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By V. Bredykhin

The efficiency of scrap processing depends firstly on reliability of information about its chemical composition. The paper presents the results of the investigation and development regarding solid copper alloy scrap in the range of lump size 40÷300 mm. Nowadays the sorting of lump scrap is done by two methods: 1. Sorting according to metals and alloys is done at places of scrap generation, and further till metallurgical processing each lot has its "certificate"; 2. Hand sorting of scrap is done according to the marks on solid items in special shops using proximate analyzers or manually by experienced workers. This sorting process is labor - consuming low efficient and involves mistakes. The informational method is a promising trend in the copper scrap sorting. The method is direct, i.e. as a result of sorting the chemical composition of each scrap lump or main elements is determined, and assured data of qualitative and quantitative composition are received.

Jan 1, 2006

By M. A. Vera

This paper proposes a simple two-parameter model for the typical inverse relationship between recovery and flotation concentrate grade. The model is based on the mineralogical limitations imposed by the material properties. One parameter (R*) describes the proportion of metal content which is floatable, and the other (b) is the rate at which the fastest floating particles are being contaminated by the other less valuable particles present in the mineral system. One significant feature of the recovery-grade curve is that initial recovery (i. e. R ? 0) is at the purest attainable mineral grade, (but as recovery rises the cumulative grade of the concentrate tends to the feed grade. The ideal recovery-grade curve for a particular mineralogical system can be obtained by release analysis: the release analysis curve determines the maximum or limiting separation efficiency. The model proposed in this work is similar to the linear recovery - cut-off grade model of Dell (1), but has the advantage of describing the whole curve.

Jan 1, 1999

By Bernd Kopacek

"Nowadays more and more consumers substitute their conventional TV-sets and computer monitors by LCD panels. In the near future huge amounts of LCDs will start coming back to recycling. As LCDs with hazardous mercury backlight lamps are used an appropriate recycling technology has to be implemented.IntroductionLiquid Crystal Displays (LCDs) are widely used in notebooks, organizers, mobile phones, pocket calculators, measuring and control instruments, electronic games, hand-held miniature TVs, audio-video equipment, large signboards, automotive displays and more and more also for PC monitors and TVs.According to a study from Stanford Resources (San Jose, California) the annual value of LCDproducts reached 35 billion EUR in 2002, about 30% of this within the European Union, representing a total area of 2,1 million m2 Liquid Crystal Displays. An annual increase rate of about 15% is estimated for the next years (up to 4,1 million m2 in 2005).As LCDs are already on the market for several years, larger quantities of the more than 2,5 billion LCDs are coming into their End-of-Life stage for treatment. In 2005 this figure will become even more dramatic - 40.000 tons of LCD-modules contained in 2 million tons of waste electrical and electronic equipment (WEEE) or about 30% of total WEEE within EU. An amount which is representing 400 million EUR costs for incineration.Currently the only method used to deal with redundant LCD units is incineration or landfill. Both are expensive and causes emissions into the atmosphere (global warming) respectively water contamination (Class II) and difficulties in biodegradation. Up to now there is no recycling solution for LC-Displays available.As a consequence European Commission requests the disassembly of LCDs with an area bigger than 100 cm2 in the Directive 2002/96/EC of the European Parliament and of the Council on Waste Electrical and Electronic Equipment (WEEE Directive) of February 13, 2003."

Jan 1, 2008

By Noboru Masuko, Sachiko Ono

"The structure and composition of anodic films formed on aluminum in a borate solution have been investigated by using TEM and SIMS with respect to the effect of current density and electrolyte temperature. The film is composed of a boron-containing outer layer and a boron-free inner layer with disc-like crystals present at the interface. The thickness of the film formed at constant current density up to an identical voltage, decreases with increasing current density. The thickness increases remarkably with elevated temperature. The transport number of Al3+ estimated from the thickness ratio .of the cuter to the inner layers is 0.4 when the film is formed at the current density of 20 Am-2 at 60°C. It increases slightly with increasing current density and decreases significantly with increasing temperature. Content of boron in the outer layer increases 1.5 times when current density .increases 10 times. These changes in film structure and composition with electrolysis conditions must have a significant role in the determination of electric properties of anodic alumina films as a capacitor material.IntroductionThe growth of anodic alumina film in ·a neutral electrolyte proceeds at both film/electrolyte and film/substrate interfaces giving a duplex structure. The oxide layer formed at the former interface includes electrolyte anions while a-pure alumina layer is formed at the latter interface. The thickness ratios of each layer respectively represent transport numbers of Al3+ and 0 2 - (1). The film thickness and the incorporated anion content as well as transport numbers of both ions must affect the dielectric properties of the film as a capacitor material. However, the correlation between film structure and electrolytic conditions is not fully understood (2). For the further clarification of anodic film growth mechanism, more detailed characterization of anodic films in relation to electrolytic conditions is advantageous. In the present paper, therefore, the effect of current density and electrolyte temperature on the microstructure and composition of anodic barrier films formed in a neutral borate solution was studied. The films were characterized by direct observation using transmission electron microscopy (TEM) and depth profiles of constituent elements obtained by secondary ion mass spectroscopy (SIMS)."

Jan 1, 2000

By Jean Igor Margem., Lucas Barbosa de Souza Martins, Frederico Muylaert Margem, Sergio Neves Monteiro, Artur Camposo Pereira, Rômulo Leite Loiola

"The fibers extracted from the stem of the bamboo plant have been investigated as possible reinforcement composites due to their relatively high tensile strength. Although previous works have already been conducted about the mechanical properties, up to now a dimensional characterization of the distribution and the effect of diameter on the elastic modulus of bamboo fiber of the specimen dendrocalmus giganteus has not been performed. The aim of the present work was to statistically characterize the distribution of the diameter of a lot of bamboo fibers of that specimen. Based on this characterization, diameter intervals were set and the dependence of the Elastic Modulus (E) of theses fibers with a corresponding diameter was analyzed by the Weibull Method. The results indicated an inverse dependence, in which the highest Elastic Modulus were obtained for the thinnest fibers. Moreover, it was found that a mathematical hyperbolic relationship fit well this inverse correlation between the Elastic Modulus and the bamboo fibers diameters.IntroductionBamboo is a well known grass-type plant with a hard and stiff stem or culm that can reach, in some species, more than 10 cm in cross section diameter and stand several meters height. Owing to its low density, approximately 0.9 g/cm3, bamboo culms have been used in house construction from scaffoldings to panels. As an abundant natural resource in tropical and temperate regions, specially in Asia and South America, bamboo is also a substitute for wood and plastics in furniture and lightweight parts of automobile [1,2]. The cylindrical shape of the culm is, however, a limitation for its direct use in engineering systems. Consequently, research works have been conducted on bamboo fibers stripped off from the culm as reinforcement of polymer composites. [1-12]. According to Shin et al [3] bamboo fiber-epoxy laminates can be made into specific sizes and shapes, preserving the natural microstructural properties. These fiber composites overcome the limitation of the culm's cylindrical macrostructure. As a further advantage, Shin et al [3] indicated that cracking and bioerosion caused by insect pests is prevented."

Jan 1, 2013

By I. Sofia Fernandez del Rio

This paper describes a process for the treatment of the dusts generated during the operation of blast and reverberatory furnaces in the lead smelter, to remove zinc, cadmium, arsenic and halides from the circuit. The process consists of a Pefloles' developed leaching/purification stage and a solvent extraction process developed by Lurgi. The plant capacity is 5,000 tonnes Zn/year. The feed to solvent extraction contains 8 g/1 Zn. Impurities such as copper, iron, arsenic and cadmium are removed by conventional cementation processes. The cadmium product is 99.99 % pure. The solvent extraction process consists of two extraction stages, one washing stage and two stripping stages. D2EHPA is used as the extraction agent and 25% ammonia as the neutralizer. The rich-zinc solution is sent to the electrolytic zinc plant for zinc recovery. The raffinate produced, which is a mixture of ammonium sulfate and chloride, is used for agricultural applications.

Jan 1, 2000

By Michael S. Moats, Alexander Derrick

"The Winand Diagram was developed and has been used for decades to illustrate the interaction between polarization, mass transport and inhibition on the resulting structure of a metal electrodeposit. Recently, Adcock et al. criticized the Winand Diagram and developed their own structural diagram based on nucleation and plating overpotentials. Their work was based on zinc electrodeposition using a galvanostatic staircase method. This work explores the nucleation and plating overpotentials for copper electrodeposition using conditions typical for primary electrowinning and the galvanostatic staircase experimental technique. Additionally, the effects of organic additives and plating substrate on these overpotentials are reported.IntroductionThe control of electrodeposited structures is critically important to modem electrometallurgy operations to insure proper quality and efficient energy use. Electrodeposition of base metals for primary recovery (e.g. electrowinning or electrorefining), while similar to plating for decorative or device manufacturing, differs in the need to produce deposits that cover large areas and grow to significant thickness. Thus, controlling nucleation and particularly growth of electrodeposits is critically important for base metal electrometallurgical operations.The control of nucleation and growth on an industrial scale is most influenced by five parameters - current density, temperature, metal concentration, electrolyte agitation and additives. The effects of these parameters on electrodeposition are interrelated. To describe their effects on the type ofelectrodeposits generated and provide practitioners with a useful tool, Winand developed what is known as the Winand Diagram [1-2]. An adapted version of the Winand Diagram is shown in Figure 1.Winand characterized electrodeposits using Fischer's classification [3] and plotted the various deposit types versus inhibition on a vertical axis and the ratio of current density to bulk metal concentration on the horizontal axis. Inhibition intensity is a complex parameter and is still not well understood even though Fischer introduced the term in 1960 [4]. Often, inhibition intensity is simplified to equal the concentration of organic additive at the deposit surface and is related to the inverse of the exchange current density of the metal being deposited. The ratio of current density to bulk metal concentration is used to represent the ratio of crystallization overvoltage to mass transport of the depositing ion. As such i/iL could also be along the horizontal axis, where iL is the limiting current density of the electrodeposition reaction."

Jan 1, 2012

By B. M. Satish

The aim of the present work is to study the effect of annealing on the vibration damping capacity of high-chromium (16%) ferromagnetic steel. The alloys were prepared from raw materials of 99.9% purity melted in a high frequency induction furnace under high vacuum. The samples were heat-treated in vacuum at various temperatures (800 to 1200°C) for 1 hour followed by slow cooling (120°C/h). The inverted torsional pendulum method was used to evaluate the vibration damping capacity. The results indicated that the vibration damping capacity of the alloys is influenced by annealing and there exists a critical annealing temperature after 1000°C. The damping capacity increases quickly below the critical temperature since the magnetic domains move more easily.

Jan 1, 2009

By J. E. Murphy

Neodymium was electrowon into a Mg-Cd molten cathode at 650 °C from NdC1,-KC1 electrolyte. With the chloride system, neodymium was deposited into the molten alloy cathode until the neodymium concentration reached 20 wt pct. The alloy was then vacuum melted to remove the Mg and Cd. The current efficiency exceeded 80 pct under optimum conditions and the purity of the metal was 99.9 pct after vacuum melting. As an alternative approach, neodymium was electrowon at 1,030 °C from Nd,O, dissolved in a molten fluoride eleotrolyte. With the oxide-fluoride electrolyte, the metal was electrowon in a molten state with current efficiencies up to 60 pct. The purity of the metal was 99.8 pct with oxygen and carbon as major impurities. A number of problems were encountered including anode effect, low oxide solubility in the electrolyte, high neodymium metal solubility in the electrolyte, and reactivity of the metal with the cell materials. Approaches to improved cell, operation and prospects for commercial adoption of the electrolytic production of neodymium metal are discussed.

Jan 1, 1995

By Johan Sundström

Anhydrous DyC13 was prepared by dehydration of DyCl3?6H20 in a fluidized bed using both batch- wise and continuous feeding. A gas mixture with varied composition of argon and HCl was used. The productivity was high, reaching values of 0.25 mol H20/m2-st during the reaction step 6- 1 and 0.062 mol H2O/m2.s during the reaction step 1-0. The product was free from hydrolytic compounds, such as DyOCI, if control of inlet gas composition versus temperature was achieved. From the results of various experiments, some relations between HCI-concentration and temperature in order to avoid hydrolysis have been deduced. The fluidization process efficiency decreases drastically after the dehydration has proceeded down to about 10 mol% of remaining water. Therefore, in a final treatment the last traces of water were removed by slowly purging gas through a packed bed. The water content could thereby be reduced to less than 1 mol%.

Jan 1, 1997

By H. H. Law

Large amounts of waste material in the form of flue dust are generated in the operation of copper smelter furnaces. As a result of increasingly stringent disposal, it has become important to develop methods for treating such metallurgical wastes to extract metals and convert them into salable products. A two-step closed-loop hydrometallurgical process, has been developed: (1) extraction with sulfuric acid removes about 90% of zinc and decreases the dust volume by 50%; (2) extraction with hydrochloric acid dissolves the lead and further decrease the dust volume by 75%. A process scheme for generating salable products is proposed.

Jan 1, 1992

By Hideaki Tokuyarna

Recovery of metal such as V, Ni and Fe from oil fly ash is important for efficient use of natural resources and protection of environment. Leaching of metals from fly ash followed by ion exchange of leached metals has been examined to develop a process which can selectively recover V and Ni from the fly ash. Experiment of leaching with water, HCI, H2S04 and NaOH leads us to propose a two-step leaching process as an effective and mild operation. The first step is leaching with water for removal of Ni, Mg, A1 and Zn and the second step is leaching with acidic solution for the recovery of V. The metals V and Ni are then separated from other metals in each leached liquor by ion exchange. Advantage of this separation process is that acidic leachant can be reused, which contribute to save separation energy.

Jan 1, 2002

By T. Asahina, M. Nakamura, M. Mabuchi, I. Shigematsu, M. Nakanishi, G. Yamauchi

"Commercial stainless steels (SUS304L and SUS430) were subjected to equal channel angular extrusion (ECAE) at room temperature to a total strain of 2.3 to 9.2. For each type of stainless steel, it was shown that the sample processed by ECAE showed higher room temperature strength than the as-quenched sample. This is probably due to the heavily worked structure. On the other hand, both strength and elongation of the ECAE processed SUS430 were increased by annealing at 773K. It is likely that higher strength is attributed to both the heavily worked structure and fine substructures. It is also likely that higher elongation is attributed to the fine substructures. It is concluded that ECAE is available for improving the room temperature strength of commercial stainless steels.INTRODUCTIONEqual channel angular extrusion ( ECAE ) is a technique that provides the repetitive deformation and allows to high intensity of deformation. With this procedure, a sample is pressed through a channel that has an equal cross section but bent at an angle of ?> [1-2]. Shear strain is introduced when a sample passes through the bending point of the channel. Repetitive processing is feasible because the cross-sectional dimension of a sample has no change during processing. To date, many reports have described that ECAE is available for the fabrication of fine-grained materials [3-14]. On the other hand, an ECAE processed sample can achieve high intensity of deformation through repetitive deformation. According to the equation given by Segal [ 2 ], a strain of about 1 is introduced in each pass through die if the angle ? is 90 deg.It is well known that high tensile strength can be achieved in metallic materials through work hardening [15]. It is also known that metallic materials with fine grain size show high strength [16]. Hence, it is expected that ECAE is available for strengthening method in metallic materials. In the present paper, we will report the mechanical properties of stainless steels processed by ECAE. As samples, SUS304L austenite stainless steel and SUS430 ferritic stainless steel were chosen. Each alloy has a single-phase structure (fee or bee) and shows no phase transformation, so that transformation strengthening cannot be applied. Hence, a heavy cold work such as ECAE may be effective for strengthening of this stainless steel. Annealing was conducted for the ECAE processed SUS430 to vary its microstructure. Then, the effect of annealing on the strength of the ECAE processed SUS430 was also investigated."

Jan 1, 2000

By B. Q. Li, H. C. de Groh, X. Lu

"A fully 3-D, transient finite element model is developed to represent the magnetic damping effects on complex fluid flow, heat transfer and electromagnetic field distributions in a metallic melt. The model development is based on our in-house finite element code for the fluid flow, heat transfer and electromagnetic field calculations. The numerical model is tested against numerical and experimental results for water as reported in literature. Various numerical simulations are carried out for the melt convection and temperature distribution with and without the presence of a transverse magnetic field. Numerical results show that magnetic damping can be effectively applied to stabilize melt flow, reduce turbulence and flow levels in the melt and over a certain threshold value a higher magnetic field resulted in a greater reduction in velocity. Also, for the study of melt flow instability, a long enough running time is needed to ensure the final fluid flow recirculation pattern. Moreover, numerical results suggest that there seems to exist a threshold value of applied magnetic field, above which magnetic damping becomes possible and below which the convection in the melt is actually enhanced.1. INTRODUCTIONThe imposition of a DC magnetic field on a moving, electrically conducting fluid, such as molten metal or semiconductor melt, produces an opposing Lorentz force that results in a reduction of flow velocity in the liquid. This effect has been explored in both the semiconductor and metals industries to control natural convection and/or surface tension induced Marangoni convection as well as thermally induced flow instability during solidification processing of these melts [1-6]. A mathematical model can be of great use in developing both fundamental understanding of the fluid-magnetic field interactions in these magnetically-assisted processing systems and basic guidelines for process design, control and optimization.This paper presents a 3-D mathematical model for magnetically damped fluid flow and heat transfer in a melt cavity, which is useful for interpreting results for unidirectional solidification processes at slow solidification rate, and some preliminary results concerning the magnetic damping effects on the flow instability in the melt. The model development is based on the finite element solution of the Navier-Stokes equations, energy equations and equations for induced electric field. The model is tested against reported results and is then applied to study the fluid flow and thermal distribution in the metallic melt with and without an external magnetic field."

Jan 1, 1999

By Petr Stehlík

"This paper is aimed at showing and demonstrating progress in technologies and improvements in units for the thermal processing of various types of waste. The following areas are covered: units for the thermal treatment of hazardous industrial waste and common MSW, technologies for the thermal treatment of industrial and sewage sludge, utilizing waste in cement production (material and energy recovery), up-to-date off-gas cleaning systems, original and unique units for the thermal processing of polluted gases, low-NOx burners. The paper represents a review based on industrial applications, papers published in reputable international journals and a monograph under preparation.IntroductionThe present contribution is an overview of the activities and achievements of the Institute of process and environmental engineering (UPEI) of the Brno University of Technology (VUT). The Institute belongs to European leading teams in the field of the thermal processing of various types of waste. The research in the institute currently revolves mainly around a strategic project “Waste and Biomass Utilization focused on Environment Protection and Energy Generation” that is supported by the national government. Due to the limited space this paper is conceived as a review of papers published especially in reputable international journals.Main (strategic) target of the research is development of new, efficient processes (eventually modernized processes with novel original elements) for effective and highly efficient treatment of waste and biomass, including their maximum utilization as renewable energy sources while minimizing harmful emissions. To this purpose, highly advanced know-how for the design and construction of the related technology lines is being developed, supported by mathematical modeling (see e.g. [1]), experimental validation and optimization.Municipal and Industrial Solid Waste – Concept of Waste-to-Energy CentersThermal processing of various types of wastes is not only waste disposal and/or treatment at present. It has to be regarded as waste to energy process wherever and whenever possible and feasible. This observation was at the origin of the concept of new regional Waste-to-Energy Centers (WTEC), outlined in the following paragraphs. The proposal of the centers is based on a combination of experience, know-how and sophisticated approach. The main fact influencing the concept of WTEC is the necessity to treat different types of wastes. Typical types of wastes as well as main products of the processes in a WTEC are shown in Figure 1."

Jan 1, 2008

By Jefferson Caponero

The tire is an expressive component of Municipal Solid Waste, manly when its occupied volume is considered. Its treatment by pyrolysis stands for a list of advantages, such as: landfill releasing and a production of a high quality fuel. The exploitation of new natural resources is becoming more difficult each day, basically due to the environmental damages caused by this type of activity. This work presents a study on the thermal behaviour of Brazilian tires using thermogravimetric analysis and differential thermal analysis, in order to optimise the pyrolysis process of tires. Samples of I to 2 mm were investigated at atmospheres of nitrogen, argon, oxygen and mixtures of these gases at temperatures up to 1273K, under heating rates between 1 to 50 Klmin . The results showed that the behaviour of each sample is related to both the atmosphere composition and the heating rate.

Jan 1, 2001

By Xiaojie Gao, Shufeng Yang, Jingshe Li, Chengsong Liu

In the blast furnace process, the dust entrained in the blast furnace gas enters into the down-comer, flows through the gravity dust separator (to eliminate coarse particles) and then is collected in a bag-house. The powder collected by the baghouse is called bag dust, while both fractions are called blast furnace dust whose main components are C and Fe. The dust also contains small amounts of nonferrous metals such as Zn and Pb, which have some value. Also, due to the small particle size and low density the dust is easily suspended in air and so can endanger human health. Therefore it is necessary to develop a process to both treat the dust to recover the metal values and to dispose of the residue – preferably by recycling to the blast furnace itself via the sinter strand. These objectives will result in good economic, environmental and social benefits [1].

Jan 1, 2014

By Yahui Feng, Zhiwen Wu, Chen Chen, Xin Hong

Large amounts of copper slag containing about 40 wt% iron is generated during the process of producing copper. Recovery of iron from the copper slag is very essential not only for recycling the valuable metals and mineral resources but also for protecting the environment. The purpose of this study was to investigate the possibility of separating fayalite by oxidation-reduction process into Magnetite and silicate phases in intermediate temperature condition. Experimental results show that when the oxidation reaction at 1000℃ for 120min and the oxygen flow is 0.1L/min, most fayalite decompose to hematite, less part of magnetite and silica. And then, the mixture of carbon and oxidation product is pressed into blocks and reduced to magnetite and silica at 900℃ for 90min. A magnetic product containing about 57.9wt% iron was obtained from the magnetic separation under a magnetic field strength of 100 mT.

Jan 1, 2015

By A. F. Sidorov

A method of improving mineral recoveries from ores by modifying the physical and chemical properties of minerals using radioisotope radiation was tested. It was observed that irradiation modifies mineral cell sizes, changes the crystal structure of some minerals, reduces the sulfur content 1 to 1.5 % in sulfides, changes the zeta potential, alters the surface properties of mineral grains I and produces other changes. Preliminary tests indicate that accelerated electron treatment of ores in connection with mineral processing has a potential for improving mineral recoveries by flotation and by magnetic separations.

Jan 1, 1989

By B. G. Belew

Recent operating improvements at the Phelps Dodge Chino Smelter, coupled with intensive capital expenditures since 1987, have resulted in a safer, higher quality, more productive smelter. This paper briefly reviews the flowsheet of the Chino Smelter with emphasis on recent capital expenditures. The main focus of the paper is to provide case studies of how operating functions have been improved. Case studies presented include: (1) safety, (2) anode quality control, (3) flash furnace cross-over build-up control, and (4) flash furnace temperature control. Most of these accomplishments have been achieved by providing specific measurable goals and subsequent feedback to operating crews.

Jan 1, 1993