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By Alexander Burns, David Dreisinger

The kinetics of the oxidation of uranium(IV) by oxygen gas in aqueous systems is dependent on acid concentration, oxygen partial pressure, and temperature. In order to better understand the relationship between these variables and the speed of oxidation, a series of experiments have been conducted where each parameter has been varied in turn. Data were collected continuously using UVVis spectroscopy, allowing for a detailed examination of the reaction rate over the course of each experiment. The data fit an overall apparent rate law that is 1.5order in uranium(IV), -2order in H+, first order in oxygen, and unaffected by uranium(VI). This relationship does not appear to hold for solutions with <0.2 mol/L initial acid, where a different kinetic mechanism appears to be dominant.

Jan 1, 2014

By M. C. Harris

"Excess Gibbs energy is a thermodynamic parameter which quantifies the difference between the value of the Gibbs energy for a real mixture and that for an ideal mixture. More specifically the partial molar excess Gibbs energy of a species (i) in a mixture is indicated by the change in the overall excess Gibbs energy of the solution as the number of moles of species (i) changes while keeping temperature, pressure and the number of moles of all other species in the solution constant. Generally it is obtained from the activity coefficient which in turn can be obtained for a species in a mixture using a variety of models. The most widely used method is to use UNIFAC. Flotation is probably the most important process in the concentration of minerals and requires the use of reagents such as collectors and frothers. There is abundant experimental data which illustrates that collectors of different alkyl chain lengths will change the contact angle and that frothers of different structures and molecular weights will result in changes in key flotation properties such as froth behavior, surface tension and critical coalescence concentration. In this paper it is shown that there is a strong linear relationship between measured parameters such as froth volume/height, surface tension, critical coalescence concentration and contact angle and the partial molar excess Gibbs energy of the molecules used. Proposals are made to explain these correlations.INTRODUCTIONAs is well known froth flotation is arguably the most widely used process in the separation of minerals. In broad terms the process relies on the use of reagents known as collectors to adsorb onto a mineral surface and thus render the mineral particle hydrophobic. Alkyl thiolates are very commonly used for this purpose. The hydrophobicity is induced as a result of the alkyl group’s molecular structural properties which results in it forming a non-ideal mixture with the process water. Surfactants (or frothers) are typically alcohols and are known to lower the surface tension of the system and also inhibit bubble coalescence and reduce bubble size. Since alcohols are polar they will also form a non-ideal mixture with water. The hydrophobic mineral attaches to the bubble and rises to the froth phase where the valuable mineral is recovered as a concentrate. Frothers have often been characterized using the so-called HLB (hydrophobic-lipophilic balance) number but recently it was shown that the use of activity coefficients (?) or excess Gibbs energy (G ex ), which is calculated using equation (1) is a much more appropriate way to describe the behavior of these reagents in non-ideal mixtures with water (Corin and O’Connor, 2014)."

Jan 1, 2016

By P. S. Arthur, G. R. F. Alvear

Development of a new smelting process is risky. Many novel processes in the metals industry failed to fulfil the initial expectations of their inventors. Large sums of capital have been invested in technologies that either didn&apos;t provide a satisfactory return on investment, or didn&apos;t perform at all, and had to be replaced. One of the keys to success in process development is incremental scale up of the technology, with potential problems being identified and rectified as early as possible. In this way the cost of any rectification that is required can be minimized. The ISASMELTTM process was developed to maturity by Mount Isa Mines through the 1980&apos;s and 1990&apos;s using incremental scale up. Commercialization only occurred once the process had been proven on laboratory, pilot and demonstration scale over many years. As a result ISASMELTTM technology now operates successfully at numerous plants around the world. The methodical approach to development of the technology has allowed owners to modernise their existing operations or create new businesses with significantly reduced technical risk.

Jan 1, 2011

By W. A. Jankola, M. T. Martin

"The world&apos;s first zinc pressure leaching plant at Cominco&apos;s Trail operations started production in 1981. Sullivan zinc concentrate is leached at the rate of 190 tpd in a four-compartment autoclave at elevated temperatures and oxygen pressures to produce a zinc sulphate solution and elemental sulphur. Zinc extraction exceeds 98% and sulphide to elemental sulphur conversion exceeds 95%.The sulphur is recovered from the discharged slurry in the underflow of a hydrocyclone, and is upgraded as a flotation concentrate. The concentrate is dewatered, melted and filtered to produce a polished sulphur product of better than 99% purity. An alternative sulphur recovery process employs an unique sulphur separation method that recovers over 90% of the sulphur in the molten state. The remaining sulphur is recovered by flotation following flash discharge of the slurry. The product slurry containing the zinc sulphate solution and the iron-lead residue joins the existing roast-leach zinc plant for purification and zinc electrowinning.IntroductionIn 1981, Cominco Ltd. commissioned the world&apos;s first commercial zinc pressure leaching plant at their Trail operations in British Columbia. As part of a $700 million modernization and expansion program for lead and zinc started in 1977, the company installed the first o f two autoclave trains.Prior to pressure leaching, zinc production was closely tied to acid and fertilizer production. Sulphur dioxide produced from roasting the concentrates had to be converted to sulphuric acid. Thus, any expansion of zinc operations with the roast-leach technology would have required extensive modifications to the acid and fertilizer plants as well as to the roasters. Zinc pressure leaching, on the other hand, offered a one-step dissolution of zinc from the concentrates with high extraction, and production of elemental sulphur. The associated dust and sulphur dioxide generated in the roasting process are both eliminated from the working environment of the pressure leach facility. The flexibility allowed by producing elemental sulphur, and the opportunity to break the sulphuric acid link for about 25 per cent of the targeted 272,000 tonnes per year zinc production was very appealing. The process was successfully demonstrated at a pilot plant in 1977(1-6)."

Jan 1, 1985

By Feng Tianran, Lu Shijie, Shen Zhengchang, Han Zhibin, Tan Ming

"As a kind of non-metallic material, high-purify quartz sand has been widely used in many fields. Flotation is a popular way to process quartz sand. But it is in difficult position for flotation to get high-purify quartz product due to large amount of coarse particles contained in the feed. In this paper, a design principle of special flotation cell for high-purify quartz sand has been put forward base on ore property analysis and laboratory test, and the pilot scale special flotation cell has been developed to meet the requirement of the quartz sand flotation process. The special flotation cell for high-purify quartz sand is featured by middle positioned impeller, false bottom and draft tube, which could decrease the rising distance of mineralized bubble and strengthen the circulation capacity of the lower part of the flotation cell. Hydrodynamic study indicates that high air dispersion degree and strong lower slurry circulation could be produced by pilot scale special flotation cell, which is helpful to create a suitable hydrodynamic environment for quartz sand processing.INTRODUCTIONNatural quartz is a non-metallic mineral, which is widely used as raw material in multiple industry process (Shifu, 2006). High purity quartz, especially containing more than 99.9% silicon dioxide, is characterized by high temperature resistance, small thermal expansion coefficient, highly insulating and so on. The demand of high purity quartz has been rising along with social and economic development, now high purity quartz is widely used in the field of photovoltaic industry, electronic information, communications and aerospace industry.Quartz is a kind of main rocking-forming minerals in the nature. There are seven genetic types, such as natural crystal, quartz sandstone, quartzite, vein quartz, konilite, natural siliceous sand, granite quartz (Baolei, Shuilin, & Dianchao, 2012). The natural crystal is primarily used as raw material to refine high purity quartz, but it is not available for two reasons. On the one hand, the natural crystal is extremely expensive and poor in resources reserves, which can not satisfy the need of large-scale industrial production. On the other hand, the chemical component of natural crystal is instability, it may lead to low stable product performance in large industrial applications, and it is also difficult to achieve raw materials standardization. Therefore, there are a lot of studies to search for other technological methods to obtain high purity quartz from other genetic quartz types."

Jan 1, 2016

By G. W. Neumann

"In order to avoid pollution of water in Flemming Brook and Little River, which drain the area in which the Brunswick No. 12 Mine and Concentrator are located, the company has gone to considerable expense in preparing tailings storage and effluent setting ponds. The attached drawing gives a plan of the six settling ponds together with elevations of the dikes and the effluent weirs.All original dikes for the six ponds were constructed from humus-free clay and rock material, which was obtained, preferentially, by excavating from within the dike area. Run-off water, precipitated on the outside slopes of the dams will drain off without contacting the tailing material. A ditch was made north of the dam site to deflect surface run-off to the east into a branch of Flemming Brook.A secondary dike, made from tailings, has recently been erected on No. 1 and No. 2 tailings pond inside and above the earth-filled dike which serves as a roadway. Run-off from the tailings dikes will be retained inside the ponds by ditching between the roadway and tailings dike into ponds 4 and 6."

Jan 1, 1969

By J. L. Huisman

Bio(hydro)metallurgy is the latest development in the ongoing search for efficient and economic metal winning processes. In addition to bioleaching, other biotechnology-based applications are becoming more and more accepted. In this paper the THIOMET process for general effluent treatment is described. With this process, it is possible to produce sulfide on-site and on-demand and to use the sulfide to precipitate metals, even selectively when required. The process is ideally suited as a treatment to remove metals after, for example, an acid regeneration process. Another process is proposed that deals with stainless steel pickling bleeds. Such effluents typically contain nitrate, iron, nickel, chromium(VI) and other species. This one process handles these compounds, as well as other metals.

Jan 1, 2006

By R. D. White

"The Cumberland Basin of Nova Scotia has long been considered a structural basin by virtue of the elliptical outcrop and inward dip pattern of the Pennsylvanian outcrops. Recent published and unpublished data indicate that subsidence began in the late Devonian, perhaps resulting from a graben or rift. The Mississippian sediments which filled the growing depression were continental, lacustrine and marine with evaporites. The cessation of the riftforming processes is recorded by the alluvial swamp-type sediments of the Pennsylvanian which filled the depression. In excess of 25,000 feet of Carboniferous rocks are believed to be present in the deepest part of the Basin. Starting with the rift hypothesis, we can speculate on the kinds of sediments, their location and the structural features present beneath the Pennsylvanian surface. Using surface exposures and a limited amount of subsurface data, we theorize that (1) the Mississippian evaporites acted as glide zones which effectively divided the Basin into two horizontal structural layers. The rocks above the evaporites, responding to Appalachian stresses, formed the long diapiric folds with cores of overthickened evaporites. Below the evaporites the structures are related to movements of the rift floor, compaction closures and structures formed by differential horizontal movements of the rift walls. (2) The rift, in its deeper parts, will have more and a greater variety of marine rocks than the outcrops indicate. Should the rift hypothesis be correct, the possibility of finding hydrocarbons is enhanced."

Jan 1, 1972

By Vishal Shukla, Prateek Singh, D. P. Chakraborty

"Continuous thickening by an operation called sedimentation is the separation of suspended solid particles from a liquid stream by gravity settling. The primary purpose of thickening is to increase the solids concentration of the feed stream. High rate thickeners are designed specifically to maximise the flocculation efficiency. A detailed investigation has been carried out to understand the influence of ore type and operating parameters such as bed level, bed mass, rake arm torque and flocculent concentration on thickening operation. Tata steel’s Noamundi plant data shows that variation in ore type, and operating parameters are major contributors to fluctuation in thickener performance. A lot of research has been done earlier on thickening operation but effect of ore type and operating variables by using plant data was never touched before.In this context, the performance of thickener was evaluated by daily data to study the influence of ore type and operating variables on thickener operation. Investigation shows that friable ore % in feed mix is proportional to slime density because friable ore is porous & brittle in nature. As a result, friable ore generates more fines/ultrafine during communition process in wash plant. Increase in flocculant concentration and bed mass is showing a positive change on high rate thickener performance Investigation shows that optimum bed mass and flocculant concentration is required to achieve desired pulp density in thickener underflow at different feed pulp density (g/cc).INTRODUCTIONOver the years, Iron Ore Beneficiation at Tata Steel, Noamundi has seen varied changes. Depletion of high grade iron and with increasing iron ore throughputs coupled with lowering of the hard ore a subsequent increase in slime generation, slime management and clear water requirement for wet Plant has thrown up myriad challenges. To overcome these challenges, many improvements initiatives were taken by Tata Steel in last decade. One of the major changes is the recent High Rate Thickener commissioning at Tata Steel Noamundi to cater the high iron ore throughput requirement. Slime reporting to Thickener has increased from 1.4 MTPA 2.5 MTPA over the last few decades. The above changes further aggravate the poor settling and dewatering characteristics of the slurry which is being feed to HRT. Considering the above mentioned constraints and stringent environmental implication proper water management has become a major challenge to reckon with. The thickener is used to increase the concentration of the suspension by sedimentation, accompanied by the formation of a clear liquid. In most cases the concentration of the suspension is high and hindered settling takes place."

Jan 1, 2016

By G. C. Bateman

Canada is a very large country with a small population which is growing very slowly. We have great natural resources, but with our limited population we are continually looking afield for new capital to develop these resources. Our mining areas are among the most important fields offering opportunities for new capital and because of the wide-spread appeal which mining makes this industry commands a great deal of attention. While we are glad to see new capital from any source, we welcome it particularly from Great Britain, for, although we offer equal opportunities to the nationals of any country we would be glad to see the development of our natural resources financed as far as possible within the Empire. However, when we invite ne capital we must accept certain responsibilities, and while we have opportunities to offer, we should ask ourselves how these opportunities are taken advantage of and what sort of treatment the foreign investor receives.

Jan 1, 1925

By Walter Greaves

THIS paper describes a series of tests performed at the Hollinger mill during the past four years, in which both metal and rubber-lined pumps were used for pumping sand and slime. While conditions will not be the same at other mills, it is felt that the information gained from the tests should be of value to other operators and of assistance to them in selecting the most efficient size of pump and kind of lining for economical operation. For the successful operation of pumps with rubber linings there are certain conditions, which, if recognized at the outset, will save the operator a good deal of work and trouble. First is the necessity of keeping sharp pieces of steel, or anything that might cut the lining, out of the pumps. This can be effected by placing screens in the proper locations. Second is to recognize the fact that the rubber lining of the shell, and the rubber cover of the impeller, are subjected to very different conditions. The shell lining, :being at rest and well supported by the metal case, has a relatively easy job compared ? with the impeller covering, which is subjected to centrifugal force and has a tendency to tear itself away from the metal core. Also, the pulp travels through and past the impeller at a high velocity. These two factors, centrifugal force and velocity of the pulp, would appear to set a limit to the speed at which, for a given set of conditions, it is economical to run a rubber-covered impeller. Therefore, a pump should be large enough for the work to be done. To get the best mechanical efficiency, it must be operated somewhere near the limit of its capacity, but this may not give the best overall cost, because the saving in power, due to the high efficiency, may easily be lost through excessive wear on the lining. It would appear that this condition is more critical in a rubber-lined pump than in one lined with metal.

Jan 1, 1939

By Atsuki Sado, Akira Ueno, Kazuaki Takebayashi, Kunio Watanabe

The Saganoseki Refinery of Pan Pacific Copper Co., Ltd., Japan, introduced the ISA 2000® process in 2006 to improve product quality and productivity. After resolving various technical difficulties associated with the process, a current density of 325 A/m2 and electrolytic copper production of 234 000 tons per year were realized in 2018. In recent years, Saganoseki Smelter & Refinery has promoted treatment of recycled materials in addition to copper concentrates. Accordingly, the amount and type of impurities charged to the smelting process have tended to increase. In the electrorefining process, impurities such as nickel and antimony cause anodic passivation and formation of suspended solids, respectively. Although these undesirable phenomena can be avoided by controlling impurity concentrations in the anode and electrolyte to appropriate ranges, this also limits the choice of recycled materials that can be processed by the smelter. To achieve both stable operation of the electrorefining process and flexibility in treatment of recycled materials in the smelting process, Saganoseki Refinery improved the capacity of the impurity recovery processes during 2016 to 2018. This paper describes the expansion of the purification plant to remove and recover nickel and antimony. INTRODUCTION The Saganoseki Refinery of Pan Pacific Copper Co., Ltd., Japan, introduced the ISA 2000® (wax- less permanent cathode method) in 2006 to improve product quality and productivity. Since then, the refinery has gradually increased current density, and has been committed to establishing stable operation and high productivity via various improvements related to the electrolyte filtration and additive management systems. Figure 1 shows the trends of current density and current efficiency at the refinery. Although the current efficiency temporarily dropped when the current density was raised to 322 A/m2, it consistently exceeded 97% thereafter. At present, stable operation at 325 A/m2 has been achieved and continues.

Jan 1, 2019

By Kevin B. Doyle

"Canada now supplies 23 per cent of the world demand for potash. Although potash is produced by many countries, Russia and Canada have the greatest reserves and capability to supply the future substantial demand over the next decade. It is estimated that demand will grow from 38,000,000 mt KCl in 1975-76 to 60,000,000 mt KCl in 1985-86. Current firm expansion plans and development underway in the world will move Russia to the forefront in supplying this demand growth. Russia will move from supplying 40 per cent of world demand in 1975 to supplying as much as 52 per cent in 1981. Canadian deposits suffer from natural disadvantages, such as high costs and risks of mine development and operation, and high-cost transportation to international markets, but experience has shown that these natural barriers can be surmounted to effectively compete in these international markets. However, Canadian potash is losing out in the race to supply the growth in the world potash demand over the next ten years because of artificial barriers raised through the unhealthy environment created by the current battle between different levels of government and the industry over resource taxation and legislation."

Jan 1, 1976

By Lionel A. York

This paper outlines the type of water-bearing formations encountered in the Prairie Sediments and describes a method for effectively sealing these zones in order that shaft-sinking operations may be carried out with safety. Details are given of the procedure for carrying probe holes ahead of the shaft bottom. These probe or grout holes are employed for establishing a series of overlapping grout covers around the proposed shaft excavation to safeguard against large inflows of water during sinking. The pattern and length of grout covers cannot be standardized, and each cover needs to be specially designed to suit the varying ground conditions. In order to provide effective protection through the Prairie Sediments, the number of holes in any one cover would not be less than 8, and possibly as many as 64 would be required in certain zones. The length of covers would vary from 100 ft. to 250 ft. Emphasis is placed on the need for obtaining accurate geological and water information from exploratory holes, drilled in the shaft vicinity, in order to effectively plan all grout covers.

Jan 1, 1964

By G. V. Sirianni, G. E. Viens, R. A. Campbell, G. N. Banks, R. L. Sachdeva

"A combined shaft-electric furnace for the smelting of ores and the melting of metallized iron pellets is being developed. The materials are preheated, and in some cases pre-reduced, in the shaft before being transferred to the electric furnace, where melting or smelting is completed. It has been demonstrated that this combination of equipment will enable much of the relatively expensive electrical energy to be replaced by cheaper energy in the form of oil or natural gas, and preliminary experiments indicate that the total energy requirements for a melting or smelting operation are significantly reduced. Projections based on results obtained from the preliminary experiments indicate that further improvements will be possible when certain modifications to the equipment are completed."

Jan 1, 1968

"The Val d&apos;Or Division now comprises the Lucien C. Beliveau Mine and Concentrator (formerly the Pascalis, described below) and the Chimo Mine. Cambior acquired an initial 50% interest in the Chimo Mine in May 1989 and the remaining 50% in April 1990. Cambior&apos;s share of 1989 production was 2121 ounces; the company expects to net 23 750 ounces from Chimo in 1990. Pascalis MineUPDATERenamed the Lucien C. Beliveau Mine at its official inauguration in September 1989, the mine is exceeding forecasts, producing over 11 500 ounces of gold in the first half of 1990. Cambior expects 1990 production to total 34 000 ounces.IntroductionThe Pascalis Mine is located 16 miles east o f Val d&apos;Or, Quebec, and is accessible by a three mile gravel road off highway 117 (Fig. I).The property is wholly owned by Cambior.The Pascalis gold deposit consists o f a sub-vertical diorite dyke 1000 ft long by 30 ft wide containing quartz and tourmaline veins with inclusions of pyrite and native gold . Three vein systems ca n be seen in the deposit , the most important being tensile veins oriented at a right angle to the direction of the dyke and inclined at 40 degrees. These overlapping veins vary in thickness from 4 in. to 40 in. and occur at intervals of six to ten ft. The deposit is, therefore, very difficult to evaluate; a complete evaluation would require drifts over the whole width of the dyke combined with relatively short drill holes (Fig . 2)."

Jan 1, 1990

By C. C. Walden, D. W. Duncan, P. C. Trussell

Thiobacillus ferrooxidans released copper from -400-mesh chalcopyrite at a rate of 54 mg/I/hr. Any flotation chemicals remaining on the concentrate did not inhibit the leach rate. Zinc rougher tailings were also leachable. With bacteria, 75 per cent of the zinc and 68 per cent of the copper came into solution. In the sterile controls, only 16 per cent of the zinc and 10 per cent of the copper were released; 100 per cent of the copper and 36 per cent of the zinc were leached from pyrite cinders through the action of bacteria, and 17 per cent of the copper and 10 per cent of the zinc were solubilized in the sterile controls. Less than 0.027 per cent of ~he iron came into solution. The majority of the copper in a converter slag was acid-soluble, but a reverberatory slag responded to microbiological leaching. About 62 per cent of the copper came into solution, compared to 12 per cent in the sterile control. The various factors influencing the rate and extent of microbiological leaching are discussed.

Jan 1, 1966

By Freislich. M., Y. Gordon

"In the changing global market scenario for raw materials for the steel industry, a number of novel iron- and steelmaking process technologies are being developed to provide the steel companies with economically-sustainable alternatives for iron- and steel-making. In addition, the steel industry is also focusing on reduction of energy consumption as well as green-house gas (GHG) emissions to address the crucial subject of climate change. In this context, it is important to assess these critical issues for the alternate iron- and steelmaking technologies that have been developed. This paper presents a comparative evaluation of energy-efficiency and GHG emissions for some selected iron- and steelmaking technologies that are being considered for implementation. In this work, Hatch’s G-CAP™ and En-MAP™ tools that were developed with the main objective of quantifying and qualifying the potential energy savings and CO2 abatement within the iron and steel industry, were employed in the evaluation conducted. INTRODUCTIONThe iron and steel industry continues to transform itself and evolve in the ever-changing global market place – the raw material scenario is constantly changing with respect to quality and quantity (availability), there is stiff competition in both global and local markets, and there is increasing pressure to address global climate change issues, especially since the steel industry is highly energy- and carbonintensive. There is growing importance of steel production in developing countries such as China and India – this means that the steel industry in these countries will play an important role in defining and shaping the future of the industry.Climate change is expected to present new risks to the steel industry with respect to ensuring a sustainable business. Legislators are proposing to limit GHG emission by placing an implicit price on CO2 emission - market-based “cap and trade”, carbon tax etc.. In this scenario, it is important for the steel companies to reduce exposure to climate-related risks and at the same time, find business opportunities within these risks. Thus, there is a need to strategically manage the climate change risks; the key steps to strategically manage climate change risks are presented in Table 1[1]."

Jan 1, 2012

By C. R. Whittemore

Introduction The technical library in the service of industry is gradually becoming a well recognized and important part of all progressive industrial organizations. The larger mining, metallurgical, and chemical firms of Canada are establishing extensive reference libraries in connection with their research and operating departments in order that the members of the organization may keep abreast of the rapidly developing fields of engineering in which they are interested. It is the purpose of this paper to point out the usefulness of such a department in any industrial organization, to give a general outline of a system for filing and dispensing information, and to outline briefly the literature to be consulted and the procedure to be adopted in instigating a literature search. The technical library falls under the classification known as &apos;Special Libraries&apos;, and is quite different from the general library in that it is a storehouse of facts and owes its value to the ready presentation of information required for each specific case, and in a form most ready for use. The library brings all the available information relative to the interests of the corporation from without the plant to the organization within, and also keep in touch with each department of the organization.

Jan 1, 1930

By T. Ward, K. Shah, K. Murray

The mining industry is processing deposits with ever decreasing grade at ever increasing operating costs while margins are under constant pressure by material substitution and recycling. We are reaching the point where building it bigger just isn’t good enough as social and environmental constraints become more intense. In response to the growing demands on our industry, Goldcorp has embarked on a journey to increase resources by converting Waste to Ore. Gravity pre-concentration and sensor sorting testwork has been completed on samples from our Canadian operations in order to determine the amenability of our mineralized waste to sorting and upgrading. As expected some material was amenable to sorting and a review of the economics supported demonstration plant testing. The ability to economically sort mineralized waste into ore and barren rock is being demonstrated by Goldcorp. It has been made possible by leveraging the experience mineral sizer manufacturers have gained in the oil sands and hard rock applications, seeking more energy efficient screening machines and embracing the advancements that ore and recycling sorter suppliers have achieved. The paper will discuss the testwork and results achieved to date from both the lab and demonstration plant.

Jan 1, 2018