Search Documents

By R. P. Bhagat

The paper reports results on sinterability of iron ores from the mines of Tata Steel Limited. The objective was to improve tumbler index (TI) of sinter and its reduction parameters, reduction degradation index (RDI) and reducibility (RI) while maintaining strand productivity same or to improve. Pot sintering experiments were carried out with Joda and Noamundi mines having LOI 3.8% and 2.9% respectively. Sinter basicity (CaO/SiO2) was varied in the 2.1 to 2.5 range and its MgO content was kept in the 1.4% to 1.8% range according to the blast furnace requirement. The ignition condition and vacuum was maintained according to the plant practice. The effect of variables namely, granulometric composition of ores vis-à-vis that of sinter mix, bed height, solid fuel, moisture content of green mix on the sintering indices was studied. The productivity with Noamundi ore (26 %+6.3 mm) was lower than that with Joda ore (45% +6.3 mm) at 4% coke in the mix and sinter basicity (CaO/SiO2) 2.1. However, with 4% coke (ash 22%) the RDI value was significantly high in case of Noamundi Ore, which decreased significantly to 29% with 5% coke. The size parameter of ore fines and its LOI content do influence the sintering speed and the sinter properties significantly. At 2.1 basicity ratio, the sinter with the Joda ore having coarsergranulometry had highest TI (=70.2%). The RDI (27%) in this case was inferior to that (23.2%) when Joda ores with finer size was sintered. Better RDI with finer sized ore could be attributed to better assimilation of CaO/ MgO with more balanced and uniformly distributed hematite minerals. The size parameter has been inter-influenced by the coke requirement. With the lower mean sized Joda ore the sinter RDI decreased significantly to 23% and the productivity improved to 42.9 T/(sq m*d) when the coke in the mix increased from 4% to 5%. An attempt to reduce the coke in the mix from 5% to 4% with respect to both the ores was not successful as it resulted higher RDI and lower strand productivity. The present study has revealed that sinter RDI improves (decreases) with decrease in the sintering time, while such correlation was absent between TI of sinter and speed of sintering. Corollary to this observation, one can take advantage of other stronger parameters to increase the sintering speed (and hence sinter productivity) without affecting the sinter strength. In the present study higher FeO sinters has displayed excellent RDI, however cold strength of sinter was not correlated with its FeO content. The TI and RI parameters of sinter improves marginally with increase in its MgO content while RDI got worsened. Keywords: LOI content, iron ore, reduction properties, sinter, noamundi, joda

Sep 1, 2012

By P. V. Ramesh Babu

India has sizeable number of small deposits of rare metal bearing minerals namely columbite-tantalite, pyrochlore, beryl, lepidolite, spodumene and rare-earth element bearing minerals monazite and xenotime in different parts of India. Pegmatites, alkali granites, syenites, and the derived gravel and soils are the main source for rare metal and rare earth (RMRE) minerals. The RMRE minerals are classified as prescribed substances under Atomic Energy act of 1962 keeping in view the uses in the nuclear industry. Atomic Minerals Directorate for Exploration and Research (AMD) of Department of Atomic Energy (DAE) is the sole agency responsible for exploration and exploitation of RMRE minerals in India since 1962. The latest technological advancements and applications in the field of space, electronics, communication and nuclear industry using these metals and their products have necessitated to augment the production and resources of RMRE minerals. These minerals play a significant role in the technological and economic development of the country. The light rare earth element bearing mineral monazite is abundant in beach sands and is being commercially exploited by Indian Rare Earths Limited (IREL). Columbite-tantalite, the chief source for niobium and tantalum (Nb-Ta) metals present in the pegmatitic gravel are recovered by small mobile beneficiation plants. The cut and fill method of mining adapted is eco-friendly. The processing flow-sheet consists of wet sizing at ½ in and 1mm followed by gravity concentration of sized products utilizing the methods of jigging and wet tabling. The sizing equipment include revolving and vibratory screens and the gravity concentration equipments used are fixed sieve jigs and movable screen jigs for final upgradation. The gravity concentrates are further upgraded by magnetic separation to remove magnetite and ilmenite. The mine areas are reclaimed by filling with coarse size tailings and new plantations. These mobile pilot plants were earlier operated in Bihar mica belt, Jharkhand, pegmatitic areas of Karnataka and Nellore mica belt of Andhra Pradesh and are currently being operated in Bastar-Malkangiri pegmatite belt of Chhattisgarh and pegmatites of Jharsuguda district of Orissa. Beryl, lepidolite, spodumene and cassiterite minerals are the by-products from the pegmatite ores. Fergusonite, samarskite and microlite are the other niobium and tantalum bearing minerals which are also found in pegmatites. Xenotime, the chief mineral of yttirium generally occurs in granites and pegmatites. The rare earth minerals monazite and xenotime get concentrated in the placer sands of rivers and beaches. The occurrence of xenotime in the sands of Siri River and Deo River in Chhotanagpur granitic terrain in parts of Chhattisgarh and Jharkhand are an example. These sands containing 1-2.5% heavy minerals were processed by a mobile plant consisting of sizing equipments like trommel and vibratory screen followed by separation of heavy minerals from -1mm sands with the help of gravity concentration equipments like spirals/shaking tables/sluices. Xenotime and monazite from the pre-concentrate are further separated by magnetic and electro-static methods. The present paper illustrates the pilot plant set up for the recovery of rare metal as well as rare earth minerals. Keywords: small deposits, rare earths, rare metals, pegmatite, Nb-Ta, xenotime, India

Sep 1, 2012

By S. M. Bradshaw, V. Rocher, L Kabondo, B. Combrink, C. A. Snyders

Media losses are a significant contributor to the operational cost in a dense media separation (DMS) circuit. Of these losses, up to 80 wt% can occur on the drain and rinse vibrating screens. Although these screens are an integral part of any DMS circuit, surprisingly little work can be found in open literature regarding the effect of aperture configuration on the drain rates (draining water and medium). To establish the effect of slot aperture size, experiments were conducted on a 0.6 x 1.2 m vibrating screen with polyurethane (PU) panels at slurry densities between 1.6 – 2.8 kg/L, and volumetric flow rates of 19 – 25 m3/h for both ferrosilicon and magnetite. Results showed that an increase in the volumetric flow rate led to an increase in drainage rate, moisture content and medium carryover. Once an optimum volumetric flow rate was exceeded, a further increase in flow rate resulted in a decrease in drainage rate with a sharp increase in moisture and medium bypass to the oversize stream. An increase in ferrosilicon slurry density led to a decrease in drainage rate with an increase in moisture and medium bypass with each of these rates increasing as the slurry density increased. For magnetite, a gradual decrease in drainage rate was observed with increase in slurry density and volumetric flowrate beyond the screen optimum point. It was found that an increase in aperture size from 0.63 x 8.8 mm to 0.8 x 8.8 mm to 1.0 x 13 mm resulted in an increase in ferrosilicon drainage rate of between 1.3 - 1.8 m3/m2/h depending on the flow rate and slurry density with a reduction in moisture and medium carryover of between 1.0 – 1.2 % and 14.1 – 20.2 kg/t/m respectively. For magnetite, the drainage rate increased between 1.0 - 1.4 m3/m2/h as the slot width increased from 0.63 x 8.8 mm to 0.8 x 8.8 mm while an increase in slot length from 0.63 x 8.8 to 0.63 x 12 mm only resulted in an increase in drainage rate of 0.1 - 0.5 m3/m2/h.

Jan 1, 2018

By Diana Drinkwater

As ore grades decline, ore deposits get harder and mineralogical complexity increases, metallurgical skills are more important than ever to ensure that today?s mining operations are operating efficiently and profitably. Yet specialist undergraduate degree programs have all but disappeared and metallurgical skills training for graduate engineers in the workspace if often haphazard. In response to this situation, specialists at the JK Centre in Queensland, Australia, have put together a professional development program designed to fast-track skills development for early career metallurgical professionals. The program, called ?MetSkill ® ?, is offered as a group training package for young metallurgists in the workplace. It is centred on a meaningful technical investigation negotiated between the JK Centre delivery team and the client company. As well as learning about project management and data collection and analysis, the participants study specialist topics such as comminution, flotation and mineralogy under the tutelage of senior research and consulting professionals. The technical investigation provides an opportunity for immediate practice of these new skills and JK Centre specialists are on hand to provide feedback and support throughout the program. The participants are employed across different operations in Australia and the Asia-Pacific, and although they occasionally come together for group training activities they are often separated by considerable distance. Specialist educational professionals from The University of Queensland have provided an innovative web platform to support collaboration and communication between all participants. This paper will describe the MetSkill ® program in detail, as well as providing a report on its initial roll-out to 2 groups of Australian graduate metallurgists in 2012

Sep 1, 2012

By Diana Drinkwater, Tim Napier-Munn

"This paper argues that, although specialist mineral engineering expertise is essential for the efficient design and operation of mineral processing plants, the environment in which these skills are supplied to the industry has changed forever, and not for the better. Most of the mineral engineering programmes in western universities have died or are dying. The long-service mine site mentors have gone, operations are run on a staffing shoestring so that there is no longer the time (or inclination) for considered decision-making, and the FIFO model has discouraged continuity of optimisation projects and communication between professionals. At the same time the technical challenges of designing and operating effective process plants are increasing. These trends are not going to be reversed any time soon, if ever. The ability to run efficient mineral processing operations has been materially compromised as a consequence. We propose that well-designed professional development can help to recover this situation, and it can be done easily and cheaply. The workplace is the best environment for such skills development. Professional development training should be integrated with normal duties throughout the early years of a graduate’s service (and probably beyond), and the cost should be regarded as non-discretionary expenditure for the business. If such programmes are properly resourced and managed and extended over longer time periods, there will be a measureable rise in the level of technical understanding and competence within companies and a resulting beneficial impact on resource utilisation and thus shareholder value. The paper outlines some of the approaches that we believe will work, and the benefits that we expect will accrue."

Jan 1, 2014

By V. A. Luganov

The processing of pyrite concentrates may be accomplished with a preliminary enrichment due to withdrawal of iron sulfides from initial concentrate. The withdrawal of iron sulfides is possible with the help of magnetic separation when the magnetic iron sulfides (pyrrhotites) separate from non-magnetic fraction?the sulfides of non-ferrous metals. The conversion of non-magnetic pyrite to magnetic pyrrhotites of adjusted structure occurs because of roasting with the withdrawal a part of sulfur. The resultant pyrrhotites are strong ferromagnetic with hexagonal structure. This paper contains results of studying magnetic properties of pyrrhotites, findings of the de-composition of initial pyrite with the consequence homogenizing of product and hardening of product of decomposition in liquid nitrogen. Define the type of pyrrhotites super lattice structure, was established that at increasing of sulfur contention the magnetic properties of pyrrhotites are change ? pyrrhotite begin evince the properties of antiferromagnetic material and magnetic susceptibility of material is interruptive changing from 0 to 1.7×10-3~1.9×10-3 SI units/g system. The paper contains results of technological researching of pyrrhotizing-magnetizing roasting of pyrite concentrates in different condition: in unoxidizing, with the decreasing contention of oxygen and in autogenous regime in air atmosphere. Established that the magnetic susceptibility of products depend of pyrite degree dissociation and achieve 2×10-3~3×10-3 SI units/g system at 40%~45% desulphurization. Defined the conditions of steady regime autogenous roasting, at resultant products possess coefficient of magnetization, and this can be used magnetic separation for separating ferromagnetic pyrrhotites from gangues and non-magnetic sulfides of non-ferrous metals. This technology of pyrrhotizing roasting is recommended for effecting in industrial condition. The initial materials and products of roasting subjected to chemical, thermogravimetric, Moss-bauer spectroscopy and X-ray analysis, defined the magnetic properties.

Jan 1, 2014

By Jing Zhou

2-hydroxy-3-naphthoy hydroxamic acid code name F203 is a good collector of cassiterite, 1-hydroxy-2-naphthoy hydroxamic acid code name ZJ-3. F203 and ZJ-3 are similar series of isomers. They have similar naphthye, and similar series of functional OH and ?CONHOH, but the seat of OH and ?CONHOH group are different, on the F203 is 2.3; on the ZJ-3 is 1.2, ortho position too. According to Isomeric principle ZJ-3 is a good collector of cassiterite slime too. Using ZJ-3 as collector flotation -10µm occupies 90%, grade 1.16% Sn cassiterite slime of Da Chang Chehe concentration plant, pass one coursing flotation, two cleaning and one scarenging flotation, and obtains grand 18.26% Sn, recovery 92.68% cassiterite concentrate. The result proves the Isomeric principle of flotation reagents is correct again. This principle may supply to synthetize new flotation reagents reference. Keywords: F2O3, ZJ-3, cassiterite flotation, Isomeric principle, Isomeric principle of flotation reagents

Sep 1, 2012

By Y. S. Sun, P. Gao, Y. F. Li, J. W. Yu

"Oolitic hematite ore is one of the most refractory iron ores in the world. It is not feasible to separate iron minerals from raw ore by conventional mineral processing methods. In recent years, a new technology called coal-based reduction followed by magnetic separation has been employed to produce metallic iron powder from oolitic hematite ore effectively. In order to find the nucleation mechanism, a thermodynamic analysis of the carbothermic reduction of oolitic hematite ore was conducted by the HSC 6.0 thermochemical software. The phase transition and microstructure changes during the coal-based reduction were also investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). The results showed that the iron oxides in the oolitic ore were reduced to metallic iron following the route of Fe2O3–Fe3O4–FeO–Fe in reduction process. The reduction reactions preferentially occur in the high activity regions to form a higher concentration of Fe elements, and then more supersaturated Fe separated out to form new phase nuclei. Under the action of homo-aggregation and principle of minimum free energy, the iron cores continuously absorbed migratory Fe around and grew into quasi-spherical iron particles embedded in slag phase. INTRODUCTION With the rapid increase of steel industry, premium grade iron ore in China has been gradually exhausted, and its supply has become bottleneck for the development of iron and steel industry (Guo et al., 2015). Therefore, it is urgent to exploit the refractory iron ores, such as oolitic hematite ore. Oolitic hematite ore is widely distributes in France, Germany, America, Canada, Pakistan, China, and among other countries (Maynard and Van Houten, 2004; Li et al., 2011). In China, the explored reserve of oolitic hematite ore is 3.72 billion tons, which accounts for approximately 1/9 of total iron ore resources of China (Gao et al, 2016). Oolitic hematite ore possesses complex composition,"

Jan 1, 2018

By Hamid-Reza Manouchehri

"Sustainability calls for maintenance, rational use and enhancement of natural resources as well as balance consideration of ecology, economy, and social justice. The challenges in mining industry call for a sustained global effort using the leverage of available technologies and emerging new technologies. The industry uses significant amount of energy with the highest portion in comminution. To conserve energy, attempts have been made to improve the efficiency of the conventional crushing and grinding equipment. Nevertheless, the new and energy efficient comminution technologies are favorable through a longer term strategy. Since crushers are more energy efficient than mills, it is logic to conduct part of milling, in the crushing stage. After years of research and development, Sandvik introduces a new crushing technology, VibroconeTM, to change traditional crushing concepts. The new crushing device is able to crush and grind particles with a higher reduction ratio, more than two fold, than that of conventional crushers. By implementation of the new technology, a suitable feed size for milling can be provided to conserve energy as well as media and liner consumption, to reduce milling circulating load or increase mill capacity. There are other benefits associated with this machine, one of them being providing a higher surface area. This paper discusses the performance of the machine and its applications for comminuting different ores."

Jan 1, 2014

By I. A. Makalin, V. N. Yakovlev, S. V. Imangulov, I. V. Zyryanov

"The presented studies aimed at solving the problem of recovery of low-luminescent diamonds, which are not recovered using X-ray luminescence method of processing of diamond-bearing ore. The purpose of the studies is the determination of possibility and feasibility of recovery of such crystals using dual-energy X-ray transmission separation technology. In preparation for studies methods were developed for testing technical and process parameters of XRT-400 Aliud GmbH (Germany) sorter, manufactured according to design specifications of Yakutniproalmaz Institute, and XRT/D TOMRA Sorting Solutions GmbH (Germany) sorter, designed for processing of -50+5 mm ore, as well as RGS-1M, RGS-2 X-ray sorters, developed by JSC NPP Bourevestnik (St. Petersburg) in cooperation with Yakutniproalmaz Institute, for material size of -6+3 mm. In 2018, in-process tests of RGS-OD-3 X-ray sorter prototype on material size of -3+1 mm are scheduled. Studies to determine the content of low-luminescent diamonds and feasibility of their recovery using XRT-400 and XRT/D sorters at the Processing Plant #3 of Mirny Mining and Processing Division (MPD) were carried out. The results of the studies confirmed presence of such diamonds and possibility of their recovery using the dual-energy X-ray transmission method. In-process tests of RGS-2 X-ray graphic sorter were carried out at the Processing Plant #16 of Nyurba MPD. According to the results of sampling of RGS-2 sorter separation products, the recovery of -6+3 mm sized diamonds from tailings of X-ray luminescence sorters was achieved at the level of 96%, while the diamonds recovery was 98.5% in value terms, the concentrate yield was 0.1%. In-process tests of RGS-1M sorters at final recovery of the grease separation concentrate at the Processing Plant #3 of Mirny Division were carried out. Recovery of low-luminescent -6+2 mm sized diamonds by RGS-1M sorter amounted to 92.4% for single operation, and with the double control operation reached 99%. As a result, -6+2 mm sized base product recovery increased by 0.2%."

Jan 1, 2018

By Xiong Dahe

In recent years many creative technologies are applied to SLon vertical ring and pulsating high gradient magnetic separators. SLon-2500 and SLon-3000 vertical ring and pulsating high gradient magnetic separators are created towards larger scale. Through optimizing the magnetic system and lowering the electric current density, their energy consumption is obviously dropped. New magnetic matrixes are developed to raise the beneficial efficiency of valuable minerals. Special SLon vertical ring and pulsating high gradient magnetic separators are developed which can treat coarser particles of 0-5 mm. Through these technology creations, the mineral processing efficiency of SLon magnetic separators is further raised and their processing cost dropped. Therefore, they have been found wider applications. SLon-2500 applied in Essar Steel of India. In 2007, Essar Steel did a test on its Kirandul hematite ore with SLon magnetic separator and got very good results. The feed grade is 59.77%Fe, after SLon one roughing and one scavenging, the total iron concentrate grade is 65.00%Fe and iron recovery 93.86%. In 2008-2010, the company bought 10 SLon-2500 magnetic separators to treat such iron ores. In 2010 the first SLon-3000 was applied to processing ilmenite. The magnetite-ilmenite deposit is located in Pan Zhi Hua, Si Chuan Province of China. The ore processing flow sheet is: Drum low intensity magnetic separator is used to take out magnetite, and then the SLon-3000 is used to recover ilmenite for roughing. The mags of the SLon-3000 are further cleaned by flotation. The SLon-3000 average operational results are: feed grade 9.52%TiO2, mags grade 17.43%TiO2, mags mass ratio 41.01%, TiO2 recovery 75.09%, non-mags grade 4.02% TiO2, non-mags mass ratio 58.99%. SLon magnetic separators Applied to treat 0-5mm limonite: The feed of SLon magnetic separator is usually 0-2 mm which needs to be ground by ball mill. As many Chinese iron ores are poor grades, if we can throw part of tails before grinding, the grinding cost will be greatly reduced. In 2010, a SLon-1500 and a SLon-2000 were specially built to treat 0-5 mm limonite. The feed grade is 26.51%Fe, mags grade 53.20%Fe, iron recovery 64.26, and tails grade 13.66% Fe. SLon-2500 applied to purify quartz. In 2009, a SLon-2500 magnetic separator was applied to purify quartz in Shan Xi province. Its feed is 0-1mm quartz which contains 0.15%-0.25%Fe2O3, the designed non-mags grade need to be less 0.08% Fe2O3. The production results of SLon-2500 non-mags are 0.05-0.06% Fe2O3, much better than the designed data. SLon applied in Si Jia Ying Iron Mine to recover hematite. Si Jia Ying is a big oxidized iron mine located in He Bei Province of China. In 2005-2010, a plant annually treating 10 million tons of oxidized iron ore was built in which 39 SLon magnetic separators are applied. The total flow sheet results are: Feed grade 30.44%Fe, iron concentrate grade 66%Fe, iron recovery 80%Fe, tails grade 9.65Fe%. SLon applied to recover specularite. Li Lou Iron Mine in An Hui Province of China built a plant annually processing 5 million tons of iron ore in 2010-2011. 25 SLon-2000 magnetic separators are applied to recover specularite. The total flow sheet results are: Feed grade 31.65%Fe, iron concentrate grade 65%Fe, iron recovery 80%Fe, tails grade 10.37%Fe. SLon applied in Da Hong Shan Iron Mine. Da Hong Shan Iron Mine is located in Yun Nan province of China. It treats 4.5 million tons of oxidized iron ore annually. 15 SLon-2000 magnetic separators are applied to recover hematite. The total flow sheet results are: Feed grade 35.61%Fe, iron concentrate grade 64.95%Fe, iron recovery 74.08%Fe, tails grade 15.55%. Keywords: SLon magnetic separator, iron ore, ilmenite, quartz, beneficiation

Sep 1, 2012

By Katja Ohenoja

Polymer dispersants, also known as grinding aids, are widely used to reduce the viscosity of mineral particle suspensions and to improve energy efficiency during fine grinding. In this study, the effect of polymer dispersant with different molecular structure on the suspension properties in the wet stirred media milling of limestone was studied. The stability of suspension was studied by combining rheological and zeta potential measurements. The PDI value of polymers corresponds to the width of the molecular weight distribution so that low PDI corresponds to narrow MW distribution and high PDI to the wide one. In this study, two traditionally fractionated polymer dispersants with high PDI (over 2) and one novel polymer dispersant with low PDI (1.2) has been tested. It was noticed that dispersants worked as electrosteric stabilizators and prevented the agglomeration of ground limestone particles. The uses of dispersants could increase solids concentration used in the grinding experiments and at the same time lower the particle size and specific energy consumption. The obtained particle sizes were about 1 µm regardless of which dispersant was used or the amount of it. The novel dispersant with low PDI reduced viscosity most when compared with the traditionally fractionated polymer dispersants. Results indicated that even higher solids concentrations can be used at the same amount of dispersant when the novel low PDI polymer dispersant is used. Alternatively, lower dosage of novel low PDI dispersant can be used compared to traditionally fractionated dispersants.

Sep 1, 2012

By C. Dorfling, S. Bradshaw, J. Eksteen, M. Khesa, C. A. Snyders

Titaniferous ores serve as a major feedstock for the production of a white titanium dioxide pigment, a titanium metal and several other titanium-based products. Such ores exist mainly as heavy mineral sands. Ilmenite is upgraded to intermediate products namely synthetic rutile and titania slag through the synthetic rutile route and the reductive smelting route respectively. Tronox KwaZulu Natal Sands (Pty) Ltd recovers high titania slag via the reductive smelting process while slag is used as a feedstock to the pigment industry and furnace dust from the gas cleaning plant is disposed as waste. Previous investigations have shown that such furnace dust can contain significant amount of titanium-bearing minerals. This study looks at the characteristics of the furnace dust obtained from Tronox KwaZulu Natal Sands and investigates a possible high temperature recovery route in detail. The furnace dust was examined by using x-ray fluorescence, x-ray diffraction, microscopy and laser-diffraction size analyses. The characterization work showed that the furnace dust was rich in titanium and iron, containing 49.4 wt% ??????2 and 29.5 wt% ????2??3. These oxides were associated with Si, Mn, K, and Al oxides as impurities. A Carbolite® vertical tube furnace was used to investigate the extent of formation of titania slag and metallic iron on a laboratory scale at 1500°C, 1600°C and 1650°C. The laboratory reduction tests revealed that the slag samples with an equivalent titanium dioxide content ranging from 70.9 -76.9 wt% at 1600°C and 1650°C could be obtained. The Fe content of the metallic iron samples produced ranged between 93.0 and 97.1 wt%. The experimental results were found to be in relatively good agreement with the FactSage simulations, both of which demonstrated the potential of producing a titania slag and a metallic iron from the furnace dust.

Jan 1, 2018

By J. D. Miller, C. L. Lin

In general, x-ray computed tomographic (CT) techniques are able to provide 3D images of the internal structure of opaque materials in a nondestructive manner. The unique cone beam geometry allows acquisition of all 2D projections with only one rotation of the sample thus providing for fast data acquisition and better x-ray utilization, as a complete 2-D detector array receives the cone-shaped flux of rays. Thus, an isotropic 3D volume can be reconstructed without the mechanical translation and the stacking of sequential slices as is the case for more conventional CT scanners. In this regard, a state-of-theart, custom designed x-ray microtomography facility to provide very detailed 3D spatial analysis of multiphase particles has been installed and is in operation at the University of Utah. The reconstructed 3D tomographic volume allows for an adjustable spatial resolution from 5 to 20 microns for sample dimensions from 10 to 40 mm in diameter, respectively. For example, a packed bed of coal particles is shown below in which different crystalline froms of pyrite are distinguished in 3D.

Jan 1, 2003

By S. J. Neethling

"Liberation is a key driver in all mineral separation processes as it limits the maximum possible grade for a given recovery. In flotation, this is further complicated by the fact that it is surface exposure of the floatable minerals that determines the ultimate performance. Liberation, grade and surface exposure are commonly quantified using Scanning Electron Microscopy coupled to Energy Dispersive X-ray spectroscopy (SEM/EDX) analysis of polished sections. The intrinsically 2D nature of this technique can result in significant sampling errors and stereological effects that can affect the quantification of the ore’s textural characteristics. X-ray micro-Tomography (XMT) is an imaging method that can non-invasively and non-destructively delineate ore fragments in 3D, thus providing an alternative method that eliminates the need for stereological corrections and readily provides surface exposure. A methodology and automated algorithm were designed for extracting this information from images of closely packed particles, thus allowing samples containing a large number of particles to be assessed.The main drawback of XMT is that, unlike SEM/EDX, it cannot directly measure the mineralogy of the sample, instead producing a 3D X-ray attenuation map. We therefore also present an algorithm for calibrating the thresholding of the XMT images based on SEM/EDX images of sections through the same sample, thus allowing the liberation analysis to be carried out on a 3D mineral map in which the uncertainty in the mineral assignment is small and statistically quantified.The methodology was tested on low grade porphyry copper ore as this is both an industrially relevant and traditionally difficult system to quantify using XMT due to the similarity in the X-ray attenuation of the sulphide species, especially the pyrite and chalcopyrite. As each 3D volume imaged contain 100-1000s of grains, large data sets can be readily produced. By dividing these particles into classes based on both their surface exposure and grade, the extent to which there is preferential breakage of the particles can be assessed—an important consideration if sufficient surface liberation for good flotation performance is to be achieved at coarser particle sizes. It is also shown that erroneous conclusions can be drawn when basing the analysis on 2D sections through the particles."

Jan 1, 2018

By R. Sakthivel

Blue dust is a high grade soft haematite material containing 96.14% Fe2O3 transformed into magnetite (Fe3O4), when it is subjected to planetary ball milling in the presence of iron powder as reducing reagent. X-ray diffraction (XRD), Field emission scanning electron microscope (FESEM) and Laser particle size analyser have been employed to characterize various samples collected at various milling times to know the phase evolution, particle size distribution and morphology of particles. X-ray diffraction studies reveal the formation of magnetite phase at the optimum milling time of 40 hours. Vibrating sample magnetometry (VSM) study demonstrates, that sample obtained at 40 hours of milling time exhibits saturation magnetisation of 14.757 emu/g whereas the starting material used in this study shows only 1.0425 emu/g. Keywords: Blue dust, reaction milling, magnetite, saturation magnetization

Sep 1, 2012

By Ana C. C. Pacheco, Maurício L. Torem

"The aim of this work was the study of the effect of the type (Fe3+, Al3+ and Fe3+ and Al3+ mixture) and of the coprecipitant concentration on As5+ removal by ACF. Removal of As5+ using Sodium Dodecylsulfate (SDS) as a collector was studied by Adsorbing Colloid Flotation (ACF) at laboratory scale. The morphology of the precipitate retained in the foam was analyzed by Scanning Electron Microscopy (SEM/EDS).By comparing the coprecipitant type and concentration studies it could be concluded that As5+ removal in the presence of Fe3+ (160 mg.L-1) alone, or a Fe3+ (80 mg.L-1) and Al3+ (40 mg.L-1) mixture, is equivalently effective (99,9%) and greater than in the presence of Al3+ (80 mg.L-1) alone (97,7%).Through SEM/EDS analyses, it was possible to observe that both morphology and composition of the precipitate produced in the solution and retained in the foam depend on the physico-chemical conditions of the system, that is, on the species present in the solution."

Jan 1, 2003

By David Verrelli, Melissa Kistner, Leanne Smith, Chris Aldrich, Lidia Auret, Warren Bruckard

In this investigation, different mixtures of realgar and orpiment particles were floated in a laboratory batch flotation cell and multivariate image analysis was used to estimate the arsenic content in the froths. The analysis was based on the froth colour, as well as extraction of three groups of textural features, namely those based on grey level co-occurrence matrices (GLCMs), wavelets and local binary patterns (LBPs). Collectively, these features provided better information on the arsenic content of the froths than any one of the individual groups of features. Partial least squares models could explain approximately 78% of the variance in the arsenic by using all the features combined. The colour content, particularly the green component in the red-green-blue (RGB) features, provided almost as much information as each of the three sets of texture-base features individually.

Jan 1, 2014

By J. Y. Liu

The comminution in a high-pressure roller mill is modeled by an energy-based population balance approach considering three aspects of breakage taking place in the active zones of the mill: the interparticle breakage in the high-compression zone, the breakage at the edges of the rolls, and the pre-breakage in the acceleration zone. Together with an appropriate model of classification, this model can be used to simulate steady-state performance of closed-circuit grindings with high-pressure roller mill. After a brief description of the basic modeling approach, the algorithm of the steady-state calculation for a generalized grinding-classification circuit is presented, from which the circuit configurations commonly met in industrial practice can be derived. With an iron ore as feed material for example, simulation results are shown and discussed in respect of circulating load, specific energy consumption and product fineness for closed-circuit grindings under various operating conditions. The effects of stressing intensity, working gap, classifier parameters as well as circuit configuration on the overall circuit performance are investigated systematically by means of computer simulation.

Jan 1, 2014

By C. L. Lin

Previous research on particle damage during high pressure grinding roll (HPGR) crushing was limited by the resolution of point-projection micro CT systems and the extent of damage was described by the percent of particles cracked for different crushing methods as determined at a voxel resolution of 40 microns. With recent advances in X-ray optics, the resolution afforded with point-projection micro CT systems has been improved by at least an order of magnitude using a lens-based X-ray micro CT system. With the use of X-ray lens imaging the resolution is determined by the lens rather than by the spot size of the micro-focus X-ray source. The high resolution X-ray micro CT (HRXMT) system made by Xradia with a voxel resolution of less than 1 micron is now being used for the characterization of particle damage during HPGR crushing. In this way, the direct 3-D determination of the internal damage of crushed ore particles which vary from 40 mm down to 100 microns in size is being studied at a voxel resolution of a few microns. The number, size, and shape of cracks can now be measured at this improved resolution and for the first time the specific crack surface area distributions of the crushed product can be calculated from HRXMT images using specially designed software tools for 3D analysis. Results from selected crushing operations are presented. Copper ore particles from HPGR crushing at high pressure (6 N/mm2) are severely damaged having crack specific surface areas as great as 10 mm2/mm3. Keywords: HPGR, particle damage, X-ray micro tomography, crack surface area

Sep 1, 2012