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By Tugba Cebeci, Bahjat Khoshaba, Bern Klein, Libin Tong, Andrew Bamber

"Sensor-based sorting technologies have potential to pre-concentrate low grade subeconomic ores through discarding the barren waste particles. However, the inability of sensors to accurately discriminate ore from waste is a barrier to prevent their wide applications. The present study focuses on the development of more intelligent sensing systems by using correlation and regression analysis of X-ray fluorescence (XRF) sensor responses on the copper ore samples obtained from Chile. The responses obtained through XRF scanning were reported both in the form of counts and the grades of elements. Linear and multiple linear correlation analyses were made between the XRF counts and the copper grades obtained through chemical analysis. Both the heterogeneity of the ore particles and the matrix effect in the XRF measurement are discussed in the study.INTRODUCTIONSorting can not only discard waste rocks away from the concentrator but also recover metal bearing ore particles that would be lost to the waste dump. The benefits of ore sorting include reduced energy consumption, water and reagent usage in the downstream operations (Bamber, 2008; Gunson, Klein, Veiga, & Dunbar, 2012; Kleine & Wotruba, 2010; Knapp, Neubert, Schropp, & Wotruba, 2014; Kobzev, 2014; Lessard, de Bakker, & McHugh, 2014; Mazhary & Klein, 2015; Robben, Wotruba, Robben, von Ketelhodt, & Kowalzcyk, 2013). X-ray fluorescence belongs to sensor-based sorting technologies and Xrays are a high energy-high frequency form of electromagnetic radiation inhabiting the region between the ultraviolet radiation and gamma rays (Shackley, 2011). Recent XRF sorting studies on low grade copper ores were carried out at MineSense Technologies Ltd. aimed at increasing the capacity related to improving the understanding of ore heterogeneity as the basis for developing semi-bulk or bulk sorting systems (MineSense Technologies Ltd., 2016)."

Jan 1, 2016

By M. Maley, S. Burling, R. Ring

ABSTRACT The numerous global uranium deposits vary significantly in mineralogy, grade, and textural characteristics; therefore, information from traditional (or conventional) sources on the fundamentals of leaching uranium and gangue minerals is not always applicable when studying particular ores. Empirical studies can be effective in understanding leach systems and can lead to improvements in process design but there remains a lack of fundamental understanding necessary for ongoing process optimization as ore bodies continue to vary. ANSTO Minerals has undertaken a work program to address several fundamental questions about uranium leaching, including the unexpected impact for some ore types of leaching at high oxidation potential.

Jan 1, 2012

By A. J. Makoka, B. C. Qi

Reliable monitoring of corrosion is vitally important in the combat against corrosion and over the last two decades the interpretation of electrochemical noise has received considerable attention as a means to discriminate between different types of corrosion. To this end, many different analytical methods have been proposed, such as power spectral density analysis and analysis via various other stochastic criteria. However, although many corrosion systems are nonlinear and therefore not readily interpretable by the abovementioned analytical approaches, few studies in the analysis of electrochemical noise to date have exploited advances made in the analysis of nonlinear systems. In this paper, the use of phase space methods to analyze and detect change in corrosion systems via electrochemical noise is considered. In particular, the electrochemical noise data are used to reconstruct trajectories in the so-called phase space of the system and changes in the topology of these trajectories or attractors as represented by correlation dimension curves are consequently interpreted as an indication of change in the dynamics of the system.

Jan 1, 2005

By B. Tonn, F. Kröger

"The continued development in engine technology is leading to an augmentation in power density which steadily elevates the requirements for thermally and thermo-mechanically highly loaded components such as cylinder heads and pistons. Due to these high performance requirements conventionally applied Al-Si alloys have reached their application limits, since their mechanical properties deteriorate quickly under the influence of heat. Improved applicability is given by Al-Cu-based casting alloys which have a superior high-temperature strength than Al-Si alloys. Since Al-Cu alloys exhibit insufficient casting characteristics, especially regarding hot tearing susceptibility and increased tendency for porosity, it is currently not possible to cast geometrically complex components in robust permanent mold casting processes. The further development of Al-Cu alloys is aimed at finding an optimum between improved castability while high-temperature strength and thermal conductivity are not deteriorated. It is known that a high amount of eutectic reduces the hot tearing susceptibility of an alloy, but it reduces thermal conductivity at the same time. In this paper it will be presented how the conflicting objectives – improved high-temperature strength, good thermal conductivity and reduced hot tearing susceptibility – can be brought together to develop an optimized Al-Cu alloy for application in permanent mold casting.INTRODUCTION At the beginning of the 21st century car, engine blocks were primarily made of gray cast iron (GJL). Less than half a decade later, the choice of material had shifted towards lightweight materials. Ever since, the car engine manufacturing is dominated by aluminum-based alloys. The weight of car engine blocks could thus be reduced by around 50% due to the lower specific weight of aluminum alloys compared to gray cast iron. Furthermore, the high thermal conductivity of aluminum alloys allowed a reduction of complex cooling channel systems and thereby promoted the advancement of this material group. The further development in engine technology leads to an augmentation in power density which elevates the requirements for thermally and thermo-mechanically highly loaded components. For example, in diesel-powered car engines the upper required limits can reach an ignition pressure as high as 230 bar and gas temperatures of up to 1000°C. Thereby, thermal loads can cause high alternating thermal stresses (Grzincic, 2003) which can effectively be reduced by providing high thermal conductivity."

Jan 1, 2017

By Davood Moradkhani, Maryam Rasouli

"The present study reports solvent extraction and separation of zinc from concentrated nickel sulfate solution. In our previous study, Zn and Cd in cold filter cake (CFC, 45-55% Zn, 11-16% Cd, and 2.5-4% Ni) were extracted by alkaline leaching followed by electrowinning processes respectively. The strip solution from electrowinning process, was a pregnant liquor solution (PLS) containing 16.8 g/l Ni and 4.2 g/l Zn. In this work, PLS is subjected to the solvent extraction process for separation of traces of Zn from high grade nickel. The zinc free raffinate containing 16.6 g/l Ni sulfate solution will flow to nickel electrowinning plant for cathode production. Di-(2-ethylhexyl) phosphoric acid (D2EHPA) is the organic phase used in this study. The effects of various parameters such as organic phase concentration (10- 40 % v/v), pH (1.5-3), and temperature (25 and 45°) are investigated. Zinc over nickel separation factor increases by increasing pH from1.5 to 3. The results show that 98.7% of Zn was loaded at25°C O/A ratio of 1, pH 3, and 10% vol. D2EHPA. A 10 M NaOH is used for pH control. However, replacement of pH controlling agent with ammonia solution (25%. v/v) results in interesting observations. Ammonia addition, reduces the solubility of Ni2+ cations in solution. Nickel starts to precipitate from raffinate in a crystalline bluish-green form. The obtained crystals are characterized by XRF and identified to be nickel-bearing analog of boussingaultite, a rare sulfate mineral of nickel with chemical formula of Ni (NH4)2(SO4)2.6H2O. The crystallization rate of crystals is studied. It is a slow precipitation process with 75% in 4 days.INTRODUCTION Annually, many hydrometallurgical processes such as electrowinning, solvent extraction and leaching are applied to waste filter cakes in Zanjan, Iran. These additional processes on filter cakes are critical from both environmental and economic points of view. CFC (cold filter cake) is a toxic but valuable filter cake (45-55% Zn, 11-16% Cd, 2.5-4% Ni, and 0.2-1.5% Cu) produced in many zinc production plants. Our research group at Research and Engineering Company for Non-ferrous Metals (ReCo.), developed a series of hydrometallurgical methods for extraction of zinc, cadmium and nickel from CFC (Moradkhani, & Rasouli 2012). The recovery of zinc and cadmium with alkaline leaching and electrowinning was successfully studied. The strip sulfate solution from cadmium electrowinning unit, contains high concentration of nickel with some traces of zinc impurity. This pregnant liquor solution (PLS) was analyzed and reported to contain 16.8 g/l Ni and 4.2 g/l Zn. In this work, PLS is subjected to the solvent extraction process to separate Zn from nickel (Fig. 1). The organic phase stripping solution containing 4.2 g/l zinc and 200 ppm nickel can be circulated and used in the acidic leaching step. This generates nickel solution with high purity suitable for nickel cathode production."

Jan 1, 2017

By S. M. Grillo, Fiori. M., R. Bornioli, C. Marini, S. Fadda

Abstract - The Na-feldspar orebodies in Sardinia occur along structures belonging to a regional ENE-WSW system that developed during the late stages of the Hercynian orogeny, and that was reactived during the Alpine orogeny. The main petrographic facies include granitoids, albitized granitoids, albitites (more or less rich in quartz), and albitites containing Mg minerals. Field observations and petrological and geochemical data point toward a metasomatic origin for the albitite orebodies. Albitization involved depletion of K from K-feldspar and biotite, dissolution of free quartz, and a lowering of Sr/Na2O and CaO/Na2O ratios in the protolith, under conditions of a positive thermal gradient. The absence of later K-metasomatism implies that, during a subsequent decline in temper- ature, the composition of the albitizing fluids was modified by an influx of meteoric or other waters.

Jan 1, 1996

By D. G. Osborne

"The paper describes current 'tools' available to the coal preparation engineer for carrying out the evaluation of data, process design, selection of equipment and layout and design of coal preparation plants.Laboratory and pilot-scale equipment is widely available and test data can be used to provide valuable design information regarding capacities and sizing for specific applications. Pilot plants, unless they fit closely to the basic design envisaged for the eventual commercial plant, C(In often provide only limited useful information.Computing aids such as equipment simulation, plant modelling, etc. are becoming widely applied for establishing design criteria and investigating flowsheet options . Other computer tools such as computer-aided design systems are taking over some of the time-consuming tasks of detailed layout and design and estimation of quantities, etc. and providing the means for detailed examination of more than a single option.Besides computer modelling there is also physical modelling of plant buildings, plant sites and entire proposed mining areas; the former can be especially useful in finalizing design and threading' pipework and electrical reticulation systems through the plant without the resultant risk of impairment of flow, obstruction or wastefulness. Not the least of the benefits of plant models is the assistance provided for training new operating and maintenance staff."

Jan 1, 1985

By S. M. Grillo, M. Fiori, R. Bornioli, C. Marini, S. Fadda

The Na-feldspar orebodies in Sardinia occur along structures belonging to a regional ENE-WSW system that developed during the late stages of the Hercynian orogeny, and that was reactived during the Alpine orogeny. The main petrographic facies include granitoids, albitized granitoids, albitites (more or less rich in quartz), and albitites containing Mg minerals. Field observations and petrological and geochemical data point toward a metasomatic origin for the albitite orebodies. Albitization involved depletion of K from K-feldspar and biotite, dissolution of free quartz, and a lowering of Sr/Na2O and CaO/Na2O ratios in the protolith, under conditions of a positive thermal gradient. The absence of later K-metasomatism implies that, during a subsequent decline in temperature, the composition of the albitizing fuids was modified by an influx of meteoric or other waters. Copyright © 1996 Canadian Institute of Mining, Metallurgy and Petroleum.

Jan 1, 1997

By J. A. Finch

In this paper, the author offers a personal view of what the next 30 years holds for mineral processing. Restating that mineral processing will remain a vibrant industry in raw material production, growth opportunities in waste management are identified. The processing sequence familiar now (mining ?mineral processing ?extraction) will become more interwoven. In situ processing (i.e., milling underground) will evolve from concept to demonstration. Opportunities to exploit physical properties altered in chemical (pyro- and hydro-) processing will present themselves. In primary grinding, the path to AG/SAG milling will progress with little deviation but opportunities in regrinding are wide open. Flotation will see the trend to designing bubble/particle reactors accelerate simultaneously with a vigorous response from mechanical cell suppliers. Gravity separation remains a bastion of the lone inventor but this author anticipates that the new lines will come from the waste management business. The paper concludes with the examination of the “research cycle” and identification of growth in small “high tech” companies and university research centres

Jan 1, 1998

By J. E. Nesset

"This paper discusses the importance of considering residence time distribution (RTD) in the design of flotation and mixing circuits and in the analysis of operating problems. The experiences and successes of Brunswick Mining in this area are covered and include: the development of a practical RTD measurement technique using pulp conductivity, baffle installation to improve the RTD of existing process equipment, and the method in which RTD considerations have been used to design the newest flotation and conditioning operations IntroductionThe use of residence time distributions (RTDs) in the design and analysis of unit operations is well understood by the chemical engineering profession in while mineral processing engineers have tended to rely on empirical and rule-of-thumb factors. For example, in scale up from laboratory and pilot test results to full size flotation plant design, empirical rule s are often used to establish residence time and number of cells in the bank. Coleman suggests a factor of at least 2, and up to 5 for gold ores, be applied to laboratory determined flotation times. This is further illustrated in Table I, taken from Denver equipment. The number of cells in series to achieve the required retention time while minimizing short-circuiting has generated a variety of conclusions (Table 2). Obviously there is less than complete agreement on the subject. Young notes that a clear difference of opinion has emerged and cites as extremes, (i) the publications of Outokumpum showing unimpaired recovery for its largest machines (38 m3) compared to equivalent retention times for numerous smaller machines, and (ii) the experiences of Eastern European countries where the practice is to install banks of 30 unit s or more, operating in series, often with unit retention times of only a fraction of a minute.The empirical factors used by engineers presumably account for other than tested feed conditions, inefficiencies in large continuous machines, inevitable day-to-day circuit disruptions, gradual equipment deterioration and any other safety factor the engineer feels compelled to incorporate. An understanding of RTD concepts and techniques should help the practicing mineral engineer to develop more soundly based factors. Thi s paper relates the experiences of Brunswick Mining in using RTD techniques in the unit operations of flot ation and mixing"

Jan 1, 1988

By J. E. Nesset

"This paper discusses the importance of considering residence time distribution (RTD) in the design of flotation and mixing circuits and in the analysis of operating problems. The experiences and successes of Brunswick Mining in this area are covered and include: the development of a practical RTD measurement technique using pulp conductivity, baffle installation to improve the RTD of existing process equipment, and the method in which RTD considerations have been used to design the newest flotation and conditioning operations. IntroductionThe use of residence time distributions (RTDs) in the design and analysis of unit operations is well understood by the chemical engineering profession in while mineral processing engineers have tended to rely on empirical and rule-of-thumb factors. For example, in scale up from laboratory and pilot test results to full size flotation plant design, empirical rule s are often used to establish residence time and number of cells in the bank. Coleman suggests a factor of at least 2, and up to 5 for gold ores, be applied to laboratory determined flotation times. This is further illustrated in Table I, taken from Denver equipment.The number of cells in series to achieve the required retention time while minimizing short-circuiting has generated a variety of conclusions (Table 2). Obviously there is less than complete agreement on the subject. Young notes that a clear difference of opinion has emerged and cites as extremes, (i) the publications of Outokumpum showing unimpaired recovery for its largest machines (38 m3) compared to equivalent retention times for numerous smaller machines, and (ii) the experiences of Eastern European countries where the practice is to install banks of 30 unit s or more, operating in series, often with unit retention times of only a fraction of a minute.The empirical factors used by engineers presumably account for other than tested feed conditions, inefficiencies in large continuous machines, inevitable day-to-day circuit disruptions, gradual equipment deterioration and any other safety factor the engineer feels compelled to incorporate. An understanding of RTD concepts and techniques should help the practicing mineral engineer to develop more soundly based factors. This paper relates the experiences of Brunswick Mining in using RTD techniques in the unit operations of flotation and mixing."

Jan 1, 1988

By James Logan

BC Alkaline CuBC Cu--Au PorphyriesAu Porphyries ?Formed over narrow time interval ~205 Ma ?from silica deficientvsalkali-enriched magmas ?At shallowdepths ?Structuralcontrol ?Cu-Au-Ag, trace Mo ?Oxidized system anhydrite, magnetite ?Multipleintrusions & multiplemineralized centres

May 1, 2006

By G. F. Warning

"THE H. B. Mine is situated on the north side of Sheep Creek valley, about six miles southeast of Salmo, B.C. It is the most northerly producer along a belt containing a number of zinc-lead deposits, including the Jersey mine of Canadian Exploration Limited, 3 miles to the south, and the Reeves MacDonald mine, 12 miles to the southwest. The important zinc-lead producing area around Metaline Falls, Washington, lies 23 miles to the south. Two prospectors, Horton and Benson, located and staked the oxidized outcrops in 1.907. The property was named the H.B. after the two discoverers. Exploration by a number of operators failed to locate any sulphide orebodies until 1946, when Cominco began a geological study followed by surface drilling which was successful in locating extensive sulphide mineralization. A program of underground exploration revealed sufficient ore to war-rant mill construction. A 1 ,000-ton mill was completed by 1953, but due to low metal prices production was deferred until May, 1955. To September 1, 1959, 1,900,000 tons of zinc-lead ore have been milled; present milling rate is about 1,250 tons per day. Concentrates are trucked to the Trail Smelter, a distance of 35 miles."

Jan 1, 1960

By K. Hasselwander, K. Knabel

"A significant area of Outotec’s business involves fluidized bed roasting. With several decades of experience, more than 300 reference plants and strong R&D capabilities, the company provides several industries with optimum processing solutions. Applications include oxidation and sulfation of sulfides found in copper, pyrite and zinc concentrates. Gold production and de-arsenifying roasting are also within this scope. This paper describes the latest furnace developments and includes novel trends. Moreover, hot and wet gas cleaning systems are examined focusing on unit operations related to the removal of components such as dust, SO2 for sulfuric acid production, fumes, halides, Hg, hydrocarbons, nitrous oxides and metals.INTRODUCTIONGenerally, when defining roasting processes, it can be stated that the respective primary pyrometallurgical reaction is exothermic, of gas-solid nature and relates to a value solid product. These processes are a key focus within Outotec’s scope and include: (i) dead roasting (ii) sulfating roasting (iii) partial de-arsenifying roasting and (iv) two-stage, de-arsenifying roasting.Dead roasting involves the oxidation of a given sulfide, thus allowing for a subsequent leaching process, and has been applied to producing ZnO. Dead roasting of pyrite has also been extensively utilized with a primary goal of producing sulfuric acid. In contrast, sulfating roasting involves converting a sulfide to its sulfate, enabling a selective sulfation of components, such as Cu or Co, and their separation from ferrous components during leaching (produced sulfates are soluble). Partial roasting involves partially oxidating the metal sulfide to its oxide with the simultaneous production of gaseous As4O6, which is handled during gas cleaning. The solid product, containing hardly any As, is rich in S and can be fed to a respective smelter (e.g. in the case of Cu). Alternatively, if the production of oxide is required, a dead roasting step is added after the partial roasting step, with the overall process considered as two-stage roasting."

Jan 1, 2012

By A. L. Valdivieso

"The correlation obtained by plotting pH of maximum adsorption of dextrin versus the isoelectric point of involved metal hydroxides can be used to predict the depressing effect of dextrin on flotation in ""pure"" sulfide mineral systems. Sulfides are strongly depressed by dextrin whenever their surfaces are coated by the corresponding metal hydroxide. The efficiency of dextrin as a depressant is affected by the adsorption of the sulfhydryl collector. Hydrolyzable cations modify this relationship in flotation of sulfide ores. This type of deviation of the real-life systems from the predictions based on the behavior of the pure systems shows the possible ways that could be followed to further improve the obtained correlations. Advances in Mineral Processing Science and Technology Proceedings of the 48th Annual Conference of Metallurgists ofCIM Sudbury, Ontario, Canada Edited by"

Jan 1, 2009

By J. M. Janssens, Van Quach Tinh, M. Ruel, R. Leblanc

"Microscopic studies of peat moss indicate a highly porous material. In view of using this natural product as an adsorbing agent for the treatment of polluted water, studies of its adsorbing power for beef extract and alkyl benzene sulphonate solution were determined. The effects of time of contact, particle size, concentration of adsorbent and concentration of pollutant were studied. In the case of beef extract, there is a COD reduction of around 27 per cent; in the case of the alkyl benzene sulphonate, the percentage reduction varied from 72 to 95 per cent. A water treatment plant based on the adsorbing power of peat moss with simultaneous recuperation of the pollutant is proposed."

Jan 1, 1971

By Michael P. Davies

Mine waste facilities, and in particular tailings impoundments, are one of the highest risk aspects of any mining venture. There are far too many recent examples of how real and/or perceived physical or environmental impact from one of these facilities has had enormous economic impact on both the specific project and the overall parent mining company. In many cases, such dramatic impacts have followed a period where a due diligence of the mine had been carried out (e.g. in an acquisition, merger or similar) or an internal or otherwise audit had taken place. Consequently, it is suggested that there is a need for an audit/due diligence framework to assist those processes in terms of assessing mine waste facilities. This paper presents a recommended framework for completing either an audit or due diligence assessment of mine waste facilities under a number of typical scenarios. The framework will be of relevance to reviews carried out prior to mine construction, during operations and for mines that have been in a care and maintenance position and are to be re-opened. Concepts of risk management are introduced as an essential part of the recommended framework. The paper should be of value to current and prospective mine owners involved in stewarding an area of significant risk to viability of their mining venture. The paper should also interest prospective lenders to these ventures.

May 1, 2007

By Richard Simon

This paper presents an ongoing study on the use of borehole breakouts to estimate in situ stresses at depth in a Canadian underground mine. Breakouts were identified using an acoustic televiewer (ATV) probe. Rock samples were tested in a laboratory to determine their failure curve. Breakout analyses were performed using a 2D failure criterion and a multiaxial failure criterion. Analyses were carried out using both short-term (peak) and long-term strengths (the latter considered here as being represented by the damage initiation threshold DIT). The analyses have shown that the use of the longterm strength and a multiaxial failure criterion leads to results that are more consistent with stress measurements performed in the field, in the vicinity of the mine.

Jun 1, 2012

By Zhiwei Wang, Chunsheng Qiao

"Aiming at the problems of the existing calculation methods for the support pressures of shallow tunnels in layered jointed rock strata, by using OAT (orthogonal array testing strategy) and DEM (distinct element method), 12 influencing factors including the thickness of the weathered overburden, and the states of the rock joints were considered. Then, the classification of the loosening zone was analysized. On this basis, by using the DEA (data envelopment analysis) theory, quantitative analysis on the influencing factors was conducted. By analyzing the influence of the key factors, a prediction formula of the boundary of the ringent trumpet-shaped loosening zone was established. According to principles of stress transformation, the formula of support pressures of the loosening zone which could considering the key factors were deduced. Finally, a practical case was introduced and studied to verify the proposed method.INTRODUCTIONIn recent years, various urban subway tunnels are increasingly carried out through jointed rock strata in many cities. Rock masses are discontinuous mediums with fissures, fractures, joints, bedding planes, and faults. The frequency of joints, their orientation with respect to the engineering structures, and the roughness of the joint have a significant importance from the stability point of view. However, there is a lack of understanding about the influence of the joints on the stability of tunnels. Therefore, how to measure the degree of the joints’ influence is a problem that needs to be solved.For the calculation of the support pressures, until now, many research results were focused on soil ground (Bierbäumer 1913; Terzaghi, 1943; Peck, 1969; Sabatini et al., 1999). In terms of site tests and model indoor tests, by measuring strut loads and calculating earth pressure based on strut spacing, the results proposed by Peck (1969) and Tschebotarioff (1973) have been widely used in practice for designing excavation support systems under sand (drained) and clay (undrained) soil conditions. Note that, it is unclear whether these findings could be extended to rock strata. For numerical simulations, how to simulate the states of the rock joints is a key problem that needs to be solved."

Jan 1, 2015

By Guangyuan Li

A 3-D block-spring model (BSM) has been developed for simulating the behaviour of jointed rocks. The model uses a discontinuous formulation and an iterative procedure to solve the large displacements in jointed and faulted rock masses. The 3-D BSM has been used to simulate mining excavations in jointed rocks around an open pit and underground settings. The applications have demonstrated that it is a practical tool to solve complicated problems of rock mechanics in civil and mining engineering. This model has recently been modified to incorporate complex geological conditions, such as underground water flow (seepage), unstable blocks and the time-dependent behavior of backfill materials. To demonstrate the capability of the 3-D model this paper presents the fundamentals of the 3- D BSM and its application for open-pit mining. A complete computer package BSM3D has been developed based on the 3-D block-spring model. The package consists of a solving engine for numerical analysis and a Windows based processor for mesh generation and results display. The multi-functioned pre-processor provides tools and menus to help users setting up models easily and conveniently. The fully featured post-processor allows users to view the results in different windows and orientations. The graphical results include contours, vectors, animation of rock movement, and the failure state of the rock structures.

May 1, 2001