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By P. H. Agson Gani, T. Sitorus, N. P. Widodo

"PT ANTAM UBPE Pongkor underground mine use blasting to develop its tunnels which will cause poisonous and dangerous gases trapped inside mine. To analyze this case, a study of mine ventilation, the dispersion of carbon monoxide (CO) gas concentration and diffusion coefficient is commenced. At the end, the re-entry time formula will be determined. Results indicate that this study is site specific and could only be applied in the place this study executed. The aim of this study is to be further developed by applying Principal Component Analysis (PCA) to find a universal re-entry formula. KEYWORDS Mine Ventilation, Re-Entry, Smoke Clearing, Diffusion Coefficient, Carbon Monoxide Gas, Gas Dispersion INTRODUCTION Pongkor underground mine is using cut and fill as its mining method. Thus, its development and production processes require blasting to develop its tunnel. This process caused poisonous and dangerous gases spread and trapped inside the mine, one of them is carbon monoxide (CO) gas. CO is formed in an unbalanced reaction of explosives detonation and could be the cause of headache, blackout and death to people who inhale CO at certain concentration (McPherson, 2011; Hartman, Mutmansky, Ramani, & Wang, 2012). Mine ventilation system is installed in the mine to resolve this problem. Mine ventilation play an important role to disperse CO gas by absorb the poisonous/dangerous gases and deliver clean air into mine. The important parameter is diffusion coefficient, because diffusion is affecting particulates or gasses spreading from its sources throughout the mine. Diffusion coefficient is the total diffusion in axial direction of turbulent flow mainly by convection of bulk motion, advection and eddy diffusion, while the effect of molecular diffusion is appreciably negligible (Widiatmojo et al, 2015). Taylor (1953, 1954) develops a theory about the dispersion by inducing a slow stream of solvent into a capillary tube. Taylor used Reynolds assumption of radial diffusivity to be analogous with the transfer of the matter in turbulent flow as well as the transfer of momentum and heat. Then, Taylor proposed the formula of diffusion coefficient, D (m2/s), against pipe diameter and turbulent shear velocity are as follow:"

Jan 1, 2019

By Larson. William

What is Lunar In-Situ Resource Utilization (ISRU)? ISRU involves any hardware or operation that harnesses and utilizes ?in-situ? resources to create products and services for robotic and human exploration In-Situ Lunar Resources ???Natural? Lunar Resources ??Discarded Materials Lunar ISRU Products and Services ??Excavation, Site Preparation, and Outpost Deployment/Emplacement ??Mission Consumable Production ??Outpost Growth and Self-Sufficiency Benefits of ISRU ??Increased science and exploration hardware (instead of consumables) ??Increased safety, crew exploration time, and self-sufficiency ??Technology spin-in/spin-offs help recycling on Earth & space economy

May 1, 2009

By B. Konda, R. Lauer, D. Camilucci, D. Gladwin

"Income based taxes are significant cost elements to be considered in evaluating investment in new mine development. This paper presents the results of comparative analysis of effective income-based tax rates for mining in the Northwest Territories (NWT), selected Canadian provinces and international jurisdictions. The study was done as background to a review of royalty regulations for the NWT. ObjectiveThis paper presents results of comparative analysis of effective mining royalty1 rates, and combined effective mining royalty and income tax rates on selected mine models for the Northwest Territories (NWT), with those for several other jurisdictions in Canada and abroad which compete with the NWT for mining investment.BackgroundThe February 27, 1995 federal budget directed the Department of Indian Affairs and Northern Development (DIAND) to proceed with a comprehensive review and amendments to northern natural resource management legislation in order “to increase revenues and ensure a fair return to the Crown.” DIAND is responsible for the administration of the Territorial Lands Act, and its regulations.The Territorial Lands Act gives the Governor-in-Council the authority to “… make regulations for the leasing of mining rights in, under or on territorial lands and the payment of royalties therefor,…”. In the NWT, the Canada Mining Regulations (CMR) provide for the disposition of mineral rights for most minerals, other than coal, petroleum and related hydrocarbons, in return for the payment of a royalty to the Crown.As part of this review of the NWT mining royalty regime, several computer mine models were developed and tax regimes in a number of jurisdictions were analyzed. Effective mining royalty rates, and the combined effective mining royalty and income tax rates were compared across the jurisdictions. The results presented in this paper are a part of the background work done in preparing a discussion paper on proposed changes to the NWT mining royalty that is expected to be released for public consultation in the very near future."

Jan 1, 1997

By Tim Watson

Andacollo Hypogene Project ?Overview Project description: Sulphide copper concentrator Throughput:55,000 tpd Location: Approximately 50 km from La Serena Elevation: Approximately 1,000 m ASL Start feasibility study: July 2005 Start of construction: May 2007 Construction completion: December 2009 Final cost(1,2,3):435 Million US $ (1) Excludes third party costs, 220 kV power line (2) Cost is based on a Chilean Peso to US Dollar foreign exchange rate of 535 to 1 (3) Does not include US$40.3 million for the Elqui River Pipeline Project or US$8.0 million for the stock pile cover

May 1, 2010

By G. P. Demopoulos

The solubilities of calcium sulfate in HCl-CaC1z-H20 solutions up to 100°C were successfully modelled with the aid of OLI software after bringing proper modification to it. Modelling, more specifically, was carried out with the help of the Environmental Simulation Program, V-6.6.0.4 (www.olisystems.com). New model parameters were obtained by regressing the solubility data. A private databank was established by adding the newly defined model parameters and the calcium sulfate hemihydrate phase that is not included in the original OLI database. The McGill-modified OLI software was successfully applied not only to modelling solubilities but also the transformation of the various CaS04 phases, namely dihydrate, hemihydrate and anhydrite. In this paper, the modelling methodology will be discussed along with a comparison of the capabilities of the newly developed model vs the original OLI model.

Jan 1, 2005

By P. Rosario

"Industry practice for high-pressure grinding roll (HPGR) assessment and sizing relies on tests using pilot-scale machines with 0.7–1.0 m roll diameters. Typically 1–10 t of sample are required, depending on the level of study and resource complexity. This is challenging during early-stage development, which hinders incorporating HPGR into designs. With support from the Canadian Mining Industry Research Organization, researchers at the Norman B. Keevil Institute of Mining Engineering at The University of British Columbia developed bench-scale piston–die press tests (PPTs) that correlate to pilot- and full-scale HPGRs. This paper describes a new regression model to estimate the HPGR-specific throughput rate using both PPT results and an HPGR database. A case study is presented to show how the current PPT method is used for engineering studies. ¦ KEYWORDS Empirical modelling, High-pressure grinding roll (HPGR), Piston–die press test (PPT), Sizing and scale upRÉSUMÉ La pratique en vigueur dans l’industrie concernant l’évaluation et le calibrage d’un cylindre de broyage à haute pression (HPGR, de l’anglais high-pressure grinding roll) dépend d’essais menés à l’aide de machines à l’échelle pilote dont les diamètres de bobine sont de 0,7 à 0,10 mètre. On a généralement besoin de 1 à 10 tonnes d’échantillons en fonction du niveau de complexité de l’étude et des ressources. C’est une pratique difficile durant les premières phases de développement, qui empêche l’intégration du HPGR dans les plans. Bénéficiant du soutien de la Canadian Mining Industry Research Organization (CAMIRO, l’organisation de recherche de l’industrie minière canadienne), des chercheurs du Norman B. Keevil Institute of Mining Engineering (l’institut Norman B. Keevil de génie minier) de l’université de la Colombie-Britannique (UBC) ont mis au point des essais en laboratoire sur des presses à matricer à pis¬ton (PPT, de l’anglais piston–die press tests), qui mettent en corrélation les HPGR aux échelles pilote et réelle. Cet article décrit un nouveau modèle de régression qui évalue le taux de production spécifique aux HPGR à l’aide des résultats tirés des PPT et d’une base de données dédiée aux HPGR. Une étude de cas est présentée afin de décrire l’utilisation de la méthode actuelle des PPT dans les études techniques. ¦ MOTS CLÉS calibrage et mise à l’échelle, cylindre de broyage à haute pression (HPGR), essai sur presses à matricer à piston (PPT), modélisation empiriqueINTRODUCTION It is widely accepted that high-pressure grinding rolls (HPGRs) are a viable, energy-efficient solution for modern comminution flowsheet design. Table 1 summarizes select examples of HPGR applications in the mining industry. The main benefits of HPGRs are energy savings, which leads to lower operating costs, and stable operating characteristics that can better cope with variations in ore hardness compared to the conventional autogenous (AG) or semi-autogenous (SAG) mill-based comminution circuits."

Jan 1, 2019

By R. B. Harkness

Many of us are familiar with the history of oil in the Province of Ontario, but for the benefit of those who have never heard the story I will repeat it. In 185 7 J. H. Williams, of Hamilton, an old-country Scotchman, who had the advantage of experience gained from the primitive methods used for refining the oil collected at seepages in Roumania, heard of the "gum beds" along Black creek in Enniskillen township, Lambton county. He erected a small plant in the bush and refined illuminating oil, where the village of Old Springs now stands. The labor of collecting this thick ?gummy substance from the sluggish water of the creek, prompted him to dig a well, the next year ( 1858), in the hope of obtaining a greater quantity. When his excavation reached a gravel bed on top of the rock, oil, resembling "lubricating oil of commerce", rose several feet. Several of these wells were dug and his refining business flourished. The following year the Drake well, in Pennsylvania, was drilled into rock, resulting in an oil find which encouraged one James Shaw to make a similar attempt on Black creek. With a spring-pole drill he completed his well in the spring of 1861 to a depth of 160 feet, and at that depth struck a gusher that flowed uncontrolled for several days. Great excitement followed and the village of Oil Springs had a mushroom growth. The Petrolia field was discovered in 1865. Lick followed up the Thames with a spring-pole rig testing the formations along that river and discovered the original Bothwell field in 1865. During the sixties wells were drilled in many counties in southwestern Ontario.

Jan 1, 1924

By R. I. Cavanagh, A J. Last

THE USE of higher grade charges in blast furnaces in the form of sintered or pelletized concentrates has been increasing rapidly. The question of beneficiation of iron ores for this purpose is therefore receiving much attention as more deposits are developed. Many iron ores may respond well to magnetic roasting procedures followed by magnetic concentration, however, in most cases other more standard ore dressing methods are competitive and cheaper. For magnetic roasting as applied to iron ore beneficiation, the present question is "Can it be economically justified in situations where it appears to produce good results?" The following collection of information on the general status and operations of magnetic roasting methods may be helpful in considering this question. Magnetic Roasting Magnetic roasting involves the transformation of non-magnetic iron oxides, hydrated oxides and carbonates by means of heat and suitable

Jan 1, 1961

By Atul Bhatnagar, M. P. Sinha, Md Zahid Ahmad, Pallav Garg, Sanjay Kumar Singh, Shashi Ranjan, An Ecolab Company Nalco Water

"Froth Flotation is undoubtedly one of the most critical processes in coking coal washing plants. This work was carried out at Bhelatand Coal Preparation Plant of Tata Steel was with an objective of cost optimization in fine coal processing. The sources of raw coal for the plant include coal from underground mines of Jharia coalfield and procured open-cast raw coal. Coal from different sources vary in quality and possess different floatability characteristics.Synthetic collector is being used in plant as a flotation reagent. An alternate collector with new chemistry was developed for reducing total treatment cost without compromising product yield and quality. A series of laboratory tests were conducted to assess the performance of various sources of raw coal and plant scale trial was started. At first, the new generation coal collector was entirely substituted with the existing collector in the laboratory scale. However the plant scale trial data was not in accordance with laboratory results and indicated inferior flotation performanceThe issue was studied and data based conclusions were drawn that the new generation collector aids faster and uncontrollable kinetics. A decision was taken for co-dosing of the synthetic and new collector for the second phase of the trial. A detailed laboratory analysis was done again and few dosing ratios that predicted optimum results were selected for plant trial. The dosing ratio was optimised as per flotation yield and product ashes during the plant trial. The results showed significant improvement from the first phase and optimum dosing rates were decided based on plant observations and data collection. The influence of various process indicators including water quality, feed and product ashes and process yield was studied during all the trials and promising results were established. The co-dosing of both the collectors conferred cost advantage and enabled to achieve superior performance."

Jan 1, 2016

By R. Walker

This paper deals with the selection and design of a belt conveyor handling steam coal between a mine and a barge loading terminal, and extending for some 5 ¼ miles over some of the most rugged terrain in the state of West Virginia, U.S.A. After a thorough analysis by consulting engineers and the owner's engineers, a single-flight cablebelt conveyor was chosen as representing the alternative of greatest reliability and lowest over-all cost. The value analysis and design features of the system are covered in this paper along with an updated report on the performance of the system since its start-up in the spring of 1969.

Jan 1, 1971

By W. A. Gow, G. M. Ritcey, M. C. Campbell

"Uranium is a unique commodity. It is both a metal and a fuel, It has both commercial and military uses. It yields ""clean energy "" but presents environmental concerns. All of these factors have an impact on the commerce of uranium.Being a metal, uranium is extracted from ore like many other metallic minerals. As a fuel, it is subject to the vagaries of energy commodity market forces. The history of uranium in the first nuclear weapons has led to nation al governments carefully controlling production and sale of uranium. The spectre of radioactive contamination of the environment adds further to the public concern over the disposal of low-level radioactive wastes from uranium processing and use.There have been a number of excellent reviews on the commercial aspects of the uranium industry. In this discussion, these aspects will be briefly summarized to provide a general picture of the strengths of the Canadian uranium industry and the pressures to which it is being subjected currently. The principal thrust of this paper will be to outline Canada's resource strength and to identify some factors which will affect Canada's ability to continue holding a sizeable share of the world uranium market."

Jan 1, 1985

By E. W. Shaw

The past year (1950) has been a big one for the oil industry in Canada, with new records being set in almost every phase of exploration and development activity. New highs were reached in acreage holdings, in geophysical activity, in wildcat drilling, and in field development and production. The only item that did not show a substantial increase over recent years was the amount of reserves added by new discoveries. This was not due to a decrease in the number of new discoveries, however, hut rather to the fact that most of the discoveries were made during the later months in the year and could not be fully evaluated by the year end. The foregoing remarks pertain mainly to activity in Western Canada. In Eastern Canada, operations continued on a modest scale. with exploration drilling down slightly from the previous year but with development drilling and production at about the same level. Returning to Western Canada, it is observed that the general exploration play was one of expansion and intensification. The issuing of new petroleum and natural gas regulations by the province of British Columbia precipitated a moderate entry of companies into the northeastern part of the Province.

Jan 1, 1951

By J. P. Harrison, M. Grenon

"This paper summarizes the results of numerical studies on drift stability in moderately jointed rock masses. It investigates the relative pertinence of geomechanical factors such as joint orientation, spacing and stress regime. This is undertaken using a distinct element model and a series of parametric studies. IntroductionIn evaluating the stability of drifts in jointed rock, it is often necessary to compromise by employing models that capture the complexity of the rock mass, but which are still simple enough to allow for their routine implementation. The distinct element method can arguably provide an eloquent method to accomplish this. This paper explores the applicability of the method by means of a parametric study aiming to identify the dominant factors that influence the stability of drifts in moderately jointed rock. To this end a commercially available 2D distinct element numerical model was used. A series of techniques are presented in an effort to quantify the results of any instability predicted by the model.This paper also demonstrates a case study where a 3D joint network model was integrated into the distinct analysis software package. The advantages, as well as the current limitations of this approach, are discussed."

Jan 1, 2001

By R. Horn

The financial performance of the mining industry, measured by return on equity and capital employed, has been inadequate for many years. Consequently, mining companies are not valued highly by stock markets. Among the more important causes for the decline in the sector are the conservative working practices and reluctance to adapt to change or to develop new technology, although some relatively recent developments such as SX-EW copper and heap leach gold have made a significant impact on the cost base of these metals. The subsidiary business of metals exploration suffers from the same problems as the rest of the industry. The rate of discovery of ore deposits has been falling over many years and since the late 1990s, there has been a sharp reduction in global exploration activity that, if it continues, will further reduce the global supply of new ore reserves. New technological developments, particularly in geophysics and different operational practices may help reverse this trend. Statistical methods for evaluating the risk of ore reserve estimates will also improve the economic return on new mining ventures. The science of ore geology has potential to reduce exploration risk, but modern ore genetic theory has not contributed greatly to recent discoveries. The junior exploration market has almost ceased, but a new style of technically specialized efficient small exploration company has emerged which, in alliances with major companies, may be the vehicle for future global exploration. Exploration in virgin terrains has a higher risk discounted potential for the discovery of very large orebodies than that in known mining districts but mining companies have little financial incentive for this high risk exploration because of the very long lead time to production. Alliances of two or more companies reduce the risk in both the exploration for and development of major new mining projects. If new orebodies are not found, then metal prices will inevitably rise in the long term. Governments of industrial countries, particularly those with a significant mining industry such as Canada, should therefore provide assistance to exploration in order to maintain their existing industry and prevent a metals shortage from developing in the future with its consequent impact on the world economy and increased environmental damage as large lowgrade orebodies are developed to supply an expanding market.

Jan 1, 2002

By Z. D. Hora

The major fluorite producer in British Columbia was the Rock Candy Mine, inactive since 1942. Other deposits of economic interest include the Rexspar deposit, in which fluorite is associated with uranium and rare earth mineralization, and the Eaglet and Liard River occurrences. THE former Rock Candy fluorite mine, located 26 km north of Grand Forks, is the only major past producer of fluorite in British Columbia. The deposit was in production from 1918 to 1929 and again in 1942; total output was about 36,000 tonnes with average grade between 22 and 32 per cent CaF2. The fluorite body occupies a steeply-dipping vein structure, approximately 175 m long and up to 12 m wide, in porphyritic syenite. The chief vein-filling minerals are quartz and fluorite with local small len ses of barite. Fluorite content decreases with depth and the deposit becomes silicified. The Rexspar (or Birch Island) fluorite deposit is located 130 km north of Kamloops. The deposit is complex with rare earth elements and high uranium values, but !1uorite mineralization forms an independent zone adjacent to the uranium orebodies. Fluorite is present as fine-grained impregnations and as breccia cement in strongly schistose or brecciated alkali feld spar porphyry. Reported reserves are 1,088,000 tonnes of 22 per cent CaF2 or 450,000 tonnes of 29 per cent CaF2. 268 Another potential deposit of fluorite is Eaglet, situated on the north side of Quesnel Lake. Fluorite occurs as a stock work with scattered veins and irregular lenses up to 20 centimetres wide and as impregnations in altered Proterozoic Kaza Group feld spathic gneiss over an area of 1,500 metres by 500 metres. To date (1983) approximately $2 million have been spent on the exploration of this property and reserves of 18.8 mimon tonnes grading 11.59 per cent CaF2 have been outlined . A group of significant occurrences is known from north of Liard River Hot Springs Park , where fluorite occurs in small zones up to 17 m thick along the interface between Middle Devonian Dunedin Formation limestone and Middle Devonian to Mississippian Besa River Formation argillite. Fluorite, associated with witherite, barytocalcite and barite, is present as replacement bodies, breccia fillings and minor veins.

Jan 1, 1984

By Sarah Bélair, Denis Beltrami, Valérie Weigel

"Mabounié is a polymetallic deposit in Gabon containing niobium (1.2%), tantalum (0.03%), rare earth elements (REE) (1.4%) and uranium (0.03%) that are mostly carried by Pyrochlore minerals. Classical route for niobium recovery is a pyrometallurgical process that consists in pyrochlore flotation, dephosphorization of the niobium concentrate and aluminothermy to obtain ferro-niobium. Pyrochlore concentrates can also be treated by a hydrometallurgical process with a mixture of sulfuric and hydrofluoric acid leaching followed by solvent extraction to separate niobium and tantalum. However, the first process does not allow recovering REE and the second one is not environmentally friendly because of the use of HF.ERAMET is looking for new opportunities on strategic metals market and has recently developed a hydrometallurgical process for the recovery of all these metals based on a sulfuric acid treatment of the ore. After solubilisation of the valuable elements, niobium / tantalum are precipitated as a concentrate (12% w/w Nb and 0.3% w/w Ta) while REE (2.7 g L-1) and uranium (90 mg L-1) remain in solution. Nearly 90% of REE are recovered from the solution by conventional REE double salt precipitation [NaREE(SO4)2.xH2O) method but some REE still remain in solution as this method does not allow to quantitatively recover medium (Sm, Eu, Gd, Tb, Dy) and heavy (Ho, Er, Tm, Yb, Lu, Y) rare earth elements. From the different process routes studied (solvent extraction, precipitation, ionic exchange etc.), an innovative method has been developed and patented to recover REE residual concentration in solution. This is based on an aluminum removal step followed by precipitation of REE as REE phosphate concentrate (REEPO4) by phosphate addition into solution. The phosphate concentrate is then purified according to the conventional monazite treatment, i.e. caustic conversion and REE solubilisation in acidic media."

Jan 1, 2016

By Daniel E. Walsh, P. D. Rao

"A four-inch compound water cyclone (CWC) was tested to evaluate its gold recovery characteristics when processing -4.8 mm run-or-pit, placer material. Neutron activated placer gold particles (840 to 37 microns) were used as radiotracers (/98Au) in a closed circuit ewe test loop to determine concentrator recovery; a procedure believed unique to this study. The effect on gold recovery of gold size and shape, feed pulp density, feed pressure, vortex finder clearance (VFC), ewe cone type, top-size of the feed solids, presence or absence of heavy minerals in the feed, and the quantity of-37 micron slimes in the feed was investigated in over 300 tests.CWC concentration ratio and the top-size of the underflow solids were both affected by cone type, VFC, and feed pressure. Gold recovery was significantly affected by gold size, gold shape, and concentration ratio. These effects are complex, because significant size-concentration ratio and size-shape interactions exist. Radiotracer techniques showed gold particles had a residence time within the ewe of approximately one second. This study suggests ewe gold recovery is a concentration. This work suggests ewe gold recovery is a function of particle size and shape, and the flow rate through the cyclone. CWC cone ""bed density"" is considered important only as a thin, protective layer, which shields coarser gold particles from the entraining currents and facilitates their movement through the CWC.IntroductionCompound water cyclones (CWC), or automedium cyclones, are enhanced gravity concentrators for the beneficiation for slurries of sand, coal, and ground ore (Fig. 1). They are called compound water cyclones because of the compound slopes of their basal cones (Fig. 2) and are operated to suppress classification phenomena in favour of gravity concentration effects. The compound water cyclone is not a new wet concentrator. It was developed in the late 1950s by Dr. Jan Visman through research sponsored by Canada's Department of Energy, Mines, and Resources. Since that time, it has become a common unit in coal washeries for cleaning fine coal. CWCs and other versions of concentrating cyclones have also shown promise for heavy minerals and precious metals recovery."

Jan 1, 1988

By M. Laframboise, M. Buarzaiga

High-pressure acid leaching (HPAL) of nickel laterites has received considerable attention in recent years. High paymetals extraction, good selectivity, and advances in pressure hydrometallurgical technology are some of the reasons for this interest. Falconbridge Limited (Sudbury. Ontario) investigated the HPAL process using both fresh water and seawater for ore processing. The use of seawater resulted in a chloride concentration of 7.8 g/L in the autoclave feed. A test program was developed to study the effect of process water and leach temperature on the leaching behaviour of different ore compositions from the Koniambo deposit in New Caledonia. The work showed that salinity has a major effect on autoclave chemistry. This paper explores the results.

Jan 1, 2004

By L. A. Kaufman

"AbstractThe Bureau of Mines, Ottawa, in conjunction with Eldorado Mining and Refining (1944), Limited, has developed an automatic concentrator for uranium ores.A brief review of radioactivity is given which shows the present limitations for obtaining •good results by electronic concentration. The ores after being mined, or at any other stage of a concentrating process, can be analysed for the uranium dissemination and from these results the possibility of an economical concentration can be estimated.The electronic and mechanical parts of the equipment are described. Difficulties in the operation's, and means by which they have •been and are •being overcome, are discussed. The capacity of the units, the results obtained, the man-power required, and other pertinent data are presented. Simple control analysis on the percent U3O8 has been developed.Research is continuing along lines to develop a more completely automatic unit using a scintillation detector, and applying a few new ideas and some devices that have been developed in colour sorting.IntroductionIt is well known how important the Geiger counter is in the field of exploration for uranium. It was in late 1946 that Dr. C. Lapointe, of the Bureau of Mines, Ottawa, first started work on an automatic picking unit to concentrate uranium ores. He used the principle that if a number of pieces of unknown ore, some of which contained uranium, were individually brought up close to a Geiger-Müller tube, then the pieces containing uranium could •be easily picked out due to their activity. Since then a good deal of work has been done by the Bureau of Mines in conjunction with Eldorado Mining and • Refining (1944), Limited, to develop an electronic concentrator."

Jan 1, 1950

By I. I. Betcherman

INTRODUCTION A DISTILLATION process offers one of the most effective methods of refining metals. Its use is particularly attractive in the case of reactive metals which are not readily treated by pyrometallurgical or electrolytic methods. The 1ow vapour pressure of most metals severely restricts the applicability of the disti1lation process and only one or two metals may be effectively treated under atmospheric pressure at a reasonable temperature. If operations are carried out under reduced pressure several additional metals may be effectively distilled. Table I shows the vapour pressure of a number of metals together with a value of the free energy of formation of their ?oxides. Zinc and cadmium head the list and for many years? they have .been effectively refined by distillation. Sodium, magnesium, and calcium follow in descending order, and they may be distilled readily in vacuo and with difficulty at atmospheric pressure. Sodium, which is not of great metallurgical interest, is not considered. Magnesium has recently been produced in considerable tonnages by distillation methods ( 3). This paper describes the vacuum distillation of magnesium and calcium, their separation from each other, and their separation from less volatile impurities.

Jan 1, 1951