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By K Saito, M Hasegawa

Removing sulfur and phosphorus from molten iron can be expressed by the following reactions, respectively. [S]Fe + (O2-)slag = (S2-)slag + [O]Fe [P]Fe + (3/2) (O2-)slag + (5/2) (FeO)slag = (PO43-)slag + (5/2) Fe(liquid) These equations indicate that desulfurisation and dephosphorisation have opposite oxygen potential conditions. If a small amount of desulfurisation slag not removed is carried over to dephosphorisation process, the reaction of sulfur mentioned above proceeds toward left hand resulting in increasing sulfur content in molten iron. For better understanding of such re-sulfurisation reaction in hot metal pre-treatments, the present study aimed at evaluating the effect of iron oxide on the sulfur distribution ratio between slag and hot metal. To measure sulfide capacities and FeO activities simultaneously at temperatures below the melting point of pure iron, CaO-SiO2-FeO and CaO-Al2O3-FeO ternary molten slags were brought into equilibria with copper-iron-sulfur liquid alloys, and the equilibrium oxygen partial pressures were determined with an electrochemical technique involving the stabilised zirconia solid electrolyte. The experimental results showed that the sulfide capacity increased with an increase in FeO content, and this trend was consistent with the fact that FeO was basic. Although the addition of FeO raised the FeO activity and oxygen potential, the calculated value for sulfur distribution ratio between slag and hot metal increased with increasing FeO content.

Jun 19, 2024

By Cudmore JF, Rowlands D

Incidents associated with spontaneous combustion of coal have resulted in the loss of many lives and considerable capital and equip- ment. Nevertheless, the factors controlling the propensity of coal to spontaneous combustion are not clearly understood and there is a need for research to study the effects of rank, petrog- raphy, moisture contents, etc. This has been attempted in a study of the propensities of selected Queensland coals to spontaneous combustion. An adiabatic calori- meter was constructed to study the self-heating of a large number of coals. Chemical and petro- graphic analyses of the coals were determined and an attempt was made to relate these propert- ies to the self-heating characteristics of the coal. The results show a strong relationship between rank and self-heating characteristics and that petrographic composition of coal may also be of importance. Some observations on the application of the laboratory results to the practical situation are made as are recommendations for future research.

Jan 1, 1981

By Seymour K. M, Sampson D. B, Walker I. W

Ashton Mining Limited is the operator of two wholly-owned gold mine/mill complexes at Laverton and Leonora. In addition, Ashton owns 43% of the Bardoc Joint Venture mine/mill complex, which is operated by Aberfoyle Pty Limited. All three of these operations are located in the Eastern Goldfields region of Western Australia (Figure 1). At Laverton, milling capacity is in the order of 1 million tonnes per year in 3 mills (Duketon 200,000 tpa, Cork Tree Well 650,000 tpa and Craiggiemore 150,000 tpa). These mills service a distance of 80 km, from Baneygo in the north to Craiggiemore in the south. Mineral tenements cover a 150 km long stretch of a series of sub-parallel mineralised structures. At Leonora, the Harbour Lights mill is designed to treat 750,000 tpa of sulphide ore, and has treated oxide ores at an annualised rate of over 1 million tonnes/year. The mill is supported by several tenement blocks that lie within a 50 km trucking radius of the mill. The most important of these is the Mertondale tenement block, which covers approximately 25km of the Mertondale Shear Zone.

Jan 1, 1991

By L Kormos, V Lawson, G Hill, G Marrs

"In sulfide nickel deposits throughout the world, pentlandite and pyrrhotite are commonly found together along with varying amounts of chalcopyrite and platinum group minerals (PGMs). The mafic or ultramafic host silicates associated with the sulfide mineralisation commonly exhibit a complex assemblage of magnesium bearing silicates, many of which themselves contain significant nickel. Four types of ore are proposed, each presenting their own processing challenges. These are: economic grades of Ni, Cu and PGE (platinum group element) in a pyrrhotite-bearing sulfide deposit, with low pyrrhotite to pentlandite ratios  economic grades of Ni, Cu and PGE in a pyrrhotite-bearing sulfide deposit, with moderate to high pyrrhotite to pentlandite ratios uneconomic high pyrrhotite: low tenor deposits low-grade low sulfide, high MgO ± PGE deposits that can sometimes be economically mined and processed.The grades and recoveries of nickel concentrates produced from sulfide ores can be significantly impacted by the ore mineral texture, the nickel tenor of the sulfides, and the polytype of pyrrhotite which may be either hexagonal (non-magnetic) or monoclinic (magnetic). The mineralogy of the silicates is also of great importance, especially the magnesium silicates and those which tend to produce particles which are asbestiform or which affect slurry viscosity. Other magnesium silicates such as serpentine carry nickel in solid solution, limiting the recovery entitlement of nickel by flotation because serpentine is not amenable to sulfide flotation mechanisms. Differences in plant flow sheets and reagent assemblages are required to effectively separate these minerals.Experience from a variety of plant operations and from extensive flow sheet development programs are discussed. Examples are given of where significant improvements in nickel circuit performance can be made by adjusting plant physical processing conditions or process chemistry to compensate for measurable ore properties and characteristics.CITATION:Lawson, V, Hill, G, Kormos, L and Marrs, G, 2014. The separation of pentlandite from chalcopyrite, pyrrhotite and gangue in nickel projects throughout the world, in Proceedings 12th AusIMM Mill Operators’ Conference 2014, pp 153–162 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Sep 1, 2014

This paper is written as a supplement to that of Edwards, Baker and Knight on "The Geology of the Wonthaggi Coalfield" 1, the West Area pit being in an early developmental stage at the time of their paper. The thin seams to the west of Dudley Basin 2 had beenknown for many years but it was not until 1935 that it became necessary to work them. The West Area Pit came into production as Dudley Area Pit approached exhaustion in 1937. From available information it was estimated that early work would be in a 36in. bottom seam. The present top seam was not included in the reserves, but it was to be extracted where it proved thick enough for economical working.THE SEAMSEdwards, Baker and :Knight (1944) had insufficient information to correlate positively the West Area seams with those in the Dudley Basin. Their opinion was, however, that they were a westerly extension of the Bottom Seam. Since then the driving of the present north-east heading towards No. 4 Bench McBride Tunnel has established that the West Area seams are those worked as Bottom Seam in the Dudley Basin. West Area Top Seam is a seam that occurred above the Bottom Seam in the Dudley Basin. Only sporadic attempts have been made to work it in Central Area, because 30in. was considered an economic minimum height until recent times. This seam should not be confused with Top Seam, Dudley Basin, which lies some 300ft. above the bottom seam measures and except in isolated areas over deeper workings has been eroded away in West Area.

Jan 1, 1953

Mssissippi Valley-type (MVT) and sedimentary-exhalative (SEDEX) zinc-lead deposits represent about half to three-quarters of the world's production and reserves of lead and zinc. The two deposit-types have traditionally been regarded as separate entities in terms of genesis largely because they possess very different morphologies, resulting from the epigenetic nature of MVT deposits and the syngenetic origin of SEDEX deposits. Similarities in regional setting, metal ratios, size and grade, lead and sulphur isotopes, and source(s) of fluids and metals in the two deposit-types, however, suggest that they could be products of similar genetic processes. The physical properties of MVT ore fluids suggest that certain types of SEDEX deposits could have been formed from fluids possessing similar salinities and temperatures. The hypothesis is further strengthened by the facts that: 1. in several cases MVT and SEDEX mineralisation occurs in the same region, and 2. recent advances in establishing the timing of MVT mineralisation has revealed that some MVT deposits are contemporaneous with nearby SEDEX deposits. If MVT and SEDEX zinc-lead deposits do indeed share a common ultimate derivation from fluids that emanated from sedimentary basins, then the presence of one deposit-type in a region could be used to infer the possible presence of undetected deposits of the other type. Furthermore, knowledge of the mineralisation age of one type will constrain the exploration target host rocks of the other type. A genetic relationship between MVT and SEDEX mineralisation may also explain why certain individual deposits, such as several in Ireland and eastern Canada, appear to be 'hybrids' and possess geological attributes of both end-member types.

Jan 1, 1993

By Chander S

Properties of surface films on chalcopyrite and pyrite differ due to variations in the mechanism of oxidation of the two minerals. In the case of chalcopyrite the first step in the oxidation is the release of iron as ferric ions, which hydrolyse depending upon conditions prevalent in solution. The iron oxide/hydroxide layer formed by hydrolysis of ferric ions is quite porous and easily detachable from the surface of chalcopyrite. When the surface oxide layer is detached a sulphur-rich layer is exposed making chalcopyrite hydrophobic. The thickness and properties of the sulphur-rich layer determine its flotation response, both in the absence and presence of collectors. In the case of pyrite, on the other hand, iron is released as ferrous ions which require much higher pHs to hydrolyse. These ions remain adsorbed on the surface of pyrite making the surface hydrophilic. When the iron species are complexed with chelating agents such as ethylene diamine tetra acetic acid, pyrite was hydrophobic. Siderite forms in the presence of carbonate ions, which might be present in several flotation systems. Siderite nucleated on isolated sites at the surface. The presence of such a precipitate is likely to influence the interaction of pyrite with various reagents thereby altering its flotation behavior. To determine the mechanism of oxidation, kinetics of oxidation of chalcopyrite and pyrite was studied using several electrochemical techniques, namely, cyclic voltammetry, polarisation and impedance spectroscopy. Floatability of the minerals was investigated by measurement of contact angles on mineral electrodes and by Halimond tube flotation. Impedance spectroscopy was especially useful for estimating various properties of surface film for both the minerals. Properties such as charge transfer resistance, porosity, and capacitances of the surface films on the two minerals are compared under several conditions of oxidation. These properties were found to be a strong function of the rate and the extent of oxidation.

Jan 1, 1993

By F J. van Zyl, C A. S Thomson

"Anglo American Thermal Coal conducted a high level study of all of its underground collieriesto determine if there were electrical power saving opportunities at the main fan stations.A systems approach to electrical power savings was used to identify potential savings in the various components of a primary ventilation system. Furthermore, only technological interventions were considered to obtain electrical power savings. From generic technological driven electrical power saving strategies four energy savings strategies were identifi ed, namely potential overall reduction in ventilation volume, improved underground air utilisation, optimisation of fan-set effi ciency and potential fan drift design optimisation. The study indicated the colliery (say Colliery D, Shaft A) that showed most potential in the four technology driven energy savings strategies. A detail study was undertaken at Colliery D, Shaft A to increase the confi dence level and the study confi rmed that up to 45 per cent of the main fan absorbed power can be saved (475 kW) with an estimated capital payback period of 18 months. The study clearly showed that an integrated approach to optimise the entire mine ventilation system has great potential for power saving, and that a clear, well -defi ned methodology will be applicable to similar underground collieries. This paper discusses the background to the study and the process followed to implement the energy savings initiative at Colliery D, Shaft A."

Jun 1, 2012

By Brimblecombe P

Morwell Open Cut is a continuous mining operation employing 5 buck- etwheel excavators, I bucket chain excavator and 54 conveyors. The combined bunkering capacity at both client Power Stations represents less than 12 hours maximum coal demand. This creates an extremely dynamic operating environment, which is further complicated with significant variations in both excavating and transportation plant capabilities. To achieve set objectives, including- I adequate reserves, 2 coal supply reliability, 3 cyclic plant maintenance, 4 minimal cost of coal, scheduling of the operation requires constant monitoring and reappraisal. Investigations are in progress to develop a computer based scheduling tool capable of simulating the complex operating environment. A review of computer scheduling packages currently available within the State Electricity Commission of Victoria has found limitations making most unsuitable for the task. The type of package found to be most suited is a knowledge based system ('Expert System')capable of operating within a set of rules defined by the user. Work is proceeding on the development of a knowledge base to test the effectiveness of Personal Computer based `Expert Systems'.

Jan 1, 1989

By Kavetsky A, Scott A

As well as breaking and moving rock, blast energy sets up a seismic wave in the ground which can cause significant damage to rock structures and buildings and disturbance to human occupants. This seismic ground vibration is potentially most damaging when its dominant frequency coincides with the resonant frequency of a structure, leading to high amplification factors between the input ground vibration and the resulting structural response. This paper outlines methods of identifying the resonant frequency of structures. It also describes a practical numerical method for the modification of blast designs to reduce the ground vibration energy in critical frequency ranges. The method is illustrated with two recent case studies.

Jan 1, 1990

By Wood CJ, Davis JJ, Askew H

A dynamic model of a dense medium circuit has been developed and tested against plant data. The model shows the response of the circuit to both controlled (changes in specific gravity set point or changes in circuit coal feed rate) and uncontrolled changes (changes in raw coal moisture, loss of raw coal feed) in operating conditions. The model is built up from dynamic models of the individual sumps, pumps, pipes, splitters, magnetic separators and automatic controllers in the circuit. The model can be used for design of automatic control loops and for investigation of possible process modifications such as changes in water addition points. This paper describes the model construction, the testing of the model against actual plant data and gives some examples of its use in investigating plant response to changes in operating conditions.

Jan 1, 1978

By Denby B, Hollands R. Schofield D

Surface mines are in operation worldwide, the vast majority employ large haul trucks for the transfer of material both to the outside world and around the site. The sheer size of these trucks and the operating conditions means there is a high

Jan 1, 1998

The major copper orebody at Mount Isa is being extracted at a rate of four million tonnes per year. The method used requires an equivalent rate of back filling with (mainly) cemented fill. There were three major incentives for developing this mining system. The first was the prospect of high ultimate recovery of the orebody. The target is 100% recovery. Also the proposed stoping layout appeared to offer significant advantages in development and production costs. Finally, extensive subsidence above the northern end of the orebody could have disturbed permanent surface installations and jeopardised a possible future open cut. The full implications of this ambitious strategy were not apparent in the early years. Now, after twelve years of production the benefits are being realised and they can be weighed against the costs. Probably the most interesting result which comes from this analysis is the significance of cutoff grades and dilution factors in balancing mining and filling rates.

Jan 1, 1980

By Zeni J. T

Gold was mined from quartz bodies at Ballarat East from the 1850s until closure of the last mine in 1917. The average depth of mines was about 350 m.Ballarat Goldfields Limited (BGL) carried out diamond drilling from surface between 1985 and 1987 which proved the continuation of gold-quartz mineralisation beneath the old mines.During 1989 an underground development program was commenced to access the mineralisation for detailed exploration. The program included two simultaneous shaft developments. These were known as B2 shaft and Llanberris No.1 shaft.

Jan 1, 1992

By Stewart WJ

Australia's first offshsore well was spudded in on 27th December 1964 and resulted in the discovery of the Barracouta gas field. Further exploratory drilling led to the discovery of the Marlin gas field in December 1965, the Kingfish oil field in April 1967 and the Hblibut oil field in June. 1967. In September 1968, a small oil reservoir was found in a sand below the main Barracouta'gas reservoir. The Snapper gas field was discovered in May, 1968 Information on exploration activities associated with the discovery of oil and gas in the Bass Strait area may be found in the paper, "Exploration in the Gippsland, Bass and Otway Basins, Australia" by B. M. Hopkins. _ Development of the commercial fields is being undertaken on an equal participation basis by Hematite Petroleum Pty. Ltd. and Esso Exploration and Production Australia Inc. Esso Standard Oil (Australia) Ltd. is responsible for the design, construction and operation of the production facilities.

Jan 1, 1970

By Rogers M, Sullivan B

Golden Crown Mine is a narrow vein gold mine producing 75000 tpa. Production has been predominantly by shrink stoping using hand held machine and airleg. Bogging from these stopes is done with Toro 150 LHD units.Previously the standard development method consisted of developing a sill drive, a footwall drive and millholes every 7 m. This meant that for every metre of ore development, 2 m of waste development was required.

Jan 1, 1993

Lightweight polymer grids have recently been introduced to the mining industry. They are currently being used for roof and rib control, longwall shield recovery, safety guarding or barricade, highwall screening, internal reinforcement of gunnite/shotcrete applications, sub-base reinforcement, construction of steepened slopes, retaining walls, mine reclamation (i.e. erosion control, turf reinforcement), and in numerous mining waste related projects. These polymer mining grids utilize a strong, lightweight polymer, usually special grades of polypropylene or polyethylene. High tensile strengths are achieved by molecular orientation of these polymers in the manufacturing process. The first step in the manufacturing process is to extrude the polymers into thick continuous sheets. These sheets are then punched, and drawn into open grid structures. Aperture size and configuration are controlled by the geometry of the punched hole and the degree to which the grids are stretched. The drawing process is the key to the molecular orientation required for the tensile strengths. These long chain polymer molecules in their natural state have a random orientation. When stretched, the molecules are pulled into a parallel alignment, thus creating a lightweight product with tensile strength comparable to Steel.

Jan 1, 1992

By Sakurai F

Akita Zinc Refinery of Mitsubishi Metal Corporation (MMC) started operation in 1953 with a capacity of 560 tons of electrolytic zinc per month. Its capacity has been expanded gradually and reached 8,100 tons per month in 1973. However, present production level is about 6,500 tons per month due to the depressed zinc market. In 1963, newly developed sulphate roasting was incorporated for residue treatment. Since 1973, electric power from Ohnuma geothermal power station of MMC has been supplied in addition to hydroelectric power from Komata power station of MMC. At present, about 40% of power is supplied from our company's power station and the rest is from the power company. Recent customers' demands for zinc prod- ucts include various kinds of shape, weight and chemical composition of galvanizing zinc alloy. It is necessary for zinc producer not only to meet the requirements of customers but also to enhance the value of zinc product in order to expand the market of zinc.

Jan 1, 1987

By D Obeng, D Alexander

Over the past five years, commodity prices have been high and the focus of many plants has been æthe more metal the better, at whatever costÆ. In the recent economic crisis, the focus has shifted more to reducing the cost of production and operating at higher efficiency. Since 2002, JKTech has partnered with the Century mine in north-west Queensland to transfer technology and understanding through the good, bad and ugly economic environments, using methodology and techniques arising from research at the Julius Kruttschnitt Mineral Research Centre (JKMRC) and other research institutions around the world as part of the AMIRA International P9 Project. The JKTech studies were concentrated around the primary zinc circuit. During this period, Century expanded the primary zinc regrind capacity, installed additional scavenging capacity, installed and commissioned a Jameson cell for concentrate cleaning in the carbon preflotation circuit, and installed additional primary grinding capacity. Flotation circuit models were developed for each of the survey campaigns and enabled opportunities for further improvement to be identified, implemented and tested in the subsequent campaign.

Jan 1, 2009

By Kavetsky A

In surface mining operations, the ease with which a muckpile may be dug is a dominant factor in mining efficiency. Within broad limits, this is largely dependent on muckpile shape and looseness within a muckpile. Moreover, prediction of grade boundary movement and subsequent dilu- tion is of interest to most open cut mines. Such a predictive tool would enable blast design changes to be made to reduce mixing of certain grade regions. At the very least, a good knowledge of post-blast region bound- aries can reduce layout of the grade boundaries and decrease grade dis- crepancies between pit and plant. The model presented in this paper is able to consider various options for a production blast and predict consequent muckpile shapes and grade boundary movements in a three dimensional manner. The overburden geometry, hole patterns, hole inclination and charge distribution are all explicit model inputs. The model divides the rock mass into blocks and calculates a velocity for each block. Three controlling parameters are used in the model, which are related to the explosive energy per unit length of blast hole, energy attenuation of the rock mass and inter-row delay, respectively. The output of the model is a 3 dimensional muckpile shape (contour or any cross section) and a contour map of grade distribution within the muckpile. The model parameters are site specific, since their values depend on the rock condition and explosive-rock interaction which varies from site to site. In order to "tune" the model to a particular site, parameter values must be found which reproduce an observed muckpile profile shape from a given blast design. This calibration of the model requires at least one surveyed muckpile profile shape from a production blast. The model parameters which best reproduce that shape are found by a pattern search technique, and may then be used to predict the effect of changes in blast design on muckpile profile shape and grade boundary movement.

Jan 1, 1989