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By M. Remillard, M. Garon, M. Thérien, D. Hodouin

"Nineteen streams in the copper and zinc flotation units of the concentrator of the Matagami division of Noranda Inc. have been sampled for particle size distributions chemical assays, and gold and silver contents in each particle size interval. The data are upgraded by the mass balance package BILMAT. These results, in conjunction with microprobe analyses, are used to quantify the silver losses in the copper clean¬ing flotation stages and to determine how overall silver and three silver-bearing minerals are recovered in the plant final products.RESUME Dix-neuf produits des circuits de flottation du cuivre et du zinc de la division Matagami de Noranda Inc. ont été échantillonnés pour leur distribution granulométrique, analyses chimiques et le contenu d'argent et d'or des fractions granulométriques. Le bilan métallurgique a été obtenu à l'aide du programme BILMAT. Ces résultats couples avec une etude minéralogique à la microsonde sont utilises pour quantifier les pertes argentifères aux diverses étapes de nettoyage du circuit de cuivre et pour de¬terminer la repartition de l'argent et des trois minéraux argentifères dans les produitsfinals de l'usine.INTRODUCTION The Matagami division of NORANDA INC. produces copper and zinc concentrates from a sulphide ore which contains a small amount of gold (0.34 g/t) and silver (20 g/t). Only a small part of the silver (~-30%) is presently recovered in the copper concentrate. The objective of this study is to evaluate the metallurgical behaviour of silver, and secondarily of gold, in the flotation circuit for a possible increase of its recovery in the copper concentrate to improve its economic value. For that purpose it is worthwhile to study the minerals which bear silver and to determine the critical flotation stages where they are lost in the tails. The methodology proposed here is based on a coupling of a mineralogical study and a detailed mass balance calculation in the flotation circuit."

Jan 1, 1986

By Zoë Mullard

Just as a mine has a lifecycle, employees working within the mining sector also make several transitions throughout their career, from initial recruitment to retirement from the industry. Throughout the employment lifecycle, employees bring skills and knowledge that significantly contribute to the global economy. These skills are developed through education, professional training, coaching and through hands-on experience. Despite the current economic conditions and the demand for minerals, the mining industry is facing a substantial skills shortage due to the disparity between the number of new workers entering the mining industry and a largely ?graying workforce?. Although educational programs continue to evolve to attract people with a wide range of skills, the diversity of jobs and the strains of working in remote mining operations continue to present challenges for recruitment and retention of employees. This gap also presents challenges around knowledge transfer at a corporate and mine-site level; employers will require cultural and techno-sociological approaches to ease through these transitions. At the same time, there has been an explosion of social media tools that facilitate information sharing, cross-organizational collaboration, distance learning and knowledge capture. These tools have become increasingly popular in the last few years and their applications vary widely. The mining sector has started to adopt these tools for a number of purposes, including opportunities to harness social media to enhance human resources interactions, outreach and oversight. This paper will outline several case studies that explore leading practices for how the application of new media can assist organizations and individuals as they progress through their careers. This paper will illustrate how new social media communication technologies can be used to increase employee engagement and build organizational capacity in the mining industry. The paper will also include strategies for how to implement social media to enhance human resources applications and will cover ideas for monitoring and evaluation.

Aug 1, 2013

By John H. Fowler

Nova Scotia has been mining and exporting industrial minerals for over two hundred years. As an industrial mineral producer, this province continues to rank as the number one gypsum mining and exporting region in North America. Mining of many other commodities is ongoing, supplying many local and export markets. In all, excluding aggregate producers, there are nineteen industrial mineral producers operating at thirty sites producing nine commodities including anhydrite, barite, clay and shale, dolomite, gypsum, limestone, salt, silica sand and stone (Fig. I). Numerous aggregate producing operations supply all the province's aggregate requirements and export some of these materials to other regions of Atlantic Canada and as far away as Bermuda (Fig. 2) . Production value of industrial mineral commodities in Nova Scotia for 1982 was $105 million , representing 39% of the total value for all mineral production for the year. Because of the general improvement in the economy, indications are that the 1983 value of production will be higher.

Jan 1, 1984

By Ray Mason

Marathon PGM Corporation?s PGM-Cu Project in Northwestern Ontario (Figure 1.0) serves as a case study to describe the process involved in advancing a deposit from grass roots exploration to the completion of several feasibility studies and the parallel commencement of environmental permitting. Through the following examination of historical exploration activities, it is clear that these activities are directly related to economic stimulus, mostly measured by downturns in the mineral industry. Other factors that influence the success of exploration advancing to feasibility and new mine development includes the ownership of the mineral claims, which also changes under these economic influences and the crucial role of interactions between the Company, the Crown and First Nations. The Marathon PGM-Cu deposit is hosted within the Eastern Gabbro Series of the Proterozoic Coldwell Complex, which intrudes and bisects the much older Archean Schreiber-Hemlo Greenstone Belt. The sub-circular complex has a diameter of 25 km and a surface area of 580 km2 and is the largest alkaline intrusive complex in North America (Walker et al., 1993). Mineralization at the Marathon PGM-Cu deposit is part of a very large magmatic system that consists of at least three cross-cutting intrusive olivine gabbro units that comprise the Eastern Gabbro Series of the Coldwell Complex (Figure 3.2.4-3). In order of intrusion, the three gabbroic units consist of (1) Layered Gabbro Series, (2) Layered Magnetite Olivine Cumulate (LMOC) and (3) Two Duck Lake (TDL) Gabbro. The relative size and abundance of the gabbroic units decrease in the order Layered Gabbro Series>TDL Gabbro>>LMOC. Late quartz syenite and augite syenite dikes cut all of the gabbros but form a minor component of the intrusive assemblage.

May 1, 2010

By P. K. Kaiser, D. D. Tannant

"A support system for large ground convergence conditions or burst-prone ground must contain holding elements (rockbolts, cable bolts, etc.) that are strong yet capable of sustaining large deformations, i.e., they must absorb as much energy as possible. Steel wire rope anchored in a borehole by a friction bolt provides these desired yield characteristics if the frictional anchorage is placed deep enough into the rockmass, i.e., in non-yielding rock or beyond the expected depth of rock ejected during a rockburst. Pull-out tests were conducted on wire ropes anchored by inflated Swellex bolts to assess the feasibility of this support concept. The test results demonstrate that a Swellex bolt generates a frictional anchorage that allows the wire rope to slide at high loads and to absorb significantly more energy than either a Swellex bolt alone, or a cement-grouted cable.The rope/friction bolt combination can be engineered to provide the desired energy absorption and allowable deformation by varying the installed lengths of the friction bolt and the rope. For yielding rope support, the contact length between the rope and Swellex bolt must be short enough to ensure that the rope can slip well before its tensile capacity is reached. A safe maximum overlap length is about one metre for the wire rope used in this testing. When used as support in the backs of drifts, a swaged button on the ropes end must be used to ultimately mobilize the full rope capacity thereby protecting against gravity-driven falls of ground."

Jan 1, 1995

By Michael Samis

Conventional project valuation techniques, such as discounted cash flow (DCF) method, are more frequently being criticised for the manner in which they consider the interacting effects of uncertainty and project structure (including management flexibility) on project value. Modern asset pricing (MAP; often called ?real options valuation? when applied to the analysis of flexibility) is a more general valuation framework that corrects many of the shortcomings of common valuation methods. Previous mining applications of MAP have tended to treat the ore deposit as a homogenous entity. While useful for demonstration purposes, this is inadequate for practical application in industry. This paper presents a MAP valuation example that allows for the heterogeneous nature of an ore deposit. It shows that deposit structure may increase the complexity of the mine planner?s decision so that results of a standard DCF analysis, or a simple MAP analysis that ignores the details of deposit structure, are misleading. In the example, a management is considering the development of an adjacent low-grade zone while mining operations in a high-grade zone are ongoing. If the low-grade zone is developed before high-grade reserves are exhausted, the proposed development will include both low-grade zone development and a capacity expansion to handle additional low-grade reserve production. If development of these reserves is delayed until the high-grade reserves are depleted, then the low-grade reserves can be developed without a capacity expansion. A typical DCF analysis would reduce the management?s decision problem to three alternatives: 1) continue mining only in the highgrade reserves, 2) immediately develop the low-grade reserves and expand capacity, and 3) delay low-grade zone development until the high-grade reserves are exhausted. The model presented here allows the management to reconsider the development and capacity expansion decision on a discrete half-year basis. It delineates price regions, for given levels of high-grade zone reserves, in which it is optimal to develop the low-grade zone, defer low-grade zone development and abandon the mine irrevocably. The model presented here extends the ability of mine planners to describe actual project structure while using the MAP valuation framework that is already noted for its capacity to combine project uncertainty and risk insights with a dynamic project description.

May 1, 2001

By Ralph Harris, Javier Jara

"Oxygen is essential in gold cyanidation. It is supplied to the leaching media by sparging oxygen or compressed air into the cyanidation tank. The rate of oxygen transfer is critical to achieve the desired oxygen concentration in solution.The performance of a novel device for gas sparging recently developed at McGill University is compared to the mass transfer characteristics of the two spargers most used in the gold industry: the four lance configuration and the inverted cone. The distribution of gas and the kinetics of oxygen desorption of the three types of spargers was studied in a 140 litre tank. The oxygen dissolution of the new device is three to five times faster than the other spargers. This could increase the leaching rate and/or decrease the cyanide and oxygen consumption.IntroductionIn hydrometallurgical processing, it is often necessary to bubble gas through a pulp to carry out the wanted reactions. The gas can act to agitate the pulp and it can also supply reactant. The rates of the reactions which require a reactant supplied by the gas are often dependent on the rates of mass transfer from the gas to the solution.A common example of this is gold cyanidation which requires oxygen for gold dissolution. Since the gold containing slurry is rich in other oxygen consuming substances (sulphide like pyrrhotite), it is important to provide enough oxygen to allow complete gold dissolution within the residence time of the cyanidation reactors. It has been demonstrated that the rate of gold dissolution is directly proportional to the dissolved oxygen concentration of the pulp which in turn is proportional to the oxygen partial pressure in the bubble 1 2 3. Improving the rate of mass transfer of oxygen increases the dissolved oxygen concentration of the slurry and therefore improves the rate of the reaction.The rate of mass transfer from a bubble to its surrounding solution increases with decreasing bubble size and increasing gas bubble residence time which in turn increases with decreasing bubble size. The generation and dispersion of small bubbles is thus critical to achieving high rates of mass transfer. Different configurations and devices used to inject gas have different effects on the bubble size and the residence time, influencing the overall rate of mass transfer. Therefore better mass transfer can be achieved by adopting a more efficient method.The methods tested in this report are the four lance configuration (wall spargers), the inverted cone and a new device, designated HCD. The wall spargers and the inverted cone are used widely in the industry today."

Jan 1, 1994

By Mel Owen, Bob Tipman

"A number of studies have identified the presence of heavy minerals in the Athabasca oil sands. A 1996 Mineral Development Agreement study into the recovery of Co-Products identified low operating costs, a simple flowsheet and access to market as key drivers in advancing interest in a viable project.Commercial bitumen extraction processes recover 50% of the titanium heavy minerals and 85% of the zircon into froth containing 1 % of the feed solids. Froth treatment tailings grade is 11.5% Ti02 and 3.6% Zr02.Processing this high grade feed in a combination of flotation, roasting, screening, gravity concentration and magnetic separation, results in concentrates of rutile, leucoxene, ilmenite, zircon and rare earths of marketable quality.A combination of high grade feed and a simple process lead to operating costs among the lowest in the industry. Low cost heavy minerals and low energy costs indicate an intriguing potential for low cost pigment production in Alberta. The production of heavy minerals from oil sands remains one of the largest untapped resources in the Province of Alberta1.0 IntroductionThis paper describes the results of an investigation into the recovery of heavy minerals from tailings produced by the major oil sands plants. The study was carried out under a Canada-Alberta Mineral Development Agreement (Alberta Chamber of Resources 1996). The MDA Co-Products Study examined the potential for the economic recovery of heavy minerals from oil sands tailings."

Jan 1, 1998

By F. A. McLean

The past decade has witnessed a rapid increase in the number and variety of uses found for internal combustion engines in mining operations. Gasoline engines are now widely used for operating core drills, pumps, compressors, small hoists, switching locomotives, tractors, boats, and other equipment. The heavy-oil engine is employed for operating compressors, generators, shovels, ore-milling machinery, and- in the iron, copper, and coal districts- in connection with that' latest newcomer in modern railroading, the oil-electric locomotive. Each of these applications could well form a subject for a lengthy treatise in itself. This paper, however, will be confined to a discussion of some of the features of internal combustion engines as applied to mine compressing plants and mill drive. Perhaps at no time in the history of mining in Canada has the search for new mines been more vigorously carried on, more old properties rejuvenated, or more remote districts exploited than during the past three years. The mine operator of today has a far wider range of equipment and facilities at his disposal than had the pioneers of Rossland, Cobalt, or Porcupine. Each year now witnesses the hinterland driven farther and farther back as improved forms of transportation, machinery, and methods make possible the exploration of properties once considered too inaccessible to warrant serious attention. Howey, Sherritt-Gordon, Callinan-Flin Flon, Jackson-Manion, Picard Gold Mines, and a number of properties in British Columbia, afford excellent examples of work carried out on an extensive scale miles from a railway, or in comparatively inaccessible mountain regions.

Jan 1, 1928

By Matthew A. Baumann

Tooth wear on mining shovels presents a challenge for productivity. A shovel with worn teeth suffers from increased digging forces, longer fill times, and an increased likelihood of lost or broken teeth and adapters. Efficient maintenance planning relies on knowledge of tooth decay rates and patterns. A fully automated wear monitoring system can record detailed logs of tooth wear, permitting G.E.T. personnel to optimize maintenance scheduling. Studies have demonstrated that planned tooth change-outs result in significantly reduced costs as compared to unplanned maintenance. A machine-vision-based tooth-wear monitoring method is introduced. A rugged camera is installed on the boom of cable shovels, or on the stick of hydraulic shovels. The images are processed using a photogrammetric algorithm to determine the individual tooth lengths. Tooth length data is collected at intervals during shovel operations, forming a profile of the current wear state, speed of decay, wear pattern, and expected lifespan of teeth. A case study in a South American mine on a Komatsu PC8000 hydraulic front shovel is presented. Tooth wear is tracked over a 6-day period and wear rate statistics are computed for 6 teeth. This validates the system and provides an example of how wear patterns can be recorded and analysed by an automatic system. Armed with this data, mine personnel can reduce the cost and lost time due to unplanned maintenance, and observe the effects of mine conditions and operator behaviour on tooth wear.

May 1, 2011

By T. R. Eger

Miners can be exposed to whole-body vibration (WBV), when sitting or standing to operate mobile equipment. In order to prevent vibration-induced injury it is important to understand how miners can be exposed to vibration, the health risks associated with vibration exposure, methods to evaluate vibration exposure, and strategies to reduce vibration exposure. WBV exposure typically occurs when operating mobile equipment, such as a load-haul-dump vehicle, haulage truck, or dozer. The probability of health effects such as low back pain, neck pain, headaches, and gastrointestinal track problems occurring from daily vibration exposure can be determined based on criterion values published in ISO 2631-1 and EU Directive 2002/44/EC. A special case of WBV termed foot-transmitted vibration (FTV) occurs when a miner is exposed to vibration that travels through the feet. FTV typically occurs when standing on vibrating surfaces associated with the operation of locomotives, jumbo drills, bolters, or raise platforms; however, there is no set standard to evaluate health effects associated with FTV. Recent medical evidence confirms workers exposed to FTV can develop cold induced blanching of the toes, in addition to numbness and tingling in the feet and toes. In order to reduce the risk of adverse health effects from exposure to vibration, the hierarchy of controls (elimination; substitution; engineering; administration; and personal protective equipment) should be followed. Best practices should be used to minimize vibration exposure through equipment purchases (i.e. vehicles with lower vibration emissions and seats that attenuate vibration), reduced driving speeds, and improved road maintenance for example. The elimination of other risk factors, which increase injury risk when combined with WBV exposure, such as awkward working postures, should also be eliminated. Very little is known about FTV exposure therefore further research is required in order to develop exposure standards and identify prevention strategies.

Aug 1, 2013

By Nirmal Weerasekara, Lian X. Liu, The University of Queensland, Weiguo Xie, Benjamin Bonfils, Ping Yu

A mill model structure based on the population mass balance framework incorporating breakage characteristics, slurry and solids transport, product classification and discharge and energy consumption was reported in XXVII IMPC and named the Generic Tumbling Mill Model Structure Version I (GTMMS I). In this work, a new 4D (four dimensional) appearance function sub-model based on the experimental results of the JK Rotary Breakage Tester (JK RBT) was developed to describe the breakage characteristics and was applied to this new model structure. The newly developed 4D appearance function model has fewer fitting parameters and is more generic in nature. Most importantly, it is applicable to both high and low energy impact breakage. It is therefore much more versatile in comparison to the existing JKMRC t10- tn appearance function and the size-dependent JK M-p-q t10-tn appearance function. In addition, the Discrete Element Method (DEM) energy distribution model was integrated into the new model structure. With DEM results providing energy distribution information inside the mill directly, the selection function and the back-calculation method used in the existing JKSimMet modelling method are not needed in this model structure. With the above two revolutionary innovations, the previous model structure was upgraded to the Generic Tumbling Mill Model Structure Version II (GTMMS II). Furthermore, the new model structure is dynamic in nature with time-stepping technique for non-steady-state simulation. A case of the dynamic grinding of a SAG mill was studied to validate the GTMMS II. The model simulation results agreed well with the plant data. With the newly developed 4D appearance function model, the incorporation of DEM energy distribution and transport function, the GTMMS II is an important step forward towards mechanistic modelling of tumbling mills.

Jan 1, 2016

By B. R. List, E. R. F. Lord

The Syncrude open pit mine, located near Fort McMurray in northeastern Alberta, produces approximately 410 000 tonnes of oil sand feed daily, which, after undergoing a bitumen extraction phase, generates approximately 315000 tonnes of tailings solids daily. The tailings are used to hydraulically construct containment dykes and supporting beaches of the storage facilities. Tailings deposition commenced in May 1978 with the commissioning of the Mildred Lake Settling Basin which is currently composed of approximately 600M m3of solid sand approximately 300M m3of contained fluids with fine tailings in suspension for consolidation. Two other storage facilities, commissioned over the past six years, have been developed to store sand and consolidated fine tailings referred to as mature fine tailings. Fine tailings reduction initiatives being developed will be successful in reducing future production of fine tailings volume by 20%. These initiatives include spiking (addition of fine tailings to coarse tailings lines for deposition), composite tailings (addition of gypsum to promote consolidation) and freeze/thaw dewatering, also to promote consolidation. The mandate of research efforts is to enhance tailings disposal and to develop economical and technically feasible reclamation initiatives. Final tailings landscapes will be geotechnically stable and ecologically productive to minimize or eliminate long-term liability. This technical paper will review the design philosophies of the current facilities and provide an overview of the areas of continuous improvement in the field of tailings management practices through the concerted research efforts and their implementation.

Jan 1, 1997

By J. Jin, J. D. Miller

"Bubble attachment at hydrophobic surfaces is of critical importance in the flotation recovery of mineral resources and fundamental experimental results have been reported in the literature describing the details of film thinning, rupture, and displacement. Now, for the first time, bubble attachment phenomena are examined using Molecular Dynamics Simulations (MDS). The simulation involves a nitrogen bubble containing 906 nitrogen molecules in a water phase with 74,000 water molecules at the hydrophobic molybdenite (001) surface. During the simulation period of 1 ns, film rupture occurs and the nitrogen bubble attaches to the molybdenite (001) surface, resulting in a contact angle of about 90o. In contrast, the film is stable at the hydrophilic quartz (001) surface and the bubble does not attach. Contact angles, determined from MD simulation after stabilization of the three phase line of contact, are reported and these results agree well with experimental and MDS sessile drop results. In this way, film stability and bubble attachment are described with respect to interfacial water structure for surfaces of different polarity. For example, the interfacial water molecules for the hydrophobic molybdenite (001) surface have relatively weak interactions with the surface when compared to the hydrophilic quartz (001) surface, as revealed bythe presence of a 3 A water exclusion zone at the molybdenite/water interface. INTRODUCTIONAttachment of air bubbles to mineral particles is of fundamental importance in understanding flotation separation phenomena. It is well known that attachment of an air bubble at a hydrophobic surface includes film thinning, film rupture, and film displacement (Somasundaran, 2006; Wilson, Adlard, Cooke, & Poole, 2000). Experimental techniques, such as high speed video, can catch the process of bubble attachment at a mineral surface (Drelich & Miller, 2012; Niecikowska, Krasowska, Ralston, & Malysa, 2012). However, molecular scale information to examine the phenomena has not yet been reported."

Jan 1, 2016

By C. T. Dzgoev, S. S. Gudkov, IRGIREDMET JSC, S. G. Schtoick, A. V. Yepiforov, S. V. Balikov, I. I. Yevtuschevich

The pressure oxidation (POX) and pyrometallurgical process comprises POX of gold containing sulfide and polymetallic lead-zinc concentrates prior to reduction smelting of POX products to generate a lead-silver-gold alloy. Refined lead and gold-silver alloys are then obtained using conventional processes. Zinc and other base metals are recovered from the POX solution. In the course of POX, zinc dissolves in the solution and lead concentrates in a solid residue in the form of sulfate compounds. Sulfur forms the major iron sulfates and jarosites. In order to dissolve sulfur and arsenic from solid residues to the solution, the slurry hot curing was carried out at the temperature of 95°C within 2 hours. After filtration of the slurry, zinc was recovered from the solution. The resulting cake was washed with water and subjected to hot alkaline treatment. After alkaline treatment, the cakes were blended with fluxes and subjected to reduction smelting to generate lead concentrate containing precious metals. This concentrate was refined to obtain refined lead and gold-silver alloy. After iron and arsenic were removed from POX solutions using sodium carbonate, zinc was precipitated as carbonate. After thickening and filtration, zinc precipitate was roasted to generate saleable zinc oxide. Using this process, the recoveries of values to saleable products were 97% Au and 95% Ag to the alloy, respectively, 91% Pb to refined lead and 5% Pb to lead and antimony alloy and 94% Zn to zinc concentrate. The features of the technology is that it has high recovery indices of precious and base metals to saleable products and can be used to process various polymetallic ore and technogenic raw materials.

Jan 1, 2016

By G. W. H. Norman

"During the past few years emphasis has been placed on the importance of major faults, fault zones, and associated structures in localizing ore deposition. This interest has developed partly through experience in mining camps in other parts of the world, and partly by the discovery of such structures associated with ore deposits in the Abitibi region, northwestern Quebec. The recognition of these structures has been brought about chiefly by detailed mapping that has been gradually extended along most of the southern gold belt of Quebec and across adjacent parts of Ontario. In the Chibougamau region of northern Abitibi, progress has been made in mapping major faults by using aeroplane photographs with a scale of about 1,000 feet to 1 inch for field mapping. These studies have shown that many large faults occur in the Abitibi region; also that there is a relationship, direct or indirect, between faults and mineral deposition. The faults are, however, of more than one type and age, and this should be clearly appreciated in any planned programme for prospecting this great region adequately.Geology of the Abitibi RegionGeneral GeologyFaults of more than one age and type occur in the Abitibi region. In order to appreciate some of the age relationships of the faults, a brief summary of the historical aspects and major structural features of the geology (fig. 1) is necessary. These historical aspects may be briefly summarized in chronological order as follows:(1) Accumulation of Archæan lavas and associated pyroclastic rocks, either alternating with, or essentially followed by, deposition of sedimentary rocks, and interrupted at least once by local and perhaps regional folding and erosion."

Jan 1, 1954

By P. R. A. Andrews

"Graphite is one of the most versatile of non-metallic minerals because of its diversified properties, for example: it is unctuous; it marks readily; burns slowly; is almost chemically inert; is flexible over a large temperature range; is a good conductor of heat and electricity; is hydrophobic; has a negative temperature coefficient of resistivity; has excellent weathering properties; tends to emulsify with water-in-oil; is readily soluble in iron; and after oxidative treatment, can exfoliate like vermiculite. These properties give rise to its major uses in lubrication, refractories, marking instruments, electrical products and paints.Flake graphite is the variety which commonly occurs in Canada; the provinces of Ontario and Quebec contain the deposits of economic significance, although graphite occurs in other provinces. The beneficiation of graphite has been the subject of many investigations at CANMET, thus reflecting graphite 's importance as an industrial mineral. Thirty-eight studies relating to various aspects of beneficiation were conducted between 1918and 1989anda review of some of the more important studies is presented. The information includes mineralogy, beneficiation methods and results; flotation parameters and reagent concentration data are presented in tabular form. By so arranging the principal data, the research worker and production metallurgist will be assisted in the evaluation of graphite ores from a variety of origins."

Jan 1, 1992

By Alf Hartling

"Most of the Paleozoic section of the Williston Basin is a thick accumulation of numerous carbonate to evaporite, shallowing upward, cyclic sequences. These sediments were deposited in broad epeiric seas, and the deposition of the evaporite facies marked the final stage of each cycle. Many of the sequences display a pervasive replacement dolomite in the uppermost portion of the carbonate units. This secondary dolomitization is, at least in part, an early diagenetic event, synchronous with evaporite deposition.The inception of evaporite precipitation resulted in the seepage of a dense, Mg-rich brine into the underlying sediment. The heavy brine moved down the gentle regional dip displacing the more normal marine interstitial pore fluid and dotomitized the primary calcitic sediments en route. The supply of Mg-ions decreased away from the source, and correspondingly, the degree of dolomitization decreased and larger crystals formed because of slower nucleation at fewer sites.The seepage refluxion of dolomitizing brines gave rise to the frequently observed textural variation of cryptocrys talline, impervious dolomite grading into a finely sucrosic, permeable dolomite down-dip. This diagenetic facies change provides the critical up-dip barrier for potential hydrocarbon reservoirs. The lateral pool boundaries are controlled by either structural relief or a similar diagenetic facies change. The reservoirs are capped by the tight evaporites.Hydrocarbon production is attained from diagenetic traps in the Mississippian Oungre Zone and the Ordovician Red River 'C' Zone . Reservoir creation and the pooling mechanism are the result of dolomitization by the seepage refluxion of dense, Mg-rich brines beneath restricted, hypersaline lagoons. When formulating an exploration/ exploitation program for these oil prone horizons, it is essential to understand the complete geological history in order to establish where the reservoirs will be found and to define the areal extent of each accumulation."

Jan 1, 1984

By P. A. Gonzalez Contreras

Scorodite is considered as a secondary mineral formed from the product of weathering of primary minerals by chemical or biological reactions. In the case of biological scorodite formation, microorganisms mimic and accelerate what in nature takes a very long time, i.e. biocrystallisation. The goal of the biological scorodite formation is to form very stable arsenic crystals suitable for long-term and safe disposal. The biological formation of scorodite is a novel combination of biological oxidation, biocrystallisation, and proper bioreactor design to achieve the biological formation of scorodite crystals in one step. We have explored simultaneous biological arsenic and iron oxidation at 30ºC and at 70ºC leading to arsenic-jarosite phases and scorodite, respectively. As biologically formed scorodite crystals are very stable (TCLP < 1 mg/L As (V)), the risk of arsenic toxicity is minimized when leaching takes place. This process is suitable for arsenic concentrations above 0.5 g/l As achieving up to 20 mg/l As in the effluent. This biological scorodite formation system is a selfsufficient bio-oxidation system and therefore many new applications can be explored such as reprocessing of arsenic trioxide, orpiment or calcium arsenate to scorodite crystals for a stable and safe disposal.

Jan 1, 2014

By G. M. Ritcey, A. W. Ashbrook

"This paper summarizes the optimum leach conditions for each Of several cobalt-containing arsenical feed materials, describes the solution treatment prior to purification of cobalt recovery, and discusses the plant operation on one feed as well as the treatment of effluents.IntroductionDuring the period 1962-1964, when the demand for uranium was low, Eldorado Mining and Refining Limited (Eldorado Nuclear Limited) made a decision to undertake a three-year diversification program. One area chosen in this program was that concerned with the processing of cobalt-nickel materials. Many such materials were evaluated over the three-year period, ranging from tailings, residues, ores, concentrates and speiss to metal scrap. Cobalt feed materials, on which much of the effort was concentrated, were those containing arsenic together with other metals such as silver, copper, nickel and iron. This paper describes the treatment of arsenic-bearing feed materials (ranging from 0.3 to 570/0 As) and the subsequent purification stages required before the separation and recovery of high-purity cobalt. Because of the current interest in treating cobalt ores, it seemed appropriate that the information on the treatment of various cobalt feeds should now be made available . Although a large amount of data were generated during the research and process development program, a complete scientific correlation and understanding could not be achieved. Nevertheless, the data may provide a guide to others involved in processing not only cobalt, but other arsenical ores."

Jan 1, 1981