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By V. A. Chanturiya

There is an obvious disproportion in Russia gold-mining industry between the structure of gold reserves and the gold-mining techniques. The bulk of gold (over 70%) is extracted from alluvial deposit, 20%~25% from bedrock occurrences and 5%~7% from complex copper-zinc and polymetallic ores. The proved gold-bearing reserves are distributed as follows: alluvial ?19%, bedrock ?80%, the latter being sufficient to supply gold at the current production level for 100 years to come. In Russia, like elsewhere in the world, development of primary gold deposits is considered a first-priority line of development for gold-mining industry. Most of the gold-containing ores characteristic of Russian gold deposits are resistant ores with gold content varying between 3 ppm and 5 ppm usually showing quite low gold and silver recovery by cyanidation. Processing resistance of gold-containing mineral complexes is related to the presence of gold particles of submicrometric (<1.0 µm) and nanometric (10~100 nm) size, mostly asso-ciated with pyrite and arsenopyrite. Therefore switching over to processing bedrock entails a num-ber of technological problems that stem from chemical and physical resistivity of ores. The chemical resistivity can be overcome through flotation, oxidation roasting, autoclave leaching (biohydro-metallurgical oxidation), etc. The physical resistivity can be dealt with by resorting to traditional power-intensive methods,e.g. grinding to a ?40µm size, thermal treatments of sulphide concentrates and non-traditional high-energy methods of liberating the sulphides by means of power attack, e.g. electro-chemical oxidation, exposure to electron beam radiation and other methods. The modern non-traditional processes for treatment of rebellious noble metal-bearing ore, aimed at improving disintegration efficiency for finely dispersed mineral complexes are analysed. Advantages and perspectives of a new high-efficient, energy-saving and ecologically safe process of the nanosecond high-power electromagnetic pulses (HPEMP) effect are proved. The said process provides a stable increase in the valuable component recovery at lower energy consumption and production costs of the finite product at the stage of dressing rebellious gold-bearing ores and concentrated products. The experimental data prove high efficiency of the preliminary impulse treatment, thus, the increase in the gold recovery at the cyanidation stage amounted to 4%~12% from rebel-lious ores, 10%~30% from gravity concentrates, 5%~45% from flotation concentrates, 30%~80% from oil flotation tailings.

Jan 1, 2014

By Z. Naziemiec

Since several years in Poland a huge demands on mineral aggregates occur, for the reason of intensive development of housing and road industry, as well as industrial building. Limitations in re-sources of broken aggregates in Central and Northern parts of Poland cause, that both the non-waste production of aggregates with high quality and the production of alternative aggregates from recycling gain greater importance, nowadays. It entails increase in demands for crushing devices, which are easy and reliable in operating as well as inexpensive and enabling to obtain a good quality products. Jaw crusher, regarded as the most spread in Polish industry, meet these requirements, however, their crucial disadvantage is a large content of irregular grains in crushing products. Numerous investigations show, that the shape of grains is a significant feature of aggregates, which influences on durability and quality of produced concretes. The advantage of jaw crushers is their easy operation, low price as well as low amount of dusts (wastes) generated in comminution products in comparison to other types of crushers (i.e. hammer crushers).

Jan 1, 2014

By B. Orberger, J. M. Milazzo, S. B. Blancher, J. Lützenkirchen, J. L. Dubos

"Industrial dusts are commonly agglomerated using empirical recipes with binders such as bentonite, while Sludges are agglomerated into mixes. Those materials contaminate the products, are expensive and generate significant amounts of slag. Achieving cold dust agglomeration with little or no binder requires understanding the controlling parameters in order to predict and optimize the process behavior. This in turn necessitates comprehensive dust characterization to base predictions on measurable characteristics. In the present work we collected 13 Mn-rich dusts over all the process chain: feed fines, smelting, and refining dusts, as well as ferromanganese alloy dust. This is the first systematic study of dusts along the Mn-processing chain for chemical, physical and mineralogical parameters. X-Ray Diffraction, Qemscan® and laser granulometry analyses show that the mineralogy, Particle Size Distribution (PSD) and morphology evolves from complex heterogenous to simple, homogenous along the process chain: The mineralogy of the primary ore dusts shows various hydroxides, oxides, carbonates, tectosilicates and phyllosilicates. The furnace dusts contain oxides, tectosilicates and carbonates with volatiles, while the refining dusts present only oxides and metal. Finally, the Metal dust is nearly pure metal. Particle morphologies and PSD vary from jagged, irregular particles with broad PSD (>1 mm to <0.3 µm) to smooth and spherical with narrow PSD (100 µm to <0.3 µm). The Metal dust is an exception with angular particles. The Cationic Exchange Capacities (CECs) of all samples range from 0 to 22 meq/100g. Specific surface areas (SSAs) range from <0.1 to 27m²/g, and seem to decrease with from ore feed to Metal dust. This may be due to the disappearance of hydrated and/or sheet-bearing minerals, since a smaller grain size usually implies an increased SSA. The zeta potential varies strongly over the range of the samples tested. However, beside the Gabon ore which has an Isoelectric Point (IEP) ~ 4.1, the other IEP ranges between 2 and 2.5."

Jan 1, 2018

By A. S. Choudhary

India is endowed with a reasonably large reserve of chrome ore, amounting to about 100 million tons in different grades and is one of the leading producers of ore/concentrate along with South Africa, Kazakhstan and others. Chromite production in India has registered a 10 times increase during the last 30 years. Till late 1940s, the practice was to mine the high-grade ore for making ferrochrome and charge chrome and export the same leaving the low and medium grade ores stacked around the mine as waste material. This practice was continued for quite some time till the increase in world wide de-mand of chromite initiated an increase in production of chromite ore in India and the aspects of ?economy of operation? and ?conservation of mineral? dawned on the producers and associated authorities. Recovery of chrome values from low and medium grade ore was initiated to produce high-grade saleable concentrate. Suitable legislation was made by Government of India to induce and provide incentives to the operators to do so. First large scale chromite beneficiation plant in India was commissioned about three decades back at Byrapore in the Southern state of Karnataka. The ore, rather simple in nature and relatively free from clay, was obtained from underground. The processing consequently was simple washing and wet tabling. Further more, some test work, on the samples from eastern coast particularly from Orissa, was carried out at an internationally reputed laboratory by a large private operator and the plant was set up. This consisted of a combination of crushing-grinding-de-sliming-classification followed by concentration in multi stage spiral concentrators and shaking table. The plant was commissioned and operated successfully. Soon a state owned company followed suit on the basis of test work carried out in a well equipped Indian laboratory. The plant worked satisfactorily after some initial teething trouble and the company plans to double the existing plant capacity by installing balancing facilities. This development prompted a number of operators, including industry leaders to join the fray and the chrome ore processing industry flourished in India. More and more operators are now in the process of adding capacities to their existing plants. This paper attempts to chart the evolution of chrome ore beneficiation industry in India through a case study with reference to an existing plant. The process technology adopted and modified to suit the altered requirements as well as the future trends are outlined.

Jan 1, 2014

By Z. Pokrajcic

The traditional comminution circuit is a major consumer of energy ? both as electrical energy and through consumption of media and wear resistant liners. Up to 40% of electrical energy con-sumed at a mine site is attributed to comminution however only a few percent of this energy is used in the generation of new surfaces from size reduction. This paper describes the evaluation of modifications using simulation models based on two operating comminution circuits. The aim of these modifications is to decrease both the amount of electrical energy consumed in the size reduction process, known as direct energy, as well as to decrease the consumption of grinding consumables such as steel grinding media and mill liners, designated as indirect energy. The approach is two-fold: ??Employ, where possible, autogenous grinding techniques to eliminate the need for grinding media and reduce mill liner wear. ??Optimise the use of the grinding energy distribution in the comminution circuit by using more energy efficient grinding devices to target typically problematic features of a comminution circuit such as critical size material from the primary mill and overgrinding in the secondary mill. The investigations show that significant total energy savings, as high as 50% in some cases, can be achieved by employing the techniques described while maintaining circuit throughput and product size. Investigations also show potential benefits in downstream flotation processes as the product size distribution generated from the eco-efficient circuit is generally ?narrower? in shape for improved flotation performance and containing less material in the coarse fraction for overall better liberation.

Jan 1, 2014

This investigation addressed two products from Samarco?s desliming circuit, namely underflow of cleaning cyclones and underflow of desliming cyclones. The roughing cyclones receive the product of the grinding circuit. The underflow of the roughing cyclones feeds the cleaning cyclones and the overflow feeds the desliming cyclones. The underflows of cleaning and roughing cyclones are combined to constitute the feed of the flotation circuit. These fractions were characterized and a new process route was proposed. The size distributions of the two fractions are quite different. The desliming cyclones underflow presents higher amount of material passing 37 µm and of ultrafines as compared with the cleaning cyclones underflow. Laboratory scale flotation tests were performed in a mechanical machine aiming at comparing the performances of these products in the presence of the reagents employed in the concentrator. Pi-lot scale column flotation yielded enhanced iron recoveries for both products in comparison with those achieved in laboratory mechanical cells, without impairing the concentrate quality. The in-crease in recovery was more significant in the case of the cleaning cyclones underflow. These results suggest the use of columns in the flotation of this product aiming at increasing the overall iron recovery. Nevertheless the results also showed that the use of columns to float the cleaning cyclones underflow should also be taken into consideration. Despite the fact that this product requires a longer residence time in order that the required silica content in the concentrate is achieved, the indication is that higher levels of iron recoveries might be reached. The conclusion is that, due to the different behaviors of the two products, they should be processed in distinct circuits to maximize the iron recovery.

Jan 1, 2014

By X. Q. Cui

The surficial collapse pits of the mining areas are continuously spreading in Beiminghe iron mine of Hebei Province as a result of the exploitation, which has done a lot of damage to the circumjacent ecological environment of the mine. It is a new path to handle the mine tailings at the present time that the thickened tailings are used to backfill the collapse pits, in which way the problems of the surficial collapse and the nowhere discharge of the tailings are both solved, and the rational utilization of the mine tailings and the clean production of the mine enterprise are realized. The?200 mesh content of the tailings of Beiminghe iron mine is 76.87%, and?325 mesh content is 63.50%. Semi-industrial dehydration experiments to the tailings have been done using the hydro-cyclone classified thickening process. The results show that when FX125 hydrocyclone is adopted, the concentration of underflow can achieve 73.31%, and the yield ratio is 61.78%; when FX150 hydrocyclone is adopted, the concentration of underflow is 70.57%, and the yield ratio is 54.31%, which indicate that the minor diameter hydrocyclone is propitious to improve the yield ratio of the underflow. The semi-industrial dehydration system of hydrocyclone classified thickening process is com-posed of FX125 hydrocyclone, D3600 high-efficient thickener and D2000 thickening bucket. The capacity to tailings disposal can achieve 3.07t/h and the tailings can be thickened from 28.86% to 62.45%. Compared with the traditional thickening-filtrating process and the total tailings directly filtrating process, the hydrocyclone classified thickening process has the merits of simple flow and high thickening efficiency, so it is easy to be realized in the mine.

Jan 1, 2014

By Yuhe Tang, Jun Zhang, Jianguo Liu

"The nature high carbon graphite with fine particle size has low commercial value because of its narrow application range. In order to improve its value, this paper has studied the methods for nature spherical graphite. The nature spherical graphite can be used as the battery material in the field of electronic product battery and new energy automobile battery, basis on the physicochemical characteristics and particle feature of graphite. In this research, the Fixed Carbon (FC) grade of the graphite sample is more than 95.0% and the particle size of the graphite sample is from +325 mesh to -100 mesh. There are many methods for nature spherical graphite, including the fluidized bed airflow mill, the hydro-spheroidization mill and micropowder mill. The testing results indicate that the method of ACM micropowder mill is the best because the spherical shaping ratio and production yield of spherical graphite are both the best.According to the testing results of the ACM micropowder mill, the best process includes two stages of coarse crushing, four stages of fine crushing and twelve stages of shaping. And two kinds of spherical graphite products can be got, which are the product of D50=22.85 µm and the product of D50=15.43µm, and the whole yield of them is up to 54.43%. So, it lays a foundation for the high value utilization of this kind of graphite resources.INTRODUCTION Graphite is isomer of the diamond. Graphite ore resources are mainly concentrated in China, Brazil, India, followed by Czech, Korea, Mexico, Canada and other countries. Graphite ore has lots of characteristics by itself crystal structure, such as good resistance to high temperature, electrical conductivity, thermal conductivity, thermal shock resistance, good lubricity, plasticity, chemical stability and so on. So, Graphite is widely used in metallurgy, machinery, electrical, chemical, petroleum, nuclear industry, defense industry and other areas. [1,2,3] Natural graphite ore has low geological Fixed Carbon (FC) grade. FC grade should be enriched to more than 94.0% by mineral processing. [1,2] The particle size composition of this high carbon graphite affects its application value. The part of +100 mesh particle size has high application value. The part of -100 mesh particle size has low value because of its limited application field. In order to improve the value of-100 mesh particle size, this part high carbon graphite can be made into spherical graphite. And the value of the spherical graphite is great, it is more than 8 times of the feed. This paper has lots of tests for spherical graphite preparing with the fine particle size natural high carbon graphite. And it lays a foundation for the high value of this kind of resource."

Jan 1, 2018

By J. J. Cai

The status of fossil fuel and secondary resource in metallurgy industry in China were reviewed, and conversion efficiency of fossil fuel, utilization technologies of secondary energy were studied. Fossil fuel, accounting for over 90% of energy structure in metallurgy industry, took in the highest flight in China, and a great deal of which was converted to secondary energy through the equipment of blast furnace and coke oven. These secondary energy which were mostly made of blast furnace gas(BFG), coke oven gas(COG) and Lindz Donawitz gas(LDG) occupied about 30% of total secondary energy. The way enhancing fossil fuel conversion efficiency, secondary resource recovery and the secondary energy such as BFG, COG, LDG utilization promoted to save fossil fuel was discussed in this paper. And efficient use of lower caloric value fuel was studied, such as preheating combustion air and fuel, generating electricity power etc. and regeneration purposes of high-caloric fuel was also researched, for producing hydrogen, methanol or direct reduction iron etc. The using model of secondary energy at iron and steel works was presented as fuel and chemical materials. The results suggest that utilization of these energy efficiently and reasonably could help to energy saving and environment protecting.

Jan 1, 2014

By E. L. Chanturiya

During the mineral processing of pyrites sulphide ores of some deposits of Russia loss of gold with tailings and pyrite concentrates amounts up to 40%~90%. The problem of selective allocation of gold-bearing pyrite is crucial. There are 4 mineralogy-technological groups of pyrite determined in copper-zinc sulphide ores, based on the increase of contents of gold in pyrite. The gold associated with group 4 pyrite contents of 85% the total mass of gold found in the pyrite. The flotation behaviour of the enriched fractions of pyrite (98%), of the allocated from the ore of Gay deposit, were studied essentially in various conditions ?? and the charge of Butyl xanthogenate of potassium (ButX). Some products of selective pyrite flotation were investigated by methods of scanning electronic microscopy, energy-dispersive and X-ray spectral microanalyses, definition of specific resistance and thermoelectric moving force.

Jan 1, 2014

By J. H. Starkey

SAGDesignTM Testing for grinding mill design was introduced commercially in 2004. Up to January 2008, 18 projects have been completed and 99 samples have been tested using this method. Two papers have been published describing the patented test procedure and one of these shows how the results compare with other grinding test methods. This paper will briefly discuss the theory on which this technology is based, and explain the procedures used to develop the calibration equation. Case studies are also included to demonstrate the effectiveness of the test work being done. These case studies show how the SAGDesign test is being used today: to design new grinding circuits for commercial full scale use; to calculate throughput in existing mills for production planning; and to accurately define grinding mill requirements at the scoping, pre-feasibility or feasibility study stage of project development, in order to economically identify the size and cost of the grinding mills that will be needed for the project. This is important because if the full rec-ommended SAGDesign testing program is done at an early stage in the project, the definitive cost for a guaranteed throughput, grinding mill design (by Outotec if their mills are purchased) is available. New grinding mill design for final engineering will be represented by the test work done on the Climax Molybdenum Project for Phelps Dodge (now FMI) in Colorado, USA. The SAG mill and ball mill for Climax are now in fabrication with project start up in late 2009. Next, the sizing of grinding mills at the scoping, pre-feasibility or feasibility study stage of mine development will be represented by a large metal mining property in Russia. Finally, calculation of the throughput for existing mills will be represented by work done at a base metal mine, in eastern Canada. Test work for designing SAG mills is now done in four laboratories at the time this paper was written. One in the USA at Dawson Metallurgical Laboratories, Inc. in Salt Lake City, two in Russia at the TOMS Research and Design Institute and at the Irgiredmet Research Institute, both in Irkutsk, and a fourth mill has been installed in Australia at AMMTEC Limited?s lab in Perth. A fifth SAGDesign test mill for radioactive ores has been built by Starkey & Associates, specifically for testing uranium ores and can be moved to any licensed lab in the world on a project basis.

Jan 1, 2014

By B. Tora

The new method of evaluation of grindability of hard coal and its blend is shown. Standard Hardgrove test is used as a base to work out this method. The essence of this method consists of simulation of milling process in close circuit (mill-classifier) and determination of energy consumption and quantity of product under the constant feed flow. The research equipment designed specially for this project is described New method of grindability measuring completes standard Hardgrove method withdrawing its faults: ? bigger (c.a. 10 times) and more representative sample is used; ? the milling process is carried out in close circuit (similarly to the industrial condition); ? energy consumption of the milling process is determined for three samples, which differs in grain size. The new method of evaluation of grindability of hard coal and its blend is shown. Standard Hardgrove test is used as a base to work out this method. This method allows us to determine energy consumption of the milling process. The essence of this method consist of simulation of milling process in close circuit (mill-classifier) and determination of energy consumption and quantity of product under the constant feed flow. Our results will complete the Hardgrove method and will help us to better characterise coal. At the same time investigations in industrial scale are carried out. These investigations will verify this new method. Also a new mathematical model of the milling process is being elaborated. It will be used to predict behaviour of coals in industrial conditions.

Jan 1, 2014

By F. Henríquez

Traditionally, the implementation of an automated control for a ball mill has been a challenging one. First, it must be capable of processing a variable SAG mill feed while at the same time avoiding to become a process bottle neck. Second thing is, it must deliver an adequate quality product (P80) to the process downstream. Then the ball mill itself and its associated classification equipment has problems of its own: it must maintain adequate control of cyclone?s pressure, density and pump-box level with often, less manipulated variables than needed, namely, variable pump speed and the opening/closing of cyclones. Thus, it becomes a non-linear multi-variable type of process with often too multiple and contradictory control objectives to satisfy simultaneously. On top of that, to extend cyclones availability and yet, maintaining their performance, is must both for process and maintenance purposes. Trying to solve the puzzle, Minera Los Pelambres implemented a novel and successful combination of MPC (Multivariable Predictive Control) and advanced control in two of its newest ball mills, reducing considerably process variability while maintaining high throughput and keeping the process well within constraints limits. Because of their differences in processing capacity, size and topology, two different stabilizing-control strategies were developed, tested and tuned. Hence, for both control approaches their implementation process, main results, areas of applicability, limitations and their key performance indicators are discussed further. This paper also discusses the need of such advance control technologies in the mining industry, including the impact of these technologies on best practices for their implementation, operation and long term sustainability

Sep 1, 2012

By Sravya Kosaraju, Christian Ekberg, Stefan Allard

Li-ion batteries are now used in electric vehicles (EVs), plug-in hybrid vehicles (PHEVs) and, hybrid electric vehicles (HEVs). Nanostructured Li(NiyMnzCo1-y-z)O2 is one of the more popular cathode chemistries for automotive Li-ion battery, due to its enhanced properties such as large surface area, short diffusion length, enhanced ionic and electronic conductivity, improved mechanical strength and structural integrity [Pan et al, 2013]. Recycling of Li-ion batteries helps to mitigate environmental effects of virgin metal extractions along with improper disposal of end of life batteries. To fulfill these objectives of the recycling, recovery of pure streams of the involved metals should be considered. In this study, the batteries were first discharged and dismantled in an inert atmosphere (Ar). The electrodes were then heat treated in a box furnace. This was done in order to break the chains of the adhesive (PVDF) and consequently separate the metallic substrates Cu and Al from the electrochemically active compound. This heat-treatment also helped to simplify the dissolution of the metal constituents in the electrochemically active compound from the cathode in the acid leaching process. Solvent extraction was chosen to achieve separation and recovery of metals with higher purity from these leachates. In the scope of the present work, a complete process from the point of dismantling to separation of constituent metals using solvent extraction was studied.

Jan 1, 2014

By S. N. Titkov

Flotation of halite?new, recently begun to be developed method of processing water-soluble minerals. In the paper the results of studies of the new directions of the application of halite flotation are represented. Studies on the flotation separation of halite and sylvite in the salt solutions of different composition, showed the possibility of the halite flotation realization not only in the carnallite brine (content of salts: MgCl2 25.5% ~ 26.0 %, chlorides of potassium and sodium 5.5% ~ 6.0%), but in the sylvinite brine, which contains 10.5% ~ 10.8% KCl and 20.5% ~ 21% NaCl. On the basis obtained results are carried out experiences on the halite flotation from samples of the converted products of sylvinite ores by flotation method and by the method of the electrostatic separation. It is shown that in all cases it is possible to accomplish effective and selective recovery of halite. The halite recovery into the foam product of flotation makes 80% ~ 90% with an increase in the content of KCl in the cell product of flotation in comparison with a composition of flotation feed: - from the product after the electrostatic separation of ore ? from 76% KCl to 95% ~ 97% KCl; - from the small fraction of ore (- 0.25 + 0 mm) ? from 30% KCl to 60% ~ 64% KCl; - from middlings (intermediate products) of sylvite flotation from 16% ~ 31% KCl to 45% ~ 80% KCl. An increase in the molecular weight of alkylmorpholines increases the selectivity of the flotation separation of halite and sylvite. Halite recovery from small size fraction of ore or/and middling of sylvite flotation with the sub-sequent joint filtration halite product and tails of sylvite flotation allows to reduce considerably expenses for manufacture potash chloride from Pilot-industrial tests for the first time confirmed the possibility of the effective halite flotation in the saturated solutions of chlorides of potassium and sodium (sylvinite brine).

Jan 1, 2014

By Andrew Logan

Newcrest has a strong history of growth over the past 20 years, yielding value from previously marginal ore bodies. We have grown regionally in Asia Pacific through our operations in Australia, Indonesia and Papua New Guinea, and also established a beachhead in West Africa. The company has a reputation of realizing value from large, low-grade deposits adopting step change approaches. Newcrest is focused on an overall strategy of gold, low cost, long life and moderate growth. Capability step changes play a large delivery role. They transition from a business offline-to-online approach as opportunities mature. Newcrest believes in a) Knowing what ?good? looks like, b) An open innovation approach to actively working with others, c) The leap frogging leverage of making the ?old new again?, d)An adopt-adapt-develop methodology enabled by rapid prototyping/piloting, e) Getting our handsdirty with test work and plant analysis, and f) Staying focused on a few high business leverage areas. This paper describes Newcrest?s approach and our experiences in establishing renewed metallurgical processes, specifically aimed at increasing innovation adoption. Some of our step changes discussed include: 1) Early waste rejection to avoid high energy processing downstream, 2) Broader gold product channels to reduce site based processing needs, 3) Lower energy processing, and 4) Geo-Metallurgy approaches. Keywords: Newcrest, gold, step change, open innovation, adopt, adapt, develop, offline, online, prototyping, old new again, waste rejection, low energy, geo-metallurgy

Sep 1, 2012

By Y. G. Sun

This paper mainly reported separation manganese silver oxidized ores process by amylum de-gradation reduction and its influencing factors. When dosage is given according to nMn : nH2SO4 : n(C6H10O5)n : nH2O=1:k21.8: k116.66:30, the amount of up to 95.93% Mn leach rate and less than 2% silver loss can be obtained. Cyanidation process was used to extracted silver from leaching Mn residues. Silver leach rate could reach 94.15% at consumed amount of 1kg/t NaCN for 1h. Silver leach recovery rate was more than 92.27% by leaching Mn and cyanidation two-step processes so manganese and silver were separated effectively.

Jan 1, 2014

By Jie-Liang Wang, Yongdan Cao, Zhao Cao

"The effect of ethylenediamine tetraacetic acid (EDTA) on flotation separation of fluorite from bastnaesite and its selectively depression mechanism on fluorite were studied by single mineral flotation, artificial mixed minerals flotation, solution chemistry analyses, Zeta potential and XPS measurements.The results show that fluorite can be deeply depressed by EDTA while the flotation of bastnaesite is almost unaffected when octanohydroxamic acid (OHA) is used as a collector. The separation index (SI) between bastnaesite and fluorite increases with the dosage of EDTA, SI can be raised from 1.18 to 12.66 when EDTA dosage increases from 0 to 2×10-3mol/L.Solution chemistry analyses show that EDTA is able to convert the Ca(OHA)2 hydrophobic precipitation on fluorite surface to a soluble Ca-EDTA complex but cannot complexly dissolve the Ce(OHA)3 precipitation on bastnaesite surface. Therefore, the Zeta potential of OHA conditioned fluorite can be reduced significantly by EDTA while the reduction degree to Zeta potential of bastnaesite is relatively low. XPS measurement shows that EDTA removes the chemically adsorbed OHA from fluorite surface but has little effect on the adsorbed OHA on bastnaesite surface. As a result, fluorite can be selectively depressed by EDTA in bastnaesite flotation, which behaves an important industrial application prospect in rare earth ore flotation.INTRODUCTIONNowadays, Rare earth elements (shortened as RE) and compounds are of significant importance for a range of rapidly expanding industrial applications including catalysis, metallurgy, renewable energy, and special materials due to their unique electrical, magnetic, optical and chemical properties [1]. The seventeen RE elements, including the lanthanide-group fifteen elements, yttrium and scandium, could be divided into three groups, i.e., light, medium and heavy RE elements based on the different solubility of RE sulfates [2]. Bastnaesite ((Ce,La)CO3), containing approximately 75% REO, is one of the most important light RE minerals [3]. Flotation is the common method to recover basetnaesite [4-6]. Nonetheless, basetnaesite is often associated with calcium-bearing gangue minerals such as fluorite, and the separation of basetnaesite and fluorite by flotation is usually difficult due to their similar surface properties and therefore floatability [7-9]. Therefore, research on high selective flotation reagents of bastnaesite over gangue minerals has attracted a lot of attention [10]."

Jan 1, 2018

By Z. G. Song

As a kind of complex physicochemical process, grinding would affect the subsequent mineral processing such as flotation considerably. In this study, the effect of wet grinding on malachite and calcite flotation using sodium oleate as collector was studied. And the mechanism of the effect of grinding was investigated. Laboratory scale grinding and flotation testing of malachite and calcite samples were performed. Different grinding media were used, including steel balls and zirconia balls. It was the aim of this work to study the effect of grinding on the pulp chemistry paying particular attention to flotation recovery. The effect of grinding media and different addition location of sodium oleate on malachite and calcite flotation was studied. The methodology used in this project involved grinding the ore with and without the addition of sodium oleate in mill, measuring the pH and metal ions produced by minerals after grinding, adding various quantities of sodium oleate and determining the copper recovery. The presence of species of products on the minerals after grinding was probed using X-ray photoelectron spectroscopy (XPS), and the metal ions produced by minerals after grinding were measured by atomic absorption spectrometry (AAS). It is showed that the mil-ling environments evaluated significantly affected the flotation of malachite and calcite. This study also discusses the effecting mechanism of grinding environment on floatability of malachite and calcite.

Jan 1, 2014

By T. Badrujaman

In September 2005, after 30 years experiencing in operating an ESF using a falling water film shell cooling system, Antam entered the new era in operating an ESF, after completely modernized its ESF No. 2 from a falling water film shell cooling system to a copper cooling system. Further, in the beginning of 2007, Ferronickel plant No. 3, where its ESF also uses copper coolers, was successfully commissioned. By operating an ESF using a copper cooling technology, Antam has to face some challenges to establish the operation stability. Besides that, the chances to maximize the furnace efficiency are greatly opened. The shielded-arc mode of electrode tip is selected to operate an ESF under relatively high furnace power to produce metal having tap temperature below 1500? and slag having tap temperature below 1600?. It leads to electric current unbalance. Further, operating an ESF using a copper cooler system under high voltage as consequence of the furnace power raise increases metal and slag tap temperature. This condition damages furnace integrity fast. Besides that, relatively high metal temperature increases its pressure during metal tapping. It leads to failure in closing the metal tap hole. The main different ways in operating an ESF using a falling water film shell cooling system and a copper cooling system lie in the electrode tip mode, the water specification used for cooler, metal tap block maintenance and allowed metal & slag level in furnace. Since a copper cooler system allows an ESF to be operated by consuming nickel ore having ratio Fe / Ni up to eight and producing slag having relatively high Fe content in slag, an undesirable silicon reversion phenomenon becomes an obstacle in reaching the operation stability. A copper cooler technology lets Antam to take a chance to increase its capacity. Modernizing the ESF No.2 had increased its furnace power from 17 MWh to 25 MWh. Meanwhile the ESF No. 3 can be operated up to 42 MWh. This technology allows an ESF to be operated under relatively high furnace power above 25 MWh safely as well as prolong the campaign life of ESF brick. Further, lowering ESF power consumption, extending the limitation of ratio S/M in nickel ore consumed and adjusting Ni grade in ferronickel product can be gained by applying this technology.

Jan 1, 2014