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By L. C. S. Dharmasiri, S. M. Shin, A. Senaputra, J. S. Sohn, K. H. Park, J. Avraamides

Reducing agents can be applied to leach metal values from natural and secondary resources such as laterite ores and deep sea manganese nodules and recycled materials such as spent batteries / catalysts which contain high-valent metal oxides of manganese, cobalt and iron. Selective leaching of some metals can be achieved by selecting conditions to control the saturated solubility and dissolution rates of metals from oxides or mixed metal/oxide matrices. The leaching results are rationalized on the basis of chemical species, Eh-pH diagrams and heterogeneous kinetic models. The role of reducing agents such as hydrogen peroxide, sulfur dioxide and iron(II) sulphate, in acid, alkali and in the presence of complexing ligands such as ammonia for the improvement of the leaching of metal oxides and metals is discussed. Previous studies on acid leaching of metals from nickel laterites, manganese nodules and spent catalysts/batteries in the absence or presence of reducing agents show that the rate controlling step involves the diffusion of protons through a thickening product layer on the particle being leached. It is shown that the leaching of nickel and cobalt from manganese nodules and zinc-carbon batteries in ammoniacal sulphur dioxide solutions also obey shrinking core kinetics.

Jan 1, 2014

By F. Chiesa

The permanent mould process, which is a favoured process for producing premium quality aluminium casting, is rarely used to produce magnesium alloy parts. This may be attributed different factors such as: the reservation with which the automotive industry considers using magnesium in structural castings; also the relative hot shortness of most magnesium alloys when compared to aluminium A356/357 is another factor. A third reason stems from the fact that the "heat content" of magnesium is much less than that of aluminium, resulting in the difficulty, for a relatively slow process such as permanent mould (versus pressure die casting), to reach a mould dynamic equilibrium temperature sufficiently high to avoid premature freezing and misruns. The present work will address this problem by carrying out controlled cycling of a laboratory mould, poured with aluminium and magnesium alloys. The influence of insulation of the mould and artificial electric heating on the run-in mould temperature will be determined experimentally. A thermal model will be sought for these thermal devices that will allow to predict the thermal behaviour of moulds of different geometry before a single casting is poured. The model will be tested on an industrial casting in a workshop environment.

Jan 1, 2006

By F. Rashchi, N. Naseri Joda

Recycling of electronic wastes is an important subject both from an environmental point of view and also the recovery of valuable materials. In this research, PC board scraps were leached to recover Cu, Ag, Au and Pd. Due to the high cost of the shredding process and to avoid secondary pollution from odors and dusts, board scraps were cut into 5X5 cm2 pieces. To determine the most effective leachant, aqua regia, nitric acid, hydrochloric acid, ammonium persulfate and potassium persulfate were tested. The effect of the leaching parameters, the leachant concentration, temperature, leaching time and liquid to solid ratio were studied and optimized using response surface methodology.

Jan 1, 2011

By C. H. Sleeman

"The Iron Ore Company of Canada constructed a beneficiation complex in Sept-Iles, Quebec, to concentrate and pelletize earthy red hematite iron ores from the Knob Lake area. The plants were scheduled for initial production during the first quarter of 1973.Many problems have been experienced to date. Difficulties in controlling the process, excessive mechanical failures, design deficiencies and manpower-staffing problems have caused an extended start-up. The problems are now essentially solved and, with the completion of some additional minor modifications, it is expected that the plants will be producing premium iron ore pellets at or near rated capacity within the next immediate period."

Jan 1, 1976

By Scott A. Trebilcock

Nautilus Minerals Inc the world?s leader in exploration and development of deep ocean mineral resources is today focused on the recovery of high grade copper-gold from in seafloor massive sulphide mineralization. These mineralized belts, analogous to land based volcanogenic massive sulphides (VMS) deposits are located near tectonic plate boundaries of the Western Pacific and around the world. Nautilus; first development project is Solwara 1 located in benign waters in Papua New Guinea. Since 2006 the company has completed detailed environmental and geological studies at Solwara 1, culminating in a number of world firsts, including the first Environmental Permit for a deep ocean mineral project and the first NI 43-101 compliant seafloor massive sulphide resource statement. Nautilus has relied heavily on proven deepwater technologies from the oil and gas industry in the design of the first mineral extraction system. Pipeline trenching units, workclass ROVs, deepwater production risers and drill cutting removal systems will all be adapted at Solwara 1. Key contractors to the project have all been selected for their deepwater experience, creativity and determination to launch this new industry. Innovation is at the forefront of Nautilus? success to date. This paper gives an overview of the Solwara 1 development and describes the exploration and production technologies adapted for seafloor mineral extraction.

May 1, 2010

By Josée Dartois

En 1988, à l?instar de plusieurs états du monde industrialisé, le Québec décidait d?accélérer la cadence de l?assainissement des rejets industriels et lançait un programme intégré de réduction de la pollution industrielle visant, à la fois, les rejets dans le milieu aquatique, les émissions atmosphériques et les matières résiduelles. Ce programme fut intitulé le Programme de réduction des rejets industriels.

Nov 1, 2002

By R. G. Rosehart, S. Y. Lee

"The current investigation concerns the removal of arsenic from waste waters using ion-exchange resin and activated carbon as sorption media. Use of certain weak and strong base anion exchange resins permits the removal of arsenic. Arsenic may be loaded on the weak base resin in the pH range of 2 to 3 and on the strong base resin above pH 5. The elution of arsenic is successfully achieved using 0.5 M NaCl or a mixture of NaCl and NaOH. The activated carbon investigated was less effective on loading arsenic, but the arsenic loaded was easily eluted by simple pH adjustments."

Jan 1, 1972

By G. O. Oniyide, H. Yilmaz.

"This paper presents the result of the research done on the effect of temperature on the dilatancy of rocks from the Bushveld Igneous Complex (BIC), where the South African Platinum mines are located. The BIC has higher virgin rock temperature (VRT) than the gold mines of the ‘Witwatersrand Basin Complex’. If the platinum mines advance to ultra-deep levels as the gold mines, since the Merensky Reef has been reported to extend beyond 5km, then the virgin rock temperature at 5 km below surface would be approximately 140oC. Hence, there is a need for the investigation of rock behaviour at high temperatures. Five different rock types (norite, leuconorite, mottled anorthosite, pyroxenite and chromitite) were tested in a 2600 kN servo-controlled multi-purpose triaxial testing machine. The tests were done at a constant strain rate of 5 x 10-1 S-1 and a confining pressure of 10 MPa within temperature range of 20 °C (ambient temperature) to 140 °C. The results show a general strength reduction and increasing dilation angles with increasing temperatures. The results also demonstrate that dilation angle is close to the internal friction angle at lower temperatures; however, they are greater at higher temperatures.INTRODUCTIONMany challenges are faced with increasing depth of mining in underground mines. The most obvious are heat, in-situ stresses and those associated with logistics. Issues related to underground heat have mainly focused on the side effect of heat on workers' health, increasing production costs as a result of higher cost of ventilation. The effect of increasing temperature with increasing depth on the behavior of rock has not been given much consideration. Generally, gold mines in South Africa are deeper than the platinum mines but the latter have higher temperature gradient, which makes the platinum mines to be warmer at similar mining depths. Although the study of the effect temperature on the behaviour of rock can be beneficial to both gold and platinum mines, the focus of the research is limited to the platinum mines because of their higher temperature gradient. Donoghue (2004) stated that the virgin rock temperatures (VRT) and air temperatures increase with depth, due to the geothermal gradient and auto-compression, that is, compression of air by its own weight."

Jan 1, 2015

By Qian Liu

Mining in highly stressed ground conditions has been an increasing challenge at the Brunswick Mine. Two large regional pillars were established on the 1000 m Level to support the ground for safe extraction of the surrounding ore. The South Regional Pillar contains about 5 million tonnes of ore and the North Regional Pillar has about 3 million tonnes of ore. In the fall of 2000, mining activities were suspended following a series of ground movements around the South Regional Pillar along weak geological structures. After extensive geotechnical investigations, a decision was made to carry out a mass destress blast in the West Ore Zone (WOZ) to cut the principal stress across an area of 135 m along strike and 86 m high. At the end of July 2001, the WOZ mass blast was successfully initiated. Following this success the mine decided to take a similar approach to destressing the North Regional Pillar (NRP). The final mass blast was taken in early February 2003. Advanced blasting technologies, including state of the art electronic detonators and blast simulation, played an important role in achieving the successful blasts. The high precision of delay timing and long delay duration of the electronic detonators ensured accurate and reliable initiations of over 800 blastholes in the WOZ mass blast. Orica?s DMC_Blast (Distinct Motion Code) simulation code was used to study different blasting blocks for the desired timing in the initiation sequence. This paper describes the process of applying electronic detonators in complex blasts, and discusses how blast simulation results were interpreted to guide engineering design of the mass blasts.

May 1, 2003

By C. A. Ingram

The Cigar Lake ore body is a high-grade uranium deposit situated within water-saturated sandstone. In order to extract the uranium ore remotely, ensuring minimal radiation dose to workers, and also to access the ore from stable ground, the Jet Boring System (JBS) was developed. This method of mining involves drilling a pilot hole up through a frozen ore body and utilizing a high-powered water jet to mine out cavities. During the mining process an ultrasonic sensor will be used to provide feedback to the operator, who is located beneath the ore body, as to the dimensions of the cavity. However, more precise data is required to determine final shape, volume, and location of the cavity for mine planning purposes. Selecting a device that will provide sufficient range data in the challenging environment will be vital to optimizing the mining process. Major issues include fog build up and flying debris during mining, and an environment that is wet, dark, and cold A test cavity has been designed and constructed at the Saskatchewan Research Council (SRC) so that a study comparing three different technologies, as prospective candidates for the survey system, can be conducted. The devices being evaluated include a Senix ultrasonic sensor, an MDL Cavity Auto-Scanning Laser System (C-ALS), and a MESA Time of Flight (ToF) camera. The ultrasonic sensor is known to provide range data in foggy conditions but has low accuracy. The C-ALS has been developed for surveying remote cavities but is expensive and does not provide reliable data in fog. The ToF camera provides a high volume of data in a short time period, with potential to provide accurate information in extreme conditions, but has not been tested in a mine cavity application. Iterative closest point (ICP) registration is applied in an attempt to create a 3D point cloud from the scan data and to also compute rotation and translation of the ToF camera. This paper presents an overview of the challenges involved in conducting a survey within a JBS mined cavity, the analysis used to determine the suitability of each device, and the data collected from the test cavity.

Aug 1, 2013

By F. Nava-Alonso, A. Uribe-Salas, C. Rodriguez-Rodriguez

Ozone has been proposed to pretreat refractory ores before the cyanidation process for precious metals extraction. As pyrargyrite is one of the silver species most common in Mexican refractory ores, the ozonization of this silver sulfide was studied. The effect of pH and ozone concentration on silver dissolution was evaluated by means of a factorial experimental design. Two levels of sulfuric acid concentration and ozone in gas concentration were evaluated: 0.18 and 0.72 mol/L of acid and 0.054 and 0.077 gO3/L, respectively. The highest silver dissolution was obtained when using the higher acid and ozone concentration.

Jan 1, 2011

By Paul G. Dunn

The planning of underground mines is a complicated process involving geological, engineering and operational constraints. MIRARCO is in the process of developing a 5D Mining Exploratorium where 3D mining models are combined with time (4th dimension) and costs (5th dimension). The mining exploratorium is a collection of external and inhouse software packages specifically geared to help underground mining companies arrive at better mine plans. This paper discusses the progress made in the development of the 5D Mining Exploratorium and a change in mine planning philosophy by conducting frequent audits in a Virtual Reality Laboratory. The development of genetic algorithms for optimising stope sequences is also presented.

May 1, 2003

By C. Blawert

The corrosion properties of the skin and the bulk of semi-solid processed and high pressure die cast AZ91 alloy were studied in 5% NaCI solution by (a) analysing the corrosion morphology, (b) measuring electrochemical polarization curves, (c) performing electrochemical impedance spectroscopic measurements, and (d) immersion tests at constant pH-values. Using XRD, LM, SEM and EDX to evaluate the microstructure of skin and bulk specimens, the corrosion results were related to the microstructures of the particular alloys. However, microstructure and corrosion performance were found to be similar for both production processes, and only slight but distinct differences were found. Generally, the skin corrosion properties are inferior to those of the bulk, with the exception of the high pressure die cast AZ91 alloy, where the finer microstructure of the skin layer exhibits a better performance as showed by impedance studies and confirmed in long term immersion tests.

Jan 1, 2004

By C. Barlow

The White Mesa Mill (WMM) began operating in 1980 as a regional processing mill owned by Energy Fuels Nuclear, Inc. Original mill design was for 656,000 Mtpa of U ore producing 1,250 tpa of U3O8 concentrate. Sustained market downturns delayed facility upgrades during most of the 1980s and 1990s. The new owners of WMM, Denison Mines, elected to advance the regional mill concept in 2007 with the modernization of these facilities. This paper details decisions taken and lessons learned in plant redesign, choice of leading-edge instrumentation, motor controls and process automation, training and some example benefits from process control stabilization.

Aug 1, 2010

By A. Consigny

New "clean technologies" to treat mining and metallurgical effluents containing dissolved metals have been successfully applied at mine sites in North America and Asia, treating water flows up to 24,000 m3/day. These clean technologies offer significant benefits compared to conventional alternatives and provide a sustainable solution that eliminates residual waste sludge, improves water conservation, generates revenues from wastewater, and delivers overall improvements to the environment. This paper will profile these technologies, and provide best practice case study examples of their application at mining operations, including data for water chemistry, flows, water quality, capital and operating costs, and life cycle costs of treatment.

Jan 1, 2011

By F. Y. Hsiao, H. C. Kao

Underground excavation in hard rock is normally stable at shallow depth except for wedge failure. However, the excavation depth is rapidly increasing recently. In high overburden stress condition, the integrity of rock would be destroyed with degrading rock strength. Therefore, understanding both the peak and the post-peak strengths of hard rock are necessary to assess the tunnel stability at depths. The characteristic of the post-peak strength is seldom studied in Taiwan in the past. Various estimation methods for the post-peak strength degradation were briefly reviewed in the paper. Based on the Geological Strength Index (GSI) system is widely used in the determination of the rock mass strength, the quantitative residual GSI system was adopted to estimate the possible strength degradation for a hydraulic tunnel in Taiwan. The Mohr-Coulomb model (no strength degradation) and the post-peak strength degradation model (strain softening model) were used to simulate the excavation of the case tunnel at different depths. The analyses demonstrate that the tunnel is in stable condition at 600m of depth. And the effect of the postpeak strength degradation on tunnel deformation is progressively significant with increasing tunnel depth. Approximate 3-5 times of increase in crown settlement and horizontal convergence would occur when post-peak strength degradation are considered at 2400m of depth. Severe tunnel deformation may endanger the tunnel stability. Modeling results reveal that the post-peak strength degradation has a great effect on tunnel stability under high overburden stress condition, which should not neglect in deep tunnel design.

Jan 1, 2015

By D. J. Lloyd

"Bending is involved in the forming of many sheet parts and it is important to understand the phenomena involved. In this paper the basic equations describing bending on a global scale are compared with strain measurements of bent sheet. The development of strain on a local, microstructural scale is also investigated, as is the general aspects of plasticity and the failure process. It is shown that the global equations can be used to estimate the strains involved and the local strains can be attributed to various aspects of the plasticity. The bendability can be related to the fracture strain of the sheet and the ability of a sheet alloy to accommodate the necessary bending to form the part can be assessed.INTRODUCTION The ability of a sheet alloy to undergo bending without failure is an important capability in the forming of many parts and it is useful to be able to assess the bendability of an alloy during its development. The basic mechanics of bending were developed in the 1950s (Lubhan & Sachs, 1950; Hoffman & Sachs, 1953). When a sheet is bent the upper bend surface is in tension, the lower surface in compression and at some point within the sheet there is a plane of zero strain which is referred to as the neutral axis. For sheet exhibiting limited plasticity the neutral axis is static and occurs at the mid-point of the sheet thickness but for sheet exhibiting extensive plasticity the neutral axis progresses deeper in to the sheet as bending progresses. This results in two expressions for the maximum strain at the upper bend surface depending on the motion of the neutral axis. For Al alloys such as AA6111, AA6016 and the like extensive plasticity occurs and the neutral axis is expected to move during bending. However, very few studies have examined how the neutral axis motion and the strains develop, compared with the mechanics analysis. Geist and Parker (1984) used hardness measurements to investigate neutral axis motion but these experiments did not have the resolution necessary to compare the results with experiment but did indicate neutral axis motion. To understand the nature of plasticity and failure during bending it is important to know the extent of neutral axis motion, the scale of strain gradients developed through the sheet and the maximum strains occurring at the bend surface, finally comparing experimental results with the theoretical predictions. The influence of microstructure on the evolution of strain and failure can then be considered in the context of these parameters. Recently, bending in some automotive Al alloys has been reported mainly from the microstructural perspective (Lloyd, 2000, Lloyd et al., 2002, Mattei et al., 2013) and FEM studies have also investigated the development of plasticity under bending, demonstrating the tendency for strain localization (Becker, 1992, Shi et al., 2014)."

Jan 1, 2018

By E. Thomson

This type of microscopic investigation, although still in its infancy, has already found practical applications in several different phases of mining activity. The study of the transparent minerals in rocks, by means of the ordinary petrographic microscope, has for long been a very useful supplement to observations in the field, but the opaque minerals, until recently, have had to rest content with a more or less superficial determination with the hand-lens or the blow-pipe. In a great many cases, particularly where the association of metallics has been somewhat complex, this has been entirely inadequate, and the determination of these opaque minerals under the micro- scope, has opened up a new field of scientific investigation that bids fair to surpass, in practical value at least, the micro-scopic determination of the rock-forming minerals. As the details of this kind of microscopy are possibly not entirely familiar to all mining men, it might be well to outline them very briefly before dealing with the practical directions in which this method may be applied. The ordinary petro-graphic microscope, with but one extra attachment, will serve for this work. A small reflecting device, called a vertical illuminator, is inserted immediately above the objective lens. This reflects the light down to the surface of the specimen and from here the light is directed up the middle of the microscope tube to the eye. As it is desirable that the maximum amount of reflection should be secured from the surface of the section, it is first polished and set in a position perpendicular to the vertical axis of the microscope.

Jan 1, 1924

By C. S. Ha, H. S. Choi, D. Y. Shin

POSCO installed a new 100 ton oxygen bottom-blown converter in 2013 for the development of new steelmaking process named as PS-BOP which is reading POSCO-Saarstahl Basic Oxygen Process. This process was developed by the collaboration research between POSCO and Saarstahl AG in Germany that is based on substantial increase of CO post combustion in a converter by blowing hot air from the top of converter. The collaboration research has been finished successfully in November 2013 with 17% decrease in hot metal ratio (HMR) when hot air was blown from the top of the oxygen bottom-blown converter. After the collaboration research the converter has been tried to be operated as oxygen top and bottom-blown converter to reduce bottom wear and to decrease production cost with increased use of low cost Fe source by the help of increased CO post combustion. The presentation includes experience on the start up of oxygen bottom-blown converter, HMR reduction trials with hot air top blowing and transition from oxygen bottom-blown to top and bottom-blown converter operation.

Jan 1, 2015

By M. P. Brameld, R. H. McCorkell

"Overburden covering bedrock uranium deposits was sampled to depths of 29 m and Rn concentrations measured at the same depths. Total-alpha activities, V concentrations and Rn emanation (J) of the samples were measured. The U-flux into the overburden was greater in the past: oxidation and dissolution has since removed most U, leaving decay products which indicate the presence of U deposits when U itself does not. Distributions of U and decay products and their ratios to each other reflect U-migration and degrees of U-removal. Rn distribution in overburden is related to the J of overburden samples and the presence and movement of groundwater. Simple, rapid methods of total-alpha and J measurement are described.IntroductionThe overburden drilling apparatus developed by Bondar-Clegg and Company makes possible sampling and radon measurement in overburden from the surface down to about 50 metres. This apparatus was used here to study the diffusion of uranium and its decay products from ore deposits into over lying overburden at the N deposit of the Amok Ltd. property (Cluff Lake, Saskatchewan) and on the Imperial Minerals Ltd. property at Gooderham, Ontario. These ores are enclosed in bedrock; the overburdens were deposited by glaciers or streams. The migration of uranium and its decay products in such situations and the factors which affect it have been little studied in the past, as readily usable techniques for mapping it in three dimensions have not been available. The results reported here are somewhat sketchy and preliminary, but they indicate the value of the methods used and some of the patterns to be expected. Surface and subsurface sampling and measurements were carried out on 3-line grids crossing known zones of mineralization. The lines were 60 metres apart at Gooderham and 40 metres apart at Cluff Lake."

Jan 1, 1982