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By Louise Corriveau

Exploration strategies have traditionally considered felsic gneiss complexes of the Canadian Shield sterile. This paradigm is challenged with the discovery of extensive granulite-facies Cu-Au, Fe oxides-bearing hydrothermal systems in the 1.4 Ga Bondy and 1.5 Ga La Romaine volcano-plutonic complexes of the Grenville Province. Early identification of magnetite-rich units in association with meta-exhalite and pelite-like units was key to targeting the search for mineralization, protolith information and indicators of pre-metamorphic hydrothermal activity during regional surveys of these frontier terrains. Textural evidences for a volcano-plutonic setting were found. There remained, however, numerous impediments to the recognition that the ubiquitous magnetite-laden units and associated aluminous gneiss were hydrothermal in origin. Many metamorphic reactions form magnetite at the amphibolite to granulite facies transition, and hydrothermally-leached rocks resemble metapelite or migmatitic restite, while carbonate alteration zones may look like marble or calc-silicate rock. Non-typical metamorphic mineral assemblages, modes and colours arise when hydrothermally-derived rock types are metamorphosed. These effective markers served as tools for reliable field identification of hydrothermally-altered rocks. In our case-studies, we traced pre-metamorphic hydrothermally-driven Fe-oxide precipitation in association with sericitization, albitization, pyrophyllite alteration, chloritization, and B enrichment by mapping unusually high contents of (1) magnetite or hematite, (2) biotite, (3) albite, (4) sillimanite, (5) orthopyroxene or phlogopite with cordierite, and (6) tourmaline or kornerupine. The unveiled garnetite, tourmalinite, and aluminous gneiss had assemblages that vary according to metamorphic grade and composition. To assess if high mode of Fe-Mg-Al phases resulted from partial melting (restitic residue) or metamorphism of hydrothermal rocks, we compared leucosome mineral assemblages, shape and amount with that expected of in situ partial melting reactions. In both areas there is no compelling evidence for these units to be restites. In contrast, the presence of lapilli in garnet-cordierite-sillimanite gneiss, though extremely rare, constitutes conclusive evidence for extreme pre-metamorphic high-sulphidation alteration of a volcanic protolith, while Fe-oxides or sillimanite-bearing nodules and veins record a less pervasive alteration. Geochemical research on element mobility and mass balance calculations further testified of an hydrothermal origin for these gneisses. The magnetite-rich units, together with calc-silicate rocks, garnetite, hornblendite, albitite among amphibolite, provided effective guides to sites of fluid discharge and led to the discovery of Cu and Cu-Au showings. With the presence of highsulphidation alteration, these features suggest early Cu-Au VHMS-type alteration halos within a predominantly felsic composite volcano-plutonic arc setting for both case-studies. Evidences for subsequent F-driven orthomagmatic fluid activity are also present.

May 1, 2003

By J. Groppo, W. Zhang, R. Honaker

"The flotation of monazite is depressed when using hydroxamic acid as a collector in the presence of calcium ions which may exist due to the dissolution of minerals such as calcite. Minor dosages of sodium hexametaphosphate (SHMP) were found to effectively depress calcite, whereas the flotation of monazite was not impaired in single mineral flotation tests. However, in a mixed mineral flotation system, monazite flotation was depressed significantly. The mechanism of hydroxamate adsorption on monazite and calcite, the depression mechanism of calcite on monazite, as well as the depression mechanism of SHMP on calcite and monazite were studied using micro-flotation, electro-kinetic, and adsorption tests. Findings indicate that the adsorption of hydroxamate on monazite was due to chemisorption while adsorption on calcite was a result of physical interaction. SHMP significantly increased the negative charges of calcite surfaces which depressed the adsorption of the hydroxamate anions on the calcite surfaces due to an elevated electrostatic repulsion force. When calcium-rich minerals such as calcite are mixed with monazite, the calcium ions dissolved from the mineral surfaces specifically adsorb onto the phosphate oxygen sites on the monazite mineral surfaces thereby causing depressing effects. The addition of SHMP to suppress collector adsorption on the calcite surfaces interacts with the calcium species that were specifically adsorbed onto the monazite surface, which prevents hydroxamic acid adsorption onto the rare earth oxygen sites due steric hindrance and results in the flotation depression of monazite. INTRODUCTIONAs one of the commercial rare earth ores, monazite has been widely exploited to produce additives for catalysts, batteries, alloys, etc. Because of the complexity and the fine nature of some monazite ores, methods such as gravity, magnetic, and electrostatic separation to treat beach sand monazite fail to produce satisfactory concentrates, suggesting the use of floatation is warranted (Cheng, Holtham, & Tran, 1993). The primary associated minerals of monazite ores include ilmenite, quartz, zircon, rutile, sillimanite (Dixit & Biswas, 1969; Pavez a& Peres, 1994, 1993). Using sodium oleate as collector for monazite has been reported in many studies (Cheng et al., 1993; Dixit & Biswas, 1969; Pavez & Peres, 1994, 1993). Several investigations have reported maximum floatability of monazite occurring at pH values between 8 and 9 (Cheng et al., 1993; Dixit & Biswas, 1969). A study conducted by Pavez and Peres (1994) compared the use of hydroxamate and sodium oleate for the treatment of a monazite ore and found that hydroxamate significantly improved the grade of rougher concentrate."

Jan 1, 2016

By W. K. Muwais, R. G. Cuddy

"The Lower Cretaceous McMurray Formation contains the bitumen reserves of the Syncrude Mine in northeastern Alberta. This formation comprises sediments deposited sequentially in fluvial, estuarine and marine depositional environments. The Syncrude Base Mine area consists mostly of estuarine sediments, as much of the original marine sediments have been eroded away. These estuarine deposits consist of channel-fill sediments and interchannel tidal flat sediments with the channel-fills comprising most of the orebody.Channel-fills contain, among other lithologies, interbedded sand, silt and clay rich layers that often occur as sequences of inclined beds with dips up to 25 degrees or more. A detailed knowledge of the distribution of these inclined beds, their lithological characteristics and their continuity is very important in assessing the risk of mine highwall instability . Techniques used to identify and characterize adverse structures are reviewed. INTRODUCTIONGeneralThe Syncrude Canada Ltd. oil sand mine is located within the surface mineable portion of the Athabasca Oil Sands area about 40 kilometres north of Fort McMurray in northeastern Alberta, Canada (Fig. I). The company commenced large-scale strip mining of oil sands in June 1977in the area, referred to as the Base Mine, situated in the southeast corner of the company's two lease areas (Fig. 2).The mining method (Fig. 3) utilizes large electric drag lines operating on a single bench with highwall depths up to 60 metres. Feed grade oil sand (= 6 wt.% bitumen) is mined by draglines and windrowed parallel to the highwall crest. Lower grade oil sand « 6 wt. 0J0 bitumen) occurring as waste bands is selectively mined by the draglines and cast back into the mined out pit or placed on the bench and hauled by truck. The windrowed feed is delivered to the extraction plant by a bucket wheel reclaimer and conveyor system. Stripping of Recent, Pleistocene and Cretaceous overburden units is done outside the conveyor systems by mobile equipment. The 4.5 kilometre long mine is split into four quadrants for planning and scheduling purposes, with each quadrant having an individual dragline-bucketwheel-conveyor system.Surface mining of oil sand at Syncrude requires the removal of vast quantites of material. The design of the open pit mine relies heavily on knowledge of the distribution of ore and waste materials, and on the physical characteristics of these materials.The geology of the oil sand below the dragline bench at the Syncrude Mine is complex. Geological, geotechnical and hydrogeological factors play an important role in the design and operation of the mine. This paper describes aspects of the geology that impact on the design and operation of the mine. Some of the methods and procedures adopted by Syncrude to successfully overcome difficulties that the complex geology creates are discussed."

Jan 1, 1989

By L. K. Mireku

"Abstract - The Halfmile Lake South Deep zone, Bathurst Mining Camp, New Brunswick, was discovered by Noranda Inc. (Exploration) as a result of a 3-D seismic survey in 1998 and the subsequent drilling of ten diamond-drill cores. The deposit consists of massive, breccia, and stockwork Pb-Zn-Cu sulfide minerals, and is hosted by a volcano-sedimentary sequence belonging to the overturned Ordovician Tetagouche Group. Epiclastic rocks and interbedded fine-grained felsic pyroclastic rocks dominate the stratigraphic footwall. Locally, crystal-rich felsic tuffs and subordinate epiclastic rocks comprise the immediate stratigraphic hanging wall. The entire stratigraphic sequence was intruded by quartz-feldspar porphyritic intrusions, and cut by intermediate and basic dikes. The volcanic and sedimentary rocks can be discriminated geochemically using trace element ratios such as Zr/TiO2 and Nb/TiO2, despite intensive alteration and cleavage development. These ratios indicate that four protolith volcanic compositions exist: rhyolite, dacite, andesite, and basalt. The aphyric and feldspar- and quartz-phyric volcanic rocks are dacitic and rhyolitic in composition; epiclastic rocks have trace element ratios consistent with dacitic compositions. Pearce element ratio diagrams, general element ratio diagrams, and petrographic observations demonstrate that the rhyolitic volcanic rocks exhibit evidence of albite, potassium feldspar, and quartz fractionation, dacitic volcanic rocks exhibit little evidence of any fractionation, and epiclastic sedimentary rocks exhibit evidence of quartz sorting only. Hydrothermal alteration is best represented by the presence of phengitic muscovite and daphnitic chlorite. Minor calcite occurs in the stratigraphic hanging wall, deep in the stratigraphic footwall, and in post-mineralization dikes, and thus is not interpreted to be part of the causative hydrothermal event. Element additions and losses during alteration have been used to determine net alteration reactions, and these have been used to identify alteration parameters that are independent of other forms of alteration and fractionation/sorting, and which can be used to guide exploration. These parameters include: a bulk hydrolysis measure, (2Ca+Na+K-2CO2)/Al; a muscovite alteration measure, K/Al; an albite destruction measure, Na/Al; a chlorite alteration measure, (Fe+Mg-S/2)/Al; a chlorite composition measure, (Fe-S/2)/Mg; a sulfidization measure, S/Ti; and a carbonatization measure, CO2/Ti. With the exception of the carbonatization measure, these alteration parameters define a distinct lateral and vertical zone of intense hydrothermal alteration in the stratigraphic footwall of the deposit, and demonstrate that the epiclastic rocks are predominantly chlorite altered, and the volcanic rocks are predominantly muscovite altered. Within the alteration halo, element additions of Fe and H, and element losses of Na are characteristic. Potassium was added to muscovite-altered rocks, but subsequently removed from chlorite-altered rocks. The results from this study demonstrate that metamorphism and deformation have not significantly obscured hydrothermal alteration signatures."

Jan 1, 2006

By E. Bratygin, G. Gazaleeva

"The article describes the analysis of methods and criteria of selectivity of optimal ore preparation schemes. Traditional criteria based on study of physical-mechanical properties of ores give the comparison of obtained figures with a reference standard or statistic data and the selection of the ore preparation scheme is made on a basis of a similar scheme from the existing production.Further on estimation is given to different criteria of the crushing selectivity, the new criterion is offered, the definition of which is done by results of an optical microscopy– the estimation of a valuable mineral release degree. The final estimation of the crushing process selectivity L? is performed by a calculation of a ratio of the valuable mineral free grains quantity in a desired size grade of a crushed material to the valuable mineral free grains quantity in a desired size grade of a raw product.Besides, optimality assessment of using the specific crushing unit is preliminary performed according to a maximum crushing degree of a material, however, the priority is given to the maximum selectivity criterion. The check of the proposed criterion was done when comparing the crushing of niobium bearing ores of the Vishnevogorskoye deposit in cone inertial and centrifugal impact crushers. Different operation modes of crushers were also checked. The comparison of the crushing selectivity criterion L? showed that the centrifugal impact crusher (CC) has the value of the selectivity criterion lower than the cone inertial crusher (CIC). For the crusher CC the criterion L? is 0.82 – 0.87 units, whereas for the crusher CIC – 1.43-1.755 units. The best crushing mode for the crusher CIC-300? is as follows: turning angle of debalance is 120°, peripheral speed of a cone rotation – 1,420 rpm, specific energy consumption – 6.99 kW?t/t.INTRODUCTIONIt has been shown that the most efficient techniques of mineral raw materials disintegration are selective crushing enabling to produce liberation of particles at maximum use of destruction techniques by borders of minerals cleavage. These days, such techniques are usually called special disintegration techniques (Jankovic & Valery, 2015), and they are used in 3–4 crushing stages. The selection of optimal crushing techniques is performed based on the following main parameters:- degrees of crushing, calculated based on granulometric features of raw and crushed products;- selectivity criterion defined according to useful mineral release and slime ability degree; and- traditional criteria (Gazaleeva et al., 2015) of choice based on study of physical-mechanicalproperties of ores gives the comparison of obtained figures with a reference standard or statistic data and the selection of the ore preparation scheme is made on a basis of a similar scheme from the existing production."

Jan 1, 2016

By Avi Nanda, Robert Brandt, Alex Piatkiewicz, David M. Jones

In 2010 the United States Environmental Protection Agency (UESPA) revised the National Ambient Air Quality Standards (NAAQS) by lowering the permissible value to a 1-hour average SO2 concentration of 75 ppb. In 2012, the USEPA designated the Miami area as non-attaining for the new SO2 NAAQS. A number of options were studied to assist in bringing the Miami smelter into attainment with the new standard. The chosen solution included: Installation of a large tertiary hooding system over the converter aisle; Hooding of the anode vessels and treatment of the anode gas in a baghouse; Installation of a large 2,325,212 Nm3/hr caustic scrubber to treat the captured converter fugitives and anode off-gases; Installation of a secondary ESP for the tapping fugitive off-gas treatment system; and the continuous scrubbing of all acid plant tail stack gases. The modifications have reduced smelter SO2 emissions by 85%, achieving a world class SO2 stack emissions rate of 0.45 kg of SO2/tonne Cu. INTRODUCTION The Freeport McMoRan Miami smelter has been previously described in literature (Steinborn, Pasca, Sallee, Binegar, Bhappu). For the sake of brevity a brief description is given here. The Miami smelter is located 129 km east of Phoenix, Arizona near the town of Miami, Arizona. The smelter was established in 1915 and has undergone a number of process upgrades and modernizations over the years. The present smelter consists of an Isasmelt furnace, an electric settling furnace, four Hoboken converters, two anode refining vessels & one casting wheel; and one double contact sulfuric acid plant. Concentrates are railed & trucked to Miami from four Freeport McMoRan mines located in Arizona & New Mexico. The wet concentrates, typically containing 10% H2O with a Cu/S ratio of 0.85, are smelted in an Isasmelt furnace to a matte grade of 58%. The entire output from the Isasmelt is laundered into an Elkem electric furnace (originally installed in 1972 as the primary smelting furnace) for separation into matte and slag. Slag containing 0.85% Cu is skimmed from the electric furnace and discarded. Molten matte, containing 60% Cu, is tapped from the electric furnace and processed in one of four Hoboken converters to produce blister copper. Two anode refining vessels further refine the blister copper before the final product is cast on a single, 30 mold, casting wheel. All of the anodes produced at Miami are shipped to the Freeport McMoRan electrolytic refinery in El Paso Texas for refining into cathode copper. Smelter off-gases from the Isasmelt, electric furnace and Hoboken converters are combined and treated in a double contact acid plant to produce sulfuric acid. Acid produced at Miami is internally consumed at Freeport McMoRan mines in the region.

Jan 1, 2019

By Gary Walters, Matthew White, Thomas W. Gonzales

The copper smelting industry has transitioned into the 21st century compliant with environmental regulations, new smelter installations and brown field expansions. The industry faces new challenges as copper in concentrate grades have decreased while contained impurities have increased. A new benchmarking survey was undertaken to update the last survey of 2016 for operating copper smelters in the world. The information collected was separated based on primary smelting technology rather than by geographical location and supplemented from published literature. Each smelting technology’s unique use of specialized process equipment, concentrate smelting capacity, and impurity flexibility are discussed INTRODUCTION The 20th century was a remarkable time for the growth of copper smelting. Electric, blast and reverberator furnaces dominated the smelting technology well past WWII. In the 1970s, SO2 regulations and high energy cost drove the development of new primary smelting technology. Technological advancements decreased energy consumption and enriched sulfur dioxide concentrations of the process off-gas to levels where sulfur capture in sulfuric acid plants was economically viable. The new smelting technologies began to replace reverberatory and electric furnaces starting in the late 1940s. A new paradigm in copper smelting was established and the enabler was then Outkumpu’s® flash smelting technology from the 1940s through to today. Now, Outotec had become the dominant primary smelting technology with over 44 copper flash smelting furnace installations world-wide. Figure 1 shows the historical installation statistics of primary smelting technologies over the last 70 years (ICSG 2018). The dominance and acceptance of the Outotec® smelting technology from the 1940s to current can be seen. Isasmelt® technology for copper was introduced in the 1970s and did not see advancement in new installations until the 1990s through today. Isasmelt® has 12 world-wide copper furnace installations to date. Mitsubishi® also introduced continuous smelting and converting technology in the 1970s, but had no new installations until the 1990s with a total of 5 copper smelters. Outotec Ausmelt® smelting technology had 3 installations in the 1990s and totals 10 furnaces. Most recently the Chinese technology of Bottom Blown and Submerged Lance Smelting began commercial operations in 2005 for total installations of 11, mostly in China. Other technologies, such as, El Teniente, Noranda, Inco, and Vanyukov furnaces have contributed to the overall global smelting capacity, but have not penetrated the smelting industry to challenge the existing dominant smelting technologies. The technology distribution in Figure 1 also shows flash smelting technology for sulfide concentrate domination untill 2000, bottom blow technology has become the preference in China. Currently, China is the only country building new smelting capacity. Isasmelt® technology also seen a large increase in installations in the current decade.

Jan 1, 2019

By M. Mahdi Aboutalebi, Roderick I. L. Guthrie, Mihaiela Isac

"A preliminary computational fluid flow model has been developed to simulate the flow field of liquid steel in the mold region of billet mold casting. This study reports the effect of different Submerged Entry Nozzles (SEN) on the fluid flow in round and square billet, curved mold, casters. In this study, ANSYS Fluent 14.5 software was used to model the 3-D turbulent flow of liquid steel. The standard k-0 model was used to simulate turbulence in the mold region. Similarly, the species transport equations were discretized to simulate the dye injection test into the mold cavity. The behavior of flow in the mold region was validated against previous experimental work. Predicted results showed that different nozzle types plus the slight curvatures in the molds can significantly influence the flow patterns generated within the mold region, and thereby affect the finished quality of the billet products.INTRODUCTIONConventional Continuous Casting (C.C) processes are presently used to solidify more than 95% of the 1.5 billion tons of steel now produced in the world annually (World Steel in Figure, 2014). This overwhelming contribution of C.C processes for steel production is the prime motivation for this study, in order to understand and optimize the casting processes and thereby reduce internal defects and minimize energy consumption. The primary objective of all C.C processes is to maintain liquid metal purity during the casting process and to create a uniform flow within the caster so as to avoid internal and external defects. In this regard, studying fluid flows in the mold region of continuous caster has attracted many research groups, in both academia and industry, in recent years. The mold region is one of the most critical parts of the C.C. process, in which the transport phenomena associated with this region can significantly affect the quality of the final products. Thus, proper control of fluid flows within this region can be expected to greatly decrease both internal and surface defects such as Oscillation Marks (OM), inclusion entrapment, and Mold Powder Entrapment (MPE). In the casting process, the fluid flow in the mold region can be affected by a number of variables, such as; the flow control system (stopper rod or slide gate), nozzle geometry, SEN (Submerged Entry Nozzle) depth, casting speed, mold dimensions, gas injection, and the application of electromagnetic fields. One of the most influential and easily-changed fluid flows are the jets of steel issuing from the SEN. Nozzle geometries are variable, consisting of a number of exit ports, different port angles, and/or port sizes, the bottom shape of the nozzle, and the SEN immersion depth (Thomas, 2001). The SEN characteristics can markedly affect meniscus surface velocities, surface level profiles, and turbulence levels that can vary in terms of the frequency and the magnitude of their fluctuations."

Jan 1, 2016

By Z. Zhong, Y. J. Hu, D. Elsworth

"A standard triaxial apparatus was set up to perform sliding tests. Slide-hold-slide (SHS) tests, with hold times from 10 to 3000s and at invariant effective confining pressures of 1MPa, incremented to 3MPa and then 5MPa, were conducted on both dry and wet split limestone samples to study the evolution of fracture friction under holding and sliding processes. Limestone fracture shows time-dependent behaviors in SHS tests, friction drops (creep) gradually during hold periods, and recovers (healing) after re-slide. Frictional healing and creep increment are proportional with hold times, while are inversely proportional with effective confining pressures. Moreover, the wet sample displays heavier healing than the dry one, whereas creep increment of the wet sample is lighter than the dry one. We conclude that the evolution of limestone fracture friction is significantly controlled by mechanisms of fluid-rock interactions.INTRODUCTIONThe evolution of the mechanical properties of fractures and faults exerts a critical influence on the behavior of fault zones and on the earthquake cycle. In addition to natural processes, this behavior has broad implications in induced seismicity and influences oil and gas production, the sequestration of carbon dioxide and the disposal of nuclear wastes.Fault friction is typically measured by slide-hold-slide experiments, where fault gouge is deformed at low velocities (<0.1 mms-1) and over small shear offsets (<30 mm) (Dieterich, 1979, 1981; Mair et al., 1999; Marone, 1998, 2004) or alternatively with rotary-shear devices, that enable higher slip velocities over very large shear offsets (Hirose & Shimamoto, 2005; Mizoguchi et al., 2006). Typical experiments (Dieterich, 1972; Marone, 1998; Olsen et al., 1998; Bos & Spiers, 2002; Tenthorey et al., 2003) show significant creep during the holding period and frictional healing (strength gain) upon reloading. Fault creep and healing are often time-dependent with longer hold times typically resulting in greater magnitudes of creep and in strength gains (Tenthorey et al., 2003; Yasuhara et al., 2005; Carpenter et al., 2012). Frictional healing may arise from growth of grain contacts (potentially induced by pressure solution) (Rabinowicz, 1951; Dieterich & Kilgore, 1994; Yasuhara et al., 2005), strengthening of the contacts (correlates with cementation) (Hickman & Evans, 1992; Beeler et al., 1994; Karner et al., 1997; Olsen et al., 1998; Muhuri et al., 2003; Tenthorey et al., 2003; Li et al., 2011) or via other changes in state including changes in porosity and rearrangement of force chains. Experimental evidence (Dieterich, 1979, 1981; Johnson, 1981; Marone & Scholz, 1988; Marone, 1998; Saffer & Marone, 2003; Moore & Lockner, 2007; Ikari et al., 2007; Ikari et al., 2011; Carpenter et al., 2012) quantifies both the mode and magnitude of second-order changes in the velocity-dependent (including velocity- strengthening and weakening) evolution of frictional strength."

Jan 1, 2015

By Lluís Fontboté, François Lieben, Robert Moritz, Massimo Chiaradia

"Abstract - The Las Cañas stratabound Pb-Zn deposit, in northern Chile, is hosted by the Lower Cretaceous back-arc marine carbonate and subordinate andesitic volcanic and volcaniclastic rocks of the Chañarcillo Group, one hundred meters above a thick pile of magmatic arc-related basaltic to andesitic lavas of the Bandurrias Formation. The deposit is not obviously related to local intrusive rocks, which include an Upper Cretaceous granodiorite batholith and dacite dikes emplaced along normal faults. Stratabound Pb-Zn-Ba mineralization is constrained within several porous stratigraphic units, including a 50 cm thick lapilli-tuff and less well mineralized algal-laminated limestone. Veins that locally carry some Pb-Zn occur along normal faults that displace the stratabound orebodies, and this study shows that they represent a different type of mineralization.Fluid inclusion microthermometric data for ore-stage quartz and barite indicate saline fluids (6 to 30 wt% NaCleq) and a formation temperature in the range of 80°C to 160°C for the stratabound mineralization. Two types of fluid inclusions occur in the veins. The type I vein fluid inclusions indicate less saline (average 7 wt% NaCleq) and slightly higher temperature fluids, in the range of 110°C to 220°C. The type II vein fluid inclusions indicate highly saline fluids (25 to 40 wt% NaCleq) which might be related to minor copper mineralization.206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb ratios for galenas from the stratabound mineralization, with mean values of 18.42, 15.59, and 38.25, respectively, fall within the range of stratabound polymetallic deposits of northern and central Chile, and indicate a Lower Cretaceous magmatic rock source. Galenas from veins have slightly more radiogenic 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb ratios, with mean values of 18.47, 15.61, and 38.34, suggesting two distinct episodes of mineralization.?34S values for galena and barite range from negative values (-31.2‰ to -12.5‰ and -7.7‰ to +12‰, respectively) in the mineralized tuff to higher values in the algal-laminated limestone (-2.5‰ to +1.2‰ and +13.2‰ to +17.4‰, respectively), close to Lower Cretaceous marine sulfate values for barite, and homogeneous values for the galena from veins (-12.0‰ ±1‰). Changing redox conditions can partly account for ?34S variations in the tuff. Sulfur sources include magmatic rock sulfur (-1.5‰ to +9.7‰) as well as sedimentary sulfides and marine sulfate."

Jan 1, 1999

By John Hartlen

"The 19th century was an ""age of gold"" and Nova Scotia experienced its share of early gold rushes. Gold mining activity in the province was focussed into three ""rushes"" which occurred, approximately, in the 1860s, 1890s and 1930s; a total recovery of 1.1 million oz. Au has been recorded. The purpose of this note is simply to chronicle the technical development of gold mining and processing in the province and to comment briefly on the recently renewed interest in this precious metal. The first public discovery of gold in Nova Scotia was made by a farmer in 1860 at Old Tangier or Mooseland, and this find sparked the province&apos;s first gold rush. The mining and milling methods of the 1860s were ingenious. Initially, arrastras, crude stone-hewn grinding mills, drawn by men, mules or horses, were widely used. Nova Scotia&apos;s first conventional stamp mill was installed at Mooseland by 1862; it was comprised of four wooden stamps and is believed to have been imported from Scotland. One of the largest waterwheels of the 1860s, reportedly 16 feet in diameter and 8 feet wide with a SO-horsepower rating, was used in the Renfrew Gold District to drive gold stamps. Steam power was also employed, and many of the engines were of native construction, as was the unit at Waverley&apos;s Lake Major Company, which had a piston 1 foot in diameter by 12 feet long and was connected to a 16-ftdiameter flywheel."

Jan 1, 1999

By Robert B. Parsons

"As the 1981 annual reports of Canadian mining companies one by one see the light of day, it becomes clear that softer metal prices and rising costs are the main problems which beset the industry today. These problems are certainly not lightened by that familiar monster lurking in the shadows-taxation! Recent taxation trends in Canada, and the existing tax regimes for the mining industry, continue to be a major bugaboo.This examination by ""Tax Notes"" of the impact of current taxation trends on the mining industry is based on a speech delivered recently by Robert D. Brown, senior tax partner of Price Waterhouse, Canada, to the annual meeting of the American Institute of Mining, Metallurgical and Petroleum Engineers in Dallas.IntroductionThe purpose of this paper is to tell a story-and it is a story with a moral. The first thing to recognize is that, with depressed metal prices and weakening western economies, high taxes, in and of themselves, are not really the cause of the Canadian mining industry&apos;s present doldrums. However, the character and level of mining taxes in Canada has had a profound influence on the development of the industry over the past decade, and the expectations of what the future holds for mining men in Canada will equally play an important role in the future development of the Canadian industry. Our tax system has, in the past, served as a negative and destabilizing influence in the mining industry: it has contributed to a major short-fall in investment commitments and hence in the contribution which the mining industry can make to the Canadian economy, and the adverse effect on the industry of previous high marginal tax rates was made far worse by the confusing, contradictory and perverse nature of the tax system itself."

Jan 1, 1982

By Geo. E. Cole

A GREAT deal of time and energy is now being devoted to the study of post-war reconstruction and rehabilitation, in spite of the fact that as yet we have not won the war in which we are presently engaged. If you feel that the study of post-war problems takes our thought away from the problem immediately before us, you may well query, "Well! What has all that to do with winning the war, our most urgent problem today?" The answer has been given by Principal James of McGill University, Chairman of the Cabinet Committee on Reconstruction: "Reconstruction is something which must be thought of in advance, partly for the purpose of recognizing exactly the influence of war-time activities, controls, and regulations on the post-war Canadian scene. Many people are acutely interested in this great problem. It is not that they are not interested in the war itself, or epochal events that are taking place from day to day. They have a vision of that future which they hope will be Canada&apos;s, and this vision inspires them to even greater efforts at the present time". The trend of events would indicate that changes, economic and industrial, after this war will be greatly out of line with those that followed previous wars in history, for the present struggle has involved every nation in the world. In the peace that will come, every engineer will have a task in bringing the most desirable order out of the most distressing chaos. We certainly are living in a changing world; we are witnessing geo-graphical and economic readjustments that no other generation in world&apos;s history has ever witnessed. And there is an opinion gaining strength in our Dominion, as in other lands, that after this war we shall live in a world in which our process of thinking and our very way of life will have to undergo drastic changes to cope with the new order of things. Sadly our world of today has had to revise the sublime vision that nation shall not lift up sword against nation, while salvage operations continue to beat ploughshares into tanks and the peaceful pruning-hook into a weapon for the deviltry of the commando.

Jan 1, 1943

By D. M. Baird

Copper mineralization occurs at several places along the shore of Notre Dame bay, Newfoundland, and at one time formed the basis of a considerable mining industry. The sources of the mineralizing solutions and the structural settings of some of the deposits have not been clearly understood. This paper reports new investigations into the origin and structure of the deposits between Bett&apos;s cove and Stocking harbour, in a strip about ten miles long and two miles wide along the western shore of Notre Dame bay. The most complete previous descriptions of the area are those of Snelgrove (1929, 1931, 1938), Douglas, Williams and Rove (1940), and the writer (1947). The discovery of the Bett&apos;s Cove deposits took place about 1860, soon after the discovery of the well-known Tilt Cove deposits to the north. Several other small prospects were found between Bett&apos;s cove and Stocking harbour between 1880 and 1910. At Bett&apos;s cove, active mining began in 1875 and a small smelting plant was built near the mine in 1877. .Mining operations came to an abrupt halt in 1883 after a major cave-in. In 1900, and again in 1906, attempts were made to drain the old workings and reopen the mine but were abandoned long before completion. Total production amounted to about 130,000 tons of hand-picked copper ore which averaged about ten per cent copper, and 2,450 tons of pyrite (Snelgrove, 1938, pp. 52-55).

Jan 1, 1948

By S. C. Tadolini

"Roof bolts are the primary means of roof support in underground mines in the United States. Presently, post installation loads are measured on about 10% of the expansion anchor and combination bolts by using standard torque wrenches that Unit the accuracy of the measurements to about ±30%. No system has been available for measuring the loads generated on full-column resin grouted bolts. Mine roof bolts are long, slender, non-uniformly sized, roughly forged, and placed in a corrosive environment, creating obstacles for researchers trying to utilize ultrasonic reflection techniques to measure strain. A complete measurement system has now been developed by the U.S. Bureau of Mines, Denver Research Center. This system is being used successfully in determining loads measured on expansion anchor and combination bolting systems, examining the transfer mechanics of full-column, resin-grouted bolts, and measuring loads generated on bolts in an underground roadway support system.IntroductionMillions of roof bolts are used each year to provide structural support in underground U.S. metal, non-metal, and coal mines. Approximately 45% of the bolts used are expansion anchor, 45% are resin-assisted combination or full-column resin-grouted, and 10% are friction anchored. The effectiveness of these bolting types is dependent on a number of factors including rock density, bolt length, in situ stresses, rock properties, bolt pattern, installation tension, etc. When implementing expansion anchor and resin assisted combination bolts , installation and post-installation tension, or load, is a major determinant of support quality and subsequent behaviour of the reinforced roof. The method by which these systems carry roof loads is well understood and documented(1,2).The importance of these installation and long-term bolt tension measurements is well recognized and are required in the federal government regulations(3). A statistical sample of the bolts, lout of 4 during installation and lout of 10 inby the last open crosscut, is required to be measured using current torque wrench technology. The disadvantages of this system are the disturbance and weakening of the anchorage and limitations of accuracy to approximately ± 30%. The method by which resin-grouted bolting systems carry roof loads is much less understood, mainly because testing procedures used to evaluate point-anchor systems are not effective on resin-grouted bolts.Due to these problems, the U.S. Bureau of Mines designed a measurement technique that provided a highly accurate, low cost-per- bolt system that led to the development of ultrasonic pulse echo instrumentation. The original system was designed to measure the tension only on expansion anchor bolts. Recent developments and system modifications have permitted measurements on resin-assisted and full-column resin-grouted bolts. The use of these types of support systems has been increasing steadily in underground coal mines.The development of this instrumentation has provided laboratory and field results that help to explain the mechanics and relationships between the applied loads and the interaction between the grouted bolt system consisting of the bolt tendon, grout, and rock."

Jan 1, 1990

By D. E. M. Plaumann

"The wet grinding of asbestos has attracted the attention of engineers for many years as a means of improving fibre liberation from the ore. Today, added impetus for wet grinding has resulted from a need to minimize worker exposure to asbestos dust in conventional dry mills using air, as well as a need to provide a cleaner, technically superior fibre for use by product manufacturers. However, high viscosities of asbestos slurries create transport and grinding difficulties which have been a factor impeding use of a wet grinding process.Laboratory evaluation of reagents to reduce viscosities of asbestos slurries found that one reagent, XFS-4272.00, reduced the viscosity of a 35% (by weight) slurry by 75%. The impact of XFS-4272.00 on actual grinding parameters were evaluated using a pilot plant rod mill. Slurries containing 78% solids and XFS-4272.00 were successfully milled and asbestos fibres from that milling compared favourably in liberation and relative surface area to asbestos fibres obtained from milling a 4% slurry without additives. IntroductionAlthough the use of asbestos has been declining over the last few years, the large deposits of chrysotile in eastern Canada (Quebec in particular) remain very important. Asbestos production in Canada stands ninth in volume for mineral production with over 740 000 tonnes produced in 1985. Of this quantity, 722000 tonnes were exported with a value of $446 million. Canada is second in world production of asbestos behind the U.S.S.R. The milling of asbestos ore has been done primarily by a series of steps involving crushing, dry-grinding and aspiration using large quantities of air to release the fibres. Contrast this process to those practiced in the purification of virtually every other mineral. Ores other than asbestos are crushed and milled using an aqueous slurry in rod, ball or pebble mills. The finely ground mineral, still as a slurry, undergoes beneficiation by froth flotation, heavy media separation, hydrocyclones or any of the other aqueous techniques currently employed in mineral processing.One of the driving forces behind the use of air instead of water as a means of separating asbestos is the nature of the aqueous asbestos slurry. While most slurries of minerals contain as much as 80070 solids and can still be pumped and transported, asbestos slurries become highly viscous with as little as 10070 solids. These high viscosities reduce the pumpability of the slurry and create severe handling problems. Mills become prohibitively large and uneconomical due to having to handle slurries containing only 10% rock and 90% water.Health-related issues have affected the use of asbestos in many countries. In Canada, the asbestos-producing provinces have introduced stricter occupational legislation to improve safety in the workplace. This primarily means strict control minimizing release of air-borne asbestos fibres . Quebec and Ontario have set limitations of airborne asbestos at 2 (2) and 1(3) fibre per cubic centimetre of air. With present milling technology, maintaining these low levels in the workplace requires constant vigilance."

Jan 1, 1988

By M. Coleman, M. E. Reed

The control of feed delivery quality to the flash furnace remains an unsolved problem. Many operations around the world still have limited control of feed quality to their flash furnace. Schenck Process and WorleyParsons continue to work towards the ‘holy grail’ of simple quality feed delivering both radial feed distribution and pulseless feed delivery. Ten years ago they joined forces to offer a system based on then Clyde Process RotoFeed system which could deliver ground level installation, online mixing of materials, pulseless feeding direct to the burner, with good radial distribution. Unfortunately, this proved to be too large a step for the Flash Smelting community and met with resistance from the process owners. Since then the community has developed a range of options some of which have been implemented over this period. Despite these improvements there are still areas of concern including safety issues associated with concentrate leaks and spills, uncontrolled variations in feed rate including massive flooding events, intermittent distribution improvement and set up of the burner continues to be trial and error and hard to repeat the success in each burner campaign. These continue to impact flash furnace performance globally on a daily basis. Following the community reticence to pursue the complete solution a number of interim steps are now available to pave the way to the ultimate feed system. The mixing of material has been installed and is delivering line blended materials on a daily basis. This paper will investigate the developments over the last 10 years and discuss the pros and cons of this incremental step process for overall furnace control. INTRODUCTION Schenck Process and WorleyParsons have continued to interact and observe changes in the flash smelting industry and to consider application of the Clyde RotoFeed now incorporated in the Schenck Process ProStreamTM range for delivery of feed directly to the concentrate or matte burner. Schenck Process pneumatic injection from the Clyde Process range, ProStreamTM, utilises two types of volumetric feeders to accurately control the feed of material into an injection pipeline. These are referred to as the RotoFeed and RotoScrew technologies and the choice of feeder type is dependent on the characteristics of the material to be handled. The RotoFeed is generally used for finer, granular and powdered materials which cannot be accurately handled with a screw such as pulverised coal and copper concentrate, whilst the RotoScrew is particularly suited to coarser lump materials, particularly abrasive of cohesive materials like zinc powder, electronic scrap and metal ashes. Both units can operate at high pressures and many systems work at 3 to 10 bar with the occasional system working at 20 or 30bar for carbon to gasifiers. For the Flash furnace the ProStreamTM units can be used to deliver each of the furnace feed materials into a single line, mixing the materials homogeneously and live to the burner.

Jan 1, 2019

By C. Han, S. J. Zhou, Y. B. Shen, D. Z. Wei, P. Fang

"Collecting property of two hydroxamic acid collectors have different type of nonpolar structure to hemimorphite has been comparatively studied via monomineral flotation test, and the reason causes different collecting performance has been discussed from the view of relationship between molecular structure and collecting property. The flotation tests results show that C5-9 hydroxamic acid has an unbranched linear alkyl nonpolar group shows better collecting property to hemimorphite than cyclohexyl hydroxamic acid which has a naphthenic nonpolar group. FTIR detecting results show that the adsorption type of collector adsorbed on hemimorphite surface is chemical adsorption. Calculation results of polar group’s geometric structure parameters, polar group’s electron density distribution, octanol-water partition coefficient (logP) and molecular frontier orbital energy show that the key factor caused different collecting property of two collectors to hemimorphite is the logP; unbranched linear alkyl nonpolar group is more conducive than naphthenic nonpolar group to make hemimorphite particle more hydrophobic.INTRODUCTIONZinc-bearing mineral recovered from lead-zinc ores is the main source that people can obtain zinc resource from nature. However, natural sulfide ores are currently getting depleted steadily for the primary zinc source. In order to satisfy the future demand of zinc resource, there is an obvious recognition that the recovery of zinc oxidized minerals from the ores is a crucial alternative (Hosseini & Forssberg, 2007; Navidi Kashani & Rashchi, 2008).But the fact that can’t be ignored is the flotation of zinc oxidized minerals is much more difficult than that of zinc sulfide minerals, which is mainly due to the flotation characteristics of these zinc oxidized minerals such as lower selectivity and higher reagent consumption, as well as complex and variety of lead-zinc ores. Presently, there have been many various beneficiation technologies used for recovering zinc oxidized minerals and dealing with ores for recovering metallic zinc such as flotation and hydrometallurgy (Abkhoshk, Jorjani, Al-Harahsheh, Rashchi, & Naazeri, 2014; Önal et al., 2005). But from an overall perspective, flotation is the most common method used for the beneficiation of zinc oxidized minerals, and there have been extensive investigations conducted on the flotation of zinc oxide ores (Ejtemaei, Gharabaghi, & Irannajad, 2014). Until now, the most well-known method used commercially for the flotation of zinc oxidized minerals is sulfidization with sodium sulfide and flotation with a cationic collector of amines containing from 8 to 18 carbon atoms. However, a major problem for this method is the large amount of fines and slime results in the increase of reagent consumption and promotes the phenomenon of slime-coating. For preclude this negative effect, the de-sliming and processing optimization is indispensible (Peres, Borges, & Galery, 1994; Salum, de Araujo, & Peres, 1992)."

Jan 1, 2016

By Tibor Horvath

Dust abatement is possible on bulk materials, whether conveyed or stockpiled. Minimum (ppm) quantities of chemical additives can efficiently and rapidly control dust of conveyed substrates with no effect on floatation chemistry. Top coating of large surface areas can control surface dust and wind erosion. Environmental and toxicity impact must be considered in any treatment, especially on areas with percolation runoff, leachates, or limited containment. The most effective dust control is preventing release of substrate fines rather than trapping and removing air borne dust. Techniques to prevent release of fines from conveyed substrates will be discussed. Dust control dynamics are a very complex combination of solid phase physical and chemical interactions between the substrate and the fines. ?Smart Technology? products permit dust abatement of stockpiled substrates and tailing fields with no environmental impact. Using ?Smart Technology?, the dust abatement products remain active and can re-seal damaged areas. Efficient, low environmental and toxicity impact, dust control will be demonstrated through case studies where these principals have been applied.

Oct 1, 2010

By Shoma Sinha, Nirmal K. Sinha

Deformation in a material at any temperature is known to consist of two major components - a reversible (elastic) part and an irreversible part (often called plastic). What is not universally known is the fact that at high temperatures greater than about 0.4Tm, where Tm, is the melting point in Kelvin, the reversible part includes not only elastic but also a delayed elastic (recoverable but time dependent) component. A very simple computational model is presented here for a constant-strain stress relaxation test (SRT) on the basis of a three-component constant-stress rheological equation derived from strain relaxation and recovery test (SRRT) data. It is shown that the rapid stress reduction during the early periods of relaxation when the stresses are high is governed primarily by delayed elasticity irrespective of the imposed strain level. This is in contradiction to the popular concept prevailing today. The asymptotic approach to a quasi-stable stress rate at longer times and lower stresses is, however, controlled by viscous flow (power-law creep). The validity of the theory is examined by comparing the predictions with experimental results obtained for a titanium-base alloy Ti-6246 at 0.45Tm.

Jan 1, 2004