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By James Paone

This report on the state of the art of horizontal boring technology for underground power transmission installations was prepared by the Bureau of Mines at the request of the Department of the Interior. This paper describes the different machines and methods used in augering, impacting, pushing, drilling, and machine tunneling horizontal holes through soil and rock. A review of the borehole survey and guidance tools and techniques applicable to these methods is also given. Nonboring methods used for emplacement of power distribution and transmission lines are briefly discussed. The paper ends with a brief technical forecast, an analytical summary of the state of the art, and recommendations based on power industry needs. Horizontal boring techniques for power distribution lines installation are adequate to meet the requirements of the power industry, particularly where such burial involves relatively short distances in soil or soft rock. For burying power transmission lines, particularly in the harder rocks and over relatively long distances, horizontal boring methods are not as well advanced. Research and development as well as economic incentives to equipment manufacturers could substantially improve the state of the art. Obstacle detection and guidance systems for directing boreholes to specified targets need major improvements to meet the requirements of the power industry for underground burial of distribution and transmission lines

Jan 1, 1968

By Margaret R. Lickes

Mercury was produced originally at the Idaho Almaden mine from 1939 to 1942. When the ;.nine was shut down, more than 100,000 tons of ore, containing from 2.5 to 3 pounds of mercury per ton, was known to be adjacent to old workings but had been considered too low grade for commercial operation. Later, detailed, systematic exploration by Rare Metals Corporation of America increased and delimited enough minable reserves for further operation to be foreseen for several years. The average grade of the ore is estimated at slightly more than 3.5 pounds of mercury per ton. Open-pit mining and installation of the largest rotary kiln in the United States furnacing mercury ore have made possible profitable exploitation of these reserves (fig. 1). The bulk of the exploration was by percussion drilling, although some diamond drilling was done to check the results. When enough reserves were indicated to assure a successful operation, stripping and plant construction were started simultaneously. Figure 2 is a general view of the plant. The ore bodies, although irregular in size, shape, and grade and covered by essentially barren cap rock, are amenable to low-cost, trackless, open-pit mining. Development consists of stripping the overburden and removing, barren cap rock. Ore is being mined at approximately [5],000 tons per month and treated in a 175-ton-per-day furnacing plant.

Jan 1, 1957

By N. A. C. Smith

This report on the physical and chemical properties of typical crude oils of southern Louisiana and southern Texas is the seventh in a series of preliminary chapters of a bulletin covering the producing districts of the United States. Preceding reports* may be obtained from the Bureau of Mines on request. The details of the methods used in this survey in collecting samples and making laboratory tests have been discussed in the first three papers. A method of summarizing and interpreting the laboratory data has also been given, but most of the crudes included in the present report differ so radically from those previously reported, that it has been found advantageous to adopt a somewhat different method in making summaries. This method is described in detail later. If any errors or omissions are noted by readers, it is hoped that these will be brought to the attention of the Bureau of Mines, for correction before the appearance of the final bulletin.

Jan 1, 1922

By J. P. McGee

A 1,000-hour test with a gas turbine at 1,200° F showed a working fluid of 1 gr of ash per 100 scf of power gas (79 percent of the ash 7 to 35 microns in diameter) to be excessive for acceptable blade wear for commercial practicability. Blades in the turbine consisted of about 20 percent each of chromium, cobalt, and nickel; 3 percent molybdenum; 2-1/2 percent tungsten; and smaller amounts of manganese, columbium, and tantalum. Erosion of both the fronts and backs of the turbine nozzles was particularly heavy, the trailing edges being worn to a featheredge. Erosion of the buckets was less marked, although the leading edges were somewhat pitted. A refractory-lined combustor performed efficiently and with little abrasion of the lining by the ash-laden gas.

Jan 1, 1969

By J. C. Barrett

Bureau of Mines research on the arc welding characteristics of titanium was initiated in 1948. Little was known about the art except that the easily contaminated metal required more protection from the atmosphere during welding than most other metals. Chambers were designed and built within which titanium could be welded with adequate inert gas protection. Welds were made and their properties studied, and prototype items were made successfully. This report, presenting a resume of the titanium arc-welding experiments undertaken by the Bureau of Mines, demonstrates that the process is successful if conducted under proper conditions and describes the welding of prototypes. INTRODUCTION The Bureau of Mines' first report on methods of joining titanium covered the subject of spot welding,4/ outlining the conditions necessary for producing spot welds in ductile titanium consolidated by powder metallurgy methods and describing the characteristics of such welds. This report embraces the field of fusion weld-ing of titanium and traces the development of suitable methods and equipment for producing such welds.

Jan 1, 1956

By Gregory M. Molinda

Coalbed discontinuities historically have been hazardous to mining as well as obstructions to efficient production. An effective means of mapping these features is needed in order to plan safe and efficient mine development. This Bureau of Mines report discusses the use of surface seismic techniques for this purpose. At a southwestern Pennsylvania mine, a system of coalbed discontinu-ities (paleochannels) was accurately mapped by the Bureau of Mines using borehole log methods and underground observation. This site was chosen to test the value of a high-resolution surface seismic reflection on technique for coalbed mapping. A statistical study performed at this mine indicated that the probability of accurately delineating this paleochannel system with conventional borehole methods was remote. A total of 1.47 miles of high-resolution seismic survey, comprised of four seismic profiles, was conducted in known and suspected coalbed discontinuity areas. Several test holes were drilled on the seismic lines in order to evaluate the interpretations. It was found, based on these and other existing boreholes, that it is possible to predict these dis-continuities. Paleochannel washouts were correctly predicted in several instances but in other instances were either incorrectly predicted or not predicted in areas of known discontinuities.

Jan 1, 1988

By Warren Hastings

This paper describes the methods and costs, in units of labor end materials, of sinking a 7 compartment vertical shaft 1,261 feet through a fractured, water-saturated formation. The shaft, designed for hoisting 2,500 tons a day, is at Friedensville, Lehigh County, Pa., approximately 6 miles south of Allentown and Bethlehem. It was sunk by the E. J. Longyear Co. under contract to the New Jersey Zinc Co. Preparation for shaft sinking W8A begun July 1, 1947, and sinking was completed August 18, 1952. A total of 604,858 man hours was required to sink the shaft.

Jan 1, 1954

By D. L. Paulson

Electric furnace smelting of blister copper directly from copper precipitates (cement copper) was investigated by the Federal Bureau of Mines. Copper concentrations in five different lots of cement copper in the investigation ranged from 62.5 to 82.5 wt-pct. Laboratory-scale smelting tests were made in a 50-kva electric-arc furnace to establish the reductant and flux requirements. Best recoveries were realized by adding 60 pct of the carbon required to combine with the contained oxygen in the cement copper. Operating parameters established during the laboratory-scale smelting tests were used successfully in smelting 20 tons of cement copper during 12 pilot-scale tests in an 800-kva electric-arc furnace. Over 98 pct of the contained copper was recovered as blister-grade metal. The projected energy consumption for a commercial-size furnace was 380 kwhr per ton of cold charge.

Jan 1, 1978

By Joe B. Rosenbaum

New applications and concepts of solvent extraction as a unit operation in extractive metallurgy have been developed in the last decade. Wider use is being made of established solvent extraction techniques in processing spent nuclear fuel elements and in winning columbium-tantalum, hafnium-zirconium, thorium, tungsten, uranium, and vanadium. Commercial application has been extended to recovery of beryllium, boron, bromine, copper, molybdenum, phosphorus, rare-earth metals, and rhenium. Systems in use and proposed typically extract metals or salts as anion, cation, or neutral species from aqueous media by reaction with a recycleable organic reagent.

Jan 1, 1971

By H. A. Doerner

"During the year which has passed since the last progress report on reduction of zinc by natural gas,3 the laboratory experiments on this investigation have been completed. In this concluding report, the whole subject will be reviewed and additional data presented.Chemical ReactionsIn a thermodynamic study of zinc smelting, Maier 4 discussed the use of methane for reducing zinc oxide, and predicted equilibria at various temperatures for the sore important reactions. The study has been extended to include the following list.Maier predicted that 870°C. would be the critical temperature above which reaction (1) would take precedence over reaction (2) and that reaction (1) at equilibria would be substantially complete at or above 927°C. A subsequent papers described experimental verification of these predictions and gave data on reaction rates under various conditions.It methane is passed through a heated bed of zinc oxide at a low enough rate reactions (1), (3), and (4) reach an equilibrium which can be expressed by reaction (10). The equilibrium concentrations for the products of this reaction in the temperature range 900° to 1100°C. were calculated by applying the thermodynamic constants to the stoichiometric relations. 6 The results of these calculations are listed in table 1 and shown graphically in figures 1, A and B. These data have major importance, and experimental work has shown that they are subtantially correct."

Dec 1, 1934

By R. M. Santmyers

Caesium, rubidium, and lithium are sometimes described as the minor or rarer alkali metals. They generally occur together in nature, although, lithium is distributed more widely and is far more abundant than either of the other two. The chemical, and even the physical, properties of these three elements can best be considered In conjunction with the more familiar members of the alkali group, sodium and potassium. The five elements lithium, sodium, potassium, rubidium, and caesium show an interesting gradation properties from member to member with the increase in atomic weights. All are silvery white and soft enough to be cut with a knife. They tarnish rapidly in air and decompose water at ordinary temperatures. The lowest temperature at which the action of the several metals on water can be de¬tected is -98°C. for sodium, -105°C, for potassium, 108°C. for rubidium, and -116°C. for caesium. The chemical activity appears to increase steadily from

Jan 1, 1930

By D. E. Shanks

As part of its goal to help maintain an adequate supply of minerals to meet national economic and strategic needs, the Bureau of Mines, U.S. Department of the Interior, is investigating a fused-salt electrolytic procedure for producing zinc metal. A previous report described preliminary, small-scale work on the fused-salt electrolysis of ZnC12. The present report covers a more detailed investigation of the properties of ZnC12-alkali metal chloride electrolyte systems in relation to the production of zinc metal and also discusses electrolysis in largescale, internally heated cells. The effect of composition on bath stability, current efficiency, cell voltage, and liquidus temperature was determined for the ZnCla-NaC1-KC1, ZnC12-NaC1-LiC1, and ZnC12-KC1-LiC1 electrolyte systems. An electrolyte com-posed of 38 mole-pct ZnC12, 31 mole-pct NaC1, and 31 mole-pct KC1 gave the best overall results. Sludge (ZnO) formation in the ZnC12-NaC1-KC1, ZnC12-KC1-LiC1, and ZnC12-KC1 systems was investigated during prolonged electrolysis. The ZnC12-KC1-NaC1 electrolyte showed the least sludge formation. A 1,500-amp cell was operated using the ZnC12-NaC1-KC1 electrolyte at 500° C. Zinc metal was produced at the rate of 4.0 lb/hr with a current efficiency of 95 pct.

Jan 1, 1979

By Richard P. Walters

This Bureau of Mines report reviews and assesses the technology for preparing electrodeposited coatings of the platinum-group metals from molten alkali metal cyanide baths. Methods are described for the preparation and purification of the cyanide electrolyte. Vacuum drying, fusion, and purity of the cyanide salts are discussed. Use of a sodium borosilicate test tube as a sodium-ion-conducting membrane for the addition of the desired platinum-group metal is described. The optimum plating parameters of potential and current density for Pt, Pd, Rh, Ru, and Ir coatings that result in the best deposits are given. A method for producing platinum-rhodium alloy coatings of predetermined composition is also described. The importance of careful substrate surface preparation is illustrated. While problems still remain with respect to coating porosity, careful application of the methods described permits the preparation of adherent, coherent electrodeposited coatings of the platinum-group metals.

Jan 1, 1984

By Alla D. Mah

The energies of combustion of two carbides of tungsten and two carbides of molybdenum were measured , and the corresponding standard heats of combustion were derived . The results are as follows : WC : AH298.15 ( combustion ) = -285,940 ± 250 cal /mole , W₂ C: AH298.15 (combustion ) = -490,660 ± 400 cal /mole , Mo₂ C : AH298.15 ( combustion) = -439,350 ± 600 cal /mole , MoC : AH298.15 ( combustion ) = -269,800 ± 1,000 cal /mole . The combustion heats were combined with the heats of formation of the corresponding metal trioxides and carbon dioxide to obtain the following heats of formation : WC : AH298.15 ( formation ) = -9.6 ± 0.4 kcal /mole , WC: AH298.15 ( formation ) = -6.3 ± 0.6 kcal /mole , Mo₂ C : AH298.15 (formation) = -11.0 ± 0.7 kcal / mole , MoC : AH298.15 (formation ) = -2.4 ± 1.0 kcal /mole . The heats of combustion and formation of MoC are tentative .

Jan 1, 1963

By E. J. Matson

Under the investigation for critical and strategic minerals the Kaiser mine, formerly the Baxter fluorspar property, in northeastern Mineral County, Nev., was explored. The work comprised excavating 32 trenches averaging 90 feet in length, 8 feet in width, and 1 1/2 feet in depth. The trenches were excavated across the strike of the ore body to enable the engineer to spot the diamond-drill holes; 7 such holes were drilled, aggregating 3,276 linear feet. A total of 20 core samples and 107 sludge samples was taken. The work under this program indicated that the fluorspar southwest of the deposit extended laterally and also at depth at least 250 feet below the 400-foot level. INTRODUCTION The Kaiser fluorspar deposit is in the northeastern portion of Mineral County, Nev. Mining was begun about 1928, and the property has been a consistent producer of both Acid- and Metallurgical-grade fluorspar. The mineralized zone has been developed along a strike length of about 2,000 feet and to a depth of over 700 feet along the dip.

Jan 1, 1957

Reduce the potential of haulage related injuries in underground mines by providing a method for quickly assessing the state of repair of mine haulage track. The Problem Currently, there are no established standards or procedures for inspection or cleaning of underground mine haulage track. Many track defects are hidden from an inspector because of layers of dirt and debris on the ballast, spikes, fishplates, etc. When a visual inspection can be performed, it may be highly subjective, except for a few items that can be categorized or counted, such as missing bolts or spikes. Track inspectors may even become tolerant of defects that can gradually worsen. For these reasons, mechanical inspection methods are needed to supplement visual inspections. Approach The Bureau investigated this problem and designed a towed vehicle to both mechanically clean and inspect underground coal mine haulage track. The vehicle was developed using a systems approach, paying particular attention to human factors issues such as operator field of view, operator ingress-egress, control positioning, and seating design. The prototype was built using simple fabrication techniques and off-the-shelf components.

Jan 1, 1990

By N. S. Dalal, B. Jafari, F. H. Y. Green, M. Petersen, V. Vallyathan

"Stable coal radicals (SCRs) were detected by electron spin resonance (ESR) spectroscopy in the lung tissue of autopsied coal miners. The SCR concentrations were measured in the lung tissues from 98 coal miners with and without (a) coal workers' pneumoconiosis (CWP), (b) cancer, and (c) a history of cigarette smoking. Concentrations of SCRs were also determined in the lungs of nonminer controls. The SCR concentration was related to longer mining tenure, CWP disease severity, lung cancer, and cigarette smoking. The mean concentration of SCRs in the lung tissues of miners with 30 ± 1.4 y of coal mining exposure was 5.3 ± 1.3 x 10"" spins/g versus controls who had a nondetec¬table level (< 10 15 spins/g). An increase in disease severity was accompanied by a progressive increase in SCR concentration. A SCR concentration of 4.8 ± 0.7 x 10"" spins/g was found for simple CWP (with moderate coal macules) versus 7.8 ± 4.6 spins/g lung tissue for complicated CWP (with progressive massive fibrosis). Significantly higher (i.e., 10 x 10"") concentrations of SCR in the coal miners' lung tissues were associated with an exposure history in the anthracite regions of northeastern Pennsylvania. These results in¬dicate a possible role for SCRs in the disease process. Furthermore, ESR appears to be an adequate methodology for the quantitation of coal dust retained in the lung and for distinguishing exposures to anthracite and/or bituminous coal.THE PREVALENCE AND SEVERITY of coal workers' pneumoconiosis (CWP) differ markedly between geographic locations, mines, and coal fields irrespective of comparable levels of exposure to coal mine dust These differences cannot be fully explained by the presence of silica and other minerals in the coal mine dust.' Rank of coal is also an important factor in the pathogenesis of CWP. Equally important is that the prevalence of CWP decreases from east to west in the United States,' and South Wales miners develop more severe CWP than miners in Scotland.' However, there are conflicting reports that cast uncertainty on the influence of rank of coal in the development of CWP."" These problems are complicated but will be solved as new technology emerges and as more is learned about the disease process."

Mar 1, 1992

By R. S. Fowkes

A study was made by the Bureau of Mines of the penetration of selected granular materials in an unconfined state by wedge-shaped tools having dimensions comparable with the dimensions of the particles composing the materials. The output force for larger particles fluctuated radically. A custom-designed integrator was used to obtain work as a function of depth of penetration in the form of smooth curves. The influence of wedge angle, depth of penetration, penetration rate, entry angle, compaction state, and particle size on the force required and the work performed was ascertained. Empirical equations describing force and work as a function of penetration were obtained for each set of experiments.

Jan 1, 1973

By B. W. Jong

The Bureau of Mines studied reinforcement of sulfur concretes using glass, polyester, and aramid fibers. The objective of this research was to determine the feasibility of fiber-reinforcing the sulfur concrete to enhance the flexural properties. Optimum fiber sulfur concrete compositions were formulated with a cement-to-fiber ratio of 9.0:1 for glass-fiber and polyester-fiber sulfur concretes and 12.1:1 for aramid-fiber sulfur concretes. Test samples were prepared using techniques developed by the Bureau of Mines. Flexural strength values of up to 50 pct of compressive strength values were achieved with fiber additions. With non-fiber-reinforced sulfur concrete, the values ranged up to 20 pct. The impact strength and fracture toughness of sulfur concretes were increased sig-nificantly by reinforcement with glass or with aramid fiber and were adversely affected by use of polyester fiber. Strain tolerance was doubled and failure mode was shifted from catastrophic to noncatastrophic type by adding glass fiber. The glass-fiber and aramid-fiber sulfur concretes are resistant to acid corrosion and have proved durable in freeze-thaw cycles. This laboratory and field evaluation has shown that fiber reinforcement of sulfur concrete is feasible and that it enhances the flexural properties.

Jan 1, 1985

By Frank A. Peters

The Bayer process treating Jamaican bauxite was evaluated from an economic standpoint, using standard estimating methods and published data, to present a reference point for cost estimates for nonbauxite alumina processes. The estimated operating cost for a plant producing 1,000 tons of alumina a day is $47.96 per ton of alumina when charging $8 per ton for bauxite and $2.30 per hour for direct labor. The estimated fixed capital cost is $46 million.

Jan 1, 1966