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By S. Bastola, Y. P. Chugh

"This research determines shear strength and stiffness properties of bedding planes and joints in the roof strata rocks within 7.5 to 9 m (25-30 ft.) overlying the Illinois #6 coal seam (within the pressure arch zone). A shear test loading device was designed into a 1.334 kN (150 t) Forney Compression Loading Machine to perform direct shear tests in accordance with ASTM D5607-08 “Standard Test Method for Performing Laboratory Direct Shear Strength Tests of Rock Specimens under Constant Normal Force”. The data were used to determine peak and residual friction angles and the dilation angle. A total of 49 bedding plane samples were tested, out of which 46 (36 intact and 10 relatively weak and loose) samples passed QA/QC procedures in accordance to ASTM D5607. Samples from eight (8) different bedding planes- shale/limestone (SL), shale/sandstone (SSs), shale/bone (SB), laminated sandstone (LS), shale/shale (SS), bone/bone (BB), bone/limestone (BL), and limestone/limestone (LL) were tested. The number of samples tested for each bedding plane were: SL- 11, SSs- 8, SB- 5, BB- 4, LS- 6, SS- 9, BL- 1, and LL- 2. Peak and residual shear strength values at 2.75 MPa normal stress range 1.06 – 6.26 MPa and 0.82 MPa to 0.82 – 4.14 MPa, respectively. The average normal and shear stiffness values are about 11.98 GPa/m and 3.11 GPa/m. Dilation angles are low (<10?) and negative in some cases. Angle of sliding friction values range from 9? to 42?. Joint Roughness Coefficient (JRC) values were less than 10.INTRODUCTIONRock mass may be defined as the total in situ rock medium containing bedding planes, faults, joints, folds and other structural features. Therefore, it is discontinuous and may have heterogeneous and anisotropic engineering properties. Upon creation of an excavation in a rock mass, bedding planes and joints are the most likely points of failure initiation. The failure typically occurs either in tensile or shear mode. Upon failure initiation stresses are transferred to the neighboring rock mass and the failure progresses until stability is achieved through equilibrium of stresses and strength. An example of this mechanism is development of the pressure arch. This study determined the shear strength and stiffness properties in shear and compression of bedding planes and joints in the immediate roof strata rocks within 7.5-9 m ( 25-30 ft.) overlying the Illinois No. 6 coal seam (within the pressure arch zone). Since such data are currently not available for Illinois Coal Basin mines, researchers and engineers have been using estimated values for design purposes. The immediate roof lithology in the proposed mining area consists of shale 0.62 m; Bone 0.09 m (0.3 ft.); Limestone, 0.10 m (0.33 ft.); Shale 2.37 m (7.9 ft.); and sandstone 0.55 m (1.83 ft.). The bedding plane samples were provided by a mine in south-eastern Illinois operating at a depth of about 180 m (600 ft.)."

Jan 1, 2015

By Paul Clark

Generation - Profile l 9,726 megawatts (MW) of capacity l 46,877 gigawatt hours (GWh) produced at an average plant availability of 88.4% l 47 facilities in four geographies: Canada; the U.S.; Mexico; and Australia l Fuel mix of coal (62%), gas (26%), hydro and renewables (12%) l 23.2 million tonnes of coal mined l 47.0 million gigajoules (GJ) of gas consumed

May 1, 2004

By G. Clarkson, M. Hitch, R. Clarkson

"A novel reagent-free method of extracting gold from gravity middling concentrates in the Yukon placer fields is presented in this paper. This method exploits the malleability of gold by submitting concentrates to grinding in a rod mill. Brittle waste minerals are effectively reduced, whereas malleable gold particles are flattened and are then extracted by classification through sieves. Recoveries in the field using a laboratory-sized rod mill regularly exceeded 90%, whereas correlation laboratory tests indicated recovery to be most sensitive to the mill charge size. This method has broad potential, including application to the gravity circuits of large hard-rock processing circuits.RÉSUMÉ Cet article présente une nouvelle méthode sans agents réactifs d’extraction de l’or dans les concentrés gravimétriques mixtes que l’on trouve dans les districts placériens du Yukon. Cette méthode exploite la malléabilité de l’or en broyant des concentrés dans un broyeur à barres. Les déchets miniers cassants sont bien réduits, alors que les particules d’or malléables sont écrasées puis extraites par classification au travers de cribles. Si les récupérations sur le site à l’aide d’un broyeur à barres de laboratoire excèdent 90 %, les essais de concordance en laboratoire indiquent que la récupération est très sensible à la taille de la charge du broyeur. Cette méthode présente un grand potentiel, notamment une application possible aux circuits gravimétriques des grands circuits de traitement des roches dures.INTRODUCTIONExploiting the high density of gold to separate it from waste materials is the oldest known mineral processing technique. This basic technique is still widely used in gravity concentration circuits today; however, gravity processing invariably results in high-value middlings, especially in the Yukon placer gold fields. In addition to having a uniquely high density, gold is also the most malleable metal. This unique malleability can be exploited to extract gold from otherwise inaccessible gravity middlings.The Yukon placer gold industry has been continuously ongoing since the 1860s, and today produces approximately 60,000 oz t (1.87 million grams) of crude gold annually, most of which is from the Klondike region near Dawson City (Van Loon & Bond, 2014). It is important to note that Yukon placer miners do not use any chemical extraction methods; rather, gravity upgrading methods are the sole processing techniques used. Placer deposits are typically coarse, well liberated, and naturally gravity concentrated and recoverable, thus making more expensive chemical extraction unnecessary (Mitchell, Evans, & Styles, 1997). Furthermore, a strict permitting regime, environmental concerns, lack of expertise, and fear of repercussions from regulators prevent miners from attempting more advanced processing methods, such as flotation or cyanidation. Even simple chemical extractions like mercury amalgamation have not been implemented for decades, with one observer noting that, as many as 30 years ago, “the art of mercury for amalgamating appear[ed] to be dying [in the Yukon]” (Osler, 1983)."

Jan 1, 2017

By John D. Galloway

Mining is one of the important primary industries of Canada, with a gross production in 1927 estimated at $241,773,000- the highest in the history of the country-and an impressive dividend record. It is quite apparent, therefore, that mining is a business worthy of the careful attention of the people of Canada. Furthermore, with a vast undeveloped territory more or less mineralized, it is highly probable that our mining industry will continue to expand indefinitely, with a consequent increase in production and in the amounts of the yearly profits distributed. In recent years, the public has taken a larger interest than formerly in mining-an interest, moreover, that is not academic, but primarily from the viewpoint of profits. It is quite evident that mining is a profitable business, at least to some, and the average man on the street, hearing of these profits, is attracted thereto. I have no doubt that many of you have .read in promotion prospectuses, with figures to prove it, that mining is the most conservative, the safest, and the highest-yielding business in the world. Now, a lot of this information is best judged by the old saying that "While figures don&apos;t lie, liars figure". At the same time, mining, properly conducted, is a profitable business, even though speculative, and undoubtedly much profit will come from Canadian mines in the future. In this paper my conclusions regarding mining investments are based largely on British Columbia experience, together with some slight knowledge of mining conditions in the other Provinces. It is considered, however, that the inferences drawn are applicable to mining throughout Canada.

Jan 1, 1928

By Amir Zavichi

Today, with the necessity of timely, on-budget and high quality completion of projects, proper use of construction equipment is essential to ensure project success. Construction equipment places a large monetary burden on the project and if not utilized efficiently, it can result in economic losses. Cranes are one of the most important and expensive operational devices on construction sites. They play a central role, and often activities that rely on crane services fall on the project?s critical path. Currently, material-handling scheduling is done by the crane operator or by an on-duty superintendent using his/hers personal judgment, making the process manual and timeconsuming. Thus, developing an optimal schedule, which considers different dynamic constraints in construction job site, may not be possible based on the current practice. This leads to longer operation times and a negative impact on project cost. This paper presents the latest results of an ongoing study, which aims to design and implement a nearreal time crane operation decision support system to be utilized directly by the crane operator or as an aid for the superintendent in scheduling optimal operation services. This system has several advantages such as maximizing the efficiency of crane operations, guaranteeing the best operation possible to reduce the crane?s travel time, reducing crews and equipment idle time, and minimizing the dependence on subjective human judgments.

Aug 1, 2013

By J. Chlan

"Dryer DescriptionProctor and Schwartz Continuous Conveyor DryerThe Proctor and Schwartz Continuous Conveyor Dryer has been in operation since July 1958, and comprises six unit• - an 8• wide single conveyor with roller extruder, insulated housing, type 304 stainless steel circulating and exhaust fall system, steam heating coils, temperature controls and discharge crusher rolls. Entire dryer dimensions are 52’ x 12'0""weighing 53,000 lbs,Extruder rolls - setting is 1/8"" (Drive 3 HP 1800 RPM) clearance off the extruder screen.Conveyor - consists of 151 interlocking pans, measuring 8"" x 8' (2 HP 1200 RPM) One Exhaust Fan (5HP - 900 RPM)Steam Coils -- l"" steel pipe - with steel fins -- each coil measures 16' 2’’- 64 coils in the No, 1 Compartment- 64 coils in the No, 2 CompartmentDryer OperationThe yellowcake slurry at 28% solids is pumped to an 81 x 8' Peterson Filter. The filter media presently being used is a Neotex 4372 blanket, being 100% staple fibre nylon, 12 oz per square yard with air porosity of 9 CFM's. The cake discharge at 45 - 50% moisture falls into the roller extruder. Extrusions are formed by forcing the material by rolls through a perforated plate moving back and forth and depositing the spaghetti-like extrusion on onto the dryer-conveyor.The conveyor now carries the extruded material through the heating chamber•, The feed end of the dryer will be referred to as No. 1 Compartment, with temperature control set at 280""F. The circulating fans take the hot air off the coils and circulate the heated air through the perforated openings in the dryer conveyor pane, After passing through the set of steam coils and circulating fan in No, 1 Compartment, the material then goes through No, 2 Compartment where the temperature is set at 305'F, Final material then discharges through a set of crusher rolls set at ~"". Moisture of final dried product runs at less than 2%.The dryer conveyor load is usually run to a 3"" - 4"" depth load. Conveyor speed at approximately 90 minutes for load to pass through. Load onto the conveyor is controlled by boot level and speed of the 8' x 8' filter. The dryer steam coils are water-washed twice a month."

Jan 1, 1972

By Bernhard Schwab

A popular rule in the mining industry is that a property should only be developed if average unit production cost is less than a given proportion of the estimated long-run price of the mineral. This paper provides a comparative analysis of the average cost approach (ACA) with the use of net present value (NPV) as an investment criterion. It is concluded that the ACA is an easily understood and easily applied rule of thumb which may serve as a rough first screening device, for example in the early stages of deposit exploration. Its operational convenience is at the expense of accuracy and validity, and the NPV provides a sounder method of making decisions, especially in the case of marginal deposits.

Jan 1, 1978

DynoMiner APS Delivery Systems Overview ? New Design of DynoMiner APS-M2 ? Stand alone or attach to Cargo type 10,000 lb (4536 kg) emulsion bins. ? Hose reel w/200-ft (61-m) by 1-inch I.D (25-mm) hose capacity, power rewind. ? Increased water and trace capacity. ? Hose reel and gassing offered as options. ? New Flow Meter ? DN-100: aluminum body, UHMWPE rotors. ? Will be offered as an option. ? APS Nomenclature ? Proposed changes ? DynoMiner APS and APS-M1 to become DynoMiner APS Drifter ? DynoMiner APS-M2 to become DynoMiner APS Stoper. ? Both to have optional gassing / flow metering.

May 1, 2004

By Julián M. Ortiz

Uncertainty quantification of a spatially distributed variable at any scale can be handled through geostatistical simulation. Large computation time, storage, and post-processing of the realizations are required to obtain a final assessment of block uncertainty. Multi-Gaussian kriging is a flexible alternative to simulation. The idea is to compute the conditional distribution of uncertainty after normal score transformation of the original samples. Under the multi-Gaussian assumption, all marginal and conditional distributions are Gaussian, hence fully defined by their mean and variance. The parameters of the conditional distributions are obtained by simple kriging and can be back-transformed to the original units of the variable of interest. An estimate and any summary of uncertainty can be easily retrieved. The main disadvantage of performing multi-Gaussian kriging is that change of support is not straightforward, that is, calculating uncertainty of block grades. We propose a methodology to overcome this limitation by considering a matrix simulation to generate multiple probability fields. Each probability field is used to draw spatially correlated point values from the point-support conditional distributions, and multiple realizations of the average can be obtained. This permits the calculation of the average over the block and its uncertainty. These blocks may correspond to selective mining units or to volumes from longer production periods relevant for engineering decisions. They can even be disjoint blocks, such as when several faces are mined at the same time. POSTMG, a Fortran program to perform these calculations, is described and a case study is provided.

May 1, 2004

By P. R. Clark, M. D. Gleghorn

"IntroductionAt TransAlta Utilities Corporation&apos;s Highvale Mine, located west of Edmonton, Alberta (Fig. I and 2), dragline stripping has proved to be a practical and economical method of overburden removal and future plans have been based upon the continued use of draglines (Fig. 3) as the major stripping equipment (Williams, 1979, Nikols et al., 1986). However, long range planning has shown that the capacity of draglines alone will be exceeded in the early 1990s as mining progresses into deeper overburden cover (Tapics, 1983). Strip ratios will increase from I.3 bank m!/ t of coal in 1985to 4.5 bank m3 / t in 1995. During this period the depth of overburden will increase substantially and the areas to be mined will be characterized by weak soils including glacially displaced overburden. This increased overburden depth in relatively weak soils will make it impractical to _continue side casting by draglines without prestripping in advance. In 1983, a major investigation was initiated to determine what additional overburden removal equipment was appropriate to the Highvale operations, and recognizing the long delivery times of this major equipment. when it would be required. This paper describes studies and tests which were undertaken in 1983 and 1984 to select prestripping methods and equipment for the future operation of the mine.Previous planning studies have shown that with the current burn schedule and with the economies of progressing from low cover to high cover, as has been practiced in the past, overburden volumes will exceed the capacity of the existing draglines in the early 1990s (Fig. 4). These previous studies had placed reliance on (I tandem dragline operation for future overburden removal requirements up to a depth of 45 m throughout the Highvale Mine. New drilling together with the associated geotechnical studies and some detailed planning on the practicality of using tandem draglines, created concerns about their universal application. Even without considering geotechnical conditions there was a depth limitation to tandem dragJines and substantial prestripping would be required to achieve the ultimate depths."

Jan 1, 1987

By R. G. Burn

"A brief outline will be given of the concept of risk and its implications with regard to investment in exploration. The relationship between risk and decisions under uncertainty will be examined as a prelude to identifying those factors which contribute to exploration risks:consideration of the effects of corporate objectives (e.g. survival, expansion, diversification) on exploration strategy and ultimately on success or failure, exploration and mining as an investment (the relationship between risk and reward) and the desired return on investment; exploration odds, funding levels, staying power, financial exposure and the concept of gambler&apos;s ruin;origins of uncertainty in exploration decision-making-man-made risks and natural hazards; the nature of introduced constraints at each exploration decision stage and their effect on the rate of success;improving the chances of success and the invest reduction of risk through sound exploration strategy, effective project generation and efficient target detection capabilities."

Jan 1, 1984

By A. J. Macdonald

Gold deposits hosted by banded iron formation (BIF) in Ontario exhibit a marked association with localized zones of deformed and hydrothermally altered BI:F . Secondary sulphides and carbonates are conspicuous. Proposed carbonate-facies IF , or exhali tes, such as green carbonate in the Larder Lake camp and ankerite veins in the Porcupine Camp are structurally controlled, hydrothermally deposited zones of carbonate replacement and fissure filling. Gold precipitation from hyd r othermal fluids in strain-generated conduits may be due to (a) plating upon secondary sulphides, (b) pH change due to carbonatization of BIF or (c) destabilization of gold in solution due to sulphidation of BIF .

Jan 1, 1984

By Rene Cane, V. I. Lakshmanan, John Starkey, Richard May

"The Agrium Kapuskasing Phosphate Operation mines and processes up to 6,000 t/d of phosphate ore. Run-of-mine crushing to minus 6 inches is done in a toothed roll-crusher, while grinding is done in a SAG/ball mill circuit with no coarse recycle classification of the SAG mill discharge. The primary grinding mill is an 18 ft. diameter x 9 ft. EGL, 1500 HP variable speed SAG mill and the secondary mill is a 13 ft. diameter x 21 ft. long, 2000 HP fixed speed, ball mill. When hard ore was treated, the SAG mill restricted the tonnage that could be ground. When soft ore was treated, the ball mill and spiral classifier overloaded and restricted throughput.Recommendations from a plant benchmark and an ore hardness testing program, on how to better utilize installed energy in the Agrium SAG mill when treating soft ore, and how to obtain best results when treating hard ore, were checked in a pilot plant investigation in the 3 ft. diameter Starkey-PRO Pilot SAG Mill. Correlation between the ore hardness testing and the results from the 3’ Pilot SAG mill was very good. In addition, the work indicated the results that could be expected for the different ore types when using either smaller SAG discharge grates and/or a vibrating screen with 10 mesh square opening cloth.INTRODUCTIONAgrium Kapuskasing Phosphate Operation consists of a 6800 t/d open pit mine and a concentrator, near the Town of Kapuskasing in Northern Ontario. The two major ore types are sandy ore and cemented ore. Sandy ore is fine, soft and easy to grind in the SAG mill while cemented ore is harder, more blocky and difficult to grind in the SAG mill. The ratio of sandy to cemented ore in the deposit is thought to be in the order of 80:20 but can range as high as 5050, so it was important for the grinding circuit to have the ability to treat sandy ore alone."

Jan 1, 2002

By Darren Medd

Kumtor Gold Company (KGC) currently operates the 500,000 tonnes per day Kumtor open pit gold mine located in the Issyk-Kul region of the Kyrgyz Republic at an elevation of more than 4,000 m. To supplement the open-pit mill feed with high grade underground ore from outside the current pit limits, KGC started pre-production design and development of the underground mine for the SB ore zone in late 2006. The initial phase of pre-production development consists of exploration and haulage declines which, upon completion, will provide ventilation and access to the underground mine. Design and construction of these declines presented many challenges to the project team considering the mines unique location at high altitude, the limited experience with Western underground mining techniques in the Kyrgyz Republic, and the impact of the nearby Davydov glacier and resultant ground conditions. Completion of the exploration and haulage declines was undertaken jointly by KGC and mine contractor, J.S. Redpath Limited (Redpath). The initial phase of development including several ground falls provided detailed information on geotechnical ground types and conditions that were useful in determining the overall mine design and methodology for production. This paper covers the various aspects of the design and construction process of developing the declines under the glacier, minimizing the likelihood of further ground falls, and the journey of both KGC and Redpath which led to the successful breakthrough between the declines on 01 July 2012.

Aug 1, 2013

By Gordon. I. M., J. Blackshaw

"The wet part of the Hollinger mill is housed in two buildings, the grinding plant and the treatment plant. In the grinding plant there are four 7xl5 ball mills which grind the ore to 60 per cent through 200 mesh. There is also one 7xl5 ball mill which grinds table concentrate to 9 5 per cent through 200 mesh.The primary classifier overflow is pumped to the treatment plant where it passes over shaking tables, producing a concentrate and a tail. The concentrate pulp is pumped to the grinding plant for secondary grinding. The secondary classifier overflow is pumped back to the treatment plant where it is thickened in two 40xl 5 tray thickeners and agitated in four 20x24 mechanical agitators arranged in series of two (with 2 spares).The table tail pulp is thickened in nine primary 40xl5 tray thickeners (with 2 spares). The thickened table tail pulp and the concentrate agitator discharge pulp are mixed and pumped to four rows of 15x45 pachuca agitators, arranged in series of five tanks.The pachuca discharge pulp is divided. The smaller part goes to two rows of 3-step decantation using 40xl5 tray thickeners (with 2 spare rows). The larger part goes to six 14xl6 drum filters. The repulped primary filter cake and the thickened pulp discharged from the decantation rows are fed to eight 14xl6 drum filters. The secondary filter cake is mixed with water and pumped to the tailing line."

Jan 1, 1968

By Zhuofei Yang, Jidong Kang, David S. Wilkinson

The fatigue behavior of AM60 high pressure die casting magnesium alloys was studied in a straincontrolled manner. The fatigue test was interrupted every 2,000 cycles for X-ray tomography scanning. The specimen was removed to be scanned on a desktop micro-CT system. The value of using X-ray tomography in a fatigue properties study was assessed with respect to porosity, cracks and fracture surfaces. The 3D analysis and model results showed porosity could be well measured and modelled in 3D. Defects bands are made of pores under 50 µm in volume-equivalent sphere diameter. Larger pores are randomly distributed in the region between two defect bands. Observation of cracks by X-ray tomography occurs in three ways such that the 3D model gives the best illustration of crack-porosity interaction while the other two methods have better detectability on crack initiation and crack tip observation. X-ray tomography is also of value in failure analysis on fracture surfaces. By summarizing X-ray tomography data during fatigue testing and observing fracture surfaces on a 3D model, a better understanding on the crack initiation, crack-porosity interaction and the morphology of fracture surface is achieved.

Jan 1, 2014

By C. George Miller

"As the influence of governments has become more widely felt, the use of research techniques to analyze policy has increased. Mineral economics, as one of the foundations of mineral policy research, has grown accordingly. Policy research and analysis has been carried out within governments, university departments and the private sector. Each of these institutional environments has characteristics which influence the topics of study, the approach, the methodology and the output of the research. A brief survey of recent research activities provides illustrations of trends and developments occurring within this organizational framework.A radically different organization, the independent research institute, has begun to make an impact on policy research in recent years, and will have an increasing importance in the future. Combining certain features of the traditional research organizations, it nevertheless has important differences which are essential to its effective functioning. An overview of the formation, goals, organization and operation of one such institute is presented."

Jan 1, 1976

By James K. Gowans

"Cominco Ltd&apos;s Polaris Mine, located on Little Cornwallis Island, Northwest Territories (latitude 75degrees 30&apos;) went into production in late 1981, becoming the world&apos;s most northerly base metal mine. The concentrator, powerhouse, shops, offices, dry and warehouse, were uniquely designed and constructed on a 100f t wide by 400 ft long by 65 ft high barge. This process barge was constructed in southern Canada at Trois Rivières, then towed 3,500 miles into the High Arctic Islands and beached on Little Cornwallis Island.The paper deals with the original design philosophy, flowsheet and the initial year&apos;s operation of the Polaris process barge.IntroductionTo bring a mining property into production in the Canadian High Arctic, a company must deal with the harsh environment, the short shipping season and the high cost of labour. In trying to minimize the effect of these fact or s, the concept of a barge-mounted process plant was investigated as an alternative to the conventionally built concentrator. Cominco&apos;s previous experience gamed at the Black Angel Min e on Greenland&apos;s west coast suggested that this would be a practical alternative.The normal shipping season at Little Cornwallis Island is approximately six weeks long, from mid-August to the end of September. All equipment and materials must be delivered during the ""shipping window"". The logistics problems are enormous; if the conventional approach had been used the major process equipment would have been delivered to Little Cornwallis Island at the same time as the completed barge actually was! Construction would also be starting at the start of the worst climatic conditions, the Arctic winter. Nine months&apos; production was gained by opting for the ""barge"" approach."

Jan 1, 1983

By D. A. Trotter, G. J. Goddard

"This paper describes a method of deciding on various design parameters for a sublevel caving layout. Layout design curves are obtained from the output of a computer optimization program. The program uses mathematical relationships derived from the theory of gravity flow of material to optimize the large number of interdependent design variables which are involved.IntroductionIn the design of an efficient sublevel caving mining system, a large number of interrelated variables need to be considered. Although many papers discuss individual variables, very little exists in the literature to show how these variables interact to achieve optimum results. This can lead to trial and error in sublevel caving design, which can prove costly, particularly because sublevel caving is a mining method which requires integration with sublevels above and below. With no pillars being left, experimental stopes cannot be isolated for study. Unfortunately, the complexity of layout design and the costs associated with trial and error have caused many planning engineers to choose more tried and tested mining methods.Sublevel caving works best to extract low-value ore surrounded by incompetent rock. All phases of the mining method can be highly mechanized, allowing low operating costs and high production rates. Good safety records are achieved, as workers are always in &apos;good&apos; ground and the method is regular, making it comparable to an industrial process."

Jan 1, 1981

By Masami Nakamoto

Controlled thermolysis of gold(I) thiolate complex, [C14H29(CH3)3N][Au(SC12H25)2], at 180 °C for 5 h under an N2 atmosphere produces novel gold nanoparticles passivated by alkyl groups derived from the precursor complex, the TEM photograph of which shows spherical particles with average diameter 26 nm. Since Brust et al. reported the two-phase reduction of AuCl4 - by NaBH4 to afford monodispersed gold nanoparticles passivated by alkanethiolate ligands (1), plenty of preparative investigations on gold nanoparticles (2,3) and its surface modification (3,4) have appeared, because of their potential applications in microelectronics (5). However, those preparative methods generally involve the reduction of AuCl4 - by reducing agent NaBH4 in the presence of suitable organic stabilizers such as alkanethiol (1-4), phosphane (5), quarternary ammonium salts (6), surfactants (7) or polymers (8). On the other hand, O?Brien et al. recently reported the preparation of organically capped gold nanoparticles at 190 °C, where tri-n-octylphosphine oxide and/or n-octadecylamine are used both as a reaction medium and as a passivating ligand (6), but this procedure also needs NaBH4 as reducing agent. Our strategy of novel preparative method of gold nanoparticles is the combination of reductive elimination of thiolate ligands and simultaneous attachment of organic moiety on the growing nuclei. Gold(I) thiolate complexes with ammonium cations were useful for our preparative method. We now report the controlled thermolysis of gold(I) thiolate complexes, [R(CH3)3N][Au(SC12H25)2] and [R(CH3)3N][Au(SC6H4-p-R?)2] (R= C14H29, C12H25; R?= C8H17, CH3), under an N2 atmosphere, where the powder of gold(I) thiolate complexes completely melts to afford the precursor liquid and then the liquid gradually decomposes. In spite of no use of reducing agent and solvent, reduction reaction is thermochemically induced to afford novel gold nanoparticles passivated by alkyl groups rather than by alkanethiolate ligands. Figure 1a shows a typical transmission electron microscopy (TEM) image of gold nanoparticles prepared by thermolysis of [C14H29(CH3)3N][Au(SC12H25)2] at 180 °C for 5 h, indicating a controlled growth of spherical gold nanoparticles. As shown in Fig. 1b, these spherical gold nanoparticles display the size distribution ranging from 5 to 50 nm. Although the particle size is larger than that of thiol-derivatized gold nanoparticles (less than 5 nm) prepared by NaBH4 reduction (1-3), the aggregation of gold nuclei is smoothly regulated and the growth of core gold is limited to be 26 nm in average diameter in spite of thermal procedure.

Oct 1, 2003