Search Documents

By Alla D. Mah

Heat content and entropy data at high temperatures were obtained for cuprous oxide (Cu2O) and cupric oxide (CuO). Experimental results and smooth values are reported. Equations are given for heat content increments and heat capacities above 2980 K. Low-temperature heat capacity data were obtained for cuprous oxide. Evaluation of the 2980 K entropy gave, S°298.15(Cu2O) = 22.08 ± 0.10 cal/deg mole. Heat of formation values were determined for cuprous and cupric oxides. The values are: AH°298.15(Cu2O) = -40,830 ± 300 cal/mole, and AH°298.15(CuO) = -37,230 ± 150 cal/mole.

Jan 1, 1967

By George A. Burrell, Frank M. Seibert

The Bureau of Mines, as part of its designated duty of investigating the causes of mine accidents, is conducting at its experiment station in Pittsburgh, Pa., a study of mine gases. Some of the work already done in connection with this study is outlined below. A large number of mine-gas samples have been collected under normal conditions in returns and in splits, and at other points in the ventilating current, also at the face, in the goave or gob, in unventilated places, and wherever the air was still. Samples have also been obtained under abnormal conditions, as after explosions and while mine fires were in progress, or from sealed areas behind stoppings and darns where the air had been stagnant for some time. Chemical changes in the composition of mine atmospheres during mine fires have been studied," and conditions peculiar to certain mines have been investigated. The question of the effect of a change in atmospheric pressure on the escape of gas (methane) in coal mines has been studied. Explosives have been fired in both coal and metal mines, and samples of resulting gases have been collected to ascertain the degree to which these gases vitiate the air. A series of samples in mines where gasoline locomotives were being used have been examined in order to ascertain the degree to which the exhaust gases from such locomotives foul the mine air. Experiments have also been performed in regard to the relative effect of carbon monoxide b upon men and small animals. A preliminary report relating to the inflammable gases in mine air has been published. Full reports of the results of the investigations outlined above will be published as soon as all the necessary data have been gathered. The first part of this report deals with the methods used by the bureau in the collection and examination of the various mine gases; the latter part discusses the bureau's methods of sampling and examining natural gas.

Jan 1, 1913

By W. O. Vanderburg

The leasing or tribute system has been an important factor in the development of our metal-mining industry, particularly in the gold and silver mines of the Western States. It has received its widest application in. the early history of many camps and in the last stages of many mines. The system is especially adapted to mining where the ore's occur in narrow veins or are erratically distributed in small bunches or pockets so that selective mining, hand sorting, screening, or hand cobbing is required to produce shipping or milling-grade ore. The leasing system is also applicable to the development of prospects where the owners are unable or unwilling to assume the risks of searching for ore. The virtue of the system lies in the opportunity it affords miners with little capital to get started; at the same time, it rives owners an opportunity to have their property developed at small cost.

Jan 1, 1934

By Samuel S. M. Chan

The objective of this project was to collect information applicable to the design of ground support systems in deep mines to include in-situ rock deformations, deformation-modulus, stresses, and geology and laboratory physical properties. All data collected was to be integrated and evaluated using a finite-elements computer code. In addition, considerable professional "cross pollenization" was anticipated from the association of University and SMRC personnel. Scope of Investigation Before a ground supporting system can be evaluated, the loading conditions existing in the region of investigation, strength, deformation characteristics, as well as other engineering properties of the rock structure immediately surrounding the openings, together with the pertinent geological information, must be obtained and analyzed. It was for this reason the following items were included in this research project: (1) The selection of a suitable area for the investigation. (2) The mapping of the important geological features of the area of investigation. (3) The measurement of in-situ deformation of rock masses immediately surrounding an underground opening of the area of investigation. (4) The determination of ground stresses. (5) The obtaining of in-situ modulus of deformation of the rock masses. (6) The testing of useful engineering properties of

Jan 1, 1972

By F. W. Lee

The paramount importance of water to life of all forms on the earth is too well known to require elaboration in this brief paper. It has repeatedly been termed the most valuable of all our mineral resources. Its importance is justifiably recognized in the extensive areas covering the earth which receive sufficient rainfall to sustain a relatively luxuriant vegetation; but in those areas where rainfall is insufficient to support anything but a relatively meager plant growth, the location of a water supply and its development become of even more vital interest to those attempting to obtain a living from the soil. Geological investigations concerning the water supply of the United States have been most extensive, important work having been accomplished by Federal, State, and local governments and by private enterprise. A casual examination of the titles of the 739 Water-Supply Papers published by the United States Geological Survey3/ alone testifies 'to the vital nature of our water resources and the extensive work that has been done on them.

Jan 1, 1936

By John M. Gomes

Two molten salt systems were evaluated as electrolytes for the repetitive recovery of tungsten from tungsten oxide (W03) made by calcining commercial-grade ammonium paratungstate. Using a sodium chloride-sodium fluoride-potassium aluminum tetrafluoride electrolyte at 800° C, 1 pound of 99.8 percent tungsten was recovered for each 2.7 kilowatt-hours of energy consumed. The metal contained 1,100 ppm carbon, was in dendritic masses of spherical grains, and had an apparent bulk density of 5.41 g/cm3. T ngsten of 99.9 percent purity was won from a sodium pyrophosphate-sodium tetraborate-sodium chloride electrolyte at 1,000° C; 6.0 kilowatt-hours of energy was consumed for each pound of metal recovered. The metal contained 120 ppm carbon, was in dendritic masses of hexagonal acicular crystals, and had an apparent bulk density of 7.25 g/cm . Each metallic impurity--aluminum, calcium, copper, iron, nickel, and silicon--in the two tungsten products was 16 ppm or less.

Jan 1, 1966

By W. W. Odell

Engineers interested in the manufactured-gas industry have witnessed p pronounced improvements in gas-generating equipment and marked changes in operating procedure during the past decade. In spite of these changes, however, the trend of development in the near future seems to be doubtful. Uncertainty exists mainly because no one can yet accurately calculate the number of years which will elapse before petroleum products become too expensive for, general use in making gas. Research in this field has been active, and the ultimate results are awaited with interest. Some engineers predict that in the future coking coal will be carbonized on such a large scale that coal gas will be used (straight or modified) for city distribution; others maintain that gas oil will be used in large quantities in the production of base gas; they believe that it will be economical to use oil even at appreciably higher prices. The question involves, among other; factors, consideration of initial and relative costs of equipment, flexibility of operation, salability of coke, cost of distributing different gases, and the relative value of by-products, It is common belief that for many years large quantities of oil will be used in gas-making, particularly in the generation of peak gas or that water gas will be used for the synthetic production of hydrocarbons to enrich additional water gas. In this paper interest centers in a discussion of the practicability of employing synthetic processes in view of reported investigations of the chemistry of the synthetic reactions. For many years it has been known that the chief components of water gas would react chemically under proper conditions to form methane. As long ago as 1903 a patent3 was issued in this country for a gas-making process which included the synthetic production of methane. More recently the studies of numerous investigators here and abroad have shown that besides methane it is possible to produce other paraffins, olefins, and additional, materials adaptable for enriching water gas or for other uses. The question arises: In what manner, if at all, can such processes be incorporated, as a part of the gas-making scheme in a city-gas plant?

Jan 1, 1928

By K. H. Johnston

This guide was written to furnish the coal industry with a description of techniques, instruments, and clues on how to find abandoned oil and gas wells that have penetrated coal seams. The report includes specific information on searching techniques currently in use by several coal mining companies, gas-transmission companies, and waterflood operators, as well as information on State agencies responsible for the enforcement of laws and the preservation and distribution of data pertaining to the drilling, development, and abandonment of oil and gas wells. Comparative tests were performed with several commercial electronic metal detectors to determine the feasibility of using them to aid in the search for abandoned wells and to determine the instrument most suited for that particular use. The role of methane detectors to locate abandoned wells is described, including a case history. Tests were made to develop an efficient procedure to follow in systematically searching an area for metallic clues or hydrocarbon evidence to abandoned wells. The guide describes, in detail, a search sequence, including the collection of basic data, preparation of the selected area, and the physical search. Methods are given for evaluating the results.

Jan 1, 1973

By Thomas C. Denton

The fluorite, deposit discussed herein occurs on a property known as the Snowball and comprises five contiguous mining claims in Maricopa County, Ariz. Attention of the Bureau was first directed to this property early in 1944 through .a request by D. B. Powell, original locator; to investigate his property as a possible source of fluorite and one that might 'Warrant exploration by the Bureau. The property was examined by two Bureau engineers, Thomas C. Denton and Geo. W. Huseman. It was decided to investigate the occurrence further by trenching, sampling, and diamond drilling. Work began on May 15, 194. Preparatory work, trenching and surface sampling, was supervised by Geo. W. Huseman. Drilling was in charge of R. M. Grantham. The project was completed August 8, 1944.

Jan 1, 1949

By L. J. Kane

Applications are described of various methods for determining the weight concentration and physical properties of solid and liquid impurities of gases in connection with problems encountered in synthesis-gas production. Of special interest among these methods may be listed: 1. A method developed for determining, the weight concentration of solid and liquid impurities in. hot, crude synthesis gas containing a high concentration of moisture. 2. A method developed for the same purpose but for highly purified synthesis gas or atmospheric air. 3. A method for obtaining a uniform dispersion of dry duet or, a microscope slide for particle-size determination or other purposes.

Jan 1, 1954

By W. W. Adams

Reports received by the Bureau of Mines, Department of Commerce, from State mine inspectors, for November, 1930, showed that 219 men were killed in the coal mines of the United States during the month, an increase of 25 over the previous month and 33 over November, 1929. On the other hand the production of coal decreased, the output of 43,329,000 tons in November being 8,397,000 tons less than in October and 9,005,000 tons less than in November a year ago. The larger number of fatalities accompanied by a smaller output of coal resulted in a higher death rate4 per million tons in November than in the same month last year or in October, 1930. The November rate was 5.05, as compared with 3.55 for November, 1929 and 3.75 for October, 1930. The increase in the rate for the industry as a whole was chargeable entirely to bituminous mines,, as the anthracite mines had fewer fatalities in November than in either of the previous months to which reference has been made. Reports for bituminous mines alone 'allowed that accidents at class of mines resulted in a death rate of 5.12, based on 195 fatalities and a production of 38,122,000 tons. This rate indicated an increase of 55 per cent over the rate for October, of the same year, and 72 per cent over the rate for November, 1929. The October record was 146 fatalities and 44,150,000 tons, and that for November a year ago was 138 deaths and a production of 46,514,000 tons. Twenty-four deaths occurred at anthracite mines in November, 1970: the output of coal was 5,207,000 tons, hence the rate was 4.61 per million tons. During the corresponding month a year ago there were 48 deaths and 5,820,000 tons of coal produced, which indicated a death rate of 8.25. In October, 1930, the death rate was o.34; based on 48 deaths and 7,576,000 tons.

Jan 1, 1930

By E. K. Stanek

This volume describes software developed for programmable calculators that is useful in the analysis and design of mine electrical power systems. The programs are equally useful for any industrial or commercial power system. All programs are written for both the HP-97 and the TI-59 programmable calculators. Listings of both versions of the twelve programs that were developed appear in the report. The programs that were developed can be broken into two groups. The first group encompasses design-oriented programs. The second group encompasses analysis programs. For each program the following items are provided: a description of the program's capabilities, the solution technique used, instructions on how to use the program, a worked out example with data and results and, finally, listings of the programs for the HP-97 and TI-59 programmable calculators. Typical problems that can be attacked with these programs include ground bed design, selection of contactor size, fuse size, relay settings, instantaneous overcurrent trip settings for trailing cables, allowable cyclic cable loading, short circuit analyses, prediction of transient voltages and others.

Jan 1, 1979

By Lawrence G. Houk

In modern warfare mica is truly indispensable. The coordination of combatant units necessitates maintenance of intricate communications equipment, in the construction of which high-grade sheet mica is essential. Scrap, ground, and the poorer qualities of block mica, which are less essential to the military program, are not considered in this paper. Furthermore, as the paper is designed primarily to assist mica miners, mica derivatives such as splittings and films are also excluded from discussion. The paper therefore relates solely to block mica of strategic quality.

Jan 1, 1942

By Jr. Kauffman

The data contained in this report were obtained incidental to the Bureau of Mine's investigation of the lime-soda sinter process as applied to the recovery of alumina from siliceous bauxite, kaolin, and other high aluminous materials. The Bureau of Mines was charged by Congress to investigate processes for the production of aluminum from domestic low-grade ores. The Eastern Experiment Station at College Park, Md., conducted laboratory and pilot-plant investigations of the recover-y of alumina by the lime-soda sinter process. Reports by the College Park staff covering the recovery of alumina from these sources have been published. The lime-soda sinter process involves the sintering of the finely ground siliceous bauxite or clay with limestone and soda ash in a rotary kiln. During the sintering the alumina supposedly reacts with the soda ash to form soluble sodium aluminate and the silica combines with the lime to form the insoluble orthosilicate. In the early stages of the investigation it was considered desirable to know the temperatures at which the phase changes occurred during the sintering operation. The total time involved in the passage of any given portion of the charge through the kiln was 28 minutes. The exposure time of the charge to temperatures above 600° C. (decomposition temperature of kaolinite) was, roughly, half the total. The exposure to the full temperature of the kiln, 1,100° C was only 3 minutes. (Subsequently, the maximum kiln temperature and retention time were increased.)

Jan 1, 1949

By Robert W. Geehan

"INTRODUCTION The Bureau of Mines has been investigating deposits of critical and essential minerals in the United States since 1939. Many of the mines were developed.A preliminary examination of the Sultan mine was made in January 1945 by the author, who recommended investigation by drifting and crosscutting. The Bureau conducted a project at the mine from April to June 1946. Claims investigated are in sec. 20, T. 25 S., R. 58E., Mount Diablo base and meridian, in southern Clark County, Nev., about 7 miles southwest of Good-springs.The Sultan mine has been an intermittent producer of zinc-lead-silver ore since 1910. During World War II, ore was shipped to the Government stock pile at Jean, Nev., and to the International Smelting& Refining Co.'s smelter near Salt Lake City, Utah. Throughout the past year, ore has been milled and the concentrates have been shipped to the smelter."

Sep 1, 1947

By Frank K. McIntosh

The Hamme tungsten district is in Vance County, N. C., and Mecklenburg County, Va. Principal development has been in Vance County. The district is approximately 8 miles long by 1 mile wide and extends northeast-southwest. Its center is about 3 miles N. 65° W. of Townsville, N. C. The occurrence of tungsten in the district was first reported in 1901, but it was not until the Hamme brothers revived interest in the deposits in 1942 that commercial development began. The Bureau of Mines, as part of the war minerals program, began exploration and development of the district in June 1943 and completed it in December 1943. The Federal Geological Survey cooperated by mapping the topography and geology and logging the drill cores. The program included mapping, trenching, sampling, diamond drilling, and analyses and beneficiation of ore samples, The principal ore mineral is hubnerite, which occurs in quartz veins within the schist and granite. The veins are generally lenticular along the strike and dip. About 50 quartz veins have been noted in the area, but many are barren or slightly mineralized.

Jan 1, 1948

By H. E. Powell

A laboratory mineral-dressing investigation was conducted by the Federal Bureau of Mines on four limonitic and four sideritic iron ores from the North Basin of the east Texas iron-ore district. The samples, composited from drill cores, were considered representative of the iron-ore reserves of the area. The objectives of this research were twofold: (1) To devise a mineral-dressing method whereby the yield from currently mined east Texas iron ores might be increased and the grade improved, and (2) to extend such treatment to include the lower grade ferruginous materials that are not amenable to beneficiation by simple washing and, therefore, are not being exploited. Of the mineral-dressing methods used in this investigation, magnetic separation of roasted are was shown to be the most effective. Results show that, by this method, a laboratory recovery of 82 percent of the iron is attainable at a grade surpassing that obtained by current plant practice and that both limonite and siderite are amenable to concentration by the process. The existence of large deposits of iron are in eastern Texas has been recognized for over 100 years. These ores were first exploited during the Civil War and were mined intermittently until about 1911. From that time until 1944 when the Defense Plant Corporation financed the erection of three blast furnaces to use these east Texas ores, production was almost at a standstill.4/

Jan 1, 1960

By Gregory J. Chekan

The Bureau of Mines, in an effort to improve planning and development in coal mining, is investigating strata interactions associated with mining of multiple coalbeds. Two common interactions that occur between adjacent coalbeds are subsidence and pillar load transfer. The study described involves underground observations and measurements conducted at two Pennsylvania mines, each affected by one of these interactions. At the mine affected by subsidence, measurements show that undermining had little effect on upper mine pillar stability, but had a more severe effect on the development and maintenance of entries. Roof-to-floor measurements recorded over four times more convergence in entries developed over gob as compared with entries developed over support pillars in the lower mine. At the mine affected by pillar load transfer, Initial in situ measurements have shown the existence of a pressure arch in the lower workings. Prior research has shown that arch interaction between two adjacent openings can create stress concentrations in the in-nerburden. Underground measurements and results obtained from both mine sites correlate with theoretical and photoelastic multiple-seam models, and eventually these field data will serve to refine model accuracy. Further study of multiple-seam interaction mechanisms will lead to improved mine planning, increased resource conservation, and a safer working environment.

Jan 1, 1986

By Robert C. Dyni

This report details the investigation of multiple-seam longwall subsidence conducted by the U.S. Bureau of Mines from 1978 to 1989. A field investigation monitored ground surface movements over four upper-seam longwall panels and six lower-seam panels. The characteristics of the subsidence occurring as a result of mining these panels are examined; in particular, the angle of draw, subsidence development, total magnitude and areal extent, and critical width are evaluated and discussed. Comparisons are also made between the characteristics of multiple-seam longwall subsidence and single-seam longwall subsidence that occurred at the same site.

Jan 1, 1991

By Stewart W. Towle

In 1989, the u.s. Bureau of Mines initiated a contract to gather engineering, operating, and environmental cost data for 1988 for 30 major foreign primary copper smelters in market economy countries. Data were collected for 29 of the designated smelters together with information on applicable environmental regulations. Materials balance data obtained were used with available data for the eight U.S. smelters to determine the approximate extent of copper smelter sulfur emission control in 1988. A broad characterization of the status of sulfur emission control regulation was made. The 37 U.S. and foreign smelters represented roughly 73.2% of world and 89.3% of market economy primary copper production in 1988. The 29 non-U.S. smelters attained 55.3% control of their input sulfur in 1988. Combined with the 90.4% control of U.S. smelters, an aggregate 63.4% sulfur control existed. Roughly 1,951,100 mt of sulfur was emitted from the 37 market economy smelters in 1988. Identifiable SO2 control regulations covered 72.4% of the 29 foreign smelters, representing 66.5% of smelting capacity. Including U.S. smelters, 78.4% of the major market economy smelters were regulated, representing 73.1 % of smelting capacity. Significant changes since 1988 that may increase sulfur emission control are noted.

Jan 1, 1993