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By Eugene Barsky

"At present, theoretical concepts of gravitational separation processes are mainly limited by the study of the interaction between a flow and a solitary particle. Then the main conclusions of this analysis are applied to a mass process. However, this analysis is absolutely insufficient, because some elementary phenomena such as the ingress of coarse particles into the fine product output and vice versa cannot be interpreted from its standpoint. It is also impossible to predict the results of the classification of a material with a specific granulometric composition on a specific apparatus on its basis.In the present paper, an extended model of the process is suggested. The model is based on the behavior of all the particles of a specific narrow size class, and not on that of an individual particle. Similarity criteria of the process, which were empirically derived previously, are obtained from the analysis of this model.INTRODUCTIONIn case of gravitational separation, a part of solid phase moves, as a rule, vertically upwards with the flow, while another part settles against the flow. This flow is extremely complicated and chaotic due to various random factors. Among these factors are mass interactions of particles with each other and with the apparatus walls, non-uniform character of concentration and velocity fields, turbulent vortices and local fluctuations, real particles shape difference from spherical one, etc.Particles rotation results in a transverse force (Magnus' effect). At the motion of a non-rotating particle in a non-uniform velocity field, a transverse force also arises (Saffman's effect).A great number of publications have been devoted to the account for all these factors in two-phase flows in recent decades. Very complicated models have been developed, but the problem has not been completely solved as yet [1, 3].At the same time, simplified models of the behavior of a solitary particle in a flow are being developed. Despite their schematic nature, such models often prove to be useful for establishing general laws of the process and its similarity criteria [1]."

Jan 1, 2016

By R. Darlington, S. Ji

"High pressure die casting is a promising process to make thin-wall components with high dimensional accuracy and excellent surface quality. However, the non-uniformity is one of the important features in castings. The inhomogeneity in tensile properties and microstructural characteristics were studied for the castings with different thicknesses made by high pressure die-cast Al-Mg-Si alloys. For the local mechanical properties in the die-castings, the casting skin provided the highest, whereas the casting centre provided the lowest yield strength, UTS and elongation. The yield strength, UTS and elongation were significantly decreased towards the casting centre. The microstructural inhomogeneity is characterised by the segregation of coarse fragmented dendrites, the reduction of solute concentrations of Mg and Si, and the increase of porosity level from the surface to the centre of castings. The growth velocities of eutectic a-Al phase estimated using the Jackson-Hunt model confirm that the growth variation is larger in the thin castings than that in thick castings.INTRODUCTION Inhomogeneity is an inherent characteristic in as-cast microstructures of a variety of alloys because of their non-uniform chemistry, microstructure, defects, topology and the resultant mechanical properties in the different ranges of localization (Campbell, 2003). Generally, three types of inhomogeneities characterise casting microstructures, which include (a) the casting defects of shrinkage and gas porosity, misruns, cold shuts, inclusions, hot tears and hot spots; (b) the non-uniform microstructure from the surface to the centre of castings; and (c) the non-uniform microstructure from the dendrites grown from primary solidification and the structure formed during the subsequent eutectic solidification in inter-dendritic regions. The chemical composition and the morphology between the primary dendrites and the inter-dendritic eutectics also differ in the as-cast microstructure. Obviously, the inhomogeneity is different in the castings obtained from different casting processes."

Jan 1, 2018

By F. -Z. Ji, G. A. Irons, M. Barati, K. Coley

The use of oxygen in electric arc furnace steelmaking is tied to the use of fossil fuels, and slag foaming. The current work examines the kinetics of carbon injection into EAF slags especially the saturation injection rate and available reaction area in the slag foam. Based on individual rate data and experimental gasification rates of carbon in the slags, the available reaction surface area in the gas bubbles was found to be around 1900¬4700 cm2.kg-slg-1 for carbon injection into EAF like slags at appropriate injection rates and steel making temperatures. The ratio of number of bubbles to number of particles is 1 to 17 and the weights of carbon per unit reaction area are 0.001-0.008 gC-cm-2. Using the relationship between active reaction area and x supplied in this study, the gasification rates of carbon in slags can be estimated with gas-slag interfacial reaction rates.

Jan 1, 2004

By A. H. Winckers

"The Sullivan Mine and Concentrator are owned and operated by Cominco Ltd. and are located in the Rocky Mountain Trench, in Kimberley, British Columbia.The Sullivan Concentrator commenced operation in 1923 at approximately 2,500 tons per day. The concentrator was enlarged in several stages and by 1945 was treating 8,500 tons of ore per day. In 1949, the capacity of the concentrator was expanded to 10,000 tons per day with the completion of the sink and float plant, the installation of the rod mill, an underground crushing plant and a 4-mile underground and surface electric railway from the underground crushing plant to the concentrator. Throughput now averages 7,000 tons per operating day, or 2,400,000 tons per year.The concentrator operates 7 days per week, 24 hours per day while the underground crushing station operates 5 days per week, 24 hours per day. The ore is essentially a replacement deposit in argillaceous quartzite of Precambrian age. The ore bodies are massive deposits consisting of fine grained mixtures of sulphides, sometimes interbanded with the country rock and varying widely in their content of lead, zinc, iron and silicates. The principal economic minerals are galena and marmatite (7 ZnS:FeS). Iron is mainly present as pyrrhotite, and to a much lesser extent as pyrite. The intimate association of these sulphides necessitated the development of a successful differential flotation process before the ore could be beneficiated profitably."

Jan 1, 1981

By J. Beddoes

Many high strength aerospace alloys undergo solution heat treatment (SHT) and aging to develop precipitate strengthening. Most simply, SHT involves an isothermal hold in a single phase region followed by relatively rapid cooling to develop a super-saturated solid solution from which precipitates form during aging. However, subsequent properties are sensitively dependent on the details of the SHT, which frequently also serves a homogenization function. Altering the details of the thermal cycle during SHT significantly improves the properties attained during aging, as presented by examples of SHT design for titanium aluminide intermetallics, polycrystalline and single crystal superalloys, and 7075 aluminum.

Jan 1, 2010

By S. Banisi, M. Pourkani, A. R. Laplante, A. Partoazar

"Canadian experience in industrial modeling of grinding, classification, and flotation kinetics was applied at the Sarcheshmeh copper mine, which processes 40,000 t/d of ore at 0.9 % Cu, in an effort to improve capacity and metallurgical performance. Mcivor's functional performance analysis was applied to ball mill cyclone circuits to maximize circuit capacity. Plitt's cyclone model was applied to predict how apex wear would affect classification performance, as part of a predictive maintenance program whereby the optimum wear period is determined for cast iron apexes. The flotation flowsheet was improved using Agar's optimization criteria. The impact of these technologies has been nothing short of spectacular, with an improved capacity of 1 S to 20""/o, and increased recoveries.1-IntroductionThe Sarcheshmeh copper ore body, which may rank as third or fourth largest in the world, contains 1 billion tonnes averaging 0.90 % copper and 0.03 % molybdenum. It is located southeast of Iran and has been processing 40,000 t/d of ore since 1982. The mine produces 100,000 tonnes of copper and 2,200 tonnes of molybdenum concentrate per year. After three stages of crushing, the ore with a Fso of 12. 7 mm is fed to 8 parallel ball mills in closed circuit with cyclones to produce a product 70""/o finer than 7 S microns. The concentrate of the first stage of flotation is reground and the tailings constitute the main component of the plant final tailings. A concentrate with an average grade of 31 % Cu is obtained after cleaning and re-cleaning stages. Total recovery of the plant varies between 83 and 87 % depending on the operating conditions and ore type.To improve the overall performance of the plant, it was first decided to evaluate the performance of grinding, classification and flotation. Measures were then taken to improve performance using the following criteria: (i) The improvements should be of the types that have resulted in significant improvements in other plants (e.g. Shannon et al, 1993); and (ii) The proposed improvements must be achievable with the manual operation presently used at Sarcheshmeh. The outcome of this study could also help in making decisions on the implementation of automatic control systems in the Sarcheshmeh copper mine."

Jan 1, 1998

By P. Duran

The metallurgical gas handling system at Chagres Smelter, like that of many smelters, can be the limiting constraint to processing more concentrate through the smelter. Mass and energy balances for the metallurgical gas handling system processing off-gases from the flash furnace and Peirce-Smith converters have been used by both operations and process engineering groups to help evaluate different operational scenarios in which the use of the installed capacity could be maximized and/or an operational strategy can be change with the purpose of removing a bottleneck or justifying an investment to relieve a constraint in the gas handling system. The present work describes the development of these process balances that were carried out in Exce®. The results were validated with operational data and, subsequently, some cases of industrial interest were simulated, detecting some conditions that were limiting the operation due to the present installed capacity in the Chagres Smelter.

Jan 1, 2007

By P Hulteberg

In this article, an integrated catalytic reactor design approach to produce PEMFC-quality hydrogen is evaluated. The design is based on a high level of heat exchanging perfonned internally, highly active noble metal catalysts and a woven wire mesh catalyst support system. It consists of an integrated steam refonner and a catalytic burner section, a water gas shift section and a preferential carbon monoxide oxidation section. The reactor design is described and experiments perfonned to evaluate the two reactors built are reported. The two reactors have a maximum output of 3 Nm and 10 Nm3 hydrogen/h respectively. In the larger unit, a total of six fuels, three gaseous (methane, natural gas and liquid propane gas) and three liquid (naphtha, ethanol and methanol), were evaluated. The larger unit was also used to investigate how variations of parameters such as steam-to-carbon ratio in the steam reforming part of the system and the relation between oxygen and carbon monoxide in the preferential carbon monoxide oxidation affect the reactor perfonnance. The smaller unit was used, after implementing automatic control, to run a system life time test for 480 h. The refonner system perfonned according to specifications on almost every aspect.

Jan 1, 2005

By Jun Deng

The aim of this paper is to study the scientificity and reliability of three coal gas indices used to predict coal fire disasters, namely Graham?s ratio, CO/CO2 ratio, Litton ratio and their different characteristics and service conditions. Data from a programmed temperature experiment were applied to check their veracity and accuracy. Each index performed well in detecting the level of a fire. We conclude that it is better to redefine the definition through experimentation before applying a given index. Integrated analysis of the results can provide reliable reference data for predicting spontaneous combustion of coal.

Aug 1, 2013

By G. Cailletaud, I. Guillot, D. Larouche, R. Martinez, D. Massinon

The precipitation of Al2Cu particles in a 319 T7 aluminum alloy has been modeled. A theoretical approach enables the concomitant computation of nucleation, growth and coarsening, based on an implicit scheme using the finite differences. The equation of continuity is discretized in time and space in order to obtain a matricial form. The inversion of a tridiagonal matrix allows us to determine the evolution of the size distribution of Al2Cu particles at t + dt. The fluxes of solute in-between the boundaries, as well as the ones at the boundaries, are computed in order to respect the conservation of the mass of the system. The main results of the model are compared to TEM measurements. Simulations provide quantitative features on the impact of the cooling rate on the size distribution of Al2Cu particles in good agreement with the TEM measurements. This metallurgical model is integrated into FEA software in order to perform mechanical computations. This kind of multiscale approach allows new perspectives to be investigated in the process of designing cylinder heads. It enables a more precise prediction of the microstructure, its evolution as a function of continuous cooling rates and its impact on the integrity of the structure.

Jan 1, 2015

By G. A. Moruzi

Two sulphide dust secondacy explosions have occurred in the mines of the SUdbury operations of Falconbridge Ltd. during the past 18 months. 'Ihe main similarity between the occurrences is that they both happened in vertical crater retreat blasthole stopes. A relatively high p:,v.tier factor was noted in both instances. other details are enumerated and examined, as well as some results of tests done by Noranda Research on company ore samples.

May 11, 1988

By Glen Robertson, Jeff McLaughlin

"The Clarabelle Mill rock tailings have the potential to generate sulphuric acid through chemical and biological oxidation of sulphide minerals. Current rock tailings assay between 0.80 -1.40 %S, with sulphur occurring principally as coarse pyrrhotite. Acid generation within the tailings area can be substantially reduced by segregating pyrrhotite rich tailings in a submerged storage area and by depositing only low sulphur rock tailings in exposed areas. Laboratory tests confirmed that low sulphur tailings could be produced by flotation at reduced pH with a small xanthate addition. A plant test was conducted to evaluate the production of low sulphur tailings in conjunction with INCO's continuing commitment to environmental protection and progressive decommissioning of the metallurgical site.During the plant evaluation, approximately 5% of the mill rock tailings were reprocessed in a line of 100 tt3 Denver flotation cells. Tailing grades below 0.40% S were easily achieved through operation at pH 6 -7, with xanthate addition (dosages up to 0.02 lb/ton) and 10 -15 minutes of nominal retention time. Froth depths between 1 -3 inches combined with relatively liberal amounts of frother were required to pull the lightly mineralized froth into the concentrate which averaged 11% sulphur and less than 5% mass recovery. In addition, three field lysimeters were each filled with two hundred.ton bulk samples of low sulphur tails (0.35% S), standard rock tailings (0.98% S), and mill total tailings (2.30% S) for long term monitoring. The implications for full scale plant design, tailings area decommissioning, the possibility of increased nickel recovery and preliminary field lysimeter data are discussed."

Jan 1, 1994

By C. Campero, C. Nicolau, L. Pagliero

The Chilean Congress has recently promoted desalination as a solution to meet the mining industry’s growing water demand. However, this rapid expansion of desalination infrastructure comes with trade-offs. This includes a significant energy cost for treatment, as well as socio-environmental impacts on indigenous communities, tourism, fisheries, and the marine ecosystem. This paper advances a regional-scale model for analyzing competing trade-offs through a case study in the Antofagasta mining region of Chile. Through geospatial data analysis in ArcGIS, new desalination infrastructure investments supplying water to mines are overlain with features of concern raised by communities during the environmental impact assessment (EIA) process, such as national parks, fisheries and exploitation areas for benthonic resources. The resultant model provides a test-bed for analyzing the cumulative effects associated with desalination expansion and for investigating scenarios to mitigate negative social-environmental impacts. The model simulates alternative scenarios for desalination locations and pipeline routes according to competing constraints (i.e. to minimize cost and energy constraints while also avoiding ecological and social hotspots). The ultimate contribution of the work is a demonstration of how the proactive adoption of a regional-scale infrastructure planning might have led to different desalination investment decisions. INTRODUCTION Chile represents the largest producer of copper globally, and holds approximately a third of the world’s estimated copper reserves. However, access to water represents a major constraint to industry expansion and creates conflicts with competing water users (Aitken et al., 2016; Côte et al., 2010). Recently, the Chilean Congress has promoted desalination as a solution to meeting the industry’s growing water demand, which is likely to lead to significant growth in desalination infrastructure to support large-scale mining projects that extract freshwater over a rate of 150 l/s1. By most recent projections, the Chilean copper mining sector is set to increase seawater use by 230% by 2029 (Faversham House Group Ltd, 2019). By the year 2015, Chile had 11 projects serving the mining industry and there are at least other 12 planned plants (Cochilco, 2015). While the use of seawater allows continued expansion of the sector without depletion of scarce underground aquifers, it is nonetheless accompanied with important socio-environmental drawbacks. One such challenge with desalination is the associated energy costs, expressed, both economic and environmental (e.g., CO2 emissions). This includes the energy required for reverse osmosis treatment facilities, as well as to pump water to inland regions at high elevations around 3.100 m.a.s.l in Chile. (Dixon, 2013; Knops et al., 2013). Additionally, the impacts of desalinated water use on flotation chemistry are generally poorly understood, necessitating the need for further research into the impacts, both positive and negative (Cisternas and Gálvez, 2018; Liu et al., 2011).

Jan 1, 2019

By József L. Margitfalvi

Different Au/MgO catalysts modified with Mn, and Fe were prepared by precipitation-deposition. The catalysts were characterized by XRD, FTIR, Temperature Programmed Reduction (TPR) and CO chemisorption and were tested in CO oxidation in the temperature range of 243-523 K. The catalytic tests using both Temperature Programmed Oxidation (TPO) technique and time on stream (TOS) experiments revealed the high activity of catalysts prepared. In TPO experiments the modification by Mn significantly increased the activity above 300 K, however in the subambient temperature range the activity decreased considerably. Catalysts modified by iron did not show any decrease in the activity below 300 K, while the activity at high temperature increased significantly. Catalysts modified by Mn, Fe showed higher activity, selectivity and stability in preferential CO oxidation, carried out in the presence of hydrogen than the unmodified Au/MgO catalysts. Results of in situ FTIR spectroscopy on both the base Au/MgO and the iron modified catalyst unambiguously revealed the formation of ionic gold in the presence of CO/O2 mixture. The formation of this species was strongly hindered in catalyst modified by manganese. Results obtained strongly support the need for the formation of "metal ion - metal nanocluster" ensemble sites. These sites are involved in the activation of the CO molecule prior to its reaction with atomic oxygen. It is suggested that at subambient temperature these ensemble sites contain mainly ionic forms of gold, while at higher temperature iron or manganese ions are involved in CO activation.

Oct 1, 2003

By Balmer Neilly

To one with so little experience in matters pertaining to currency, international finance, and foreign trade, this is surely an ambitions venture on my part. However, this is a subject of prime importance to all seriously minded Canadians and, if we are to obtain any clear understanding of the factors involved, we must study the facts and debate such points as may remain at issue. During the last few years, the world' s better known economists have described the gold standard in all its ramifications and in such detail as to leave many of us even more confused than before. If we, then, are to acquire any real conception of its meaning and use, I think we must reduce it to its fundamentals and start from there. To my way of thinking, gold in ? trade and commerce is the symbol of honesty. When you seek to discharge a debt by tendering paper you hand the recipient an I.O.U. which may or may not be good, for the purchase of goods or services to the extent of its face value. When, however, you discharge a debt by the payment of gold, it constitutes a complete and final discharge. There are no reservations - no ifs and ands - and the transaction is definitely closed to the satisfaction of all concerned. Gold, then, is evidence of accumulated and transferable wealth that is immediately acceptable in practically every part of the world. However, there is not nearly enough gold to meet the demands of world trade, and. many years ago this deficiency gave rise to what we now describe as our banking system.

Jan 1, 1949

By M. Fiset, D. Belley

"To better understand the wear process of various materials that may be used as blades on snow removal equipment, the first step is to evaluate the influence of the load applied and the moving speed on road wear rates of one type of steel and three types of polymers. While the behavior of steel conforms to Archard's law, wear rates of polymers increase to a power of ex of the load applied according to a model implying that the wear of these materials is due to fatigue. The wear rate of some of the polymers varies considerably in terms of speed, unlike the steel. The wear resistance of some of these polymers outclasses the steel tested as long as the speed is not too great. They, therefore, present interesting alternatives for snow removal on more fragile surfaces such as sidewalks and zone made of inter-block slabs.IntroductionSince the dawn of the Industrial Revolution, the massive use of machines has brought with it a number of different problems regarding wear. Snowplowing roads, parking lots and sidewalks is an activity that generates enormous expense in a country such as Canada. To better understand these wear processes and in the hope of stimulating new approaches designed to reduce the costs related to this sector of activity, this paper presents the behaviour of several materials (steel, polymer and rubber) as they wear on an asphalt-fines matrix surface lubricated with water. Also discussed is the effect of various parameters such as the load applied and speed."

Jan 1, 1990

By J. J. Jonas, G. R. Stewart, A. M. Elwazri

Two important parameters for dynamic recrystallization can be derived from the changes in the strain hardening rate: the critical strain for initiation of dynamic recrystallization and the point of maximum softening. In this work, these values are determined from the flow stress-strain data obtained in continuous compression testing in the range 900-1100°C. The resulting strains are used to calculate a kinetic model of dynamic recrystallization for two materials: 304 austenitic stainless steel and a hypereutectoid plain carbon steel. The mechanical parameters used to define the proposed model are confirmed with quantitative metallographic analysis of the recrystallized microstructure.

Jan 1, 2004

By F. Logsch, H. Pempel, J. Markowski, P. Ay

"Due to the European Directive 2000/53/EC on end-of-life-vehicles, from 2015 on more than 95% of car materials have to be recycled. In order to recycle the materials back into the economic cycle, it is necessary to produce products with high quality and purity.Plastic components in cars, which are coated with metals by vapour deposition or electroplating, have a wide circulation (e.g., as cladding panel or trim strip for interiors and exteriors). In the end-of-lifevehicle recycling process, these plastic-metal composites are not considered in usual technologies (car shredder) and are not separated from Automotive Shredder Residue. These parts can be separated by optical or HF-detection sorting and then introduced to a specific treatment.Experiments with a specially developed bioleaching configuration showed that the thin coatings, which consist mainly of copper, nickel and chromium, can be removed efficiently from the polymer base materials by a bioleaching solution with Acidothiobacillus ferrooxidans as a leaching agent. The solution used was produced in special fermenters with a 9K-nutrient salt media. During the bioleaching process at 35°C maximum temperature, most of the copper is dissolved and the other metals accumulate as metal sludge. The bacterial cultures based on A. ferrooxidans are robust and resilient.After a 48-hour bioleaching period while the composites were stirred regularly with ventilation, the plastic particles were completely free from metallic coatings. The metal components are separated for further use: undissolved components (mainly Ni and Cr) are separated by decantation of the solution; dissolved copper recovey is carried out by cementation of copper. The cementated solid contains ~98% Cu, along with small amounts of other metals.With the bioleaching process, good separation and re-utilization of the metallic coatings is possible. The cleaned plastic parts were prepared by compounding for new applications with injectionmoulding."

Jan 1, 2016

By F. C. Robles Hernandez

This paper presents the results of the electromagnetic semi-solid treatment of the 319 aluminum foundry alloy, Various levels of structure modification were achieved controlling the AC current used to create the Electromagnetic Field, thus manipulating the intensity of the field, The level of grain refinement, partial modification of the Al-Si eutectic, as well as cellular dendrites were observed, A quantitative analysis of the structure was performed using Image Analysis (IA) techniques. In addition a novel Thermal Analysis methodology was developed for the on-line determination of the microstructure modification level.

Jan 1, 2004

By P. Trudel, M. A. . Cloutier

This lithogeochemical study demonstrates that the Gilman and Blondeau Formations in the Chibougamau area belong to a subalkaline suite of tholeiitic affinity poor in potassium. The Gilman Formation is composed mostly of basalts, with subordinate andesites and rare dacites, while the Blondeau Formation comprises all lithologies of the basalt-andesite-dacite-rhyodacite-rhyolite ensemble. Both AFM and Harker variation diagrams show that all these rocks originated by differentiation from the same magma reservoir, and are related to one volcanic episode, This study did not, however, identify hydrothermal alteration zones useful for regional geochemical prospect ion.

Jan 1, 1984