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By Eduard Stefanescu, James M. Mwase, Egon Sehner, Stoyan Gaydardzhiev

"The study is focused on investigating the production of synthetic rutile of 95% purity or higher from a Norwegian ilmenite ore concentrate. This was to be achieved using a sequential process involving oxidative-reductive roasting at 975°C, followed by magnetic separation to further concentrate the sample and finally leaching with 20% HCl to remove mostly Fe-based impurities leaving behind synthetic rutile. The key process parameters considered were roasting time (1 and 2 hrs), leaching temperature (100, 125 and 145°C), pulp density (15 and 25wt%) and leaching time (3 and 6 hrs). The option of directly leaching the concentrate without pre-treatment was also evaluated. Test work was conducted using samples screened to a size fraction of 105-212 µm. Samples were leached in a 1 L glass autoclave. The reactor was hermetically sealed and thus the resulting pressure was not controlled but was dependent on the process temperature. The product from leaching was calcined and analysed via XRD and SEM to determine the purity of the product. The magnetic separation step was found to be ineffective and discontinued early in the study. Thus far a product with 97% synthetic rutile purity as analysed by SEM has been produced by directly leaching the concentrate at a temperature of 145°C, pulp density of 25wt% and leaching time of 6 hrs.INTRODUCTION The study investigates the use of a process route comprising oxidative-reductive roasting, followed by magnetic separation and then hydrochloric acid leaching and calcination to produce synthetic rutile from ilmenite concentrate. The grade of synthetic rutile produced should be suitable for chlorination to produce pigment grade TiO2. Hence the proposed process should produce a product consisting of no less than 95% synthetic rutile. Additionally, the product should have no more than 1.5wt% combined content of CaO and MgO (Zhang et al., 2011) as they tend to form high-boiling-point chloride leading to the malfunctioning of fluidized bed chlorinator (Cardarelli, 2008). Finally the product should have no more than 2.1wt% of Fe2O3."

Jan 1, 2018

By N. Schreithofer

Varying flow regimes, particle populations and consequently different types of bubble-particle interactions characterize the different zones of a flotation cell. The understanding of the role of the different zones of turbulent intensity on the particle-bubble interactions is of primary importance to optimization and scale-up of flotation processes and machinery. In order to study particle-bubble interaction in turbulent flow a completely new approach was taken. A laboratory scale stationary turbulence device was developed and built. The set-up allows the observation of particle-bubble interactions in various turbulence intensities, particle and bubble sizes and surfactant concentrations. The experimental set-up consists of a transparent, specially designed tank in which liquid flows between carefully designed and placed obstacles that create different turbulent flow fields. Bubble-particle aggregates are introduced into this turbulent zone. The behaviour of the aggregates, such as attachment /detachment of particles to/from air bubbles is recorded by a High Speed Imaging (HSI) system (5400 fps). The images are then analysed and the dependence of attachment/detachment process is described as a function of turbulent intensity in different conditions for different surfactant concentrations. This paper introduces this method to study particle-bubble interactions in turbulent flow and correlation to Computational Fluid Dynamics (CFD) simulation. CFD modelling is validated for two and three phase systems; liquid-gas with liquid and solid tracers respectively. The CFD simulations using the RANS k-S turbulence model showed good correlation to the experimental data and the experimental method is a promising tool for investigation of particle-bubble interaction in turbulent flow.

Jan 1, 2014

By H. Matsuoka, M. Kawata, K. Haga, K. Mitsuhashi, C. Tokoro, A. Shibayama, R. Kawarabuki

"The mineral surface characteristic is important for the flotation because it affects the flotation behavior of the mineral. Conventionally, in the flotation process for Cu sulphide ores, the degree of ore floatabilities varies depending on the mineral phase such as chalcopyrite, bornite, or chalcocite. Therefore, mineral surfaces are treated with activators and depressants to control the floatability of target minerals and obtain high recovery performance. There are lots of flotation reagents which have many effects on ores depending on ore characteristics and conditioning methods. For example, sodium hydrosulphide (NaHS) as activator is known to have the effect of resulfurizing and activating oxidized surface of chalcocite and bornite. On the other hand, NaHS is reported to depress chalcopyrite floatability. In this study, the evaluation of mineral surfaces was conducted to predict flotation behavior. Activation of Cu minerals (chalcocite, bornite, and chalcopyrite) by NaHS was experimented. The three Cu minerals were treated in two steps. Firstly, they were oxidized in the drying oven. Secondly, they were treated with NaHS solution. After each treatment step, each mineral was measured by contact angle apparatus then analyzed by X-ray photoelectron spectroscopy (XPS). The results of surface characteristics after oxidation and NaHS treatment were utilized to accomplish the study’s objective. INTRODUCTIONCopper sulfide minerals such as chalcocite (Cu2S), bornite (Cu5FeS4), chalcopyrite (CuFeS2) are well-known abundant copper-containing minerals. Generally, these minerals are recovered and concentrated via collector flotation. In flotation, the wettability of the mineral surface is an important factor in its recovery. When the surface is hydrophobic, the mineral has high floatability and when the surface is hydrophilic, it has low floatability. Usually, Cu sulfide minerals have high floatability. However when their surfaces are oxidized, their floatability becomes lower in flotation. In this case of surface oxidation occurrence, activators are added before flotation to modify the surface property of the Cu sulfide minerals so that they can be floated at a certain flotation condition. Sodium hydrosulfide, NaHS, is known as one of the activators. Zhao et al. (2018) reported that NaHS is often used as sulfurizer for oxidized sulfide minerals (Becker et al., 2014, Clark et al., 2000, Newell et al., 2006, 2007, Newell and Bradshaw, 2007). Although the floatability of Cu sulfide minerals was raised by adding NaHS generally, the results of this flotation study showed that the flotation behaviors of mixed chalcocite, bornite, and chalcopyrite were different. Therefore, it was considered that NaHS works differently for each mineral."

Jan 1, 2018

The introduction and subsequent ascendancy of autogenous and semi-autogenous milling for comminution circuits has undoubtedly lead to many economic advantages. From a process viewpoint, however, at least one downside has been the sensitivity of these machines to process input variations. Foremost among these is ore competence, though feed size comes a close second. This sensitivity is due to the reliance of ag/sag mills on the feed ore for their grinding media competence and size. Autogenous (ag) mills are the most sensitive in this respect with semi-autogenous (sag) mills being increasingly less so as the ball charge is increased. Increasingly designers and operators are recognising the importance of feed size and the benefits of manipulating it to improve performance. This has been achieved by installing additional crushing/screening capacity ahead of the ag/sag, better operation of the primary crusher, better control of segregation cased by stockpiles and bins and by changing blast design/practices to modify the ROM size distribution. This paper describes the influence of feed size distribution on ag/sag mill performance with reference to a range of plant data. It particularly concentrates on how changing blasting practice to modify ag/sag feed size can have a considerable overall benefit.

Jan 1, 2003

By G. Y. Zhou

During Zijinshan copper heap bioleaching, pyrite was leached in plenty resulting in high ferric concentration in solution. It has affected bioleaching and extraction processing greatly. It results much acid and iron in solution and bad effect to extraction processing. The paper studied the influence factors in the course of pyrite leaching and ferric ion chemical oxidation, especially studied the redox potential for copper bioleaching so as to find key factors affecting the dissolution difference between chalcocite and pyrite. The results show that the redox potential is important factor. Copper and pyrite leaching rates are 95% and 11% respectively and there is great dissolution difference between them at redox potential 700 mV (SHE). During pyrite bioleaching, the indirect action of bacteria gives priority to bioleaching cooperating with the direct attack of microbial cells attached to the mineral surface. Redox potential is determined by ratio of ferric and ferrous, ferric in solution was supplied by the way of oxidation of T. f bacteria, sufficient bacteria concentration and active character were two vial factors of controlling redox potential. It is indicated that copper can be selectively bioleached during copper bioleaching by controlling redox potential of bioleaching. The conclusion will provide theoretic foundation on balance of acid and iron during bioleaching for copper of higher S/Cu ratio. The experinment proved that bacteria activation was decreased on condition of both low pH value and intermittent aeratation during bioleaching. It resulted that the oxidation velocity of ferrous ion was decreased and redox potential was controlled. The dissolution of pyrite was depressed. It would be possible to actualize selective leaching of secondary sulfide copper ore during bioleaching process.

Jan 1, 2014

By P. K. Sen, Mrinal K. Ghose

Tailing slurry is usually abrasive and possesses high viscosity. This paper examines the existing iron ore beneficiation process and focuses on some of the key environmental issues related to the disposal of tailings. It identifies that almost 32% of the iron ore extracted ends up as tailings and they are usually disposed in slurry form in tailing ponds. By the year 2000, 27 Mt of iron ore tailings were generated in India, which has become one of the biggest waste handling problems to the industry. Characteristics of the tailings vary widely. So the physical nature of tailings cannot be considered separately in isolation without considering the mill effluent from the beneficiation plant. In the present investigation, studies were carried out in three iron ore mines in India to evaluate the characteristics of tailings from the beneficiation plant. The tailing samples were collected from different locations during a time period of one year and analyzed. The results will be discussed and the characteristics of the tailings have been evaluated. The disposal system of tailings at the three mines was evaluated. The research on the settling characteristics of tailings indicates that the area provided in the existing tailing ponds in India is much more than that of the experimental results. This paper concludes that sedimentation tests are essential to design appropriate tailings pond with respect to size. In the proposed scheme it is suggested that an additional unit process, i.e. sedimentation tank be added to the process before the disposal of tailings to the tailing pond.

Jan 1, 2003

By William Skinner, Ishmael Quaicoe, Jonas Addai-Mensah, Ataollah Nosrati

To date, intractable ore specific operational challenges such as poor heap geotechnical stability, permeability and high acid consumption rates associated with low grade (~1 wt%) nickel (Ni) laterites still makes the adoption of heap leaching processing unattractive. This paper presents some highlights of drum agglomeration, column leaching and characterization studies undertaken to foster the understanding and knowledge of some of the desirable product attributes of -2 mm and -15 mm, low grade saprolitic (SAP) and goethitic (G) Ni laterite feed ores and their blends (SAP/G). For column leaching, 5-40 mm agglomerate beds were continuously irrigated with 200 g/dm3 H2SO4 solution at 8.5 dm3/m2/h rate over 100 days. Ni, Co, Fe, Al and Mn extraction rates, free acid concentration, agglomerate bed slump and structural changes were determined as a function of time. The results show that at equivalent feed masses, except -15 mm G which displayed slower, pseudo-layering based behaviour, all the feeds (single and blends) displayed coalescence controlled agglomeration behaviour at varying binder dosages. Whilst the agglomerate compressive strength of the G ore was markedly higher than that of SAP ore, those of the blends were substantially similar. At fixed column leaching conditions, the Ni/Co extractions and acid consumption were higher for SAP ore whilst the agglomerate bed slump was lower than those for G ore. The bed of agglomerates produced from -2 mm G/-15 mm SAP blend was more stable than that for the -2 mm G/-2 mm SAP blend agglomerate, the latter experiencing blockage within 24 h of acid irrigation due to agglomerates breakdown. The Ni/Co extractions and acid consumption rates obtained for agglomerates of -15 mm G/-2 mm SAP blend were lower than expected based on the ratios of the SAP and G ores within the blend composition. The findings suggest that judicious saprolitic and limonitic ores’ blending could reduce acid consumption rate, improve the agglomerate bed robustness and enhance bed percolation behaviour under prolonged acid irrigation periods during heap leaching of lateritic ores of variable mineralogy.

Jan 1, 2014

By M. M. Moghaddam

Charge motion is of prime importance in the efficiency of comminution in tumbling mills. Since direct observation of charge shape and its motion in industrial mill are not possible, a combination of analytical and physical studies was used to determine charge trajectory. Software packages, which predict charge motion such as the GMT (Grinding Media Trajectory) only consider the outermost layer of charge (single ball) and ignore the interactions of grinding elements. In this research, the measured charge trajectory in a 1m-diameter mill with the transparent end, called model mill, was compared with that of the GMT. Four types of polyurethane rings were accurately machined to scale down the liners arrangements at two industrial mills. To explore various charge shapes and trajectories, the model mill was operated at 55, 70 and 85% of critical speed for five levels of mill filling (10, 15, 20, 25 and 30% by volume). The angular displacement of the toe, toe departure, shoulder and charge impact point were determined from the photographs taken from the model mill. New relationships to predict charge shape and charge impact points were introduced to modify the GMT results. The relationships were validated by the model mill using the new liner of the Sarcheshmeh copper complex SAG mill. The relative error of prediction was found to be 1.1%. The results indicated that when the lifter face angle increased from 7 to 30º, the distance between the charge impact point and the toe decreased from 52 to 31º for 25% filling. This meant increasing the probability of charge impacting the toe not the liner which favoured more efficient comminution practice. After converting AG mills to SAG mills on account of liner profile change, 31% increase in throughput (from 419 to 548 t/h) in addition to 4% decrease in the product size (from 516 to 496 µm) were realized which was a significant contribution in the plant performance improvement.

Sep 1, 2012

By Behzad Vaziri Hassas, Firat Karakas, Mehmet Celik, Onur Guven

Since dewatering is a costly process, removal of moisture from relatively fine size lignites is an important industrial problem. As the lignite gets finer, the presence of micropores and relatively low hydrophobic nature of lignite lead to trapping of large quantities of water in the coal matrix. Lignites used in power stations need to be dried to a certain degree of humidity before it is transferred to the combustion chamber. It is generally wise to dewater coal as much as possible by physical means before it is dried. However, dewatering cost in some cases may be prohibitive. Thus, sometimes removal of even little percent moisture may be of great help in such operations. Surfactants have been used to increase the efficiency of coal dewatering. It is crucial to select appropriate type and amount of surfactants in order to get higher efficiency. Since the hydrophobic characteristic of coals increases with increasing the coal rank, dewatering of bituminous and anthracite can be accomplished using low HLB surfactants (Oily), however, these surfactants are not efficient in the case of low rank coals like lignites and brown coals. It is suggested that adsorption of low HLB surfactants on high rank coals is governed by Acid-Base interactions rather than electrostatic and van der Waals forces. Since this characteristic in lignites is not strong enough, low HLB surfactants could not be effectively adsorbed on low rank coals to make surface more hydrophobic. In this paper, a special set-up has been designed to study the effect of high HLB surfactants on dewatering of fine lignite particles. It is shown that high HLB surfactants function more efficiently on low rank coals than low HLB ones.

Jan 1, 2014

By Alan Bax, John D. Lewins

"Platinum Australia Limited (“PLA”) is currently undertaking a Feasibility Study into the development of the Panton Platinum Palladium Project located in the Kimberley region of Western Australia. The Panton Intrusive is a layered, differentiated mafic to ultramafic structurally complex body that has undergone numerous folding and faulting events. This has resulted in a southwesterly plunging synclinal structure some 10 kilometres in length and 3 kilometres wide.High grade PGM mineralisation is hosted within a number of stratiform chromitite reefs within the ultramafic sequence. The focus of the Feasibility Study is on the Top Reef which is situated approximately 150 metres below the mafic/ultramafic interface. The average true width of this reef is approximately 1.2 metres and the reef has a defined resource is 10.1 million tonnes at an average grade of 6.1 g/t PGM + Au.The Palladium to Platinum ratio of the Top Reef is approximately 1.15:1 and the reef also contains an average of 0.4 g/t Au and 0.3 g/t other PGM’s. The Panton ore is considered refractory in nature and standard flotation techniques achieve a PGM + Au recovery of less than 65% with a concentrate grade of less than 100 g/t PGM + Au. As part of the Feasibility Study Platinum Australia in conjunction with their major shareholder Lonmin Plc developed a new metallurgical process which has achieved an overall PGM + Au recovery of approximately 80% into a high grade PGM concentrate which is suitable for feeding direct to a PGM refinery.THE PANTON PROCESSThe Panton Process incorporates a two-stage Milling and Flotation circuit with no cleaning stages to produce a low grade, high recovery flotation concentrate. Typically the concentrate mass constitutes 25% of the feed and has a PGM + Au grade of 25 g/t.This low-grade concentrate is subjected to calcination in a rotary kiln or fluid bed at a temperature of approximately 400 0C for a period of 60 minutes. This step is designed to render the platinum minerals soluble in cyanide and both the temperature and the duration of calcination are critical to the efficiency of the leaching process."

Jan 1, 2003

By A. Usov

The studies carried out by the Russian researchers and those carried out jointly within some contracts with scientific organizations and companies of other countries, show that the electric pulse disintegration of materials (ED), proposed and investigated in detail in Russia (Kalyatsky, et al, 1980; Usov et al, 1987; Semkin et al, 1995; Usov and Tsukerman, 2000; Kurets et al, 2002) has been widely recognized and developed abroad (Andres, 1995; Inoue et al, 2000; Biela et al, 2008). The Russian and international journals and the proceedings of the conferences dealing with the electric pulse disintegration pay great attention to the principal principals of selective disintegration of materials. There is no, however, any information concerning both the technical means developed to implement the technique and the assessment of their performance, which would be necessary in objective assessment of the industrial use of the technology. The results of long-term studies of the technique and technologies of electric pulse disaggregation by research institutes such as Research Institute of High Voltages (Tomsk), Kola Science Centre of RAS (Apatity), Institute "Mekhanobr"(S.Pertersburg) described. Exploratory stands and technological installations are developed to carry out pilot tests and operations under production conditions. Basic circuits and classification of technical means electric pulse disintegration of the materials are proposed, the analysis of transportation schemes and classification of the material in the disintegration apparatus are given, construction of chambers for continuous stadial disintegration of ores and materials are presented. The features and technological efficiency of electric pulse disintegration of various types of ores, and the spheres of effective use of the method have been determined. Keywords: electropulse disintegration, disintegration machines, chambers of comminution, stadial comminution.

Sep 1, 2012

By S. Banisi, A. Ghasemi, S. Zare, F. Ghorbani, E. Nematollahi

"Comminution is the most energy intensive operation which constitutes the major portion of operating and capital costs of the mineral processing plants. Working at the maximum operating capacity of comminution equipment plays a significant role in the efficiency of the circuit. Appropriate design of cone crusher feed box could result in the choked crushing which is known as a vital factor in achieving target performance. In this research, the non-uniform cone crusher feeding at the Sarcheshmeh copper complex was studied and appropriate measures were taken to solve the problem. The problem resulted in non-uniform and high wear rate of crusher liners and high fluctuations of power draw. In recent decades, the discrete element method (DEM) has been applied successfully to study the effect of different factors on the behavior of particles flow. In this work, various designs for feed box were tested using an in-house developed DEM software called KMPCDEM©. The best feed box design obtained from the simulations was selected, constructed and installed in of the cone crushers. The new feed box design resulted in more uniform feed distribution on the distributor plate of crusher indicated by a reduction of the standard deviation of power draw measurements from 13 to 3 kWh. The better control of the crusher, 49% increase in the crusher throughput and finer and narrower product size distribution were the main outcomes of the installation of the new feed box. Furthermore, the wear rate on mantle and liners of crusher not only decreased but it also became uniform.INTRODUCTION Comminution is the most energy intensive operation which constitutes the major portion of operating and capital costs of the mineral processing plants. Reaching the maximum operating capacity in comminution equipment is a key sign of approaching the nominal productivity of the process. Due to the effect of crusher efficiency on the downstream circuit performance, optimization of the crushing circuits has received considerable attention (Herbst, & Potapov, 2004; Quist, & Evertsson, 2010; Li, Huiqi, McDowell, Glenn R, Lowndes and Ian, 2014; Cleary, Sinnott, Morrison, Cummins, & Delaney, 2017). Improving the performance of crushing circuits not only decreases the capital and operating costs but also increases the efficiency of downstream grinding circuits (Jacobson, Janssen, & Urbinatti, 2010). In cone crushers particles can be subjected to two different modes of compressive breakage; single particle breakage (free feeding) and inter-particle breakage (choked feeding). The maximum efficiency of the cone crusher directly depends on the type of feeding arrangement (Operation Manual, 1977). An appropriate feeding must lead to choked feeding the cone crusher. If the rate and method of feeding the crushers are correctly be executed, the maximum efficiency of the crushers could be available (Jacobson et al., 2010)."

Jan 1, 2018

By Sanggono Adisasmito

"The quality of the higher education in Indonesia is being improved by implementing a program financed by the World Bank under a project named QUE (Quality for Undergraduate Education). The investments are provided to selected study programs through a competitive selection process. The grant finances staff development, the purchase of equipments, textbooks, consumables, technical assistance, and incentives for outstanding faculties such as teaching grants, project grants, lecture note awards, and educational policy studies. These additional investments are provided to produce chemical engineering graduates that will compete beyond the national market.Chemical Engineering Department of Institut Teknologi Bandung in Indonesia has been selected to receive the QUE grant beginning the year 2000 and ending the year 2004. The department is actively involved in the mineral processing issues, particularly in the aspects of energy supply and the environmental protection. The activities are distributed in different laboratories and areas of expertise, such as: thermodynamics and utility systems, process equipment, chemical reaction and catalysis, microbiology and bioprocess engineering, process control, ceramics, as well as polymer and membrane technology. The main objectives of the QUE project are to improve the undergraduate program in the following aspects: Relevance, Academic atmosphere, Institutional management and commitment, Sustainability, as well as Efficiency and productivity, or abbreviated as RAISE. At the end of every fiscal year, the progress of the program is evaluated to measure the effectiveness of the project.The achievement of the QUE project objectives were assessed using performance indicators developed during the program design. There are six indicators to measure the performance of the individual program of study, such as: (1) Admission Test score, (2) average students' Grade Point Average (GPA), (3) average graduates' length of study, (4) graduates' waiting time before getting first job, (5) Test of English as Foreign Language (TOEFL) score, (6) Graduate Record Examination (GRE) score. Essentially, the RAISE evaluation criteria will be used to perform three main functions, such as (1) to measure the achievement through the six quantitative performance indicators, (2) to support the progress of evaluation and reporting throughout the implementation of the program, (3) to provide a universal framework for qualitative evaluation."

Jan 1, 2003

By Jim Petrie, Mary Stewart, Damien Giurco

This paper describes a generic approach to analysing the environmental and economic performance of a global mineral/metal value chain, with the express view of improving the quality of prospective decision-making within the industry in order to ensure more sustainable outcomes. The starting point for this analysis is the development of a global stocks flows and transformations model, for the metal of interest. Any aspect of the value chain, e.g. “metals refining, “goods manufacture”, “use and disposal”, can be assessed, either relative to other stages in the value chain, or in more detail by focusing on the technologies used within that stage. The use of this model as a decision support tool is explored here for the case of copper. Both primary and secondary production routes are enumerated, covering a range of processes, for seven distinct geographic regions round the globe. The value of the modelling approach is explored for different energy mixes. In particular, the case study examines the impact of increased recycling on the (re) distribution of global and regional environmental impacts for technologies-in-place in these different regions.

Jan 1, 2003

Certainly, one of the core processes for the recovery of fine magnetic susceptible iron ore particles, mainly hematite iron ores, is the wet high intensity magnetic separation or WHIMS. This paper outlines a variety of recent developments and innovative process designs in the JONES® type WHIMS. It highlights the latest examples of flow sheets in terms of the diversity of combined rougher, scavenger, cleaner stages and adds to this the new more advanced JONES® type WHIMS equipment technologies like the HIGH FLOW ? HF, the QUATTRO ? Q and the SPLITT OPERATION ? SP. As a result of the increase of the capacity and magnetic intensity, the specific production cost could be decreased. The high worldwide acceptance for this continuous development testifies for the success and state of the art technology.

Sep 1, 2012

By Chris A. Fleming

"The ability to recover cyanide from gold plant tailings has been known almost as long as the cyanidation process has been practiced, but there has been little incentive to process tailings in this way in the past. With the development of technologies that make it possible to recover and recycle free or complexed cyanide directly from gold plant slurry tailings, which indicates, on paper at least, significant cost savings compared to cyanide destruction, coupled with the introduction of legislation to seriously limit the discharge of cyanide to the environment in most gold-producing regions of the world, many companies are evaluating the cyanide-recovery alternative.There is arguably an even more compelling reason for mining companies to consider cyanide recycling. With the growing storm of negative public opinion that the use of cyanide in the mining industry is attracting - following several highly publicized spills over the last couple of years - the time has come for the gold industry to demonstrate environmental diligence and stewardship in the use of this commodity that is so vital for their industry. There is no doubt that the widespread implementation of cyanide recycling will reduce the impact of the cyanidation process on the environment, both by reducing the risk of spills (with less cyanide being transported from manufacturing plants to gold mines), and by reducing the loading of toxic and nontoxic metals and ions in the tailings.This paper briefly discusses the pros and cons of the different processes that are available for the treatment of gold plant tailings to regenerate and recovery cyanide for recycling, and presents a techno-economic argument for the incorporation of this technology into many gold plant flowsheets today."

Jan 1, 2003

Three high-grade limestone ores (CaO content over than 53 %) with different geological origin have been characterized for the synthesis of aragonite precipitated calcium carbonate. Limestone ores examined in this study showed different crystal particle size that cause difference in disintegration degree and surface area of the synthesized slaked limes. The limestone ore with smaller crystal particle size showed higher disintegration degree and also yielded slaked lime with smaller surface area, which is good for the synthesis of aragonite precipitated calcium carbonate. The synthesis of aragonite PCC using the limestone with a small crystal particle size was yielded needle-shaped aragonite with the aspect ratio of about 14. Keywords: limestone, lime, slaked lime, precipitated calcium carbonate, aragonite, accelerated carbonation

Sep 1, 2012

By V. V. Musaev, A. M. Klyushnikov, R. R. Galimov

"A study was made of chemical and material compositions of the oxidized gold-bearing ore of the Kochkovskoe deposit. It was demonstrated that examined ore consisted mainly of quartz, carbonate and feldspar with a gold content of 2.2 g/t and a silver content of 6.1 g/t. By means of agitation leaching tests it was founded that about 79-80 % of gold can be extracted from ore using cyanide leaching solutions. The achieved high-speed dissolution rate of gold was due to its presence in a finely dispersed state (less than 2.73 µm), which was confirmed by the research of Uralmekhanobr. It was proposed that the ore can be processed by heap leaching process using cyanide leach solutions. Technological studies on the modeling of the heap leaching process were initially carried out in percolators with a capacity of 5 kg on agglomerated ore. It was preliminary established that agglomeration should be carried out at a cement consumption of 12-16 kg/t, with the moisture content in pellets reaching up to 10-12 %. The best percolation leaching results can be obtained with ore crushed to the size of -20 mm. The maximum extraction of gold to the solution was 79-80 % while the L:S ratio reached 1.2-1.4:1.In cooperation with the research center of OJSC ""Berezovsky mine"" a semi-industrial heap leaching test was accomplished. The result of a test performed was an extraction of 78.5 % of Au and 21 % of Ag from ore to a pregnant solution. This extraction degree was achieved at a L:S ratio 0.9: 1. On the ground of results obtained, a technical regulation was developed for design of the heap leaching plant with the capacity of 500 thousand tons of ore per year.INTRODUCTION The ore of the Kochkovskoe deposit represents an important reserve of gold in the Zabaikal region. Of the upmost interest are oxidized ores, the processing of which can be carried out by heap leaching (HL) with cyanide solutions. The purpose of this work was to study the composition and to develop a technology for heap leaching of oxidized ore."

Jan 1, 2018

By Kr. J. Dedelyanova

Selective flocculation of iron minerals could improve the economics of high intensity magnetic separation as concomitant process. When the minerals are finely disseminated is necessary a finer grinding to be applied which generates a lot of slimes. The HIMS is not enough efficient for particles below 20 microns ? territory where the selective flocculation is already well known industrial practice, so the combination of these two methods of beneficiation can bring a higher grade at high recovery to be achieved. The dynamics and selectivity of the precipitation process is studied in batch tests with flocculant starch and dispersants sodium silicate and sodium hexametaphosphate. The influence of preliminary conditioning with nitrogen acid at pH 2 before flocculation is also investigated. Flowsheet including these two methods is tested and the distribution of iron is shown.

Jan 1, 2014

By I. V. Shadrunova

Annually it is formed more than 95 Mt of clinkers in iron and steel industry of Russia, including 79 Mt of clinkers in blast-furnace, steelmaking, foundry and ferroalloy productions. Complex development of clinkers will provide not only extraction of valuable components, but also preservation of ecosystems. Processing of solid slags is realized, as a rule, in a cold condition by mechanical methods only including stage-by-stage crushing of slag on devices, working on principles of compression and shift (jaw and roll crushers). However it doesn?t provide the complete extraction of metals from clinkers. The intensification of decomposition, in our opinion, can be provided under the use of the devices working on a principle of free kick. At such influence on a material, its destruction occurs on micro cracks, sides of cohesion that is there is a selective destruction of the components possessing various resistances to impact. Decomposition of a piece on the basis of free kick about a material or metal is realized in centrifugal-shock crushers and mills of research-and-production association ?Ural Center?. The share of the joints sharply lowering the efficiency of enrichment thus is minimal. The efficiency of application is proved by morph-metrical measurements with the help of system of image analysis ?SIAMS-600? and physical-mechanical tests of clinkers and their components (impact strength, micro hardness). The experience of application the devices of centrifugal-shock crushing for processing clinkers in blast-furnace, martin and converter productions of Open Society MMC, clinkers of rough-edged copper melt of Joint-Stock Company "Karabashmed" and aluminium clinkers of Joint-Stock Company « Samara plant of aluminium alloys » has allowed to confirm the efficiency of application these devices for selective decomposition of metallurgical clinkers and the opportunity of using clinkers as resource of ferrous and nonferrous metallurgy.

Jan 1, 2014