacuum filtration was impractical , whereas pressure filtration was feasible when the cake thickness was limited to about three- fourths of an inch . Fired pellets of the filter cake yielded a firm , hard product analyzing 56 percent iron and less than 0.1 percent sulfur .

Jan 1, 1964

By Dennis A. Hansen

The solubility of anhydrous aluminum chloride in solutions of titanium tetrachloride and vanadium tetrachloride was determined as part of a re-search project-by the Bureau of Mines to make a homogeneous alloy sponge of titanium, vanadium, and aluminum. Solubility curves were established using an autoclave at 75°, 100°, 125°, and 150° C. The solubility of AJC13 in TiC14 is 0.2 wt pct at 75° C; it increases to 18.3 wt pct at 150° C. The data concur with data from earlier researchers of this bi-nary system for 75° to 125° C. For the VC14-AlC13 binary system the solubility of AlC13 is 0.1 wt pct at 75° C, increasing to 1.6 wt pct at 150° C. For the TiC14-AlClrVC14 ternary system the solubility of AlC13 decreases from the values found with a pure TiC14-AlC13 system to the lower values found with a pure VC14-AlC13 system at the respective temperatures.

Jan 1, 1986