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By W. C. McLaughlin

Under a cooperative agreement, the Bureau of Mines, Magma Copper Co., and ASARCO, Inc., tested backfilled ground support systems at t.wo elevations in Magma's San Manuel, AZ, mine. The tests were mainly for guidance in designing the loading crosscuts of the new ASARCO Sacaton underground mine. Two-piece, wide-flange steel sets for 8-by 8-ft (2.44-by 2.44-m) and 11-by II-ft (3.36-by 3.36-m) openings were designed. Set spacing was 3 ft (0.91 m) and 5 ft (1.52 m), respectively. After erection, the sets were lagged with various test materials. The void between the lining and the ground was backfilled with sand and pea gravel. Instruments measuring strain (used to determine changes in stress) were placed beneath the sets and in the backfill. Results indicate the backfilled sets in the smaller drift (2315 grizzly level, panels 6 and 7) of 8-by 8-ft (2.44-by 2.44-m) cross section are a viable permanent support system, lower in cost than the standard formed concrete. Results are inconclusive in 2615 grizzly level, panels 5 and 6, where wide-flange steel sets were used with 5-ft (1.52-m) long concrete gob lagging of T-design.

Jan 1, 1983

By A. R. T. Dennues

"INTRODUCTION There are presented in this report the results of limited studies by the Bureau of Mines of the firedamp safety of some powder-powered tools proposed for use underground in coal mines. This study was made to obtain general information and specific technical data for a cable splicer and some rail punches now commercially available, the aim being to keep abreast of developments and to anticipate hazards.ACKNOWLEDGMENTSAcknowledgments are made to the Mine Safety Appliances Co., Pittsburgh, Pa., for supplying equipment for these tests, and to the Pittsburgh Coal Co. for making possible observations of the use of these tools in coal mines.The assistance of other members of the Explosives Division is acknowledged: J. E. Crawshaw, for examination of ammunition and, propellant powders; H. L. Wilson, for analyses of the natural gas used in the gallery and Jerome C. P. Weinheimer and Martin Bashel, for conducting the gallery tests.GENERALDescriptions of the DevicesPowder-powered tools of the type tested utilize the energy of charge of,propellant powder accomplish tasks. They are essentially small guns adapted to special work. Of the family of such tools now commercially available from one manufacturer, two have been proposed for use underground in coal mines, namely a cable splicer known as model TI and two models of rail punch known as R40 and R60. These tools employ blank-cartridge ammunition and special projectiles to accomplish the work indicated by these descriptive names."

Jul 1, 1947

By N. A. C. Smith

[The beau of Mines made its first survey of motor gasolines sold throughout the United States in 1915, a second in 1917, and a third in April. 1919. These surveys shored that motor gasoline had become notably less volatile during each two-year interval. In order to ascertain whether this change was continuing, it was planned to institute semi-annual surveys, the first of which teas made in January, 1920. Contrary to expectations based on the previous surveys, the average volatility of the gasoline tested at this time was practically identical with that of the average volatility of the gasoline from the same districts in 1919. The next survey, made in July, 1920, showed a very marked decrease in volatility but as it has long been recognized that the volatility of motor gasoline manufactured for sale during the summer months is loss tan that of gasoline made and sold during the winter, part at least of the change was attributed to this factor. The average boiling point of the samples collected in the present survey is 263 degrees Fahrenheit, as compared with 264 a year ago. This shows that the average gasoline marketed at the present time is fully as volatile as that marketed a year ago. There has been, however, a noticeable change in the character of the product: the initial boiling point and 20 per cant point are lower than a year ago, whereas the 90 per cent and end-points are higher, which indicates a greater proportion of gasolines made by blending casing-head, or natural gas-gasoline, and naphtha.]

Jan 1, 1921

By G. E. McElroy

This report discusses the construction and use of an all-pressure psychrometric chart in which the requirements of simplicity of appearance and absolute accuracy have been waived, to a certain extent, to provide for the rapid determination of psychrometric data and for the rapid solution of air-conditioning problems of major interest to the mining industry. Many mines in which air-conditioning problems are important are situated at elevations far above sea level and embrace great differences in elevation - in excess of 8,000 feet in certain mines - throughout their airflow circuits. Under these conditions, the effects of variations in the pressure of the atmosphere upon the physical properties of the mixture of air and water vapor of which it is composed are considerable and should be taken into account in the solution of problems. The simple types of psychrometric charts in common use, such as the Carrier, Bulkeley, Hill, and Goff (American Society of Heating and Ventilating Engineers Guide), are not generally suitable, in that they are drawn for a single barometric pressure - 29.92 inches mercury.

Dec 1, 1947

By Carl F. Wingquist

In support of Bureau of Mines studies of thermal fragmentation of rock, the elastic moduli of four types of rock were measured at temperatures ranging from room temperature up to 1,500° F (1,089° K). The sonic method was employed to determine the resonant frequencies of the rock specimens and from these frequencies, the elastic moduli were calculated. Data for Young's modulus, shear modulus, and Poisson's ratio are given as a function of temperature for Dresser basalt, Reserve taconite, Jasper quartzite, and Charcoal granite. Young's modulus and the shear modulus decreased with increasing temperature up to about 1,200° F and then became relatively insensitive to temperatures from 1,200° to 1,500° F.

Jan 1, 1969

By Bernard Porter

The densities of LiF, NaF, and KF, of binary mixtures of these alkali fluorides, and of binary mixtures of UF4, ThF4, YF3, LaF3, and CeF with each of tie alkali fluorides were measured as functions of the melt composition and temperature. Molar volumes at 1,000° C were calculated for all the mixtures. Binary systems containing LiF exhibited molar volume ideality. Binary fluoride systems containing either NaF or KF as the alkali fluoride exhibit positive deviations from molar volume additivity. However, molar volumes in the NaF-KF system are ideal.

Jan 1, 1966

By F. J. Wiebelt

Production of small tonnages of asbestos has been reported from 18 California counties; 16 additional counties have occurrences of asbestos. The counties in the northern part of California that have had a recorded production are: Alameda, Amador, Calaveras, Contra Costa, E1 Dorado, Napa, Nevada, Placer, Shasta, Siskiyou, Trinity, and Tuolumne. No deposit in the State has maintained consistent production. Serpentinized peridotites (potential chrysotile-bearing rocks) are widely distributed in the coast ranges, Klamath Mountains, and western foothills of the Sierra Nevada.

Jan 1, 1958

By R. F. Abernethy

Recent investigations in the United States and in other countries have produced considerable information on the nature and occurrence of minor elements in coal. The possibility of recovering certain elements, particularly germanium and uranium, from coal ash and other coal products has received considerable attention. Some flue dusts are potential sources of germanium, and certain lignite deposits are potential sources of uranium, but industrial recovery of these elements has been limited to small quantities for technical and economic reasons. Considering the large amount of coal mined annually, a small percentage of a rare element may have industrial significance if an economical method of recovery can be developed. In 1944 information on the occurrence of rare elements in coal was reviewed in Bureau of Mines Technical Paper 669 (46).3 This report is a revision of that paper with the view of summarizing published information available for United States coals, and pertinent information concerning coals of other countries. Selected references from the original paper are retained. New references do not include all preliminary reports when more permanent literature describing complete projects is available. Consequently, the list of references should not be considered complete.

Jan 1, 1963

By Timothy M. Barton

The U.S. Bureau of Mines is conducting research to assess the effectiveness of different chain pillar designs in maintaining gate entry stability. A particular concern is ground control for deep-cover 1ongwalls located at depths in excess of 1,000 ft. The study described in this report was performed in two experimental sections in one longwall headgate section which contained three different pillar designs. Two of the designs used conventional abutment pillars, while the third was a total-yielding pillar system. Both of the test areas were located under 1,800 ft of cover. The purpose of this study was to evaluate the effectiveness of these three pillar designs for gate road stability. As the longwall mined passed the test areas, Bureau engineers monitored entry convergence, roof sag, and changes in roof quality. The study indicated that the all-yield system performed nearly as well as the better of the two abutment pillar systems; but all of the three designs would have failed to provide acceptable stability for second panel mining without considerable artificial support.

Jan 1, 1989

By J. W. Town

Recrystallization studies on chrome-bearing spinel materials were made by the Bureau of Mines to determine the effects of certain fluxing agents and cooling rates on the chromium-to-iron ratio of recrystallized spinel. Statistically designed and evaluated tests showed that the ratio of chromium to iron in naturally occurring chrome spinel could be increased from 1.5 to 1 to over 7 to 1 and that the ratio of chromium to iron in the chrome-spinel in a stain-less steel slag could be raised to over 18 to 1. Silica, magnesia, and lime had significant positive effects, while alumina had a significant negative effect. Cooling rates of 200 C per hour in a programmed spiral globar electric furnace were satisfactory for growing crystals of recoverable size.

Jan 1, 1967

By E. V. Cilento, K. A. DiGregorio, R. C. Lantz

"DIGREGORIO, K. A., E. V. CILENTO, AND R. C. LANTZ. A kinetic model of superoxide production from single pulmonary alueolar macrophages. Am. J. Physiol. 256 (Cell Physiol. 25): C405-C412, 1989.-A kinetic model was developed to describe the production of superoxide (02) by single pulmonary alveolar macrophages (PAM). Model predictions were compared with experimental results obtained from single rat PAM. The 02 was quantified by measuring the reduction of nitro blue tetrazolium (NBT) to a diformazan precipitate (NBTH,) from video-recorded images of individual cells. The kinetic model considered three reactions: 1 ) the production of extracellular 02 from the reduction of oxygen by NADPH oxidase using intracellular NADPH as the substrate, 2) the subsequent dismutation of 02 to form H,O,, and 3) the reaction of 02 and NBT to form diformazan. NBT specificity for 02 was analyzed by comparing results in the presence and absence of superoxide dismutase (SOD) that catalyzes the dismutation of 02 to H,O,. Measured PAM heterogeneity was accounted for by varying the concentration of intracellular NADPH, its rate of depletion, and the concentration of intracellular NADPH oxidase in the kinetic model. Model predictions compared favorably with experimental results except when SOD was present. This discrepancy may be due to diffusional limitations because NBT is a relatively small molecule (818 mo! wt) compared with SOD (34,000 mol wt). In addition, the cell surface is both ruffled and negatively charged, which may introduce steric hindrances and/ or electrostatic effects, since SOD is also negatively charged, whereas NBT is positively charged.PULMONARY ALVEOLAR MACROPHAGES (PAM) protect the lungs by phagocytizing foreign debris and bacteria. This process is accompanied by the production of superoxide anion (02) at the surface of the plasma membrane (3, 31). Superoxide readily dismutates to form H20 2 and subsequently, other oxygen metabolites which have been shown to be both antibacterial and cytotoxic (21, 25, 35).Superoxide is produced from the reduction of extracellular O, at the surface of the cell membrane by NADPH oxidase by the following reaction (3, 4)"

Jan 1, 1989

By H. A. Watson

The introduction and use of synthetic materials in various applications may lead to potential hazards from toxic, gaseous, decomposition products if these materials are subjected to conditions abnormal to their intended use, such as high temperatures or burning from accidental causes. This report covers an investigation of such possible hazards from toxic gases produced by the burning or thermal decomposition of some low-density, expanded, synthetic materials, three of which consisted of polyvinylchloride and one of acrylonitrile. In the production of certain expanded plastic materials, Chemical blowing agents frequently are used to produce a cellular structure. One of these blowing or foaming agents contains azo-bis-isobutyronitrile, which is designated in this report as PN. Information indicates that a product of decomposition of this blowing agent, formed in the blowing operation, is tetra-methyl-succino-nitrile, designated as TSN, Which is significantly toxic. Decomposition of the blowing agent, with release of its azo nitrogen, is represented by the following reaction:

Jan 1, 1951

By Oliver C. Fursman, Lloyd H. Banning

This research was undertaken to determine the feasibility of producing steel from hydrogen - reduced , pyrophoric iron powder . Before steelmaking tests were begun , investigations were made to develop procedures for handling the pyrophoric powder safely , and melting tests were made in a single - phase , electric - arc furnace to determine inert gas requirements for preventing powder oxidation . Steelmaking tests were conducted in a conventional electric - arc furnace , usually by a two - slag basic procedure . Results of the research indicated that ( 1 ) pyrophoric powder can be handled safely and can be prevented from oxidizing excessively during charging and melting in electric - arc steelmaking furnaces ; ( 2 ) little , if any , more electrical energy is required for melting Cerro Bolivar iron powder per unit of contained iron than is required for melting heavy melting scrap ; ( 3 ) high - quality steel can be produced readily from high- grade iron powder , having recoveries up to 95 percent of the total iron ; ( 4 ) steel can be produced from simulated titaniferous , chromiferous , and manganiferous iron powders ; and ( 5 ) the electrical energy required for melting increases with increase in the proportion of slag - forming constituents in the furnace charge .

Jan 1, 1964

By D. R. Mathews

Electrorefined vanadium was evaluated with respect to tensile properties and the effects of interstitial contaminants in the temperature range of 77° to 273° K. The yield strength of 18,500 psi and hardness of 63 diamond pyra-mid hardness (DPH) of electrorefined vanadium are approximately equal to that of iodide crystal bar vanadium. The ductile-brittle transition temperature was found to be below 77° K, but with 0.175 weight-percent oxygen or 0.10 weight-percent nitrogen, it increased to between 123° and 190° K. With carbon content up to 0.11 weight-percent, the transition temperature remained below 77° K. The yield strength of the interstitial-containing alloys can be expressed by: au = 7.5 + 480 (pct N) + 290 (pct 0) + 280 (pct C), where au is the upper yield stress in 1,000 psi at 273° K. Profuse deformation twinning occurred in the alloys tested at 77° K. However, twinning could be suppressed by dissolved oxygen or nitrogen in excess of 0.15 and 0.086 weight-percent, respectively. Carbon, even though present in excess of the solubility limit, did not affect twinning.

Jan 1, 1965

By P. C. McWilliams

Researchers at the U.S. Bureau of Mines investigated the use of close-range photogrammetry and subsequent stereo digitizing to obtain data from rock fracture roughness profiles. The photogrammetric process yielded results that were acceptable but somewhat inferior to those obtained by a mechanical profilometer. On the basis of this study, further pursuit of photogrammetry as a data collection method in mining is proposed. Fractal geometry was investigated as a means of measuring the roughness of rock fracture profiles. Four fractal algorithms were used: divider method, modified divider method, box method, and spectral method. A comparison of the methods gave ambiguous results. Brown's modified divider method provided the best means of obtaining the fractal dimension. Shear strength estimates were obtained using the parameters of the modified divider method and Myers' Z2 measure. Because of differences in results when comparing the different ways of obtaining the fractal dimension, future users of fractals in studies of rock fractures are advised to cross-check their results carefully.

Jan 1, 2010

By J. Pasini

The Bureau of Mines has investigated novel methods of stimulating petroleum production from reservoirs in the Appalachian Region. An important consideration in applying stimulative production methods is the control and removal of solid precipitates from the boreholes of production wells. Where paraffin-base crude oils are produced, as in the Appalachian Region, the accumulation of paraffin may be particularly troublesome. Paraffin deposition is a major production problem that has confronted the petroleum industry for many years. Although considerable effort has been expended by industry and government, a suitable solution has not been found because of the individuality and complex nature of the deposits. Remedial methods used to prevent or remove paraffin fall generally into four classes: (1) Chemical, (2) physical, (3) operative, and (4) combination. Each class has many subclasses that apply to particular problems in different oil- producing areas. Recently, chemical inhibitors and the sonic pump have assisted operators in preventing and removing paraffin deposits. Because these methods are relatively new, their degree of application has not been completely evaluated.

Jan 1, 1963

By David C. Grant

In situ uranium mining offers the advantages of minimal environmental disturbance, low capital and operating costs, and reduced mining development time. It is becoming an increasingly attractive mining method for the recovery of uranium from secondary ore deposits. In order to better understand the process, a laboratory technique was developed and used to study and simulate both the chemical and physical phenomena occurring in ore bodies during in situ leaching. The laboratory simulation technique has been used to determine effects of leaching variables on permeability uranium recovery, and post-leach aquifer restoration. This report describes the simulation system and testing procedure in sufficient detail to allow the construction of the system, and to perform the desired leaching tests. With construction of such a system, in situ leaching of a given ore using various leach conditions can be evaluated relatively rapidly in the laboratory. Not only could optimum leach conditions be selected for existing ore bodies, but also exploitation of new ore bodies could be accelerated.

Jan 1, 1985

By Ann G. Kim

The U.S. Bureau of Mines applied its mine fire diagnostic method to an abandoned anthracite mine fire site in Carbondale, Lackawanna County, P A. The technique to locate fires in abandoned coal mines and coal refuse piles includes the determination of hydrocarbon concentrations in mine gases, the imposition of an underground gas flow direction, and use of a surface mapping method, to define heated and cold zones in underground coal strata. The heated zones at Carbondale were characterized by elevated methane concentrations. The results of 25 communication tests were analyzed to define 2 large (approximately 100 by 250 ft) and 5 small, isolated heated zones. An approximate correlation existed between the location of the heated zones and areas of anomalous snow melt. The correlation between the results of the diagnostic? test and subsurface temperatures was not significant.

Jan 1, 2010

By B. M. Stewart

Researchers at the U.S. Bureau of Mines conducted a long-term groundwater monitoring and site characterization program at an abandoned 10-ha, acid-producing, copper-gold tailings impoundment in north-central Washington State. The purpose was to investigate contaminant release and transport, and attenuation mechanisms in the tailings, sediments below the tailings, and gravels downgradient of the impoundment. This report summarizes the monitoring results and physical properties of the tailings, the sediments below the tailings, and the groundwater system associated with the tailings. Water samples from the vadose and saturated zones of the impoundment were analyzed for 15 constituents. Concentrations of the same constituents were determined in water samples up to 3 m beneath the impoundment and in the shallow colluvium and deep bedrock at 76, 335, and 550 m downgradient and 168 m upgradient. Constituent concentrations within the tailings are quite variable and are influenced by pH, depth of oxidation, grain-size differential (surface area), hydraulic gradient, groundwater mixing, and the presence of hardpan layers, carbonaceous material, and organic matter. Most of the metal constituents decreased to background or near-background concentrations in the farthest downgradient well.

Jan 1, 2010

By Edward L. McHugh

The appraisal of mineral resources of the Challis National Forest, Idaho, by the U.S. Bureau of Mines, was made so that the mineral resources of the forest could be appropiately considered in land use planning. Information from this study is intended to tip the U.S. Forest Service to incorporate mineral resource data into forest plans The study was done in conjunction with the U.S. Geological Survey, which released a companion report on the geology and mineral potential of the Challis National Forest in 1989. This summary report is derived from a more detailed USBM Open-File Report (MLA 6-91) that includes descriptions of mines and prospects, commodity profiles, and development cost models. Since the 1860's mines within the Challis National Forest have produced mineral commodities worth more than $590 million at current (1989) commodity prices. Identified mineral resources have a gross value of about $2 billion at current prices, including 8 strategic or critical minerals. The U.S. Bureau of Mines study identified and described 723 active and inactive mineral properties within the forest. Mineral properties with identified resources were evaluate to determine their economic significance, and an assessment was made of the feasibility of mineral development. Of the 2,516,191 acres in the Challis National Forest, about 390,000 acres were classified as having mining development interest. Commercially important mineral production, mainly of molybdenum, gold, and silver from the Challis National Forest is likely for the foreseeable future.

Jan 1, 1991