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By J. Petersen, H. Naderi, H. Zare, M. H. Nikzad, M. Karimi

In the copper electrorefining process, the dissolution of anodes is significantly reduced or even stopped when the passivation phenomenon occurs. The results of this phenomenon are increasing energy consumption, residual formatting, and voltage levels in the cell. In this study, the electrochemical behaviour of blister copper in the presence of sodium persulfate (PDS) was studied. The electrochemical methods of LPR, Tafel, and Electrochemical Impedance Spectroscopy (EIS) were used. The results showed that the addition of sodium persulfate activates the electrode surface and increases the open circuit potential. In the presence of PDS, the polarisation resistance of the electrode shows an increasing or decreasing tendency, based on the PDS concentration. This tendency is probably due to the formation of surface layers (such as slime layer or copper sulfate) and dissolution of this layer at various concentrations of PDS. The lowest polarisation resistance of 1.8 ohms and the highest corrosion current of 60.6×10-3 and 36.6×10-3 A/cm2 from LPR and Tafel techniques respectively were obtained at the concentration of 40 g/l PDS. Based on the results of potentiodynamic and electrochemical impedance spectroscopy tests, the addition of sodium persulfate to the solution reduces the corrosion resistance, therefore the passivation time of the blister copper anode increases. Keywords: Blister copper, electrorefining, sodium persulfate, anodic passivation

Jan 1, 2020

By J. W. Drelich, H. Zeng, L. Xie, X. Cui, Z. Gao, M. Tian, Y. Hu, W. Hu, W. Sun

Flotation is a mineral separation technology that uses the surface hydrophobic difference of valuable minerals and their associated gangue minerals to separate them. The flotation collector adsorbs on the valuable mineral surface to improve its hydrophobicity, and metal ions are usually used as activators to enhance the collector adsorption. Different mineral surfaces show different charging properties and adsorption behaviours with the collector or metal ions. Moreover, the order of adding metal ions and the collector also show significant and different flotation performance for the same mineral. The adsorption or flotation behaviour or both are governed by mineral surface chemistry, such as surface charging and reactivity. In our recent studies, force measurement using atomic force microscopy (AFM) was employed to study the surface charging and adsorption mechanism of metal ions and collectors. By preparing collector-functionalised AFM tips, AFM can directly measure the adsorption strength of the collector on the mineral surface to determine the anisotropy of mineral surface reactivity. The preparation of collector-functionalised AFM tips provides the foundation for further study of the activation role of metal ion in the collector adsorption. The application of AFM for force measurement in the surface chemistry of mineral flotation can provide important information on developing flotation reagents and lays the foundation for the specific regulation of mineral surface characteristics. Keywords: Scheelite; flotation; surface chemistry; AFM force measurement

Jan 1, 2020

By C. S. Kucukkargoz, A. Bhalla

"The solid-state reduction of ilmenite concentrate with graphite was studied under argon atmosphere at temperatures between 1050°C and 1350°C. The rate of reduction increased with increasing temperature and decreasing particle size, with the maximum extent of reduction found to be 80% at 1350oC with a particle size in the range of -106 +90 µm. The activation energy for the reduction reaction was calculated to be 257 kJ/mole. The trivalent iron oxide was reduced first to divalent iron oxide and then to metallic iron. An annular ring of a partially reduced oxide phase containing metallic nuclei was formed around the core of ilmenite, which grew in size as the original ilmenite core shrank with progressive reduction. The reduction of titanium dioxide also took place during this stage, which produced the Magneli oxides in the form of TinO2n-1. The metallic phase had very high Fe and low Ti contents throughout the reduction, whereas the partially reduced oxide phase adjacent to the metallic phase was high in Ti and depleted in Fe. The metallic phase globules formed during this stage were small and are considered suitable only for leaching and not for other concentration processes. The core of the particle generally retained the composition of the original ilmenite. The purpose of this work was to remove iron and increase the titanium oxide content of the ilmenite to produce a high-titanium containing charge for subsequent smelting.IntroductionThe titanium-bearing minerals ilmenite (FeTiO3) and rutile (TiO2) are the primary natural raw materials used in industry to produce titanium metal and titanium-based products. The common titanium-bearing minerals are ilmenite, rutile, anatase, brookite, leucoxene, arizonite, and perovskite. Although the formula of ilmenite is commonly expressed as FeTiO3, the mineral can accommodate Mn and Mg, which are chemically bound in the form of (Fe,Mn,Mg)TiO3. Ilmenite concentrate can also contain Fe2O3 and Al2O3 in addition to the physically separable oxides such as SiO2 and CaO. The crystal structure of ilmenite is an ordered derivative of the corundum structure with a trigonal-rhombohedral symmetry. Fe2+ and Ti4+ ions occupy the octahedral sites, leaving the tetrahedral sites unoccupied. In each FeTiO3 unit, there are three O2- ions creating three octahedral sites, two of which are occupied by Fe2+ and Ti4+ (Wilson et al., 2005)."

Jan 1, 2017

By C. Chibwe, M. Tadie

Copper electrowinning models are useful for prediction of process performance, optimisation and improved understanding of complex phenomena such as current distribution without the expense of physical experiments. Recently, finite element models such as those generated in COMSOL Multiphysics have been developed for the electrowinning process. The predictive capacity of these models is improved by incorporating physical and chemical phenomena. Since physicochemical properties of electrolytes can have a significant effect on the quality of copper produced, this work was conducted to investigate the effect of such properties on electrodeposition at varying levels of copper, sulphuric acid concentration, iron concentration and temperature, in the presence of a smoothing agent. Tests were conducted at conditions similar to those for industrial copper electrowinning. Mathematical correlations were developed for the following properties; density, conductivity and diffusivity which were compared to existing models in literature and thereafter applied in a COMSOL generated model. The model predicts, current distribution at the cathode surface, deposit thickness (morphology), concentration of species within the cell and current efficiency. Current distribution output shows the impact of several phenomena on the deposit generated including the relationship between increasing copper concentration and current density and lack of influence of acid concentration on this property. Keywords: Electrowinning, physicochemical properties, electrolyte composition, modelling

Jan 1, 2020

By S. Soren, K. Deo Mehta, G. Jha

The paper aims to find a sustainable sintering process through cleaner means, in order to achieve the desired outputs with zero environmental impact. At present, sintering has no control over its environmental impacts. These impacts occur when fossil fuels such as coal and coke are used in metallurgical sintering. These fossil fuels are undoubtedly effective in their assigned reducing task, but simultaneously emit about 220 kg of GHGs (greenhouse gases) per tonne of sinter produced. The current attempt has focused on reducing these emission levels by switching from coke to a renewable fuel source such as biomass. Biomass is a cleaner fuel source with a significantly lower emission footprint compared to coke. In the experimental campaign, sawdust and wood-charcoal were used in substitution for coke. Experiments were designed in a progressing substitution to obtain the maximum substitution ability without compromising the sinter properties. Sawdust as raw biomass source optimally substituted 10% of coke. The substitution levels were remarkably higher (30%) for wood charcoal due to its low moisture and high calorific values. A fuel blend with 30% biomass and remaining coke succeeded in producing a sinter with acceptable quality indices. Sinters prepared with or without biomass contribution shared an identical phase transformation and microstructures. In order to to maintain consistency in the process, every effort was made to maintain all operational and process parameters identically, except for the fuelling framework. Keywords: Sintering, sustainable, biomass, GHGs, fuel substitution

Jan 1, 2020

By W. Gabryk

A large new underground platinum mining project required that all different mining options were investigated during an option study before proceeding to the prefeasibility stage of the project. The capital project team identified 21 different options requiring investigation. These options considered 10 different access methods and 4 different mining methods. Each of the 21 options required a mine design, a valid production schedule, and the associated economics in order to facilitate a comparison on project Net Present Value (NPV) and other metrics. The project sponsors required this work to be completed in 3 months and therefore the project team decided to adopt an object-oriented modelling approach as implemented by Cyest Corporation. This would allow all 21 options to be valuated within the tight time frame due to the generation and re-use of templates. Standard objects were configured into templates containing the mine layout, design, and scheduling logic. These templates could then be assembled into a model to represent the option being investigated. The adoption of rules-based design and production scheduling then allowed for the rapid generation of a valid production schedule for each option with different iterations of varying production ramp-up and mining efficiency assumptions. The activity-based operating costs, labour, and capital were also linked to the standard templates such as a half level or barrel, which were then replicated to represent the overall mine structure for each option under consideration. Using this approach for each option, a full production schedule was produced per mining activity, the operating costs were calculated using activity-based costing, an infrastructure capital expenditure estimate was determined, the development capital requirements costed, and an overall NPV determined. This options study was completed in an unprecedented 10 weeks and a recommendation was put through to the Business to take three of the options to the next study phase.

Jan 1, 2012

By D. Mjonono, S. T. L. Harrison, N. Maliela, A. Kotsiopoulos

The improvement of coal waste management practices, through the co-disposal of waste rock with sulphur-lean fine waste tailings (<1 mm in size), can potentially mitigate acid rock drainage (ARD). On exposure to natural oxidants, the sulphide compounds present in mine discards generate acidity, creating a cyclical oxidation process intensified by iron and sulphur oxidising microorganisms. To inhibit the emergence of ARD, a stable mine dump may be constructed that is structurally stable and incompressible through the mixing of complementary waste fractions that reduce voids and access to acid generating surfaces. However, large voids manifest as scale increases, due to decreased particle interlock, enabling the unrestricted access of oxidants leading to the early onset of ARD. To avoid this phenomenon, enhanced packing approaches based on geochemical and geotechnical characterisation tests were employed to improve bed stability. These were assessed for long-term prevention using aggressive oxidative conditions typical of heap leaching applications. Favourable results were obtained for both blended and multi-layered systems. However, long-term success was most notable in beds with alternating layers of waste rock and fine waste tailings with co-mingled systems being more susceptible to failure. Deconstructed co-disposed beds provided valuable insight into post-leach structural transformations. Results indicated that relative changes in initial coarse discards to fine waste ratios were most notable in blended systems. Mass fractions of the comparatively more mobile fine wastes increased axially down these test columns that ultimately resulted in increased contact of oxidants with the acid generating waste discards. Conversely, more consistent ratios were observed in multi-layered configurations. In these systems, near impervious hardpans were created by the moisture retaining fine tailings, forming stable structures with neutralising barriers sustained at each alternating layer. Consistent with post-leach geotechnical characteristics, static acid-base accounting tests showed that the uppermost sections of blended systems were more susceptible to oxidation due to structural failure with fine particles migration, while the more stable multi-layered configuration evenly maintained neutralising capacity. Keywords: Acid rock drainage (ARD), bed structure, mobility of fine particles

Jan 1, 2020

By E. J. Walls, W. C. Joughin

"In selecting a suitable method to sink a vertical shaft for underground access, a number of constraints influence the ultimate decision of where and how to develop the shaft, not least among these being safety, development and construction time, and cost. Two additional considerations stand out: these being geotechnical conditions and technology, the latter taking into account existing underground access. Assuming a project for which an existing underground excavation is available, it is tempting to build a shaft sinking project from the outset based on the raiseboring method, which has the potential to be the safest, fastest, and least expensive method provided that geotechnical conditions permit.And therein lies the rub: regardless of project time or cost constraints, when it comes to raiseboring a long (say, greater than 500 m), large diameter (greater than 4.5 m) shaft, the rock mass conditions ultimately dictate what method of shaft sinking will be feasible. Over the course of several studies for a particular project, several geotechnical analyses were carried out specifically for the purpose of developing a shaft by raiseboring. Risk analysis and experience showed that where the rock mass conditions indicated an unacceptably high risk potential, an alternative method needed to be considered, even if this meant increasing both the time and financial requirements.In this paper we present an overview of geotechnical investigation practices for shaft sinking. Decisionmaking thresholds for raiseboring or other methods of shaft sinking are discussed, including probabilities of failure, empirical rock mass classification, basic wedge failure, and back-analysis of a failed case. The design of appropriate support, and analysis of relative safety benefits for various shaft sinking methods, falls outside the scope of this work, and will be presented in a separate paper.IntroductionThe potential for rock mass failure during shaft development and construction affects whether a project is completed safely, on time and on budget. During the course of several studies to establish ventilation shafts for an underground expansion project, geotechnical analyses of rock mass stability and failure potential were carried out. The investigations were guided by the method of McCracken and Stacey (1989) together with insights from Peck and associates (Peck, 2000; Peck and Lee, 2007, 2008; Peck, Coombes, and Lee, 2011)."

Apr 1, 2019

By J. P. Kirsch

This paper sets out to clearly identify all elements that make up an effective furnace feed system. These are outlined and the more common types of technology are listed. These technologies all play an important role in the final delivery of all feed materials to the furnace.

Jan 1, 2008

By D. Ackerman, S. Cole, G. Langefeld, I. Parker

The removal of gravel from the seabed using a hydraulic mining tool is a complex multi-phase problem that cannot be analysed using traditional continuum based simulation techniques. One potential approach is to simulate the behaviours of the solid phase via the discrete element method and the liquid phase via finite volume based computational fluid dynamics. The interaction between the phases is accounted for by Eulerian coupling. The feasibility of using the combined computational fluid dynamics-discrete element method to simulate gravel entrainment from an idealized seabed is evaluated. The simulation results are validated using experimental data. It is concluded that while the current approach appears feasible, further work needs to be done to improve the accuracy of the simulation and to evaluate the approach?s ability to model more complex behaviours.

Jan 1, 2007

By K. Bryan, O&apos

A 10-year program to integrate crushing and screening models into daily flowsheet design practice has proven successful. A Circuit Analysis Program (CAP) is used worldwide to design and evaluate new and existing crushing flowsheets. To gain user acceptance of CAP and maximize effectiveness, model development, simulation flexibility, ease of use, and developing international access are key issues. These issues have been resolved effectively resulting in flowsheet simulations to assist in justifying increased capital investment. CAP is presently utilized in Canada, United States, and South Africa with intentions to expand to Europe and Asia.

Jan 1, 1987

By C. Musingwini, M. Woodhall

An often overlooked factor in the analysis of mine layouts and schedules is technical operating flexibility, mainly due to its nebulous nature. If one glosses over technical operating flexibility the resultant mine layouts and schedules tend to be sub-optimal. The need to incorporate technical operating flexibility into the analysis and comparison of mine layouts and schedules is increasing in importance. This paper illustrates the nature of technical operating flexibility, reviews previous work on valuing operating flexibility and proposes how technical operating flexibility can be quantified for tabular reef mines by using a platinum reef deposit as a case study. Once technical operating flexibility is quantified it becomes possible to explore its incorporation into the analysis of mine layouts and schedules and subsequent optimization processes. The work described in this paper is part of a current PhD study at the University of the Witwatersrand. Keywords: mine plans, layouts, schedules, technical operating flexibility, ore availability.

By P V. Savage, T Glück, RCA Minnitt, C Bothma

Manganese Metal Operations ?Manganese Metal Company (MMC), a subsidiary of Samancor BHP Billiton, has two production facilities for electrolytic manganese metal in South Africa and produces a range of about 44 Mn metal products. ?The company is accredited with ISO 9000 and uses Six SigmaTM for continuous improvement. ?The control of the process relies on the effective functioning of approximately 250 different control loops at 50% automation.. ?Approximately 50000 samples are analysed every month. ?There are pyro, hydro and physical unit operations for the production of electrolytic manganese metal flake and value added products ? [ ]

Jan 1, 2005

Commissioning of the Cannington processing plant began in October 1997. The nameplate capacity (of 1.55 million tonnes of ore per annum) was achieved relatively quickly. Since then (like many mines) the operation has strived to increase throughput and improve valuable metal recoveries, to offset declining head grades and lift the value of the operation. The processing plant now has the capability of treating over 3.2 million tonnes of ore per annum and in financial year 2005/06 the combined concentrate production exceeded 600 000 wet tonnes, approximately 80 per cent above concentrate output in the first full year of operation (at the design feed rate). This improved performance was achieved by making changes and additions to each of the major unit processes - primary grinding, flotation, leaching, filtering and paste fill preparation. The changes have included: adding a fines flotation circuit, expanding the grinding circuit, adding a pebble crusher, switching from continuous to batch leaching, building paste conveyors and decommissioning the column flotation cleaning circuits. This paper reviews these changes, outlines the current operating practices and discusses the challenges or opportunities that remain.

Jan 1, 2007

By Y. Lizotte

This paper describes the design and implementation of the dispatching system at LAB Chrysotile Inc.&apos;s Black Lake Mine Operation, Quebec, Canada. The initial system uses a computer in a passive role, to record and display information in ongoing operations. Simulation studies were undertaken at McGill University to assess various heuristic dispatching rules which can be program- med and inserted into the dispatching system. The computer can then suggest to the operator where a truck should be sent to maximize productivity or improve fleet efficiency. The study stresses the importance of considering the effects of implementing computerized systems on those individuals who must use these systems in their daily work. The roles of individuals from the industry and the university in this joint project are also highlighted.

Jan 1, 1987

Newmont is one of the few remaining large mining companies that was established in the early nineteen hundreds. The company has a long, colourful and enviable history. This paper provides highlights of Newmont?s business and technical history since its inception in 1916, its transition to a ?gold only? company in the early 1990s and progress since that time up until the present day. Details of Newmonts current gold operations and its gold production profile for 2008 are also provided in the paper Over the last 50 years Newmont has developed a host of innovative gold technologies to meet the challenges of treating the complex refractory gold ores, found at the company owned mines in the Carlin region and around the world. Details of the technologies are provided and they include chlorination, roasting, bacterial and pressure leaching, leaching gold with thiosulphate and thiocyanate, N2Tech flotation, HPGR treatment of hard and abrasive ores and, finally, the use of Hydro-Jex technology for improving gold recovery from heaps.

Jan 1, 2009

By B. S. Xakalashe, M. I. Khama, Q. G. Reynolds

The carbonaceous reduction of manganese ore is an energy-intensive process that releases large amounts of pollutant gases. In an attempt to circumvent the greenhouse gas emissions, this research investigates hydrogen as an alternative reductant. The reduction of manganese ore with hydrogen results in the structural changes in the intermediate products, which might limit the diffusion of the reactant gases through the pores. Computational fluid dynamics (CFD) models capture the structural changes and predict the rate controlling mechanism and this is key in designing the prereduction reactors. The current work uses CFD models to predict the degree of reduction in a shaft furnace under hydrogen reducing conditions. Manganese ore is described as a collection of scalar and tensor fields such as thermal conductivity of the porous medium, density, and viscous resistance. The results indicate that advection contributes significantly towards the overall transport of hydrogen to the reaction sites. Porosity of the final product was found to be higher than porosity of the raw material.

Mar 4, 2025

By T. Szendrei, S. Tose

The fracturing and movement of rock that occurs in the vicinity of a stemmed borehole charge in open pit mining operations are described by examining the effects of the emitted stress waves – shock and elastic – and the expansion of high-pressure detonation product gases. Three principal modes of momentum transfer to fractured rock are identified, all linked to gas expansion work. This work can be delivered radially (burden), axially (stemming), and in the collar zone (cratering). Flyrock is generated under unusual combinations of blast parameters and rock properties. Although infrequent and seldom predictable, the generation of flyrock can nonetheless be interpreted and modelled in terms of the principal mechanisms of rock projection described in this study. The physical processes underlying these principal mechanisms are identified and will permit the development of predictive models for flyrock velocities.

Dec 13, 2023

By W. J. C. Pothas

This paper describes the state of the art in backfilling techniques used on East Driefontein Gold Mine. Areas covered are the preparation plant, the distribution plant, the pipeline network and finally placement techniques. The in-situ performance of placed backfill has been assessed by the Chamber of Mines Research Organization, and results to date will be shared. Details of the backfill expansion programme that will enable this facility to be made available to all working places are included. Benefits obtained by the introduction of backfilling are described, together with certain management aspects to be considered in the control of quality and quantity of support supplied via a pipeline.

Jan 1, 1988

By R. Layton

Expert Systems Technology (EST) is becoming more and more widespread in both its range of applications and the public interest. It appears to be capable of performing tasks unmatched by other techniques. Within the mining industry a large body of unsolved problems now appear to have a solution. This paper examines the current state of EST both in the context of the history of Artificial Intelligence and current efforts at building mining expert systems. It provides recommendations for those wishing to get involved, and outlines the problems for those who believe that expert systems are capable of anything and everything. The paper also provides a detailed analysis of limitations of current EST that must direct research into more fundamental, commonsense areas than have been extensively covered before.

Jan 1, 1987