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By B Crowdey, J Wall

The particular underground operation relating to this paper is a gold producer and has an orebody predominately consisting of rhyolite and marcasites pyrite. The ore has been identified as being reactive to nitrates.Operations currently utilise two twin boom Tamrock™ Super-Drill Jumbos for development mining. Capital (waste) headings have a nominal size of 7 m wide × 6 m high, while ore headings are designed at 5 m wide × 5 m high, with the lower reaches of the mine narrowing down to a 4.5 m × 5 m design. Production drilling is currently undertaken with an Atlas-Copco L6 Solo. Due to the reactivity of the ore, inhibited emulsion phase bulk explosives are used for all blasting activities, with electronic detonators utilised in the production sequence.Sublevel shrinkage stoping is utilised when the orebody is stronger than the host rock. After blasting the ore, and during extraction, the surrounding host rock cannot maintain integrity and it ‘collapses’ on top of the ore. Gravity forces this collapsing rock to follow the blasted ore through the drawpoints.The highest risk involved with sublevel shrinkage stoping is the necessity for charge crews to work upon ‘rills’ at the drawpoints, which are occasionally unstable, to charge the next blast ring to be fired. To overcome this issue a loading technique called ‘precharging’ is used whereby two to three rings are charged, but only the first ring is fired. This technique can minimise risks by taking the charge crew away from the rill and brow.As this mine contains hot and reactive ground, strict guidelines from the Australian Explosives Industry and Safety Group Inc (AEISG) are adhered to. These guidelines relate to the sleep time for the precharged rings.This paper describes the issues faced with precharging in hot and reactive ground, the monitoring required and the systems and procedures that were put in place to enable a successful outcome.CITATION:Crowdey, B and Wall, J, 2014. Precharging sublevel shrinkage production rings in hot and reactive ground with electronic blasting systems, in Proceedings 12th AusIMM Underground Operators’ Conference 2014 , pp 283–288 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Mar 24, 2014

By Morsky P, Kalapudas R, Natunen H, Virtanen M

The development of autogenous grinding modification in Outokumpu, known with the name 'Outogenius Comminution', was 'reversed'. At first the metallurgists studied and tested tens of years autogenous grinding in detail in full scale circuits at the concentrators of the company. After the final solution already had been found, also a pilot plant was built and now finally, research work is under way to develop a special laboratory method for testing the suitability of ores for 'Outogenius Comminution'.

Jan 1, 1993

By R Verreet

In April 2000 Mount Isa Mines installed hoist ropes of a new design on the double-drum winder at their P49 shaft. The ropes, CASAR Duroplast, were about three times as expensive as the previously used triangular strand ropes. The P49 shaft is situated at Mount Isa MinesÆ George Fisher Mine, located some 30 km north of Mt Isa. This shaft used the tried and proven 6 x 33 triangular strand style ropes. The rope life attained by these ropes at the time was acceptable due to many years of satisfactory performance. The following study indicates the improvement of service life using CASAR Duroplast rope in P 49 shaft, which depends on shaft and winder parameters of that particular shaft and cannot necessarily be generalised to other shafts.

Jan 1, 2005

By Dodd SF

Valuation of mining companies and their underlying assets prepared by brokers' analysts are, by necessity, approximations. The reliability of the valuations is entirely proportional to the quality of available data, the reliability of forecasts and the nature of underlying commodity price assumptions. The latter is perhaps the greatest single cause of gross variations in company and asset earnings estimates and- valuations. Assumptions are often necessary regarding commodity price achievement based on commodity hedge positions. Public disclosure from listed companies provides a sound base from which to project earnings, cashflows and balance sheets. The uncommon disclosure of projected production and cost schedules often reduces the reliability of future estimates. The application of reserve and resource estimates is contentious with practitioners applying differing weightings to importance of resources in estimating mine lives (and therefore cashflow streams). Valuation methods applied in equity markets usually focus on relative value and the identification of pricing anomalies. The commonest ""rules of thumb"" applied in the valuation of mining companies (and therefore their underlying assets) is with the use of year specific price/earnings (P/E) and price/cashflow (P/CF) ratios, with low multiples suggesting undervalued assets, high multiples overvalued situations (but these rules can often be clouded by market expectations of underlying commodity price movements). Another simply applied valuation tool is to examine the examine the value placed on reserves and resources by the market. Inexpensive gold in the ground (expressed as $ of market capitalisation per ounce of reserves or resources) might indicate a buying opportunity, but the market does discount the value of gold in the ground prior to mine development and where development risk is perceived.

Jan 1, 1994

By E Rubio, N Morales

A common practice in the mining industry is to decompose the planning process into different tasks, so the overall process and specific schedules can be constructed easily. Nevertheless, currently there are some adverse effects, such as not capturing the real value of a project by not taking into account the construction of several underground drifts and general infrastructure. Then the common practice is to compute mining sequence and cut-off grade profiles over the life of the mine without constitutively integrating the development schedule as a means to measure the constructability of a given mine design and sequence. Thus, the investigation summarised in this paper shows a novel, integrative way of treating an underground mine sequence and production schedule while considering drift development scheduling. Moreover, it is thought that, because of this original model, the whole underground production scheduling exercise must concentrate on combining the development and the production scheduling to compute a robust and a feasible production schedule.In order to quantify the effect of the conventional way of viewing the planning, the concept of the building information model (BIM) needs to be used, which was postulated by Charles Eastman and has been used extensively since the late 1970s. BIM takes other aspects of a project into account, considering at the same time the spatial relationships, quantities and properties of building components, but especially some kind of model visualisation, which is the advantage to be incorporated. This paper presents the basis for an optimisation model that allows for defining the sequence of the mining development so that the production plan can be achieved. For this, the model considers the space dimensions, time, pattern or strategy, cost or benefit, precedence and resources available. Tests were performed considering a block caving and sublevel open stoping method. Finally these tests showed the main conclusion, that production sequence changes when the building capacity is considered.

Sep 26, 2011

By Gregory L. M, Phillips G. N

Although it has long been recognised that there is a diversity of minerals associated with Victorian gold deposits, the degree to which this mineralogy is systematic or haphazard has remained uncertain. Recent work by the authors and students under their supervision permits a sharp delineation of the boundaries between different mineralogical domains, and these are interpreted in terms of recent rapid advances in Victorian tectonics, and the regional framework of Victorian gold geology described in Phillips and Hughes (1996).

Jan 1, 1997

By M Runkel, J Hammerschmidt, A Holmstr÷m, A Charitos, J Gnntner

"Roasting of sulfide concentrates and refractory ores is an important process step in the production of metals and chemicals. Sulfides of iron, zinc, copper and other metals are oxidised with air between 600 and 1000¦C into metal oxides or sulfates and gaseous sulfur dioxide. Roasting of gold concentrates and ores is a typical processing step used to produce a porous calcine suitable for cyanide leaching. During roasting, elements posing problems are removed through: oxidation (carbon, sulfur, arsenic and antimony) or volatilisation (mercury, chlorides and tellurides, as well as arsenic and antimony).This paper focuses on the environmental aspect of roasting using fluidised bed technology. The approach is to show that roasting is an attractive solution for refractory ore pretreatment since, on the one hand, it is an efficient technique yielding high gold recovery rates, while on the other it is able to comply with current stringent international environmental regulations. In that respect, roasting is compared to alternative processes, ie pressure oxidation (POX), bio-oxidation (BIOX) and ultra-fine grinding (UFG). Roaster high gold recovery rates are ensured through roasting-leaching test work, which allows the derivation of respective roasting parameters that are easily achieved in an industrial plant. On the other hand, key elements of the roasting process are analysed, which make it an efficient and sustainable technology, ie the possibility for energy recovery, the removal of off-gas impurities during the different gas cleaning steps (handling of arsenic, mercury emissions and further hazardous dust and gas emissions) and the treatment of the SO2-gas in order to produce sulfuric acid, and finally the treatment of the effluent produced. The processÆs environmental aspects are summarised by listing roasting emission values that comply with international regulations.CITATION:Charitos, A, Runkel, M, Gnntner, J, Holmstr÷m, A and Hammerschmidt, J, 2013. Roasting - a study on environmental aspects, off-gas, effluents and residue treatment, in Proceedings World Gold 2013, pp 509-518 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Sep 26, 2013

By R Moreby, J Kok, L van den Berg

The high production rates achieved from mass mining methods such as block caving, sublevel caving and longwall mining require large conveyor belts, trucking loops (diesel/electrical) and rail systems for ore handling. However, the ore handling systems used in mass mines introduce a significant amount of heat into the overall ventilation system, which may be problematic at depth or in mines located in hot climates.In particular, the heat load from a conveyor system is not always well understood and consists of various components, including frictional heat from idlers, heat from electrical motors, heat from the drive train and heat from broken rock transported on the conveyor system. This paper presents results from a study that investigated the heat introduced to the ventilation air from a large conveyor system. The conveyor system transports ore with a maximum virgin rock temperature of 41°C from a depth of over 1 km. Air, belt and rock temperatures were measured in the conveyor system to evaluate the distribution of heat loads.CITATION:van den Berg, L, Moreby, R and Kok, J, 2015. Heat load estimation from conveyor systems in mass mines, in Proceedings The Australian Mine Ventilation Conference, pp 63–70 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 31, 2015

By G W. Scott, H M. Lukey

The Lake Superior Region has been a producer of iron ore for over 150 years. Early mining operations concentrated on direct shipping ores, which are the result of post-depositional upgrading principally by deep weathering. As direct shipping ore reserves became depleted, the focus changed to the production of iron ore pellets from taconite. The post-depositional processes responsible for upgrading taconite are regional metamorphism, contact metamorphism and hydrothermal processes (Clout and Simonson, 2005). While these processes are important in iron ore genesis they can also contribute to liberation problems and in some instances reduced pellet quality (Han, 2004). Low-grade metamorphic mineral assemblages can negatively impact liberation and pellet quality. Low-grade iron formation may contain a suite of carbonate minerals including ankerite, dolomite, kutnohorite, siderite and magnesiosiderite. Variation in the distribution and composition of siderite and magnesiosiderite makes controlling the MgO content of pellets difficult. Carbonate minerals also require calcination in the pellet induration process, which requires additional heat to be added to the system, slowing down the induration process and reducing throughput. Prediction of carbonate mineralogy and carbonate mineral chemistry is an important goal of ore characterisation for pelletising properties. Contact metamorphism causes changes in mineralogy and grain size (Klein, 1973; Gunderson and Schwartz, 1962). Increasing the grain size of magnetite should improve its liberation characteristics. However, plant grinding targets may not allow the coarse-grained, more easily liberating magnetite ores to increase throughput and can actually result in decreased throughput due to recirculation. While magnetite and martite ores are well understood (Lukey, Johnson and Scott, 2007) late open-space filling microplaty haematite ores are not. These ores, while composed of similar minerals, have a unique genesis that results in fine grain size and complex textures that present liberation challenges and often make interpreting laboratory metallurgical test results more difficult.

Jan 1, 2007

By Golab K, Partridge AC, Fletcher CAJ, Holtham P

Spiral concentrators are used globally in the fine coal processing industry to segregate particles, by gravitation, on the basis of density and size. Consisting of an open trough that twists vertically downwards about a central axis, a slurry mix of particles and water is fed to the top of the concentrator. Particles are then separated radially as they gravitate downward. Since their introduction to Australia in the 1940's, the generic design has evolved largely by laboratory trial-and-error investigations of different prototypes. However, this approach has proven expensive and optimal designs have not been necessarily developed. Accordingly, Computational Fluid Dynamics (CFD) analysis has been used recently as an alternative method of investigation, to assume as is envisaged, a role in the design process. To date, CFD models have progressed to simulations of turbulent fluid flow on current production spiral designs, and are continuing to be adapted for inclusion of particles at realistic feed concentrations. To be able to use the models confidently however, laboratory experiments must also be performed to validate the predictions during the development stage. This paper reports the current findings of an ongoing CFD and experimental program applied to one spiral unit. Satisfactory quantitative agreement has been achieved for the fluid and particulate flow characteristics, and although further validations are appropriate, the model already possesses significant potential for use as a reliable predictive design tool.

Jan 1, 1998

The long-term outlook Tor Australla's traditional mining products is for flat demand and continuing low prices. This has come about because of three far-reaching changes since earlier boom days: 1. Continuing declines in intensity of usage of basic mine products; 2. The failure of newer western and third world developing countries to realise growth expectations; and 3. Continued production pressure from third world countries (and first-world primary producers) in an effort to earn foreign exchange and rectify trade balances. These trends have led to a general situation of excess supply and weak demand. In this environment, the prerequisites for survival in the mining sector are first-class mines, modern and efficient production methods, low unit costs, aggressive marketing, and products with reasonable operating margins. Many of Australia's mines meet these prerequisites. Following the A$ depreciation and widespread unit cost reductions, most of these mines will be moderately profitable at current depressed commodity prices. They are well placed to benefit from price rises if these eventuate. A new generation of mines is concentrating on a more profitable product range (gold, diamonds, uranium, mineral sands). Australia's balance of trade remains firmly dependent on the primary mining and agricultural industries (Fig. 1). Despite optimistic talk of high-tech developments, tourism and a resurgence of manufacturing, these will remain a small component of Australia's export structure.

Jan 1, 1987

By Lama R. D

The Australian underground coal mining industry is undergoing major changes. This paper analyses the technologies presently being researched in mines, and discusses their utilisation as major contributors in the underground mining of coal in Australia over the next 20 years. It describes the problems that underground mining of the year 2000 will face and the possible solutions to those problems based upon results of present day research. Methods, equipment and organisational requirements are outlined. Developments in micro-electronics, computerisation and monitoring will require a new look into human resource development, education and training, and organisation to meet the challenges of the 21st century. The mining system's philosophies of the future are Outlined.

Jan 1, 1986

By S Graskoski, S Craig, C Myburgh

Too often in mine planning, maximising revenue-generating material takes precedence over minimising costs. The ability to target both revenue and cost optimisation enables mine plans to fulfil corporate objectives of targeting maximal project net present value (NPV). The state of current mining costs and increasing government regulations in Australia are forcing many mine planners to pay closer attention to cost minimisation. Dumping waste material, which ultimately forms waste landforms, represents a large cost to mining operations. A general mine, with a waste to ore strip ration of 6:1, allocates approximately 32 per cent of total mining costs to waste haulage alone (Gregory, 2003).Most scheduling packages do not dynamically build economic or minimal cost dumps as part of the scheduling process. In most cases, waste dumps are built after a mining schedule has been defined. Automated software is now available which dynamically schedules the pit and waste dumps together. The overall shape of the waste dump is therefore dictated by minimum cost or minimum haulage hours.The purpose of this paper is to compare dynamic pit and waste schedules to traditional methods which apply haulage estimations after defining the mining schedule. This paper includes a case study on the large open pit operation at Tropicana Gold Mine, a joint venture between AngloGold Ashanti Australia Ltd (70 per cent) and Independence Group NL (30 per cent). The operation will focus on mining three large open pits over a 13-year mining life. A total of 397 Mt of waste is mined and directed to multiple destinations including waste dumps, the run-of-mine (ROM) pad and tailings storage facility (TSF) perimeter.Due to these complexities, management of the haulage fleet, especially during the critical period of operation readiness and start-up, is essential. Critical infrastructure such as the TSF and ROM pad will need to be built early and these areas, as well as the sequential development of the waste dump, will need to be developed within the constraints of structured mining fleet build-up.This paper investigates the influences of haulage estimation accuracy and compares traditional approaches for waste planning to automated approaches using EVORELUTIONÖ.CITATION:Graskoski, S, Craig, S and Myburgh, C, 2013. Dynamic pit and waste dump schedule optimisation at Tropicana Gold Mine, in Proceedings World Gold 2013 , pp 121-128 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By D Roldpo, M Vidigal, J F. C L Costa

The local cumulative distribution function (lcdf) of a selective mine unit (SMU) can be estimated by conditional simulations using the statistics derived from the sample points, generating multiple equally probable scenarios. Conditional simulations permit the evaluation of the lcdf at any support, taking into account the spatial variability, ie the variogram, and the two statistical moments, mean and variance, of the conditioning samples. The SMU ore losses and dilution depend on the mining method and mining equipment selectiveness that, in its turn, depends on the predicted block size. A new approach to predict ore loss and dilution was developed in this study. Monte Carlo simulation is used to randomly generate a grade value derived from the lcdf at the mining stage (Zs_mc(t)) in order to make a decision about the SMU destination, ie processing plant (ORE) or waste dump (WASTE). If Zs_mc(t) is lower or equal to the cut-off (Z_cut-off) the block is ORE and, conversely, if Zs_mc(t) is higher than the cut-off (Z_cut-off) the block is WASTE. Considering these binary destinations ORE/WASTE, at the mining time t, and combining each realisation of the simulated random function Zcs_i (X), there are four possibilities for each SMU simulated value: 1. the block was simulated as ore and is actually ore (OO), 2. the block was simulated as ore and is actually waste (OW),3. the block was simulated as waste and is actually ore (WO), and 4. the block was simulated as waste and is actually waste (WW).The dilution factor is given by possibility 3 (WO), while the ore loss factor is represented by possibility 2 (OW). These results comprise the classical classification and reconciliation plots used in the mining industry. The new procedure proposed in this paper is based on the use of all the equally probable simulations to define the ore loss and dilution factors. An application of this methodology was carried out at Vale's iron mine in Brazil. The grade of silica was simulated and 50 multiple equally probable 3D models were generated. The mean and the standard deviation of the ore tonnage (OO + WO) for the 50 realisations, was 233 Mt and 0.5 Mt, respectively. The mean grade increased for the diluted ore (OO + WO) as well as their respective coefficient of variation (CV). The CV increases from 62 per cent in the undiluted ore (OO), to 101 per cent in the ore, considering the dilution factor (OO + WO). The mean ore loss (OW) was 10 Mt and the waste tonnage dilution (WO) was 9 Mt.

Jan 1, 2009

The influence of strongly chemisorbed solutes such as oxygen and sulphur on the rates of reactions at the gas-liquid iron interface is briefly reviewed. Deductions from recent studies of the rates of decarbur- ization of carbon-saturated liquid iron indicate ideal adsorption behaviour for sulphur over a wide temperature and composition range. This is in fair accord with available infor- mation on surface tensions in the Fe-C-S system. Previously unpublished results for the kinetics of the 14C02-CO exchange reaction are in accord with ideal absorption of oxygen on liquid iron. The derived value for the ideal adsorption coefficient of oxygen at 1550¦C is in quantitative agreement with measurements of the depression of surface tension in the Fe-0 system. Consideration is given to the applicability of such results to the violently agitated systems of steelmaking.

Jan 1, 1980

By R Markoski, P Grealish

The requirement for rapid vertical development for underground ventilation is often a factor when dealing with dynamic mine plans, with short vertical developments being used to optimise ventilation systems. In an effort to increase the safety and efficiency of the constructions, a simple and effective sinking methodology is required that is both adaptable and repeatable. A modified shaft construction methodology is proposed that attempts to minimise risk to the personnel as well as be cost-effective. Readily available equipment is used to ensure adaptability to the various environments and shaft parameters.One of the greatest risks of shaft sinking is having personnel working suspended over open cavities or underneath suspended loads. Removing this risk, by ensuring all construction is done from solid ground, allows for safer sinking operations. As the process is repeatable, familiarity and confidence in its construction sequence will increase with each successive sink.A trial sink is performed with a 3.6 m diameter, 20 m deep shaft. The shaft was excavated using a conventional strip-and-line philosophy, with the shaft then being lined from the collar via the use of large diameter corrugated steel culverts. The annulus between the steel culverts and shaft excavation is then filled with a concrete mixture to secure it in position.The new process was successful, with no personnel at any time during the process being suspended above an open excavation. The installation had relatively low capital and operational costs and was completed faster than an equivalent, conventional concrete-lined shaft construction. Therefore when compared to conventional shaft-sinking methods, this process can be considered safer, more efficient and relatively cost-effective.Further research is required to determine whether this method can be expanded to larger vertical developments.CITATION:Markoski, R and Grealish, P, 2014. A new method for rapid vertical development of underground ventilation shafts, in Proceedings 15th Australasian Tunnelling Conference 2014 , pp 603–606 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

By A E. C Peres, P R. M Viana

The role of flotation columns in comparison with conventional mechanical flotation cells is discussed under the scenario of Brazilian flotation technology. All iron ore concentrator circuits commissioned since 1990 incorporated column only flotation technology in rougher, cleaner, scavenger configuration. Columns were also added to existing circuits, especially at the cleaner stage. Columns were also incorporated to phosphate ore flotation circuits operating mechanical cells. In two phosphate concentrators, columns substituted for all mechanical cells. Columns perform the cleaning stage in a large sulfide copper concentrator, following rougher flotation in tank cells. Scavenger of the cleaner tailings is performed in tank cells at this plant. Other ores that are concentrated in flotation columns include graphite, talc, lead-zinc sulfide, and a zinc hydrometallurgical residue for silver recovery.

Jan 1, 2005

The elements of consistent structural de sign models for underground structures are explained. Such models should comprise at least ground properties, excavation and support methods, computational models for analysis, failure hypotheses, and in-situ monitoring. The fundamental characteristics of the interaction between ground and support are investigated. Then, plane strain models for soft ground tun- nelling and design models for rock tunnelling employing stress release at the tunnel face are elaborated. Some numerical evaluations are gi- ven in diagrams, comparing approaches of dif- ferent authors. Comments are presented on nume- rical three-dimensional models (visualized by structural models for mining in rock salt), on the interaction of in-situ monitoring and design, on structural safety for underground structures, and finally on the general develop- ment of structural design models in geo- Techniques.

Jan 1, 1987

By R McDonough

DTL2 contract C916 was awarded in March 2009 for S$340 M. This contract includes two mass rapid transit (MRT) 1100?m long bored tunnels using two slurry tunnel boring machines (TBMs), with an internal diameter of 5.8?m, two cross passages and 135?m of cut-and-cover tunnels The contract also includes the design and construction of a new underground station including station entrances, subway links, architectural finishes and external landscaping. The station, located at Upper Bukit Timah Road near Jalan Jurong Kechil will also double as a civil defence shelter.The works included significant traffic management in a dense urban area in order to create the working areas whilst keeping the requisite number of traffic lanes. This involved numerous utility diversions and included the removal of a 33-year-old pedestrian overhead bridge (POB) over busy Bukit Timah Road. The station and tunnelling works were completed on time, including a ‘dock and dismantle’ TBM retrieval and subsequent breakthrough of the separating wall.This paper will detail the methods and solutions used to construct the tunnels and stations, with a focus on the requirements for construction of the station to be a civil defence shelter if required. This involved solutions to tying reinforcement and placing concrete to high standards in a restricted space, as well as the incorporation of heavy blast doors and other associated protective measures. The efforts of the management team resulted in the project being awarded first prize in the 2011 Land Transport Authority’s Annual Safety Award Convention and being named winner of the Safety and Health Award Recognition for Projects (SHARP) award at the 2011 Workplace Safety and Health (WSH) Awards. As well, McConnell Dowell won a Green and Gracious Builder Award (Excellent Category) from the Building and Construction Authority (BCA).CITATION:McDonough, R, 2014. Design and construction contract C916 Beauty World Station and Tunnels, Singapore, in Proceedings 15th Australasian Tunnelling Conference 2014 , pp 411–418 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

By Drew GJ

Smelting is a process in which heat is applied to ores to produce metals. Impurities are removed by segregation in the slag, or converted to gases or sublimates and discharged up the flues. Mate- rials delivered into the smelter have generally been previously concentrated or processed at the mine, and the size of their particles, and also their chem- ical composition, greatly affect the smelting proc- ess. Some impurities are more difficult to remove than others, and are more objectionable in the finished product. The first metal mine in Australia was opened near Glen Osmond in South Australia in 1841, for silver-lead ore. It was followed by the Kapunda Mine for copper in 1844 and by the very signifi- cant Burra Mine, also for copper, in 1845 (Figure 1). A major part of their ores could not be exported profitably for smelting in England and Wales where the large smelters were then located. In addition to treating ores from Cornwall these also smelted ores from recently opened mines in Cuba, Chile, and Mexico. The Welsh smelting process (Figure 2) was developed over a period of years to utilise Welsh coal to treat copper ores particularly from Corn- wall. The first step consisted of a calcination to remove sufficient sulphur from sulphide ores so that subsequent melting operations would produce copper matte, a copper-iron-sulphide which melted at about 1050¦C. Subsequently refined to white metal with the addition of carbonate and oxide ores when these were available, and often through an intermediate step of blue metal, this matte was finally oxidised to pure copper, or as pure as it could be made in those days. The movement of metal towards greater purity was matched by a reverse flow of slag, carrying reducing quantities of copper, so that the slag rejected from the first melting process carried the minimum quantity of copper. Chemical analysis was virtually unknown. Materials were assayed in the laboratory by a small scale smelting process, and the purity of the final refined copper was judged b} the ease with Mhich it could be hammered into thin sheets.

Jan 1, 1987