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By C J. N Wilson

The central Taupo Volcanic Zone is a region of intense Quaternary silicic volcanism accompanying rapid crustal extension. Modem central TVZ is the most frequently active and productive silicic volcanic system on Earth, erupting rhyolite at c.0.28 m3 s-1. The rhyolites show no major compositional changes with time, but the total extent of magma chamber zonation has changed with the advent of rifting and crustal extension at c.0.7 Ma. At least 34 caldera-forming ignimbrite eruptions have formed a complex sequence of relatively short-lived, nested and/or overlapping volcanic centres in central TVZ. Taupo contrasts with other large silicic magmatic systems in the exceptionally high frequency, but small size, of caldera forming eruptions. This contrast reflects the thin, rifted nature of the TVZ crust that precludes the development of long term magmatic cycles at Taupo. Within central TVZ, non-rhyolitic compositions have been erupted apparently irregularly in time and space; in particular there is no evidence for a geographic separation of basalts from andesites. TVZ is a rifted arc, but its segmented nature, high thermal flux and voluminous rhyolitic volcanism make it unique on Earth.

Jan 1, 1995

I report results of over 850 microprobe analyses of sulfides, sulfosalts and electrum from the Favona adularia-sericite epithermal deposit of the Waihi district in the southern Hauraki Goldfield of New Zealand. Pyrite and marcasite from altered wall rocks that enclose the veins are stoichiometric, with compositions of FeS2, and no significant trace elements. In contrast, pyrite in veins commonly contains appreciable As (up to 3.2 wt per cent), and locally contains several tenths of a percent of Cu, Zn, Co, Ag and Sb. Vein pyrite may contain up to 0.22 per cent Au, but Au contents do not show a positive correlation with As. Limited electrum data indicate that it ranges from Ag0.47 Au0.53 to Ag0.54Au0.41Cu0.01Zn0.04. Chalcopyrite is stoichiometric CuFeS2, and most galena is PbS, but some galena contains up to 4.4 wt per cent Se, which substitutes for S in its lattice. The galena is not argentiferous; the highest Ag content is 0.45 wt per cent Ag. Sphalerite averages 4 mol per cent FeS, but ranges up to 15 mol per cent. Tetrahedrites [(Cu,Ag)10(Zn,Fe)2(As,Sb)4S13] show variable substitution, but most are Cu- Zn- and Sb-rich. Veins also contain aguilarite (Ag4SeS), stromeyerite (CuAgS), naumannite (Ag2Se), and mckinstryite [(Ag,Cu)2S].

Jan 1, 2004

By G McMillan, P Mulvey

"Geochemical characterisation is done based upon the geology and metallurgical batch testing prior to commencement of the operation of the plant.  Tailings repository design is based upon geochemical assessment of the waste material, as well as the geomechanical issues associated with storing the waste. The resultant conceptual and detailed design is incorporated into the environmental impact statement (EIS), upon which mine approval is based. The entire environmental monitoring and harm mitigation program, which is usually a condition of the Mine Lease approval, is based upon the applicability of the original characterisation.Tacit to this process is that there is no change in the geochemistry of the tailings, i.e. no change in the implications for acid & metalliferous or saline/neutral mine drainage (AMD/SNMD) generation. But any changes in milling and processing can have a substantive impact on the geochemical behaviour of the tailings metallurgy, and potentially render an operation non-compliant within the conditions of the mine license.Environmental and statutory approval implications for continuous improvements of metallurgy need to be understood because unintended consequences could cost more than the benefits of the improvement, and in some cases cost more than all the profit made from the mine.  Examples uncovered during audit and consultant practice will be presented together with a process to ensure implications for adverse environmental harm and license conditions are fully considered.*This paper is only available for individual download. It is not included in the conference proceedings*CITATION:Mulvey, P, 2013. Continuous improvement - how changes in metallurgy can have a substantive impact on environmental impact and closure - lessons learnt from environmental auditing, presented to MetPlant 2013 Conference (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jul 15, 2013

By J L. Mauk

Low sulfidation epithermal deposits are important sources of gold and silver, and are considered the extinct analogues of modern geothermal systems. The aerial extents of alteration halos that surround twenty-two epithermal deposits range from 4 to 315 km2, with many less than 60 km2. Deposits with alteration halos <30 km2 typically have well defined limits, whereas deposits with alteration exceeding 30 km2 are commonly complicated by overlapping alteration centres related to adjacent epithermal deposits or other deposit types (i.e. high sulfidation, porphyry). Irrespective of the physical coverage of vein or alteration halos, both large (>60 km2) and small (<20 km2) deposits can contain large amounts of gold and silver. The size ranges for twenty-one analogous liquid-dominated geothermal fields from around the world have a restricted size range of 5 to 60 km2 and irrespective of physical size, commonly have multiple zones of focused fluid upflow. From an exploration perspective the comparison between epithermal deposits and geothermal fields provide the following four important points. 1) Alteration halos surrounding epithermal deposits as well as those for analogous geothermal systems show a range of sizes, although most are less than 60 km2. Therefore, where alteration exceeds 60 km2 multiple vein systems related to several paleogeothermal systems are predicted. 2) Multiple upflow zones are common in geothermal fields of all sizes (5 to 60 km2) and although difficult to demonstrate in epithermal deposits there is a strong possibility of discovering several discrete adjacent mineralised centres. 3) The orientation of veins parallels the principle orientation of the surrounding alteration and where alteration is wider than the vein strike length, this could suggest the occurrence of adjacent veins. 4) The physical size of both veins and alteration zones is not important in relation to amount of contained gold, as both large and small can contain large amounts of gold. These conclusions provide insight into the physical size limits and hydrologic structure of these paleogeothermal systems and highlight the potential for multiple mineralisation centres within a single alteration halo.

Jan 1, 2004

By P Mitchell, J Proffett, I Munajat

Batu Hijau is an island arc porphyry copper-gold deposit located in the southwest corner of Sumbawa Island in the Sunda-Banda archipelago of Indonesia. Southwest Sumbawa Island is underlain by Early Tertiary, low-K calc-alkaline to weakly alkaline volcanic and intrusive rocks. Within the mine area the oldest exposed rocks are medium- to thick-bedded, medium to coarse andesite volcanic lithic breccia, thin bedded, fine-grained volcaniclastic sandstones and mudstones and hypabyssal porphyritic andesite. In the eastern portion of the mine area there is a thick sequence of quartz diorite that postdates the andesites. A small stock of Equigranualar Quartz Diorite predates the Batu Hijau deposit and occupies the contact between the andesitic volcaniclastic sequence of rocks and the Porphyritic Quartz Diorite. Batu Hijau is a world-class copper-gold deposit that has a drill indicated mineable reserve of 914 million metric tonnes grading 0.525 per cent copper (10.58 billion pounds copper) and 0.403 g/t gold (11.8 million ounces gold). Mineralised material not in reserve accounts for an additional 580 million metric tonnes at 0.328 per cent Cu (4.19 billion pounds copper) and 0.171 g Au/T (3.19 million ounces gold), and including an oxide copper resource of 57 million tonnes at 0.37 per cent Cu and 0.12 g Au/T. Copper and gold mineralisation is directly related to quartz veining and wall rock alteration that developed with multiple tonalite porphyry intrusions. The tonalites were emplaced along the contact between the andesitic volcaniclastic rocks and quartz diorite intrusives. Copper and gold are zoned around the porphyry intrusions, which are designated by their contact-age relationships and other features as Old Tonalite, Intermediate Tonalite(s), and Young Tonalite(s). The Old Tonalite was the first copper-bearing intrusion, and although it is the smallest intrusion it has the highest quartz vein density, the strongest alteration and the highest grade. At least two tonalite porphyry intrusions followed the emplacement of the Old Tonalite. Each of these intrusions was associated with less quartz veining, weaker hydrothermal alteration and lower grade copper and gold than the previous intrusion. The intrusive cycle culminated with the emplacement of the Young Tonalite, which contains relatively few quartz veins, is weakly altered and mineralised. Hypogene hydrothermal alteration and sulphide mineralisation developed in five temporally and spatially overlapping stages. These stages consist of Early, Transitional, Late, Very Late, and I Zeolite alteration. Early alteration and sulphide mineralisation accompanied each tonalite porphyry intrusion, but with diminished intensity in each subsequent intrusion. Transitional and later stages of alteration and mineralisation postdate the tonalite porphyries and overprint Early stage alteration and mineralisation. Early alteration and mineralisation consisted of biotisation, secondary magnetite and plagioclase development, fine porphyry-style stockwork veining and ore mineralisation. Magnetite-biotite????quartz stringers and dark micaceous (biotite-sericite) veinlets were developed. The veinlets were accompanied by biotisation of magmatic mafic minerals and groundmass. Thin, irregular and discontinuous æAÆ type quartz veinlets and fine-grained chalcocite, digenite and bornite mineralisation accompanies the Early alteration. It is hypothesized that most of the copper mineralisation was originally deposited as bornite, digenite and chalcocite. Secondary plagioclase was added along the selvages of the early quartz veinlets. Early alteration is pervasive within and proximal to the tonalite porphyries. In the distal portions of the deposit, andalusite and anthophyllite formed at intermediate to shallow depths, and in the deeper portions of the deposit, respectively. The andalusite and anthophyllite probably developed at the same time as the early magnetite-biotite-quartz alteration in the core of the deposit. Transitional-age alteration consists of oligioclase/albite-sericite-chlorite- quartz-¦vermiculite and is associated with æBÆ quartz veins. Through-going planar æBÆ veins are thicker than æAÆ and æA-familyÆ veinlets and have chalcopyrite????bornite along vuggy centrelines and narrow oligioclase????albite alteration envelopes. Rare æCÆ chalcopyite¦quartz veinlets were also formed during Transitional alteration. During Transitional alteration early copper sulphide minerals (chalcocite, digenite and bornite) are converted to bornite and chalcopyrite. The majority of the copper (50 - 70 per cent) in the deposit is contained in ores in which chalcopyrite is the predominant sulphide. Late alteration consists of feldspar destruction and replacement by sericite and other minerals. The late alteration is accompanied by the development of æDÆ sulphide veinlets and veins. These veins consist of pyrite and quartz????chalcopyrite. Within the halos of the late pyritic veinlets biotite is replaced by sericite, quartz-sericite, quartz-andalusite, or quartz-pyrophyllite+kaolinite replace plagioclase, and magnetite is converted to specularite and/or pyrite. In the periphery of the deposit, the feldspar destructive alteration, together with outer zones of Transitional-age alteration, constitutes what is commonly referred to as a æpropylitic zoneÆ. Very Late hydrothermal alteration is also characterised by feldspar destruction, but differs from Late alteration in that feldspar is replaced by smectite in association with sericite and chlorite. Sulphide mineralisation in this stage consists of sphalerite, galena, tennantite, pyrite and chalcopyrite. The last stage or I Zeolite alteration consists of low-temperature, open space filling consisting of stilbite or laumontite¦calcite. Supergene oxidisation of the orebody extends to a maximum depth of 210m. Isolated deep oxidation occurs along open fracture zones to depths of ~400 metres along æDÆ vein filled fracture zones. Weak supergene copper enrichment occurs in a thin horizon (15 to 60 m thick) that blankets the top of the deposit. The main supergene copper mineral is secondary æsootyÆ chalcocite replacement of sulphide grains and as veins.

Jan 1, 1999

THE following notes, compiled in the first instance for the makers of rock-drIlls, were read by Mr. Hanton at a meeting of the Broken Hill Branch on 12th Septelnber, 1922. It was decided that all Broken Hill mines be asked to give their individual views on the subject, so that a comprehensive Broken Hill view could be published. Replies have been received from four (4), mines to date, and their'ideas fairly well coincide with those set out by Mr. Hapton. His notes were as follow:- "The Zinc Corporation Limited.NOTES ON ROCK-DRILL DEVELOPMENTSAs far as our present experience goes, the rock-drill developments on this mine will probably be something resembling the following. The programme is subject to modification or alteratian, according to circumstances. The results of further trials and improvements in present drills, and the design of new types, will, of course, affect any general scheme such as that outlined. It appears reasonably certain that the 3i-in. reciprocating drills which have done practically all the stoping up to date, will be gradually replaced by hammer drills of the internal water-feed type, and that the existing types of hammer drill on the mine will be converted into internal water-feed machines instead of being used as dry machine with outside jet.The ultimate types of machines will be four... Type 1 would be a machine equivalent to the Ingersoll Leyner: 248, Waugh Turbro, SullivaIi DX61, or Holman CH2. This would be used for driving, cross-cutting, and similar excavating work, and possiblyfor stoping also, and should be capable of efficiently working any class of ground. Features, apart from the general requirements set out later, would be the weight of the machine and mounting height of the machine above the seating (as this affects the convenience of boring back or bottom holes); absence of projections on the mounting which the air hose will foul as the machine is fed...

Jan 1, 1923

The Fraser Range is composed dominantly of basic pyroxene granulites derived from basalts, many of which appear to have been vesicular and pillowed. Acidic and basic garnet-bearing granulites are important in the west, and acidic granulites and narrow anorthosite layers are dominant in some regions east of the Fraser Range. An extensive flat-lying olivine gabbro sheet cuts the granulites, and in places has been converted to spineI-bearingmeta-gabbros and pyroxene granulites. The granulites of the Fraser Range (Proterozoic) are separated from the gneisses and schists of the goldfields regions (Archaean) by the Fraser Fault, over which there is a large gravity anomaly (gradient 20 milligals per mile). Some of the problems associated with the concentration of Cu, and Ni liberated from mineral lattices during metamorphism, and other principles of metal concentration in granulite terranes, are discussed. The recognition of vesicular and pillowed zones, even though highly metamorphosed, is of fundamental importance.

Jan 1, 1969

By Associates

The headwaters of Skippers Creek and the Shotover River are reputed to be among the richest alluvial gold catchments in the world. This alluvial gold has no doubt been derived from reef systems similar to, and associated with, the Bullendale lodes. Physiographically the prospect covers steep ridges and deeply incised gullies between the Richardson Mountains in the west and the Harris Mountains in the east. Vegetation is mainly tussock with bush either side of Murdochs Creek. Access to the area is by metalled road to Skippers and then by 4WD track to Bullendale. Alternatively the prospect area can be reached by helicopter from Queenstown in around ten minutes.

Jan 1, 1992

By K Ehrig, J Griffith

An extensive suite of elements are routinely assayed on all resource drill core samples to assist in deposit scale resource definition, local mine scale delineation of ore zones, and ore characterisation for the planning and scheduling of mining and processing of ores at Olympic Dam. This paper discusses a deposit scale geochemical relation that can be used by mine geologists to find more high-grade ore at the local mine area scale at Olympic Dam.A 3D grade shell representing 0.8 per cent Cu was created for a mine area using drill hole assay data. This defined the geometry of the ore zone. The Cu-grade shell was then overlain onto the existing resource block model to evaluate the relationships between the Cu-grade shell, copper and other elements. The strongest correlation was between copper and manganese. The block model showed a dramatic decrease in the concentration of manganese just below the below the Cu-grade shell.Several drill holes that intersected the Cu-grade shell were selected to evaluate the copper manganese relation at the drill hole scale. As expected, the individual drill holes displayed a strong inverse relation between copper and manganese. A geochemical footwall was then modelled representing 0.1 wt per cent Mn. Using both the Cu– and Mn-grade shells, several drill holes were designed/drilled and all hit high-grade copper.For the vast majority of the deposit the inverse relation between copper and manganese is valid; however, in areas with intense chlorite alteration (related to amounts of mafic to ultramafic rocks) this relation is not as strong, due to increased manganese in the rock mass. Even though using the copper manganese relation as a drill targeting method was not always as reliable in a few small areas of the deposit, it demonstrates the value of using existing assay data integrated with the resource block model to discover local mine scale geochemical relationships which can be used to more effectively design drill holes to discover high-grade ore at Olympic Dam.CITATION:Griffith, J and Ehrig, K, 2017. Using existing data to improve the delineation of ore at the Olympic Dam Fe-oxide Cu-U-Au-Ag deposit, in Proceedings Tenth International Mining Geology Conference 2017, pp 321–326 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 20, 2017

The recent boom in the mining industry has lead to some unique challenges in successfully operating processing plants. With high turn-over rates of both operators and technical staff, and many experienced personnel leaving regional sites for city based jobs there is often an onsite knowledge vacuum and this in turn puts pressure on both site training departments and senior metallurgists to provide the relevant skills to the continuous stream of new staff. Frequently both operators and new metallurgists are instructed on a æhow-toÆ basis rather than giving them the understanding as to why tasks are performed and decisions are made. This paper has been written with the plant operator and metallurgist in mind and aims to provide suitable material to be incorporated into a site training manual. Topics have been broadly divided into the following categories: factors that operational staff can control; including pulp density, air addition rate, froth depth, particle size and reagent type and use; factors that operational staff cannot control; providing general information on bubble size, froth stability, pulp chemistry and the mechanical effects of the rotor/stator system; and process improvements. Each topic is discussed with a view to clarifying the key process variables that need to be understood and optimised in an industrial operating plant.

Jan 1, 2009

By D Craw, S Clearwater, S Hammit, C Smith

Prior to rehabilitation, plant cover on quartz gravel overburden at Wangaloa coal mine was highly patchy. Stabilisation techniques have since considerably altered the condition of the main overburden yet deposits in the east and west remain largely intact. On the eastern overburden, three distinct zones of revegetation have naturally developed: Zone 1 represents a dense plant cover, Zone 2 a patchy cover and Zone 3 a sparse cover of isolated plants. Aerial photographs show much of the eastern overburden was deposited between 1940 and 1960s. Yet we found that the temporal scale of deposition did not wholly account for the differences observed in vegetation development. To investigate other influential factors, we set up 12 study plots using four replicates in each vegetation zone. The diversity and density of plants in each plot were measured to quantify the degree of vegetation development. Samples from the substrate in each plot were collected using soil cores to a depth of 10 cm. Cores were analysed for indicators of nutrient availability, metal content and physical composition. We found that substrate chemistry varied between individual study plots, but showed little difference overall along the vegetation gradient. Substrate physical differences were much greater. The ratio of coarse quartz pebbles: fines was considerably higher in Zone 3 than other zones, and within zones where plants were not growing. Bulk density also increased successively from Zone 1 - 3. We found clear evidence for the reversed stratigraphy of excavation superimposed over the time scale of deposition, and the corresponding nature of fine particles. The rate of revegetation was therefore highly dependent upon the substrate composition of the last surface deposit from the dumping truck. Our data suggests an optimum ratio exists between inert coarse material and a fine matrix for progressive natural vegetation development on mine substrates.

Jan 1, 2004

By Morabito J, Harrop D. W

Uranium exploration was commenced in 1973 and carried out at a regional scale over a wide area of the northern part of the Camarvon Basin of Western Australia by Minatome Australia Pty Limited and their joint-venture partners. As a result, pervasive uranium mineralization has been found in the Cretaceous sandstones near Manyingee Hills in the Onslow Region, which were probably deposited in a near-shore, fluvia deltaic palaeo-environment.Mineralization is generally found in poorly sorted argillaceous sandstones and siltstones near redox fronts formed by oxidizing waters circulating in reduced sediments. The principal minerals found in the two Manyingee deposits delineated so far are coffinite, uraninite with associated pyrite in the reduced zones, and phosphuranylite, siderite and limonite in the oxidized zones. The presence of dissolved uranium in the superficial aquifers, of secondary uranium minerals as coatings on granitic rocks, and of recent uranium-bearing calcrete sediments, suggest that the whole Cretaceous-Precambrian system has been subjected to the formation ofroll-front type uranium deposits since the Cretaceous. Continuing exploration is locating additional uranium occurrences. The deposits outlined so far are being evaluated for their amenability to in situ leaching tests planned for 1982-1983.

Jan 1, 1981

By J K. Wright

In recent years the production of steel from directly reduced iron ore pellets has expanded rapidly. However, continued growth will depend on an adequate supply of suitable raw materials for the various commercial gaseous and solid reductant processes now in operation. Although at present Australia does not produce pellets primarily for direct reduction, there is an increasing awareness of Australia's potential role as a supplier of high grade ores for export and/or domestic use. The properties and quality requirements of iron ore pellets made specifically for direct reduction (DR) are reviewed and the laboratory techniques and test methods used at the CSIRO Division of Process Technology for the evaluation of potential DR feedstocks are described. At the present time most of the evaluation tests for DR pellets are extensions of those designed for existing blast furnace (BF) burdens. In the case of some physical parameters such as cold compression strength, abrasion index and cold strength after reduction this extension is quite satisfactory. In the measurement of parameters such as reducibility, swelling and sticking tendency, however, it is necessary to develop meaningful standardized tests so that ores and pellets can be ranked for DR performance. To do this, data from the laboratory tests and from operating plants must be correlated.

Jan 1, 1980

The Effect of High Power Nanosecond Electromagnetic Pulses on Selectivity of Pyrite from Arsenopyrite

Sep 13, 2010

By Hellsten KJ, Butt CRM

Major Francis Hamilton Buchanan coined the term `laterite' (Latin; brick-rock) in 1807 for the red earths used for building blocks in southern India. Although these earths were actually weathered basalts, the term is now applied to weathering profiles developed upon a wide range of bedrocks. The Ni-laterites are a special class within the broad laterite family.

Jan 1, 1996

A Process for the Flotation of Chrysocolla

Sep 13, 2010

The GPS and information technology industries are now applying considerable development effort to what is being termed machine control and machine information systems, in particular focusing on the industries the of mining construction and agriculture. GPS based systems are demonstrably finding common acceptance and adding commercial value to many machine applications in industry. This has been the first step in the evolution of the information age that is now reforming mining practices. Adding the technologies of wireless data communication, modem computer databases, and networked PC's mining is on the verge of a new era in overall process management. This paper is a general discussion of what the information age means to miners and a general description of new mining operation technologies available to day from the Caterpillar technology alliance.

Jan 1, 1999

By T M. El Hajj, A C. Chieregati, M T. G C Marques, J M. Braga Jr, H Delboni Jr

"The estimate and control of sampling errors is essential for all mining operations, especially when dealing with strategic materials, such as niobium. This paper is based on a traditional quality assurance and quality control technique used to confirm mineralised intersection zones, and proposes the validation of sampling data using diamond drill twin holes, in order to evaluate and improve the quality of the current data set. The geological model of the niobium mine – located in Araxá, Minas Gerais, Brazil – was built including 77 diamond drill holes of a sampling campaign carried out during the 1970s. There are few records about the collection and preparation procedures of these past samples, making it difficult to estimate the errors associated with their analytical results. Therefore, 11 twin drill holes were drilled to compare their samples against the samples from the 1970s drilling campaign. The new hole locations were chosen as near as possible to the old holes location. The JORC Code, 2012 edition, relates the use of twin holes as a good sampling technique to assess sampling and assay data. Three parameters were considered to validate the 1970s drill hole campaign by the twin drill hole campaign: the difference of the coordinates between the paired holes the difference among the positions of the geological contacts to validate the geologic description the difference between the paired samples grades was calculated to validate the analytical results.The analysis of the grade range variation between sample pairs was based on three techniques: geostatistical interpretation of vertical semivariogram to obtain the nugget effect calculation of the relative difference between duplicates calculation of the error associated with the sampling protocol established according to Pierre Gy’s Theory of Sampling.The results were satisfactory for hole coordinates; however, the ore content showed a high deviation, although this divergence can be explained by the nugget effect. For the lithological intervals, the new results contributed to an effective identification of variations among lithologies, ie brown weathered ore and saprolite. The twin drill holes campaign successfully validated the geological model data, allowing effective mine planning and higher reliability of the reconciliation results.CITATION:Marques, M T G C, El Hajj, T M, Braga Jr, J M, Chieregati, A C and Delboni Jr, H, 2017. Theory of Sampling and geostatistics for twin drill holes analysis in a niobium mine in Araxá, Brazil, Australia, in Proceedings Eighth World Conference on Sampling and Blending, pp 97–106 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

May 9, 2017

Kinetic Behaviour of Solid/Solid Separation of Ultrafine Particles in Aqueous Suspension

Sep 13, 2010

By S M. C Verryn, K Deysel

In heavy mineral sands ilmenite, rutile and zircon are present in economic concentrations. These minerals are important sources of Fe, Ti and Zr for various industrial uses. The beach sands of northern KwaZulu-Natal, along the Zululand Indian Ocean coastline in South Africa, have been mined for 30 years. The various processes involved in mining and processing these minerals have been controlled by time-consuming and labour-intensive analysis methods which, in some cases, can be replaced by X-ray powder diffraction (XRD)-Rietveld analysis. Heavy minerals are concentrated in the plant to produce a heavy mineral concentrate (HMC). The heavy mineral extraction plant is controlled and informed of the proportions of minerals in the HMC according to their magnetic susceptibility. The different fractions are called magnetic, paramagnetic and non-magnetic fractions and quality control is based on their magnetic fraction weights combined with X-ray fluorescence (XRF) elemental analysis. This current quality control process is very time consuming and labour intensive. We have aimed to show that we can, by XRD, identify and quantify all the minerals in the HMC and also in the magnetic separations. These results are then compared with results obtained by Mineral Liberation Analyser (MLA) as well as with the results from the physical separation. It was possible to detect all minerals present in the material by XRD and use the Rietveld method for a full bulk mineral quantification. A maximum of 15 minerals can be included in the Rietveld refinement due to computational restraints. Major minerals detected are rutile, ilmenite and zircon and minor minerals are quartz, epidote, anatase, amphibole, monazite, magnetite, titanite and augite. The XRD and MLA results correlate relatively well and detailed results will be presented for HMC and magnetic fraction samples. Small differences were observed for some minerals due to the different ways in which minerals are detected or due to preparation methods within each method. Rutile seems to be more abundant in the XRD analysis and the detection of Anatase is possible by XRD, but not MLA. Leucoxene (consisting of mainly microcrystalline anatase, rutile and titanite is not detectable by XRD since it is not a mineral, but ilmenite alteration phases are observed instead. There is, however, a correlation between anatase, titanite and rutile detected by XRD and leucoxene analysed by MLA.

Jan 1, 2008