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By N. N. Orekhova, I. V. Shadrunova, N. G. Novikova, N. ?. Volkova

The purpose of the research is scientific substantiation and formulation of strategy and technical solutions of handling liquid wastes of plants producing and refining copper-zink pyritic ores. In the course of research studied are chemical composition of technogenic waters of mining plants as well as water and alluvia of intake river within and outside a sanitary zone of Southern Ural mining plant using inductively coupled plasma mass-spectrometry and X-ray fluorescence analysis techniques. A particular focus is made on microcomponent composition. Novel data on Cd, Li, Be, Mn, Co, Cu, Zn migration with technogenic flows and accumulation of these elements in alluvia is obtained. It is showed that extraction of valuable components from technogenic waters is a novel problem for refiners that can be solved only in cooperation with mining industry ecologists. Laboratory research of selective copper and zink extraction into corresponding practical products by galvanocoagulation and sulphide precipitation is carried out. Common factors of phase formation are studied using physicochemical modeling, X-ray phase analysis and electronic microscopy. Methods of intensification of processes and increasing of extraction ratio of metals in products are elaborated. A technology of comprehensive processing of undersoil waters is proposed. Enlarged laboratory and pilot plant tests of technological solutions for protecting hydrosphere and extracting metals from mine waters carried out on several plants of UMMC-Holding Corporation showed a possibility of obtaining additional products having weight content of metal which is profitable for consequent metallurgical processing and purification of waters to comply with quality standards. A possibility of transformation of technological chain depending on season variability of water quality is put behind the designed technological schemes.

Jan 1, 2018

By Janusz S. Laskowski

The flotation-related properties of hexanol derivatives and mono-alkyl ethers of propylene oxide, which include many important flotation frothers (e.g. MIBC, DF-200, DF-250, DF-1012, etc.) have been studied. The obtained results show that the DFI (Dynamic Foamability Index) - CCC (Critical Coalescence Concentration) plot can be used to classify flotation frothers. The frothers characterized by low CCC and high DFI values have properties of strong flotation frothers, while those with high CCC and low DFI values are more selective. The proposed frother classification system, based on simple CCC and DFI measurements, provides, for the first time, a solid ground-work for characterization of the flotation frothers.

Jan 1, 2003

By C. Y. Sun

Flotation of chalcopyrite and unactivated malachite with xanthates (ethylxanthate, butylxanthate, octylxanthate and dodecylxanthate) is studied in this paper. Minerals interacted with xanthates are detected by FTIR, and simulated by molecular mechanics. It shows that chalcopyrite can be floated with 4 kinds of xanthates, and unactivated malachite can?t be floated with ethylxanthate but can be floated directly with later 3 kinds of xanthates while characteristic absorption peaks of those four kinds of xanthates are all detected by FTIR on chalcopyrite and malachite surface. After simulating the interaction between xanthate and mineral, it shows that H2O and OH-can interact with chalcopyrite and malachite, and their interaction energy may be so called energy bulwark which must be overcome by collector when collector interacts on minerals; the two sulfur atoms in xanthate group interact with copper and neighbor iron atoms on chalcopyrite. It also shows that molecular mechanics results with logP of collectors can interpret the mechanism of xanthate-mineral on atom scale.

Jan 1, 2014

By Takaaki Wajima

The slag was attempted to be converted into the adsorbent for phosphate removal from aqueous solution using the alkali fusion method. The slag was mixed with NaOH powder (NaOH / Slag = 1.6), and then the mixture was heated at 600 ? for 6 h to prepare the precursor. The precursor was stirred at room temperature in distilled water to synthesize the adsorbent, and the removal ability of the obtained adsorbent for phosphate from aqueous solution was investigated. The products, including hydrocalumite and calcite, were synthesized, and the removal efficiencies of the adsorbent for F- and PO43- showed higher than those of raw BF slag, especially removal of PO43- are excellent (99 %), while the removal of Cl- , SO42-, NO3- and Br- was minor. The adsorbent could remove PO43- selectively in the co-existing solution of Cl-, NO3-, F-, SO42- and Br-.The equilibrium adsorption capacity of the adsorbent for PO43- was extrapolated using Langmuir and Freundlich models, and experimental data are found to fit Langmuir than Freundlich. The calculated maximum adsorption capacity of the adsorbent for PO43- is higher than other adsorbent reported previously. The high affinity of the adsorbent for PO43- in aqueous solution was caused by the formation of hydroxyapatite [Ca5(PO4)3(OH)] and brushite [CaHPO4?2H2O]. The prepared adsorbent is expected to be anew inorganic adsorbent for the removal of phosphate ion from wastewater. Keywords: Blast furnace slag, Alkali fusion, Phosphate removal, High selectivity

Sep 1, 2012

By Hong Zhong, Shuai Wang, Xin Ma

"In this paper, we report a simple and effective process for producing a surfactant mixture of O-isopropyl-N-ethyl thionocarbamate (IPETC) and 4-(tert-butyl)benzyl mercaptan (BBSH). The composite collector was synthesized via one-pot reaction of sodium isopropyl xanthate, 4-tert-butylbenzylchloride and ethylamine using tert-butyl alcohol as solvent. The whole process for the synthesis of composite collector involves neither foul smelling reagents or intermediates, nor any by-products requires special treatment for disposal, and thus can be scaled up to an industrial level. The flotation response of chalcopyrite and pyrite independently with IPETC and BBSH collectors and with their mixture (the mole ratio of IPETC and BBSH is 1:1) was assessed. The microflotation results showed that the collecting ability of BBSH was slightly stronger than that of IPETC and that IPETC was more selective collector than BBSH against pyrite, and that the composite collector displayed a stronger collecting ability toward chalcopyrite than IPETC, and superior selectivity for chalcopyrite against pyrite than BBSH. The batch flotation results showed that composite collector exhibited better performance than IPETC and BBSH. It was demonstrated that the mixing of IPETC and BBSH would give rise to a synergistic effect significantly enhancing overall flotation performance. In addition, the adsorption mechanism of BBSH on the surface of chalcopyrite was conducted by adsorption test and infrared spectrum measurement, and the results showed that the interaction of BBSH on the chalcopyrite surface was dominated by the chemical adsorption, and the formation of a strong S-M bond plays a key role in the adsorption of mercaptans on minerals surfaces. The developed flotation reagents with special preparation method is the author’s original design, patented (patent of the People’s Republic of China) and have no analogues in the world of mineral processing. (Application number 201810100107.1, ""Alkyl thioether alcohol compounds, methods for their preparation and applications thereof "", China).1. INTRODUCTION Froth flotation is an essential method widely used in the mineral processing industry to selectively separate valuable minerals from gangues[1]. Worldwide, more than 109 tons of materials are treated annually by this method with the majority being metal sulfides and oxides[2]. Nowadays, the judicious utilization of complex sulfides to meet the ever-growing demand of mineral resources gains more attention, due to the gradual depletion of deposits with high grade, making imperative the development of new high-efficiency collectors and mixtures of collectors to process complex minerals. In comparison to individual collectors, the use of mixtures has several notable benefits including lower dosage requirements, improved selectivity, rates and recovery and an increase in the recovery of coarse particles[3-9]. Moreover, in terms of cost and environmental issues, using collector mixtures can reduce the total amount of agents used, thus reducing the overall effect on the environment and economic costs without affecting the flotation performance. Therefore, the search for high-efficiency mixtures of collectors is still interesting and relevant."

Jan 1, 2018

By C. Perez

In mineral processing plants it is important to estimate rock composition, size and grindability to improve control of the grinding process. It is well known that variation in ore grindability and size distribution directly affects mills power consumption and throughput. This paper extends a general machine vision approach for on-line estimation of rock mixture composition using color information. Our proposed rock lithological recognition method requires the following steps: division of each image into sub-images, color feature extraction using the Binary Quaternion-Moment-Preserving thresholding technique (BQMP) and support vector machines (SVM) for classification. The BQMP thresholding technique splits the image in two and chooses representatives of each half using the histogram as features. The statistical parameters of the color data can be expressed using the quaternion moments into the representatives. This method can be recursively applied to the sub-images, obtaining 5x2n features in n iterations. Once the feature vector has been computed, each vector is assigned to one of three classes using a classifier. The method was tested on a database containing 20480 sub-images (64x43 pixels) of five ore types as follows: massive sulphide (MS), disseminated sulphide (DS), net textured (NT), gabbro (G), and peridotite (P). These ore types were assigned to three grindability classes: soft (MS), medium (DS and NT) and hard (G and P). The database was divided in 2 subsets: 15360 sub-images used for training and cross validation and 5120 sub-images used for test. The classification accuracy was compared with a method previously published based on a mixture of principal components analysis (PCA) for color, and wavelet texture analysis (WTA) for texture feature extraction. WTA-PCA approach reached a 76% accuracy in test while our BQMP method reached 90% of classification accuracy using only color features. Experimental results show that our proposed method yields excellent results compared to previously published results. Keywords: rock classification, lithological classification, grindability estimation

Sep 1, 2012

By E. L. Chanturiya

During the mineral processing of pyrites sulphide ores of some deposits of Russia loss of gold with tailings and pyrite concentrates amounts up to 40%~90%. The problem of selective allocation of gold-bearing pyrite is crucial. There are 4 mineralogy-technological groups of pyrite determined in copper-zinc sulphide ores, based on the increase of contents of gold in pyrite. The gold associated with group 4 pyrite contents of 85% the total mass of gold found in the pyrite. The flotation behaviour of the enriched fractions of pyrite (98%), of the allocated from the ore of Gay deposit, were studied essentially in various conditions ?? and the charge of Butyl xanthogenate of potassium (ButX). Some products of selective pyrite flotation were investigated by methods of scanning electronic microscopy, energy-dispersive and X-ray spectral microanalyses, definition of specific resistance and thermoelectric moving force.

Jan 1, 2014

By John A. Rumball, Martin R. Houchin

"For gold leaching of oxide ores, the optimum cyanide : oxygen ratio is approximately 106 mg/L NaCN : 10 mg/L O2 (6.9:1 by mole). In sulphide ores, galvanic coupling of the gold with the electrically conductive sulphides significantly increases this ratio such that leaching may occur in a relatively low dissolved oxygen (DO) environment.RESULTS AND DISCUSSIONGold leaching in a carbon in pulp (CIP) and carbon in leach (CIL) circuit is driven by the supply of cyanide and oxygen, as described by Elsner’s equation (1):• 4Au + 8CN- + O2 + 2H2O ? 4Au(CN)2 - + 4OH- (1)Equation 1 suggests that the ideal molar cyanide : oxygen ratio should be 8:1, or 122.5 mg/L NaCN to 10 mg/L of DO. It is generally accepted however, that oxygen is not completely reduced to hydroxide at the gold surface, and that equation (2) better represents the gold leaching reaction (Marsden and House, 1992):• 4Au + 8CN- + 2O2 + H2O ? 4Au(CN)2 - + 2OH- + H2O2 (2)Additionally, since gold leaching is limited by either the diffusion of cyanide or oxygen to the gold surface (Habashi, 1993), then the relative diffusion rates of cyanide and oxygen must also be taken into account. Marsden and House (1992) suggest that the ideal molar cyanide : oxygen ratio is 6:1, while a more recent investigation using laboratory and plant observations (Heath and Rumball, 1998) suggested a molar ratio of 6.9:1.In practice, although a cyanide : oxygen mole ratio of 6.9:1 applies to some circuits, there are many instances when this is not the case.In sulphide ores, galvanic coupling of the gold with the electrically conductive sulphides significantly increases this ratio. Galvanically connected sulphides, and possibly carbon, provide a large surface area for oxygen reduction. As the cathode surface area increases, the oxygen concentration required to sustain the same rate of gold oxidation decreases proportionately.Galvanically connected particles may be composite particles, however they may simply be liberated sulphides in the same suspension as the gold. Particle collisions within a slurry are sufficient to provide momentary galvanic connection (Greet, 1995)."

Jan 1, 2003

By N. Acarkan

Beneficiation of the pyrite concentrate of the Kastomonu-Küre (Northern Turkey) copper ore seems to be attractive due to its high Cu, Co, and Zn contents. Pyrite concentrate were used in the experimental studies. Cu, Co, and Zn were recovered from the concentrate by the sulphatizing roasting, leaching and the precipitation using H2S. Sulphatizing roasting experiments were carried out in a rotary furnace and the optimal roasting conditions were found to be at 650°C roasting temperature and 3.0 h roasting period and addition of Na2SO4 of 3 % for the concentrate containing 0.58% Cu, 0.22% Co, and 0.04% Zn. Then, the roasted product was repeatedly leached with 10 g/L H2SO4 solution. Optimal conditions were found to be 60 oC leaching temperature, 2 h leaching period, and 30% pulp density. Leaching efficiencies for Cu and Co were over 99 %. The valuable metals in the pregnant solution were selectively precipitated by H2S as sulfides. Selective precipitation of Cu, Zn, Co was achieved by adjusting the pH and the temperature of the leach solution. Final metal recoveries of 99.20% Cu, 99.40% Co, and 95.60% Zn were attained. The precipitated sulphides are marketable products. Roasting gases with their 15% SO2 content are suitable for the production of H2SO4 and the leach residues can be integrated with the iron ore processing plant as they contain 57.50 % Fe, 17.70% gangue (SiO2, CaO, etc.), 0.04% S, and 0.06% non-ferrous metals.

Jan 1, 2014

By K. D’Elia, L. D. Ogrel, O. A. Malyshev, T. I. Yushina, I. M. Petrov

"The purpose of this research is to develop enhancements in the mineral processing by flotation methods of nonferrous ores. Currently, 180-190 million tons of ore are processed by flotation in Russia. The annual processing volume of copper-nickel and copper-zinc ores exceeds 20 million tons. In the total volume of processed ores by flotation, non-ferrous ores account for roughly 35% and ores of precious metals for another 15%. The total demand of flotation reagents in Russia in 2016 was estimated at 170,000 tons. Sulfur-based collectors used in the flotation of non-ferrous sulfide ores (typically, xanthates) do not always offer sufficiently high recovery of valuable components.It has been found that reagents like DMIPEC and DK-80 improve the recovery of metals into concentrates. To identify the reasons of that higher recovery, quantum chemical calculations of the mechanism and interaction forces of DMIPEC with non-ferrous sulfides were undertaken by determining the stabilization energy of the resulting chemical complexes. It has been shown that, in the interaction of DMIPEC and DK-80 with the surfaces of sulfide minerals, ethylene and acetylene bonds act as the reaction centers, and the formation of molecular p-complexes is the result of metal-cation interactions with the surface and the flotation reagents.In the flotation of non-ferrous ores, DMIPEC and DK-80 act as selective supplementary collectors with foaming properties, and at a flow rate of 3-35 g/ton, they reduce the flotation time, and increase copper recovery by up to 3.5%, zinc recovery by up to 12%, gold recovery by up to 8-10%, allowing to increase the recovery of valuable components by 1.5-12.0%, basically this kind of reagents nearly double the flotation rate, improve the grade of the concentrate, improve the stability of the flotation process parameters, and reduce the environmental impact of flotation plants."

Jan 1, 2018

By Cuim R., M. L. Li

Fankou Lead-Zinc Mine produced pyrite concentrate (P.C.) from the zinc tailings by rougher and scavenger flotation before 2010, with the averaged S grade of 40.54% at recovery of 79.34% ( to the feed of S circuit). On the one hand, the economic value of P.C. increases with its purity, on the other hand, when the S grade of P.C. feed to sulfuric acid manufacturer is over 47%, the pyrite cinder can reach a high Fe grade of 62% which can be directly sold as iron concentrate. On this background, engineers in Fankou Mine set the P.C. with S grade of 47% as target. The direct way to reach that goal was to clean the rougher P.C.. Lots of cleaning flotation tests were conducted and the compromised strategy was to produce two ranks P.C. with the S grade of 47% and 38% at the recovery of 44.20% and 36.17%, respectively. The dual-product flowsheet was successfully industrialized in 2010. In order to further improve the quality of P.C., gravity separation was introduced into the flowsheet. The numerical simulation and separation tests were performed to evaluate the beneficiation and classification performance of hydrocyclone as it treated the rougher P.C.. It was shown that the underflow of hydrocyclone could addressed the S grade of 47%, and the finer size overflow could also be enriched to P.C. with S grade of 47% by flotation, due to the contained pyrite with well liberation. That is to say, with the ingenious addition of hydrocyclone to treat the rough P.C., single P.C. with S grade of 47% could be achieved. The new flotation-gravity separation flowsheet was commissioned to produce the high quality P.C. at the end of 2013. The averaged S grade is 47.20% at recovery of 82.26% in 2014. The two steps flowsheet improvement maximizes the enterprise benefits and leads to simple utilization of Fe in pyrite in downstream industry.

Jan 1, 2018

By D. Tang

The froth zone in a flotation cell is recognised as a region which contributes to the overall flotation performance. Froth recovery is a measure of the efficiency with which the froth phase delivers particles arriving at the pulp-froth interface to the concentrate. Poor froth recovery in scavenger stages is generally attributed to poor froth stability. The key indicators of froth performance: froth recovery, entrainment and water recovery were measured in an OK3 pilot cell installed at a zinc concentrator in Australia and supplied with scavenger feed. Cell hydrodynamic and pulp chemical conditions during the operation of the cell were also measured as well as bubble growth across the froth phase. The objective of the work was to assess the impact of a number of commercial frothers on the froth performance in the OK3 cell and assess the suitability of using bubble growth as an indicator of froth stability.

Jan 1, 2014

By Liu Jie

Refractory iron ore deposits in China have various genesis and complicated types, the nature of which is poor, fine-disseminated and complex. Therefore, refractory iron ore could scarcely be separated and utilized by traditional mineral processing technology at present. It is necessary to explore deep reduction technology to change the characteristics of refractory iron ore and to use effectively the iron resource. And deep reduction technology is that on the condition of higher reduction temperature than that of magnetic roasting and stronger reducing atmosphere, the iron oxides from iron ore was reduced to metallic iron particle that is easy to dissociate. And then production from deep reduction is easily separated by magnetic separation and iron powder production was obtained finally. Deep reduction technology for Lingyang iron ore from Jilin, China, as the refractory iron ore, was studied in this paper. The influences of such main factors as reduction temperature, time and coal content were investigated. The results showed that the Metallization rate of reduction product was up to more than 90% under optimum conditions, and then higher iron grade and recovery of reduction iron powder were obtained from subsequent magnetic separation. Furthermore, the deep reduction mechanism in the system was studied by the means of XRD and SEM analysis for reduction production and Physical Chemistry of Metallurgy. Analytical results indicated that during deep reduction, the size of iron particle from deep reduction materials was increasing as reduction temperature rising and reduction time extending. The growth of metallic iron particle from deep reduction production was divided into such three stages as reduction nucleation, deep reduction and growth of metallic iron particle.

Sep 1, 2012

By Przybycien Krzysztof, Tumidajski Tadeusz

"Materials being the feed to mineral dressing plants are the mixture of ore minerals having different physicochemical properties among others, especially susceptibility on crumbling. During exploitation of material and their preparation to communition the big number of narrow classes comes into being and they have different properties. The determination of common communition laws of multicomponent (on account of size and mineralogy) materials leads to the estimation of mutual influence of narrow classes and their rates, taking into account their endurance and mineral density, on general ratios and their simultaneous crumbling.If we try to accept the grain membership to the certain component as the differing feature, we can write the balance equation as: ( ) ( ) S= = k i i i g x p f x1where: fi – density functions of one type distribution and of different statistical moments (characterising the homogeneous materials grinding), pi – “stirring” proportions of each components, S== k i i p 1 1 . From the point of verification view of detailed versions of this equation the inverse operation should be done: in the base of the components’ mixture grinding results and the results of components grinding the legitimacy of equation should be checked.The using of finished distribution mixtures’ theories to the grinding process analysis allows, first of all, to verify the assumption of grinding independence of individual feed components. Talking more generally it would lead to the comparison of grain size distributions, obtained by individual components grinding from the defined in the mixture distributions theory calculations. One of experimental and calculation results for artificial mixtures of galena and dolomite is presented on figure below (df means distribution function)"

Jan 1, 2003

By V. Yu. Ivanov, A. I. Yuryev, L. S. Lesnikova, M. S. Datsiev

"The Talnakh Concentrator was put into operation in 1981 using a direct selective process to produce copper, nickel and pyrrhotite concentrates.In 2001, a novel selective-bulk-selective (SBS) technology for the concentration of massive sulfide ore was implemented, that allowed to increase the valuable components recovery into target concentrates with feedstock grinding coarser than before. In 2003-2005, the process upgrading included the differentiated processing of nickelpyrrhotite products recovered at the different concentration stages and made it possible to significantly enhance the contrast of the pentlandite and pyrrhotite flotation properties and to simultaneously increase separation of polymineral intergrowths.The next stage of the PD concentration complex development is the Project ""Talnakh Concentrator Reconstruction and Technical Upgrading"" to raise its capacity by half. The project has three Phases.• Phase 1. Pilot startup was carried out in January 2015 following the installation of new OK-100 TC flotation machines, manufactured by Outotec.• Phase 2. The introduction of a new technology developed by the Polar Division specialists launched in mid-2016. The new technology is based on maximization of iron and sulfur removal into tailings and maintenance of non-ferrous and precious metals losses at the same level.After the realization of Phase 3, the annual capacity of the Talnakh Concentrator will raise by another ~ 40% at the expense of processing cuprous and disseminated ores currently being processed by the Norilsk Concentrator.By 2023, due to upgrading of the PD production facilities the emissions to the atmosphere will reduce by 75%.Polar Division of PJSC MMC Norilsk Nickel (PD) searches for the ways to solve its environmental issues. Thus, in 2016, the Nickel Plant was shutdown and a new flowsheet was introduced at Talnakh Concentrator. It resulted in the reduction of sulfur specific amount sent to pyrometallurgical processing as a component of the concentrates.The Talnakh Concentrator was put into operation in 1981 using a direct selective process to produce copper, nickel and pyrrhotite concentrates.In 1981, its design capacity for processing of Cu-Ni ores from Oktyabrsky and Taimyrsky Mines did not exceed 3 million tons per year.In 2001, a novel selective-bulk-selective (SBS) technology for the concentration of massive sulfide ore was implemented at the Talnakh Concentrator, that allowed to increase the valuable components recovery into target concentrates with feedstock grinding coarser than before."

Jan 1, 2018

By A. Lewis

"Thiol collectors including the xanthates and dithiophosphates have dominated the sulfide mineral processing industry for over a century. Tecflote represents completely different chemistry, without sulfur or phosphorus, and will float all sulfides and associated precious metals. As these collectors are surfactant in nature, they comprise a head group which binds to mineral surfaces, a spacer and a long hydrophobic tail. The modification of the spacer behind the head group allows for collector optimisation for different sulfide ore types and process conditions.The Tecflote surfactants have been designed to be either very selective against pyrite at the natural pH of the ore (pH 7-9) or to float all sulfides including pyrite. Depending on the ore type and the process flow sheet, the use of lime can be maintained, reduced or completely eliminated.Tecflote can be used either as a rougher collector giving good recovery and grade for the sulfide minerals or it can be used to target valuable minerals after regrind and through cleaner flotation. It has repeatedly shown to be very effective at holding onto gold through the cleaner steps. The low solubility has a significant impact on the mechanism and surface activity of the collector, resulting in a very different flotation response compared to conventional thiol collectors.INTRODUCTIONXanthate was first made in 1882 by Zeise and first used in flotation in 1924 (Keller, 2018). In 1946 Keller patented thionocarbamate as a collector, which was produced by Dow Chemicals (Keller, 2018). Later it was replaced by Dow product Z-200, while dialkylthionocarbamate was discovered by Harris et al. (Harris, 1954. No significant chemistry change to collectors has occurred since they were introduced in the mid-20th century and now that the feed grades have been declining over the last decades creating a need to find more selective collectors to extract difficult and complex ores and pushing the industry to look at other reagents."

Jan 1, 2018

By Jaime Sepúlveda

"A broad diversity of critical operating conditions may influence, in very convoluted ways, the actual performance of any given mineral processing system, to the extent that it becomes nearly impossible to empirically determine the independent, decoupled impact of each condition. An effective approach to better understand the behaviour of such complex systems is via the extensive use of sufficiently detailed and reliable mathematical models, allowing the process analyst to explore and learn about the independent effect of all relevant operational conditions. Certainly, these tasks are greatly facilitated if the appropriate software tools - such as the Moly-Cop Tools software package - are readily available. Moly-Cop Tools 3.0 is a set of 63 easy-to-use EXCEL spreadsheets designed to help process engineers characterize and evaluate the operating efficiency of any given grinding circuit, following standardized methodologies and widely accepted evaluation criteria. Moly-Cop Tools 3.0 covers conventional and semiautogenous mills, crushers, HPGR’s, rod mills and vertimills, with the corresponding mass balance and parameter estimation routines; plus complementary spreadsheets regarding Bond’s Law calculations, grinding media selection and performance evaluations and other useful utility functions. As a relevant example of application, specifically focusing on semiautogenous grinding operations, the current publication describes how the models can help us learn and rationalise critical empirical observations such as the relationship between feed particle size and optimal ball filling, the role of the rocks as autogenous grinding media as well as the impact of feed size and discharge grate opening on the mill grinding capacity. Over the last 20 years, Moly-Cop Tools has gained wide acceptance around the mineral processing community in recognition to the quality of the mathematical models contained, their simplicity of application and ease of sharing of the calculations amongst all interested parties, since it is available free-of-charge with no restrictions to make as many copies as needed."

Jan 1, 2014

By S. Swaroopa

Copper-chromium mixed oxides are widely used as catalyst for organic chemicals industry, NOx and CO oxidation, solid propellant etc. In the present investigation, one such spent Cu-Cr catalyst has been tested for recovering copper and chromium values through hydrometallurgical route. The spent catalyst used in this study contains about 42% Cu and 36% Cr. Phase analysis through XRD indicates that major phases are copper chromium oxide (CuCrO2) and copper chromate (CuCr2O4) while minor phase is copper oxide (Cu64O). SEM images show that high energy ball milling changes surface morphology significantly ? more regular shaped grains in unmilled samples changed to fine agglomerates. Surface area also changes significantly due to milling. Preliminary leaching experiments with NH3 and H2SO4 media using unmilled samples indicate that both the media are suitable for selective extraction of copper. About 55% copper recovery is achieved in 2 h using 1.2 M NH3 + 0.2M (NH4)2SO4 solution at 100°C. Increasing NH3 concentration or temperature does not improve the recovery significantly. Under the above conditions chromium, dissolution is insignificant (max. 2.24%). XRD analysis of the residue indicates that copper chromate fraction (CuCr2O4), which is a spinel structure, remains mostly intact. In sulphuric acid media at ambient temperature, 47% copper recovery is achieved with 7.5% (v/v) H2SO4 and maximum of 57% with the increase in acid concentration to 20%. However, 67% recovery is achieved by increasing the leaching temperature to 150°C. High energy ball milled samples show improved leaching efficiency. Under the leaching conditions of 7% H2SO4 (v/v), 2% pulp density, 80°C an unmilled sample yields 47% Cu recovery whereas 3h and 5h milled samples yield 65% and 90% Cu recovery respectively in 2h leaching time. Influence of temperature is also more pronounced in milled sample leaching in comparison to unmilled sample. Water leaching of alkali (NaOH) roasted milled sample carried out at 750°C for 2 h with 100% NaOH (w/w) resulted in 80% Cr recovery as compared to 37% Cr recovery using unmilled sample under the same conditions. Keywords: spent catalyst, copper, chromium, leaching, mechanical activation, roasting

Sep 1, 2012

By Wei Sun, Xue-feng Cao, Lei Sun, Run-qing Liu

The flotation performance of kaolinite in laboratory micro-flotation was investigated with 3- (dodecyloxy) propan-1-amine (ON12) as the collector. Compared with dode cylamine (DDA), which is commonly used as the bauxite reverse flotation collector, ON12 shows stronger collecting ability for kaolinite than using the same amounts of DDA, when experimental pH value reaches more than 6. With the addition of ON12, the isoelectric point of kaolinite shifts to 6.1 from 3.6, which suggests a strong adsorption between kaolinite and ON12. Infrared spectra analysis indicates that the type of ON12 adsorbed on the kaolinite surface is mainly of electrostatic adsorption. Molecular dynamics simulation further indicate that electrostatic adsorption of ON12 cation on kaolinite (001) surface based on electrostatic interaction between NH4+ and O atoms. ON12 will be suitable for bauxite reverse flotation with the efficiency depressors of the diaspora.

Jan 1, 2014

By Alex Joseph

A tertiary amine containing polyamine in its back bone was grafted to exfoliated graphite oxide by means of a series of chemical reactions.The synthesized amine functionalized polyaniline grafted to exfoliated graphite oxide (EGAMPANI) was characterized using various techniques such as, FTIR, TGA, Raman, and X-Ray diffraction.The synthesized EGAMPANI was blended with carbon paste electrode, and used to study the response of Hg2+ in acetate buffer solution.Preliminary analysis showed that the anodic current intensity using the EGAMPANI modified electrode was higher during a potential sweep and 10-4 M concentration of mercury could be detected which could be improved to 10-6 M using anodic stripping voltammetric technique. Keywords: metal sensor, exfoliated graphite oxide, functionalization, polyaniline

Sep 1, 2012