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By Eric Toh, Michel David

"Geo-statistics was born from mining problems: grades not being what was expected; more tons of waste than expected; in other words, dilution. Geo-statisticians now claim to have solved many of these problems, but the solutions seem to have a hard time being picked up by practitionners. One of the reasons may be the jargon which geo-statisticians are using. The reason for jargon is that obtaining solutions required a strict formulation in a statistical framework. Practicing mining engineers and geologists are not used to such a framework, and they are not familiar with the jargon. In this paper, the authors re-examine dilution in operating mines and answer two extremely practical problems, using practical language as much as possible. Can dilution be reduced by improving the quality of blast hole samples? How many samples are needed to obtain a good ore-waste discrimination, i.e. to reduce dilution to acceptable levels? Citing real situations, this paper will try to show how fairly simple concepts can be used to answer both problems. It will try to present the solut ions using a minimum of jargon, even if the theoretical solution could be obtained in a few precisely worded paragraphs.The two problems considered are the following: the first one was encountered in the Panguna deposit of Bougainville Copper Limited, P.N .G., but it occurs in every open pit operation where selective mining is required. As the cut-off is lowered, more and more mining occurs in marginal areas. Grade control is mostly based on the grades obtained from blast holes, hence, it is essential that the quality of the blast hole samples be as good as possible in order to reduce dilution, waste being sent to the mill and ore being sent to the waste dump.The second example stemmed from the grade control technique used in many gold open-pit operations in Western Australia: channels are cut on lines 5 m apart and assays are taken every metre. The pattern in the same regardless of rock type, whether one is in the oxidized zone or not. The number of samples to be treated is enormous, hence, the question arises how to find an acceptable sampling grid, and whether changing it can reduce dilution at an acceptable cost.A solution will be given to each problem separately, although in fact it could be seen that the formal framework is the same in both situations."

Jan 1, 1989

By Y. Wang

Phosphates and fluorides are used as regulators for the removal of silicates from diasporic-bauxite both in direct and reverse flotation. While using dodecylamine chloride as a collector, micro-flotation studies showed that sodium hexametaphosphate has stronger depressing power on diaspore than on silicate minerals with increasing sodium hexametaphosphate concentration at pH 6.5, but sodium fluorosilicate shows poor depression on diaspore with increasing sodium fluorosilicate concentration at the same pH. Zeta potentials of diaspore and silicate minerals become more negative both in the presence of sodium hexametaphosphate and sodium fluorosilicate. Adsorption density studies indicated that the adsorption density of sodium hexametaphosphate on diaspore is much higher than that on silicate minerals at the concentration of 75 mg/L. FTIR spectroscopy studies show that sodium hexametaphosphate interacted with the Al atoms exposed on the diaspore and silicate minerals surfaces to form P?O?Al bonds through the P02 groups. It is possible that sodium fluorosilicate interacted through F- or [SiF6]2- with silicate minerals surfaces based on the analysis by AES.

Jan 1, 2006

By V. A. Leão, M. L. M. Rodrigues, L. C. Sicupira, I. C. B. Rodrigues, T. C. Veloso

Brazilian sulphide ores can contain a significant content of chloride and fluoride, which are harmful to bacteria and thus bioleaching. This work summarizes a four-year research investigation on the effect of fluoride on both bacterial growth and sulphide bioleaching, supported by studies carried out with secondary copper ores. Firstly, the influence of fluoride on the kinetics of ferrous iron bio-oxidation with Sulfobacillus thermosulfidooxidans was addressed. Values as low as 10.0 mg/L F- fully inhibited bacterial growth, although fluoride toxicity could be overcome by the presence of aluminium, which reduced the concentration of hydrofluoric acid through the formation of aluminium-fluoride complexes. This required at least a 2:1 aluminium/fluoride molar ratio, which ensured bacterial growth rate values similar to that observed in the absence of fluoride ions. Subsequently, both batch and column bioleaching with mesofiles (30 ºC), moderate thermofile (50 ºC) or hyperthermophiles (67.5 ºC) of two secondary copper ore samples were analyzed with focus on the relevant effects of fluoride-containing minerals on the bioleaching of such sulphide ores.

Jan 1, 2014

By Roland Froidevaux

"The main object of ore reserve classification is to assess the reliability of an ore reserve estimate. Because traditional classification schemes fail to provide a means of calculating this reliability, the terms 'proven "" 'probable' and 'possible ' ore were introduced as an attempt to qualify it.Geostatistics, on its part, allows the quantification of the precision of any ore estimate and thus appears as an appropriate tool for ore reserve classification.However, the problem of fixing quantitative boundaries for ore classes remains. In order to be meaningful, ore class limits based on the degree of reliability should be customized to the commodity, and the type and size of the deposit. In addition, the precision of an ore estimate will be affected by the cut-off grade and the size of selective mining units.IntroductionPrimarily, ore reserve classification should be seen as a communication tool between the geologist and the mining engineer on one hand and the management and policy maker on the other. By classifying ore reserves, the geologist tries to answer the very fundamental question: ""What quantity of metal is there in the ground and how sure am I that it really exists?""The difficult y of quantifying the degree of reliability of reserves has led to the creation of a large suite of terms and definitions, with almost every mining company having its own set of definition standards. As lower-grade deposits are brought into production, the margin of tolerable error in estimates of the grade and tonnage is becoming much narrower. Consequently, the need for unequivocal definition of the reliability of ore reserves is increasingly acute. Most of the generally accepted systems of classification, however, describe the reliability of reserves in qualitative, rather than quantitative, terms."

Jan 1, 1982

By S. Dallaire

"RÉSUMÉLes revêtements céramiques ont une moins grande visibilité que les revêtements métallurgiques. Ils ont cependant jour un role significatif dans noire développement technologique. Les procédés de revêtement ont permis de s'affranchir de barrières technologiques importantes dans le domaine de l'optique, de l'électronique, de l'usure, des hautes temperatures. L'introduction de nouvelles technologies ou la mise en service de nouveaux matériaux peut nécessiter l'adaptation de certain procédés actuels ou le recours a des procédés qui ont peu percé jusqu’ à maintenant.ABSTRACTApplications concerned with ceramic coatings are not as well known as those with metallic coatings. However, ceramic coatings have played a tremendous role in the development of technology. Ceramic coating processes made it possible to overcome technological barriers in the areas of optics, electronics, wear resistance and high temperature applications. Ceramic coatings can provide new properties to materials never considered for demanding applications. They can also open new frontiers and revitalize materials which are maturing or in decline."

Jan 1, 1990

By Scott K. Palm, Neil D. Pearson, Jr. Read

"Uncertainty is an important feature of many investments, but it is especially important for mineral properties. Mine properties often entail large investments and fixed commitments. Managers in the mining industry often view price uncertainty as undesirable, due to the possibility that the price of the mined commodity will fall to a level that prevents the firm from recovering its investment and fixed costs. This paper identifies pitfalls in conventional valuation methods and outlines a new approach to valuation based on option pricing theory and dynamic programming. In the process, it identifies generic strategies for organizing mine production in ways that allow the owner to benefit from the uncertainty in mineral prices. IntroductionRisk is pervasive in the mining industry. The operation and maintenance of a mine may involve high, and unavoidable, fixed costs. A mine owner can only begin to recover these fixed costs if the price of the mined commodity is greater than the incremental cost of production. But the prices of many minerals are extremely volatile. The price volatility of copper has been significantly higher than the price volatility of a typical stock, for example. A mine owner cannot be sure that the price of the mineral product will remain high long enough for the firm to recover its capital and fixed costs.Mine owners are able to minimize their losses during periods when the output price is below the incremental cost of production by temporarily closing operations. During these periods they incur only fixed costs. While shut-downs help minimize losses, the y do not help the firm recover its initial investment. If output prices remain low long enough, the fixed costs and original investment may never be recovered. High fixed costs, therefore, lead to substantial downside risk."

Jan 1, 1986

By A. G. Roach

IT IS generally stated that the gold ores of Nova Scotia are free-milling, and for the most part this is true. However, there is a certain proportion of the gold finely disseminated throughout the sulphides, notably arsenopyrite, and this gold is definitely not recoverable as 'free-milling' gold by amalgamation. The proportion of free-milling gold to total gold seems to vary widely in different localities in the Province and is lowest in deposits of the fissure-vein type. The problem of recovery of these relatively recalcitrant values is usually one of economics, in some plac.es a simple gravity concentrate being of such low tenor that its extraction and subsequent disposal will not bear the costs involved. In other cases, such a high percentage of values escapes from the mortars and plates that concentration is definitely indicated. The size of the mining operation is also an important factor. In the large majority of cases, however, some concentrating step is warranted, even if the resulting concentrate is stock-piled until sufficient has accumulated to justify further treatment.

Jan 1, 1940

By William Petruk, Donald Leroux, Michael Cooper

"Brunswick's primary flotation circuit (CuPb) produces a low grade concentrate containing considerable amounts of undesirable sphalerite and pyrite. To determine the cause of the poor selectivity, a series of Quantitative Mineralogical Analyses (QMA) were performed on several CuPb circuit streams. It was observed that significant fractions of sphalerite and pyrite reporting to the concentrate was liberated, meaning that their depression was not complete. The study highlighted the need for some R&D efforts to be spent in sulphide flotation fundamentals.IntroductionThe viability of many mining projects strongly depends on the performance of their concentrators. More than ever, competitive grade concentrate and high metal recoveries are criteria of paramount economic importance. The selectivity of solid/solid separation processes used in concentrators must be maintained at high levels or continuously improved.Flotation is the solid/solid separation process used by most base metal producers. In spite of its low operating cost, flotation remains a very complex process. To make it selective, precise reagent dosages and electrochemical conditions must be maintained. The difficulty in controlling flotation lies in the numerous heterogeneous reactions that can take place between the different solid, liquid and gaseous phases involved. This complex chemistry makes flotation selectivity difficult to understand and, therefore, to improve from a theoretical point of view.Brunswick Mining and Smelting, near Bathurst N.B., operates a 10500 tpd concentrator which produces four concentrates through five stages of sequential flotation (Figure I). Various reagents are added at key process stages while the ore undergoes different electrochemical conditions. Although the selectivity is important at all stages, the performance of the very first separation, the CuPb circuit, is the most critical. It is here where mineral misplacement to the wrong stream has the greatest economic consequences."

Jan 1, 1996

The steam-filtration process for dewatering solids involves the application of slightly superheated steam to a filter cake during filtration. The mechanism by which the technique promotes water removal has been deduced from bench-scale experiments on coal and on granular iron ore concentrates. The mechanism, along with some of the applications and limitations of the process, is presented. Introduction I N the steam-filtration process, slightly super-heated steam is applied to the filter cake during filtration to remove more water than can be extracted by conventional filtration. Although this process was developed by Burton for coal filtration (1), it should have far wider applicability; certainly, it could be used to treat any mineral product, because only low-temperature steam is needed and most conventional filtration equipment can be easily adapted to it. As few restrictions apply to this process, however, it is important that its more obvious advantages and disadvantages be appreciated and, especially, that the criteria on which economic evaluations can be based are understood.

Jan 1, 1965

By C. J. Hall

This paper presents a basic motive column analysis of natural ventilation and shaft resistance, using the density depth diagram. The method makes use of tables showing the state of the air as determined by thermodynamic analysis. Several theoretical examples are given.

Jan 1, 1968

By M. Pawlik, E. Arinaitwe, V. Ferrera

A series of flocculation tests were performed on dilute quartz suspensions with the use of five polyacrylamide-based flocculants of similar molecular weights but of different degrees of anionicity. The tests were performed as a function of ionic strength and pH. The macromolecular conformation of flocculants in solution was assessed through intrinsic viscosity measurements under the same physicochemical conditions as those of the flocculation tests. It was generally found that the flocculating efficiency of the polyacrylamides correlated with their ability to coil or stretch in solution. Polyacrylamides with the degrees of anionicity on the order of 10-18% showed the highest flocculating efficiency in terms of the settling rates of the flocculated solids and the residual turbidity of the resulting supernatant. At the same time, these most effective flocculants were also found to exhibit the greatest tendency to coil and stretch in solution. This result suggests that the flocculating power of a flocculant is determined not only by its ability to adsorb onto (and bridge) fine particles but also on its ability to conform to the size of the resulting floes.

Jan 1, 2009

By Andrew L. Mular, Robert P. Edwards

"The operation of flotation circuits is often regarded as a combination of art and science. Expert systems offer a method by which the art may be captured and supervisory control of flotation circuits fully realized. Operating knowledge, the art, can be consistently employed to enhance regulatory control through the judicious application of an expert system. Using an expert system, a supervisory control routine was developed, and success- fully implemented, in the copper flotation circuit at Brenda Mines Ltd.The expert system ran in conjunction with regulatory PI controllers on a personal computer. The expert system received assays via an on-stream analyzer and adjusted regulatory loop set points as required in real-time. From its commissioning in November, 1989, to the end of the mine 's operation in June, 1990, it was enthusiastically embraced by the operators and attained operating levels superior to those achievable manually.IntroductionExpert system (ES) software springs from research into artificial intelligence and is currently making significant inroads into business and industry. ES proponents make many attractive claims; they are a means of capturing the knowledge of experts and they can be programmed by non-programmers. To date, most uses of this software in the process industry are in off-line applications, meaning that the applications are not tied directly to operating (on-line) environments. Moreover, in on-line environments, they are typically employed as advisors and only suggest changes. Human operators are required to close-the-loop to the process. Yet, an ES should be applicable to operating environments and, if the claims of the proponents are valid, should also be better than existing tools. As an intelligent controller an ES must use the knowledge of experienced operators, apply it directly to a process and do this without the intervention of human operators. On-line applications have been successfully employed in the closed loop control of SAG circuits (Herbst et al., 1989) and flotation circuits (Hales, 1989). Harris and Kosick (1988)detail an implementation for flotation control at the Polaris Mine."

Jan 1, 1992

The mixer that is commonly encountered in hydro metallurgical operations consists of a single turbine and tank combination. However, it would be advantageous to examine some common solvent extraction mixing systems in the light of the fundamentals of chemical reactor design. The basic concepts of reactor design are commonly used in the chemical industry, and it should not be too difficult to apply them to solvent extraction. The factors that affect the engineering design of a reactor are: the reacting system; the type of reaction; and the configuration of the reactor. The reaction system in solvent extraction consists of a heterogeneous liquid phase, involving two immiscible liquids. It is essential f or the process that the reactor product can be separated efficiently in the subsequent settler. The type of reaction in solvent extraction system may be quite complex, and the picture is complicated by the presence of competing and side reactions. The reactors themselves have been generally continuous stirred tanks, and the nature of the mixer-settler makes it unlikely that the pumping mixer can be dispensed with. However, it appears that there should be some definite advantages to a system of stirred reactors in series. The kinetic experiments which are carried out should have the definition of optimum reaction conditions as one of their goals. The data obtained from these experiments must also be applicable to the design of reaction equipment. Reactor selection and design is often a unique problem for each chemical process, and does not lend itself to a systematic general approach. However, the application of chemical and physical principles to mixer design in solvent extraction should result in practical, more efficient plants.

Jan 1, 1979

By M. A. EI Zeky, A. E. El-Nikbaily, M. A. Shahin

"Possible mechanisms of microsilica dust formation and factors affecting its quantity have been discussed. General mathematical models to predict the dust quantity based on electrical and coke consumptions, and flue gas temperature as functions of silicon recovery in the process and silicon content of the alloy have been established. It has also been shown that the flue gas temperature can be used as an additional process control parameter. Comments are made on the effect of the dust formation on the whole process economics and it is pointed out that the formed microsilica dust is a valuable by-product and not an industrial waste. INTRODUCTIONFerrosilicon is produced in electric arc furnaces with submerged electrodes. The charge mixture consist s mainly of quartzite, coke as the reducing agent and iron chips. The products are ferro silicon and carbon monoxide, various other volatile materials, water vapour and silicon monoxide gas. Carbon monoxide and silicon monoxide oxidize at the charge surface when mixed with air entering through the furnace hood openings. The off-gas contains a considerable amount of dust, which is mainly very fine particles of silica formed as a result of oxidation. The emission of dust containing gases to the atmosphere causes serious pollution problems to the environment. Therefore, the control of the formation of the dust, preventing it from escaping to the atmosphere, and dealing with this very fine dust collected from the flue gases represent important technological and economical parameters in the ferrosilicon production industry.This paper is concerned with the relations between the quantity of formed micro silica dust, as a function of both silicon recovery and silicon content in the alloy, and various other technological parameters; and their possible effects on the energy consumption and economics of the whole process."

Jan 1, 1989

By P. M. Huck, R. John

"The National Uranium Tailings Program was established in 1982 to develop, in part, a mathematical predictive model which would allow the assessment of the impact of uranium mill tailings on the environment and particularly on humans. . To achieve this , various studies were undertaken to establish the role played by key constituents of the tailings. This paper summarizes the findings of a study carried out under that program, to examine the leachability of barium-radium sulphate sludges produced in the treatment of uranium mill tailings decants. The investigators performed detailed chemical an alysis of the sludge, applied geochemical computer models to investigate sludge leaching behaviour, and conducted experiments to assess the impact of bacteria on leaching. The modelling showed that the redox state o f the sludge-leachant system was the most important factor. Substantial bacterially-mediated dissolutio n of the sludge and release of radium was demonstrated experimentally under suitable reducing conditions . INTRODUCTIONIn September 1981, Phillip A. Lapp presented the final report of the National Technical Planning Group on uranium tailings research to the federal government (Lapp, 1981). Lapp' s group had performed an in-depth survey of the status of uranium tailings research in Canada and, as a result, recommended that a national program be funded in the amount of $18 .6 million. Half of this fund ing was to come from the federal government, with the two producing provinces , Ontario and Saskatchewan, providing the balance. However , the provinces declined to support the program and the federal government decided to inaugurate a reduced program with $8.5 million o f funds .In late 1982, the formation of the National Uranium Tailings Program (NUTP) was announced by the minister of state for mines. A primary objective of this program was to develop a mathematical predictive model that would permit the assessment of the impact of uranium mill tailings on the environment, a nd particularly on humans. The program was to use existing information to the greatest possible extent, and then fund research to fill in gaps or substantiate data where necessary .The NUTP was established to administer this program of contract research over a five-year sunset life. By the end of the 1986-87 fiscal year the NUTP had completed about 100 contracts. One of those projects was to study the effect of placing barium-radium sludge ba ck within the tailings matrix. Th is paper gives the results of that study."

Jan 1, 1989

By Amyn S. Dahya, David J. King

"The object of the paper is to discuss the developments in Carbon-In-Pulp (C.I.P.) technology for gold recovery. The CIP process is comprised of four major operations:(a) adsorption of precious metals onto activated carbon;(b) elution (stripping) of precious metals from the loaded carbon;(c) electrowinning of the precious metals from the concentrated eluate;(d) regeneration of the eluted carbon before recycle to the adsorption process.A detailed review of the technological developments in each of the above operations is presented together with a brief theoretical background of the underlying processes. The advantages and disadvantages of the CIP process are discussed in comparison with conventional zinc precipitation. IntroductionThe carbon-in-pulp (CIP) process involves the use of activated carbon for treatment of pulps containing dissolved precious metals, and provide s an alternative to the conventional gold recover y processes using filtration or counter-current decantation in conjunction with the Merrill-Crowe zinc precipitation process. The commercial application o f the CIP process in gold processing technology is a fairly recent development and it is of growing importance around the world.The fact that activated carbon ha s the property of adsorbing precious metals from solution was first published in 1847. In the following years , a great deal of work was carried out to develop an over-all recover y process using carbon, but all attempts were uneconomical because the loaded carbon had to be smelted to recover the gold.It was not until 1950 that Zadra, at the United States Bureau of Mines Research Centre in Reno, Nevada, developed a technique for stripping the loaded carbon using sodium sulphite-sodium hydroxide mixtures and then recovering the gold from the stripping solution by electrolysis. However, this process was not effective for stripping silver and further testwork was carried out on alternative stripping techniques. In 1952, Zadra published a paper describing the use of a hot sodium hydroxide- sodium cyanide stripping technique, which was effective in stripping both gold and silver. This paper included a description and flowsheet for the CIP process which is essentially the same as we know it today. This technique was used in the first major CIP plant, constructed and commissioned in 1973 by Hornestake Gold Mining Company. Since then there have been numerous CIP plants built in the U.S A., South Africa and Australia."

Jan 1, 1983

By Y. Zedan

Cutting fluids play important roles during machining, including the reduction of friction and temperature. Using a cutting fluid, however, degrades the quality of the environment and increases machining costs. The aim of the present research work is to study the effect of cutting fluids and their interactions with cutting parameters on the quality of holes during the drilling of 6061-T6 aluminum alloys. The lubrication types and modes investigated are dry machining, flood lubricant machining and minimum quantity lubrication machining (MQL), while the part quality criteria include the surface finish, the dimensional accuracy, and burr forms and sizes. A scanning electron microscope (SEM) was used to investigate the formation of built-up edges (BUE) in the drill flutes as well as the surface texture of drilled holes. It was found that dry machining and MQL machining can produce parts having quality levels comparable to those obtained in wet machining, when using the optimal cutting conditions.

Jan 1, 2011

By N. Fukatsu

The recent development of galvanic cell-type hydrogen sensor for molten copper was outlined. The principle of the sensing mechanism, the fundamental structure of the sensor, and its performance as a process control device are discussed based on experimental work undertaken by the authors. Besides sensors based on usual perovskite-type proton conducting oxide, those using magnesium-doped alpha alumina, which was recently known as a proton conductor, were investigated and the results at the laboratory scale are reported. Considering the excellent sensitivity at high temperature and the stability to the disturbance from the attendant oxygen activity, magnesium-doped alpha alumina was regarded to be a superior material for the sensors used for such purposes.

Jan 1, 2007

By B. E. Jones

"The area of uranium deposition is situated within the Churchill Province on the western edge of the Wollaston Iithostructural domain where it underlies the eastern edge of the Helikian Athabasca Formation. The Collins Bay deposit is 6 miles north-northeast of the Rabbit Lake mine. Two principal zones of uranium mineralization are described.The ""A"" zone is a partly eroded, high-grade pod of metal oxide and arsenides sheathed by clay-like minerals. It trends north-northeast and lies under 25 to 40feet of water. Uranium mineralization is localized at or adjacent to the unconformity between the Athabasca Formation and the basement rocks. The basement comprises a granitoid Archean terrain overlain by paragneisses of the Aphebian Wollaston Group. ""A "" zone ore contains phyllosilicates, quartz, pitchblende, rammelsbergite, pararammelsbergite, carbonaceous material, galena, gersdorffite, niccolite, carbonate and a trace of sphalerite.The ""B "" zone lies 6,000 ft south of the ""A "", and subcrops under till cover. It is a partly eroded zone composed of metal oxide and arsenides which occur within variably altered Athabasca Formation. Minerals recognized are phyllosilicates, pitchblende, niccotite, gersdorffite, millerite, carbonaceous material, pyrrhotite, skutterudite and a trace of galena. The Athabasca Formation varies from 90 to 160ft thick. Granitoid gneisses of probable Archean age and paragneisses of the Wollaston Group underlie the deposit. An easterly dipping thrust fault transects its length.The deposit is typical of the ""unconformity-type"" uraniumnickel deposits of the Athabasca Basin. Observed features fit well with the ""diagenetic-hydrothermal"" model for such deposits, as envisioned by Hoeve and Sibbald (/978)."

Jan 1, 1980

By W. Basuki, B. Setyotomo, L. Hakim, R. Hendrajaya

Due to high crack sensitivity of slab product of gas and oil line pipe application, its steel making process and alloy composition were evaluated and then improved to overcome its critical solidification process and reduced surface defects. The study was conducted at Slab Steel Plant Krakatau Steel. The purpose was to improve slab surface quality by reducing surface defects so that the slab surface doesn't need to be totally repaired. The method applied was by performing plant trial process, which the secondary process parameters such as alloying method and the casting parameters such as casting powder selection, metallurgical cooling, mould level control, and superheat were continuously monitored and then adjusted to the surface quality of the product. Based on the calculation of Ferrite potential of the steel, the chemical composition was designed to achieve optimum casting parameters in order to avoid high shrinkage during solidification. The results of the study are decreased surface defect quantity, and smooth casting process. The quantity of crack decreased by almost 90%. The slab surface repairing was significantly reduced from 85. % to less than 10%. These new casting parameters and developed alloy composition are then used and standardized for the mass production of the steel.

Jan 1, 2005