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By G. R. Webber, L. M. Azzaria

"The wide interest in the application of the geochemistry of mercury to mineral exploration is leading to the continued development of a variety of analytical methods for the determination of nanogram quantities of this element. The various methods have different degrees of reliability, sophistication and portability. In this investigation, two simple portable instruments were used in geochemical prospecting surveys -an ultra-violet absorption instrument and a similar one modified with gold for the removal of interfering substances. The results show the application of the method to the determination of mercury in soils of different organic content, and in rocks, sulphides and air."

Jan 1, 1969

By Abu Syed H. Kabir, Mehdi Sanjari, Steve Yue, Jing Su, In-ho Jung

AZ31 magnesium alloy sheets were produced by high speed rolling (HSR) at 1000 m/min at a low temperature of 100 ?. A high reduction of 72% can be achieved in single pass. At the reduction of 30%, the microstructure was covered by shear bands and twins. When the reduction was increased to 49%, dynamic recrystallization (DRX) was clearly observed in the vicinity of shear bands and twins and the full recrystallization was seen at a reduction of 72%. In order to study the static recrystallization (SRX) behavior on the heavily twinned structure, annealing was then carried out at 200 ? on the as-rolled specimens at the reduction of 30% for different times. Static recrystallized grains were also firstly observed on shear bands and twins after 45 s and the microstructure was mostly fully recrystallized after 1 h annealing with a few retained large elongated un-recrystallized grains. Texture weakening was found during annealing on the heavily twinned specimens by SRX, but not during high speed rolling by DRX. In the present study, effect of DRX and SRX on microstructure and texture evolutions during rolling and annealing were compared.

Jan 1, 2015

By D. J. Zuliani

A mass and energy balance for a modern electric arc furnace ("EAF") indicates that about 70% of the process energy losses are contained in the off-gas as chemical energy in the form of uncombusted CO and H2 and as thermal energy. Given the magnitude of the off-gas energy losses, improved EAF energy efficiency needs to focus first on controlling furnace practice to maximize "in-EAF" energy utilization and second, on recovering residual energy in the off-gas existing in the fume system. This paper focuses on the application of off-gas analyzers, sensors and process models to control and optimize "in-EAF" energy utilization efficiency. The paper will also discuss the application of heat recovery technology to EAF steelmaking.

Jan 1, 2015

By J. R. Parga T., P. J. Valenzuela G., L. S. Quiroz C., P. Guerrero G., J. L. Valenzuela G.

"Pressure oxidation is a hydrometallurgical pre-treatment process used for refractory auriferous sulfide ores. In the work reported here, a refractory pyrite ore sample from the Mulatos mine, Sonora, Mexico was characterized. The sample was subjected to atmospheric cyanidation, and simultaneous pressure oxidation and cyanidation under different conditions of temperature and pressure. The mineral characterization showed that pyrite is the main species in the sample. The gold extraction tests were carried out in an 1-litre Parr pressure vessel at a temperature range of 90-120 °C, a pressure range of 87.5–150 psi (using oxygen), and a cyanide concentration range of 0.8-1.2 %wt. The gold extraction results showed that diffusion through product layer is the rate controlling step.INTRODUCTIONIn hydrometallurgical precious metals extraction, the most commonly used process is sodium cyanide leaching, as shown in the next reactions involving gold and silver (Fleming, 1992; Marsden & House, 2006):4Au(s) + 8CN- (aq) + 2H2O(l) + O2(g) ? 4Au(CN)2 -(aq) + 4OH- (aq) (1)4Ag(s) + 8CN- (aq) + 2H2O(l) + O2(g) ? 4Ag(CN)2 (aq) + 4OH- (aq) (2)“Refractory” auriferous ores or concentrates often contain gold and silver locked inside other sulfide phases such as pyrite. This renders cyanidation ineffective, so oxidative pre-treatments are used in order to convert the sulfide minerals into porous oxide minerals and make cyanidation work more efficiently. Reaction (3) shows the oxidation of pyrite in alkaline media and the formation of the porous oxide (Koslides & Ciminelli, 1992):2FeS2 (s) + 15/2 O2 (g) + 8H- (aq) ? Fe2O3 (s) + 4SO4 2- (aq) +4H2O(l) (3)A process of simultaneous chemical pressure oxidation and cyanide leaching for a flotation concentrate produced in the mine of Bacís, Durango, in Mexico, gave good results (Parga et al., 2007). In the study presented here, it was intended to use this treatment for a refractory pyrite mineral from the Mulatos mine in Sahuaripa, Sonora, Mexico, modifying variables such as pressure, temperature and cyanide concentration to find the best conditions for oxidation and leaching."

Jan 1, 2012

By T. Crivits

"Freeze lining technologies are used industrially to protect the integrity of furnace walls in pyrometallurgical reactors. This is achieved by solidifying a protective layer of slag on the inner furnace wall. In the current study, laboratory experiments have been undertaken to produce freeze linings in ‘Cu2232 O’-‘FeO’-MgO-SiO slags under controlled conditions using an air-cooled probe technique. Whilst most thermal models of freeze linings have assumed the freeze lining-bath interface to be at the liquidus temperature of the bulk bath and to be planar in geometry, the current research has demonstrated that this is not the case. Experiments undertaken using this high-temperature slag system have shown the interface at steady state conditions to be at subliquidus temperatures. The solid phases present at the interface do not include the primary phase and the interface is non-planar. The study indicates the need for improved understanding of the fundamentals of freeze lining formation, and of the influence of system properties and process parameters"

Jan 1, 2015

By E. Wolmarans

The selection of the main mineralised zone (MMZ) concentrator milling circuit has followed a comprehensive route over the preceding 10 years. Many knowledgeable parties have contributed and assisted in developing the milling circuit according to the best available information. The final selection of the flow sheet was completed after DRA conducted a techno-economic study on four possible comminution circuits ranging from conventional crushing and ball milling to fully autogenous (AG) milling. The results from all the above mentioned work indicated that it is possible to treat the MMZ ore at the desired throughputs to the desired grind sizes in a fully autogenous grinding circuit. The flow sheet was designed to treat the main mineralised zone (MMZ) arising?s from both underground and open cast operations and incorporates a fully autogenous grinding (AG) circuit. Commissioning of the 375ktpm concentrator at Nkomati Nickel began in August 2009 with the first ore reporting to the mill on the 15th of September 2009.

Jan 1, 2012

By R. J. Chase, C. Davies

"Abstract- The Merelani graphite-tanzanite deposit is located in northeast Tanzania, 14 kilometers south of Kilirnajaro International Airport and in close proximity to the towns of Moshi and Arusha . The graphite mineralization is hosted by relatively undeformed linear Proterowic metasedimentary gneisses, several of which have been subjected to hydrothermal alteration resulting in tanzanite mineralization. Exploration work comprised detailed geological mapping coupled with pit and trench channel sampling and a subsequent 1500 meters of diamond drilling. In addition, metallurgical tests have shown the graphite to be of unusually coarse flake size, crystallinity and high purity.Feasibility studies have shown the economic viability of a major coarse flake graphite deposit with the measured resource to 50 meters in excess of 9 million tonnes assaying over 8o/o graphitic carbon . Production is due to start by the end of the first quarter of 1994 with the processing plant design capacity initially set at 15 000 tonnes per annum.ln addition to graphite production, tanzanite will be produced through selective mining within the graphite open pit in the upper horizon and from underground workings within the lower horizon.The Merelani graphite-tanzanite deposit will be the first major orebody to be exploited through means of private funding since Tanzania gained independence."

Jan 1, 1994

By D. E. Macdonald

"Approximately 2.0 million tonnes of phosphate rock is imported from the U.S. to Alberta annually and is used in the production of agricultural fertilizers. No phosphate rock is presently mined in Canada, although sources of igneous phosphate have been mined in the past. Sedimentary phosphate rock is found in nine geological units within the Cordilleran Foothills and Front Ranges region of Alberta. The Devonian-Mississippian Exshaw Formation, Permo-Pennsylvanian Rocky Mountain Supergroup, and the Jurassic Fernie Formation have the best potential f or future development. Most of the phosphate rock in Alberta is of low grade and lies within restricted land use areas. The best over-all resource potential lies in the Fernie basin area of southeastern British Columbia, in the Fernie Formation. The possibility of deep phosphate rock deposits in the plains region should be examined.Phosphate rock is mined in Idaho, Utah, Montana and Florida, and is shipped to Canadian fertilizer plants for processing. Raw phosphate rock is acidified, usually with sulphuric acid, by a wet process. Varying amounts of ammonia are added, and the fertilizer is pelletized. Future research, in western Canada, is needed in the beneficiating of low-grade ores and in the area of in situ mining. At the present time, phosphate rock sells for around US$50Itonne, and Alberta fertilizer companies probably pay in the range of C$7D-$85Itonne for U.S. phosphate rock delivered to the plant. Environmental concerns about phosphate rock processing are centred around gypsum tailing ponds, and radioactive wastes.U.S. supplies of phosphate rock are secure until the year 2000; however, by this time, the richer deposits in the U.S. may be exhausted. Alternate deposits, such as the ones in Alberta and British Columbia, might then be considered. Phosphate byproducts, such as uranium, vanadium, fluorine and rare earth elements, may help in making the processing of low-grade Canadian phosphates economically feasible."

Jan 1, 1988

By W. M. Tupper

Municipal governments recognize the importance of aggregates in the local economy and the need to manage this resource in the interest of the public good. They have encountered problems with regulating the industry and the dichotomy between the urban need and the rural source. They have suffered from a lack of financial benefit, an adequate aggregate inventory, provincial strategy, economic information and public understanding. A provincial strategy for ensuring the availability of aggregate supplies to developing areas of the Province is essential. The Province should also be responsible for licensing, research, technical expertise on rehabilitation, public education and financial assistance. Upper-tier municipalities (regions or counties) should assume responsibility for resource management, including resource availability, demand characteristics, truck routing, phasing of resource development and sequential land-use planning. Area municipalities (towns and townships) can best determine the social and environmental impact of a specific aggregate development proposal and should therefore have the primary responsibility for the location of new pits and quarries. They should also have the authority to supplement provincial regulations concerning operating standards and the phasing and standards of site rehabilitation.

Jan 1, 1978

By Therese Schneck

The presence of xenon isotopes from in-situ spontaneous fission of short-lived Pu244 has been confirmed in Hadean detrital zircons from Western Australia. Hadean and meteoritic zircons can retain secondary overgrowths developed after primary cristalization at 3.97-3.94 Gyr. On the moon, the metal grain in sample 66095,78 is mantled by troilite, schreibersite and cohenite. High chlorine content FeCl2 is deposited around metallic FeNi. The magnitude of Pollonium-210 to Radon-222 on the Aristarchus plateau spectrum indicates a past greater activity. The Earth Moon system from Nb/Ta systematics is consistent with a Moon iron core delayed to 3,9 Gyr.

Aug 1, 2010

By Tanai Marin

Modelling of pyrometallurgical processes can become extremely challenging when the process involves complex chemical reactions, phase change, multiphase flows, heat and mass transfer and fluid flow. Traditionally modelling involving complex thermodynamic equilibrium and thermochemistry are treated separately from problems in which transport phenomena are dominant, such as CFD and heat transfer studies. The separation is also necessary due to the lack of modelling tools that can effectively couple both solution thermodynamic and transport phenomena or even multiphysics problems. However, there are, quite often, problems in high temperature process metallurgy in which it is not possible to simplify this two modelling approaches. Typical cases of this are for example, the modelling of slag freezing on furnace walls (electric or flash furnaces) to create a protective layer in front of the refractories hot wall, the formation of build up from the matte or metal phases at the hearth of the furnace, calcine smelting from charging piles into slag phase, etc. The problem is even more challenging in nonferrous pyrometallurgy as most, if not all, of the condense phases are highly non ideal solutions involving several components and exhibiting complex crystallization paths and miscibility gaps, such as the Fe-Ni-Cu-S matte, FeO-Fe2O3-SiO2, FeO-MgO-SiO2 slags, etc. In this paper, an approach to model coupled problems involving multiphysics and solution thermodynamic is presented. The approach consists in developing in-house a library containing the Gibbs energy minimization routines and using the local equilibrium concept for process modelling from a multiphysics commercial software (COMSOL). Simple test cases, such as building a non-ideal binary phase diagram on a CFD package is presented, the limitations and of other classic approaches such as equilibrium or Scheil cooling are discussed and compared to this model.

Jan 1, 2015

By Atul Bhatnagar, M. P. Sinha, Md Zahid Ahmad, Pallav Garg, Sanjay Kumar Singh, Shashi Ranjan, An Ecolab Company Nalco Water

"Froth Flotation is undoubtedly one of the most critical processes in coking coal washing plants. This work was carried out at Bhelatand Coal Preparation Plant of Tata Steel was with an objective of cost optimization in fine coal processing. The sources of raw coal for the plant include coal from underground mines of Jharia coalfield and procured open-cast raw coal. Coal from different sources vary in quality and possess different floatability characteristics.Synthetic collector is being used in plant as a flotation reagent. An alternate collector with new chemistry was developed for reducing total treatment cost without compromising product yield and quality. A series of laboratory tests were conducted to assess the performance of various sources of raw coal and plant scale trial was started. At first, the new generation coal collector was entirely substituted with the existing collector in the laboratory scale. However the plant scale trial data was not in accordance with laboratory results and indicated inferior flotation performanceThe issue was studied and data based conclusions were drawn that the new generation collector aids faster and uncontrollable kinetics. A decision was taken for co-dosing of the synthetic and new collector for the second phase of the trial. A detailed laboratory analysis was done again and few dosing ratios that predicted optimum results were selected for plant trial. The dosing ratio was optimised as per flotation yield and product ashes during the plant trial. The results showed significant improvement from the first phase and optimum dosing rates were decided based on plant observations and data collection. The influence of various process indicators including water quality, feed and product ashes and process yield was studied during all the trials and promising results were established. The co-dosing of both the collectors conferred cost advantage and enabled to achieve superior performance."

Jan 1, 2016

By M. L. Trépanier

"Engineering and technical services are supplied by the Engineering Department, located at Thetford Mines, Quebec, approximately 60 miles southwest of Quebec City. The department serves the three operating mines in the Thetford area, the Asbestos Hill mine at Putuniq, Nouveau Quebec, and the Nordenham plant at Nordenham, West Germany. The Engineering Department is responsible for supplying the following services. 1. Administration and coordination of capital projects. 2. Engineering, design and drafting services for in-plant changes or improvements. 3. Preparation of geological plans for mine planning and ore reserves determinations. 4. Short-, medium- and long-term mining plans. 5. Rock mechanics studies and monitoring. 6. Grade control monitoring. 7. Environmental control engineering and construction. Details of the organization and services rendered will be the basis of the paper."

Jan 1, 1976

By J. A. C. Fortescue

During the past decade, geochemical prospecting methods have become important in Canadian mineral exploration. The object of this paper is to discuss the role of geochemical methods in a typical mineral exploration program involving parallel geological and geophysical methods applied at different degrees of intensity. Particular attention is given to the description of the degree of development of geochemical prospecting under different kinds of local conditions.

Jan 1, 1967

By Fazel G. Jahromi, Ahmad Ghahremaninezhad

Enargite (Cu3AsS4) is a major complex copper mineral and often is a carrier of invisible gold particles. Pyrometallurgical treatment of enargite is challenging due to the arsenic release to the environment. Hydrometallurgical treatment, on the other hand, appears to be a promising alternative for enargite processing. In an atmospheric enargite leaching process both the copper and arsenic from the mineral can be leached into a sulphuric acid solution and the arsenic can be simultaneously precipitated as ferric arsenate. The unlocked gold in the residue then can be recovered in a subsequent cyanidation circuit. The downside of the atmospheric enargite leaching in sulphate solutions is the slow leaching kinetics. In this study the effective parameters of the atmospheric enargite leaching process in ferric chloride media were investigated. All the experiments were carried out at temperatures below 100 °C. The process parameters that were investigated in this study included ferric, chloride, sulphate and cuprous concentrations, temperature, mixing rate and leaching slurry pulp density. It was found that the copper recovery rate increases with the addition of cupric chloride and also with raising the temperature. The highest leaching kinetics and the highest overall copper recoveries were achieved when cupric was initially added to the leach solution and at 90 ºC.

Jan 1, 2015

By L. D. van Dyk, G. S. Tshofu

Iron ore fines are by-products of iron ore mining operations. Unlike iron ore lumps, fines cannot directly be used in conventional iron making processes, and consequently large quantities accumulate around the world. Pelletizing and sintering can be used to convert iron ore fines into agglomerates or briquettes for processing with lump ore, but these techniques are energy intensive and produce greenhouse gases. This research investigated the extraction of iron from iron ore fines using acetylacetone (a ß-diketone) as an environmentally friendly alternative process for fines utilization. A 2k factorial experiment design was used to identify the significant extraction variables. It was found that the reaction temperature and solid to liquid ratio had significant effects on the extraction process. The extraction kinetics were studied at different temperatures and the highest iron extraction (97 %) was obtained after 48 hours at 413 K and 0.025:1 (g:mL) solid to liquid ratio for a particle size range of +106 to -150 µm. The extraction products were easily separated from the unreacted acetylacetone by flash distillation and iron(III) acetylacetonate crystals were recovered. An economic evaluation showed that selling the crystals was profitable. Alternatively, the crystals can be reduced with hydrogen to iron particles and acetylacetone (for reuse).

Jan 1, 2015

By W. F. Giuvlore, E. Mcroberts, T. S. Golosinski

"The rising demand for Canadian coal and depletion of shallow deposits, most suitable for surface mining, result in rapidly increasing volume of waste materials which have to be moved by the coal mining industry. While at present this challenge is being successfully met using conventional mining methods, in the future, innovative methods must be considered if Canadian coal is to remain competitive.The need for more efficient mining methods is also faced by the oil sands industry to assure competitiveness of the synthetic oil price.A look at the world mining practice indicates that large volumes of material can be economically mined and moved by the continuous mining systems comprising bucket-wheel excavators, belt conveyors and stackers. To assess the state of art and applicability of this mining method to Canadian conditions, the field trip was organized by the Department of Mining Engineering o f the University of Alberta, to several typical mining operations in Europe. It is in Europe where the continuous mining methods were developed and are almost exclusively used in large-scale surface mining."

Jan 1, 1984

By J. C. Heaslip

Introduction The greatest single advance in rock drilling practice since the advent of percussion drills was the introduction of tungsten carbide tipped rock drill?bits. The evolution of rock drills has been a long and highly diversified effort which has culminated in the highly refined ?drilling machines we know today, but because of the spectacular possibilities shown by ?detachable bits, and especially those with tungsten carbide inserts, there is little doubt that the cutting face of .the drilling unit has in recent days stolen the spotlight of rock drilling research and commanded the major attention of the rock drilling fraternity. "Solid" Steels Until about twenty years ago, all rock was drilled with a one-piece rod with a bit forged on one end. In the early years of the art of rock drilling, there was tried every conceivable pattern of :bit from the single-edge chisel to elaborate geometric 'designs. In the end, it was found that a 4-point bit with two sharpened cutting edges crossing each other at right angles would serve best for most rock drilling requirements. For some years thereafter, the main concern of drill manufacturers was .to obtain the best possible steel for drill rods. This was not accomplished as easily as might be thought. The cutting end had to be such that it could be hardened sufficiently to do its work without premature dulling and yet not so brittle as to shatter under the multiple impacts.

Jan 1, 1951

By D. V. Ziehlke, J. M. Franklin, T. M. Gordon, A. G. Galley

The Snow Lake-Wekusko Lake region of northern Manitoba conta ins numerous lode gold occurrences, including the largest gold deposit in the Churchill Prov ince, the Nor Acme mine. The Aphebian volcanic and sedimentary rocks of this region are comprised of submarine volcanic strata, overlain by turbidites, both of the Amisk Group, and fluvi atile sedimenta ry strata and bimodally composed subaerial volcanic rocks of the overlying Missi Group. Gold occurs as: 1) accessory gold in volcanogenic massive sulphide deposits, 2) lode gold in shear zones related to sy n- to post-FI thrust fa ults, and 3) lode-gold associated with post-F2 fault . An alteration a emblage of biotite, al bite and calc ite is associated with both groups of lode-gold deposits, and has been superimposed on the regionall y-developed metamorphic assemblages. AJthough these deposi ts are spatial ly related to britt le-ductile faul ts of different initial ages, they appear to have all fo rmed after the major period of reg ional fo lding and metamorphism, and thus may be penecontemporaneous. The alteration is different from the sericite-ankerite-quartz assemblage that is typically associated with gold deposits in Superio r Prov ince. Deposits in thi s area of Churchill Prov ince may have formed either at a higher temperature or a deeper structu ra l level than tho e in Superior Prov ince.

Jan 1, 1986

By D. Holz

In this work we present a novel level set-based model for the real-time simulation of soil deformations. A level set defined by a signed distance function and sampled in a regular 3D grid represents and tracks the soil volume under deformation. Moving away from classical 2.5D heightfield representations of soil to a full 3D volume representation allows for improved tracking of cutting tool operations and the simulation of near-vertical or vertical soil faces. The proposed level set representation furthermore provides a versatile mathematical platform for modeling additional effects such as soil slip, and does not suffer from the sampling limitations of commonly used heightfields. Cutting forces applied to the tool are simulated via a formulation based on the Fundamental Equation of Earthmoving, modified to support inclined soil surfaces and transient states of tool motion. Discretisation of this 2D cutting force model with respect to the tool surface allows capturing the effects of irregular 3D terrain shapes on blades and buckets. The surcharge created during cutting operations is tracked in the form of particles and included in the soil failure force computation. We make use of an adaptive, hybrid level set-based and particle-based soil deformation scheme, which allows the soil deformation to be simulated in real-time.

Aug 1, 2013