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By L. Rosato

In the past decade, as a result of increasing iron loads, Canadian Electrolytic Zinc (CEZinc) has become a pioneer in understanding the critical factors that affect the roasting of concentrates with high pyrite contents as well as those factors governing the effects of high iron loads on the leaching circuit. De-bottlenecking efforts in the roaster and acid plant section of CEZinc have given rise to a better appreciation of the impact of iron on roaster productivity. High standards for impure solution quality, zinc recoveries and residue disposal have all led to an increased comprehension of the limits of the leaching circuit and the optimization potentials with respect to iron and ferrites. In this paper, the impact of iron on the roasting and leaching circuits of CEZinc will be reviewed and special emphasis will be given to some of the more recent process optimization and improvement activities.

Jan 1, 2006

By J. C. Rudolph

"THE TOPIC on which I am speaking this afternoon is ""The Future of the Canadian Oil Industry.'' At the time of C + 100, we should take a searching look at ourselves, an honest appraisal of our achievements and a forthright accounting of our shortcomings as well as the uniquely Canadian aspects of this industry. I would like to put before you some of my views on the direction we are taking in the exploration field and in the production field. I would also like to speak briefly on some of our problems and the role of the various segments of our industry in solving these problems.First of all, let us look at the exploration picture. We are in the midst of an exploration boom. There were 133 seismic crews active in Western Canada this winter, the highest since 1957, land prices are appreciating rapidly, Canadian oil reserves increased + 16 per cent during 1966, there is a great demand for technical personnel of every kind and the whole industry, except the drilling segment, seems to be prospering. This surge of activity has its roots in two major occurrences. The first of these was the change in the pro-ration system in Alberta, the major producing province, accompanied by the change in spacing pat-terns. The proration change was designed primarily to encourage in-creased exploration and it has certainly had this effect. It has also had the unforeseen effect of put-ting everyone into what we, in the oil business, call ""elephant hunting."" In other words, the days of the development of barely economic, marginal fields are over. Oil companies today are only interested in high-reserve, high-productivity, high-quality reservoirs."

Jan 1, 1968

This paper presents the results of research aimed at proposing new solutions in the area of belt conveyor elements. Many factors, such as energy consumption costs, and operating costs of belt conveyor elements, including belts, idlers and drives have an impact on the operational costs of conveyors. The paper presents special tests of new materials for the bottom cover of an energy-saving belt conveyor, which decrease rolling resistance. It also presents large-scale in-situ tests of a high-output belt conveyor for the purpose of simultaneous measurements of various types of conveyor belts (standard vs several energysaving types) under typical operating conditions of a lignite surface mine. Improvements in materials used for the bottom belt covers, supported by specially developed comprehensive tests of the new types of belts have provided valuable results of various proposed solutions. Since the tests of belts were done at exactly the same time and in the same operating conditions, direct comparison of the results is valid and should lead to a substantial decrease in the conveyors? drives? energy consumption, which will improve the effectiveness of belt transport and minimize its negative influence on the environment.

Aug 1, 2013

By S. E. Kesler, C. M. Moore, J. C. Van Loon

The possibility that chlorine and fluorine form complexes with ore metals, thereby having a strong effect on the mobility of these ore metals during late magmatic and hydrothermal processes, suggests that the abundance of chlorine and fluorine in igneous rocks could be used to distinguish intrusions that have generated ore deposits. The simplest and most economical measure of this chlorine and fluorine is the water-leachable chloride and fluoride that is released from fluid inclusions in the rock during crushing of the sample. In order to evaluate the possible use of this technique, measurements of water-leachable chloride and fluoride were made with selective ion electrodes on samples from nine intrusive complexes. There does not appear to be any simple relation between the abundance of chloride and the presence of mineralization. Fluoride values in mineralized intrusions appear to be higher than those in barren intrusions.

Jan 1, 1973

By L. B. Kilius

The composite cathode system based on Ce0.9Gdo.1O2_,5 electrolyte with a painted cathode was used for an intermediate temperature (500-700°C) solid oxide fuel cell. This cathode system was chosen due to its excellent thermal expansion match to the electrolyte, its relatively high conductivity (115 S cm-1 at 700°C), and its low activation energy for oxygen reduction (99 kJ/mol). It was found that the decrease of sintering temperature of the composite cathode system produces a significant decrease in charge transfer resistances to a level of 0.25 SI cm2. The conductivity measurements of porous samples produced values between 40 and 88 S/cm for porosities of 30-40%.

Jan 1, 2005

By K. Aziz

The solutions to unsteady-state gas flow in a radial system have been reviewed in order to aid in the interpretation of drawdown data. It has been the practice to evaluate the time and rate conversion constants, directly or indirectly, by using reservoir data. This paper presents a method of determining these constants from drawdown data. A simplified approach to the de-termination for the various boundary conditions is presented. An example of a problem which illustrates the use of this theory appears in the appendix. UNSTEADY-STATE FLOW EQUATION The solution of any unsteady-state flow problem involves (1) the continuity equation, (2) the equation of state of the fluid, (3) the equation of fluid motion and (4) the boundary conditions. For the Darcy flow of a gas in the horizontal radial plane, the equation is when the viscosity, compressibility and permeability to gas flow may be assumed constant and the medium

Jan 1, 1963

By Gurinder Kaur

Selenium (Se) based materials find wide applications in rectifiers, solar cells, photographic exposure meters, data storage devices, xerography and anticancer agents. They are also used in the glass industry to eliminate bubbles and remove undesirable tints produced by iron. In addition, Se is highly reactive towards a wealth of chemicals that can be potentially exploited to convert Se into other functional materials such as CdSe, ZnSe, Ag2Se. Here, we report a review of structural investigations of Se based materials in glassy and nanostructured forms. Glasses having varying amounts of Se and Tellurium (Te) were doped with group IV and V elements such as antimony and tin. Structural changes accompanying the composition variation were characterized with x-ray photoelectron spectroscopy, differential scanning calorimetry and x-ray absorption near edge spectroscopy. At the same time Se-Te nanoalloys were synthesized in aqueous micellar phase using Na2SeO3/Na2TeO3 as the Se/Te source. Morphology change from nanoparticles to nanoribbons was investigated using Scanning and Transmission Electron Microscopy (SEM/TEM) techniques. Structural investigations were also done for well defined morphologies of Se based nano-biomaterials obtained in the presence of water soluble protein bovine serum albumin (BSA).

Aug 1, 2013

By J. G. Whellock, J. W. Matousek

"In spite of their importance to the economics of many metallurgical projects, the values and technical aspects of precious metals losses in smelting operations are relatively undeveloped subjects. This paper attempts to provide a condensed overview of precious metals losses in pyrometallurgy, using some of the limited production and experimental data available. It is intended for three general groups of metallurgists - operators attempting to improve recoveries, cost-accounting engineers making estimates of metal losses in new or modified smelting plants, and research engineers and students.Distribution coefficients of precious metals, the ratios of metal or matte assays to slag assays, are convenient means of comparing smelting processes and the tendencies of the different metals to enter the slag. For silver in lead blast furnaces this ratio is approximately 250;for gold and the platinum group metals in submerged-arc, electric furnaces it is 900. The ratio for gold and PGMs in converters varies with the degree of oxidation of the charge. The over-all cycle-average for industrial installations is tentatively estimated to be 35.IntroductionThe magnitude of precious metal s losses in pyrometallurgical operation s is difficult to assess. The primary producers are generally reluctant to discuss the subject. The by-product producers (the large sulphide smelters o f copper , nickel, and lead) might be more willing to disclose information, but these have precious metals in their feeds in such dilute quantities that accurate accounting is extremely difficult. It is not until numerous processing steps have been taken t hat the precious metals become sufficiently concentrated to permit acceptably accurate sampling and analytical procedures to be followed. Thus, knowledge of the precious metals contents o f the intermediate mattes and slags may simply be unavailable."

Jan 1, 1990

By Y. M. Shneerson, V. M/ Shpaer, E. E. Zhmarin, A. Y. Lapin, E. M. Vigdorchik

This paper describes studies of zinc concentrate oxidizing pressure leaching using the method of mathematical modeling. The concept of a kinetic function was taken as a basis for mathematical modeling of the leaching process. The kinetic function describes dependence of the unreacted component share OJ on the relative time x (the relative time is the ratio of the test duration and the time of complete dissolution). This kinetic function is determined in accordance with the results of batch laboratory tests. The laboratory tests have been carried out on zinc concentrate produced from Kazakhstan zinc-copper ores. Zinc concentrate consisted mainly of three types of minerals: sphalerite (70%), pyrite (13%) and chalcopyrite (10%). Oxidation reactions of sphalerite, pyrite and chalcopyrite have been considered as principal ones. The kinetic characteristics of the process (kinetic function, reaction order, activation energy, duration of complete dissolution of the concentrate components) have been calculated in the course of laboratory tests. The mathematical model was used for estimation of the main technological leaching process parameters (such as process rate, degree of metals extraction, autoclave capacity, heat balance, etc.). Mathematical modeling based on the kinetic function concept allows safe designing of metallurgical equipment and scaling the technology to industrial capacity.

Jan 1, 2004

By S. Pauly, U. Kühn, J. Eckert, I. Kaban, G. Wiehl, F. Silze

In the present work, the effect of Ga on the wetting behavior of the Cu-rich braze filler CuGa10 (wt.%) on the steel 304L was investigated. For this, the macroscopic and microscopic effects governing the wetting of pure Ga, pure Cu and CuGa10 alloy (wt.%) on the austenitic steel were analyzed and compared. Contact angle and surface tension measurements were carried out by means of the sessile drop technique and, in addition, the phase formation at the interface was determined. Pure liquid Ga spreads on 304L, which supposedly is related to the formation of intermetallic Fe-Ga phases growing into the liquid Ga. Depending on the annealing time, FeGa3 and Fe14.5Ga12 were identified. In contrast, CuGa10 as well as pure Cu show secondary wetting on the steel surface. Especially, liquid Cu prefers to spread laterally and vertically along the grain boundaries of the steel substrate. In spite of rather similar mechanisms, CuGa10 wets 304L steel at lower rate than pure Cu above the liquidus temperature.

Jan 1, 2014

By T. R. Chari

The safe-level dilution of low-level radioactive wastes in large volumes of selected granular material is proposed as an alternative method of permanent waste disposal to current Canadian practice of concentration and encapsulation. Accepting the fact that a "background level" of radioactivity exists throughout the world, the authors feel that the concept of controlled dilution of radioactive wastes to a level in keeping with "background" is a plausible alternative to current thinking on the subject and is worthy of equal consideration.

Jan 1, 1979

By J. Pepin

When using alternating current submerged arc welding (SAW) to produce pipes from microalloyed linepipe steels, it is critical to balance penetration depth and deposition rates, in order to minimize the number of weld passes while still maintaining good heat affected zone (HAZ) microstructures and properties. A series of bead-on-plate (BOP) submerged arc welds were performed on X70 steel, using different waveform variable settings (i.e., balance, offset and frequency). Weld bead cross-section profile deposition and penetration areas were measured, and both Vickers hardness and Charpy V-notch impact testing were performed. Both single electrode and tandem electrode welds were evaluated.

Jan 1, 2011

By B. Tiryaki, M. Ayhan, O. Z. Hekimoglu

Coal shearers are one of the major sources of dust and fines in underground coal mines. Despite considerable research investigations, no comprehensive in situ investigations coupled with extensive laboratory studies on the effects of drum design on generation of dust and fines have been found. It may be for this reason that many major shearer drum manufacturers persistently employ a certain drum-lacing pattern on current coal shearers, which is believed to cause excessive dust and fines in coal mines. This paper shows how respirable dust and fines are minimized under near-identical conditions when the drum lacing pattern was changed from a triple-tracking to a single tracking arrangement. A series of laboratory trials simulating in full scale the practical cutting action of tools was followed by extensive long-term underground trials during production operations in OAL (Cayirhan) Lignite mine in Turkey. The results are presented and discussed, and recommendations for proper drum-lacing in terms of respirable dust and fines are made.

Jan 1, 2002

Proper water and thermal management is essential for obtaining high performance of Proton Exchange Membrane Fuel Cells (PEMFCs). A steady, two-dimensional water and thermal management model was developed, aiming at considering pressure drop, open circuit voltage variation with stack temperature, water vapor effects on membrane conductivity, which made the model physically more reasonable and more suitable for various operating conditions. The model could predict the distributions of a series of important parameters along the flow channel, and thus the effects of various operating and design parameters on the fuel cell performance could be investigated easily by numerical trial-and-error method. The modeling results compared well with the available experimental results from the literatures. The results also showed that the humidification is crucial for the performance of PEMFCs. The model could be a very useful engineering tool for the optimization of PEMFCs.

Jan 1, 2005

By Alexander Smith

"The Silver Standard mine is 6 miles by road northwest of New Hazelton, B.C., a small town on the northern line of the Canadian National Railways some l 75 miles northeast of Prince Rupert. The deposits lie on the western slope of Glen Mountain (elevation 2,100 feet), with the main adit, mill, and campsite at 1,300 feet. The deposits were found in 1910, shortly after the area had been swept by forest fire and during a period of prospecting activity spurred by the construction of the railway. Crude ore only was shipped until 1918, when a 50-ton gravity mill was built which operated until 1922. Gross value of production of this period, at present metal prices, was about $1,000,000.In 1947 the present company was formed and a 50-ton flotation mill installed. Production from 1948 to 1955 has been in excess of $10,000,000, and net smelter returns about two-thirds of this amount. More than 60 per cent of the production and 80 per cent of the profit have come from one vein, No. 6. On the 1,300-foot level this vein had an ore section 375 feet long and 2.5 feet wide, averaging 0.18 ounces gold, 85 ounces silver, 10 per cent lead, and 16 per cent zinc.The mine workings follow a simple pattern. A series of parallel veins, striking northeast and dipping southeast, are numbered from 0 to 12, starting at the northwest. They lie within a zone trending south 70 degrees east, and the distance between Nos. 0 and 12 veins is about one mile. Recently several cross-veins, dipping northeast, have been found between Nos. 8 and 12. They are apparently of the same type as the others, though they may not have the same structural controls. They could be an important new source of ore.The mine has been developed principally by crosscut adits at the 1,500- and 1,300-foot levels and a 510-foot shaft with levels at I, 150, 1,000, ·and 850 feet. Drifts and crosscuts total 17,000 feet, chiefly on Nos. I, 4, 6, 7, and 8 veins. The drifts are stoped by shrinkage, top shrinkage rill, cut-and-fill with resuing, or open stope methods. The mill produces a lead-silver-gold-copper concentrate and a zinc concentrate, with indicated recovery of more than 96 per cent (4)."

Jan 1, 1949

By S. Balideh

A good understanding of the behavior of rock helps us to make more informed decisions regarding geo-structures. Engineers need accurate equations to calculate the strength and deformation of rock before and after failure. Previous studies explain the failure of rock to ultimate strength, and laboratory tests adequately determine the ultimate strength and deformation modulus of rock. However, there are few comprehensive equations to determine the post-failure strength and deformation of rock. Previous work shows that the post-failure behavior of rock depends on the behavior of the broken rock particles after failure. The following question is then posed: How can the post-failure behavior of rock be determined by the behavior of broken rock particles? In order to answer the question, this study pursues three objectives: (i) to explain the behavior of broken rock at low confining pressure; (ii) to estimate the behavior of broken rock via the extrapolation of scaled laboratory testing; and to suggest a procedure (iii) to outline the post-failure behavior of a rock mass at low confining pressure commensurate with the behavior of broken rock in a rock mass.

Aug 1, 2013

By Ye Chen, Jianhua Chen, Xianhao Long, Qingxia Liu, Zhenghe Xu

"It is crucial to understand the mechanism of the collector interacting with the mineral surface in the presence of water molecules, which could influence the relaxation and electronic properties of sulphide mineral surface due to the proximity effect for narrow band gap of semiconductors. The adsorptions of three typical collector molecules (xanthate, dithiocarbamate and dithiophosphate) on the sulphide mineral surfaces in the absence and presence of water molecule have been simulated by density-functional theory (DFT). The calculated results show that the adsorptions of collectors on clean mineral surface in vacuum are not in agreement with the observed flotation behaviours. The presence of water molecules has a great influence on the adsorption of collectors. The analysis of density of states of the mineral surface atom suggests that the adsorption of water molecules could influence the electronic properties of mineral surface and consequently influence the adsorption between the surface and the collector molecule.INTRODUCTIONIn the separation of multi-metal sulphide ores, the selectivity of a collector is a key factor for the efficient recovery of the aimed mineral. Xanthate, dithiocarbamate (DTC) and dithiophosphate (DTP) are the most common collectors used in the flotation of sulfide minerals. Generally, xanthate exhibits powerful collecting property but lack of selectivity. While dithiophosphate and dithiocarbamate show the good selectivity in the lead and copper sulphide mineral flotation. The mechanisms of these collectors interacting with the sulphide mineral had been attracted many attentions and several mechanism based on experimental results had been reported (Chander & Fuerstenau, 1974; Fuerstenau, 1990; Raju & Forsling, 1991; Crozier, 1991; Bradshaw, Cruywagen & O’Connor, 1995; Guler, Hicyilmaz, Gokagac & Emekci, 2006). However, the micro-mechanisms of the selectivity of these three thiol collectors on different sulphide mineral surfaces are not fully understood."

Jan 1, 2016

By H. S. Fowler

The Consolidated Mining and Smelting Company has been in the business of mining and exploration since its incorporation in 1906. The Company has reports written as early as 1890. Consequently, its files contain a very large number of reports, and also of maps, of ail descriptions. REPORTS Before describing the filing of maps, a brie{ note on our general system of filing reports will perhaps clarify the discussion. Reports of a non-periodic nature, primarily those based upon examinations by field engineers, are separated from all other data and filed in what we know as the Mine Series System. Each property on which reports are written is given a serial number, known as the Mine Series Number. This serial number is assigned at the time the first report is filed and it remains permanently identified with the property, regardless of its state of activity. Our mine series numbers now total over 5,000. The serial number for a property may be found by referring to an alphabetical index of properties. MAPS We found it necessary to divide maps into two groups: (1) Maps of properties (2) Maps of areas

Jan 1, 1944

By Z. Tang

A collaborative project was performed between NRC Institute for Fuel Cell Innovation and MagPower Systems Inc, to develop a cost effective fabrication process to manufacture the anode for magnesium-air fuel cell with improved performance. A novel fabrication process was developed, which resulted in a porous microstructure with increased surface area, instead of the traditional solid structure. This porous anode greatly increased power density in the magnesium-air power source. This fabrication process is very simple and cost effective. Especially, this process makes it convenient to incorporate different alloying additions, as well as hydrogen inhibitor and electrolyte management additive into the anode. The anode composition was designed so that micro galvanic cells were formed as current is drawn out of the fuel cell, and resulting increased dissolution rate of Mg. It is feasible to incorporate hydrogen inhibitor and electrolyte management additive into the porous anode, and the anode with some kinds of inhibitors exhibited improved electrochemical performance. This paper describes the microstructure and electrochemical performance of anodes with designated porous structure and alloying additions. Furthermore, quantitative kinetics analysis of the obtained I-V curves and electrochemical impedance spectroscopy were carried out to clarify the mechanism.

Jan 1, 2005

By Y. Lizotte

"This paper examines the application of blasthole sloping to narrow vein mining in Canada, for ore deposits where widths are less than two metres. While the technique has now been utilized for more than ten years, it remains in the experimental stage and on-site testing is necessary for its adoption at new mining operations or in differ¬ent geological settings. It is intrinsically a safer method than other narrow vein methods in current use.The investigation describes the main operating parameters for mines recently surveyed. The criteria for method applicability are defined and the problems encountered are studied. It is concluded that blasthole sloping for narrow vein mining is a viable modern method which promises to gain popularity and that emerging fragmentation technology and blasting research can be used to further increase applicability of the stoping method."

Jan 1, 1991