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By K. P. V. Lei

An electrochemical process was developed for the preparation of vanadium from vanadium carbide. Commercially available vanadium carbide (V2C) was used as the starting material. Vanadium was obtained by electrolysis of the V2C in a BaCl2-KCl-NaCI-VCl2 electrolyte at 670° C using a helium-atmosphere, molten-salt electrolytic cell. Vanadium products were recovered with purities high as 99.6 percent. Current efficiencies of 87 percent and vanadium recoveries of 84 percent were attained. The cathode products were amenable to electrorefining to high-purity vanadium of 99.96-percent purity.

Jan 1, 1971

By Kris Chatrathi, John E. Going, Kenneth L. Cashdollar

Two types of flammability limits have been measured for various dusts in the Fike 1-m3 (1000-L) chamber and in the Pittsburgh Research Laboratory (PRL) 20-L chamber. The first limit is the minimum explosible concentration (MEC), which was measured at several ignition energies. In addition to the three dusts studied previously (bituminous coal, anthracite coal, and gilsonite), this work continues the effort by adding three additional dusts: RoRo93, lycopodium, and iron powder. These materials were chosen to extend the testing to non-coal materials as well as to a metallic dust. The new MEC data corroborate the previous observations that very strong ignitors can overdrive the ignition in the smaller 20-L chamber. Recommendations are given in regard to appropriate ignition energies to be used in the two chambers. The study also considered the other limiting component, oxygen. Limiting oxygen concentration (LOC) testing was performed in the same 20-L and 1-m3 vessels for gilsonite, bituminous coal, RoRo93, and aluminum dusts. The objective was to establish the protocol for testing at different volumes. A limited investigation was made into overdriving in the 20-L vessel. The LOC results tended to show slightly lower results for the smaller test volume. The results indicated that overdriving could occur and that ignition energies of 2.5 kJ in the 20-L vessel would yield comparable results to those in the 1- m3 vessel using 10.0 kJ. The studies also illustrate the importance of dust concentration on LOC determinations.

By Van H. Manning

Chemical and physical tests of coals for the use of the Government have been made by the United States Bureau of Mines. These tests form part of a general study of the coals in the United States with respect to the manner in which each coal can be utilized most efficiently. As a result of this study, much information of value to all industries using coal has been compiled. Special investigations by the Bureau of Mines of the fuels used by the Government have, until recently, been for the most part limited to coal. In the course of these investigations the bureau has de- veloped new methods for use in the purchase of coal by the Gov- ernment. The application of these methods permits an intelligent selection of the coal adapted to the requirements of particular heat- ing or power plants, and has already resulted in the saving of large sums of money. In addition, these investigations have led to the compiling of a series of carefully made analyses of samples of coal collected in a predetermined manner in the mines of all the impor- tant coal fields in the United States, and these analyses are being published to enable Government purchasing agents and all users of coal to select the coal best suited to their needs. The purpose of this paper is to describe briefly the general char- acter and commercial quality of some of the coals mined in the United States that reach tidewater shipping ports, and to show in a general way the important characteristics of those coals that by reason of transportation facilities and the situation of the coal fields are most available for export. Coals of excellent physical character and of high heating value are available for export. For this reason and because of the modern facilities at the collieries for properly grading large shipments, American producers can supply coals suitable for any kind of service. The transportation system from the mines to tidewater and the coal- handling equipment for loading boats at the various ports are highly developed, so that producers are able to give excellent service to foreign buyers. Enormous quantities of these coals have been used by railroads, manufacturing, illuminating-gas, and coke plants, and seagoing vessels, and for household purposes. Much of the coal available for export is superior to the coals that have been supplied to foreign users from other sources.

Jan 1, 1916

By Frederick C. Trutt

Research performed on arcing faults and their interaction; with electrical insulating materials within coal.-mine power-system enclosures is described. This work was performed at The Pennsylvania State University from 1 December, 1976 through 30. November, 1977. Results presented are interim in nature and future research is planned to integrate the simulations which have been constructed, as well as to apply developed experimental procedures to the evaluation of electrical insulating materials for use in coal-mine enclosures. The thrust of this research has been divided into several primary areas. These include the development of a theoretical procedure for computation of three-phase and line-to-line arcing fault currents as a function of time, formulation of an arc model based upon thermal-arc plasma properties so that arc voltages and energies may be computed, development of a simulation for pressure and temperature rises when an arc interacts with an electrical insulating material within an enclosure, experimental evaluation of electrical insulating materials in terms of their tendency to support an arc as well as their potential contribution to enclosure pressure rises, and integration of the above research areas to form overall procedures for theoretical and experimental evaluation.

Jan 1, 1977

By M. C. McCall

When electric current of any appreciable magnitude flows from a power line into the earth, a change sometimes takes place in the conditions of resistivity immediately surrounding the electrode or medium of contact. If the conducting medium is composed of moist earth or clay the effect is to increase rapidly the resistance. If the conducting medium is coal or a coal bed, the effect is one of slowly decreasing resistance as the coal is carbonized, If, however, the flow of current is not enough to carbonize the coal, it will dry slowly, with a resultant increase in resistance. Measuring ground resistance, or impedance, with conventional commercial ground testers does not always indicate the current that will flow in the earth circuit from a direct-current or an alternating-current power circuit. The exact reason for this has not been determined however, it is thought to be due to the comparatively minute currents used for such testing. A typical ground, tester used by the authors for this work indicated a maximum current of 25 milli-amperes. The frequency of this testing current also has an effect on the readings in all probability. While the possibilities of the effects of varying frequencies has by no means been fully explored in this investigation, there are very definite indications that the impedance of a circuit through a section of earth will vary in some inverse relationship to the frequency of the applied voltages. This is evident at ordinary power-line frequencies ns well as at higher frequencies up to 200 kilocycles, which was the highest frequency available for tests in this investigation. This report is written in the hope that it will stimulate further investigation of the possibilities suggested for communication and the development of safety devices for increased electrical safety in coal mining.

Jan 1, 1952

By C. W. Davis

This is the first of a series of papers being; prepared as the work progresses in a study of the hydrometallurgy of manganese. The investigation is being made in an endeavor to make possible the utilization of lour-grade domestic manganese ores. The value of a hydrometallurgical process for manganese depends on the present and future uses for manganese products.

Jan 1, 1930

By C. J. Chindgren, L. C. Bauerle, J. B. Rosenbaum

Modifications of the conventional method of preparing ductile vanadium metal by calcium reduction of V2 05 in a bomb were explored for clues to a more economical procedure . The modifications examined included ( 1 ) omitting the gas purge of the bomb ordinarily used for eliminating atmospheric nitrogen , (2 ) using low- grade vanadium feed materials , ( 3 ) using alternative reductants , such as aluminum , magnesium , and silicon , and reductant mixtures , and ( 4 ) bomb refining of aluminothermic metal produced in open- vessel reductions . The most promising modification appeared to be bomb refining , using calcium to purify vanadium metal -- of low aluminum but high oxygen content-- prepared by open- vessel aluminothermic reduction of vanadium pentoxide .

Jul 1, 1960

By A. B. Hooker, P. G. Guest, E. J. Gleim

"From time to time the United States Bureau of Mines has received reports of gas explosions alleged to have been caused by correctly assembled flame safety lamps. In most of the mines where the explosions occurred the lamp was in use at a working face where the velocity of the ventilating current would be relatively low. The inference has been that the lamp was correctly assembled but that the gauze became sufficiently overheated to ignite the surrounding atmosphere.As part of its routine investigation of flame safety lamps the Bureau of Mines subjects each lamp to a test in still and moving atmospheres to determine its safety. Heretofore, as long as the lam, successfully passed this and other tests no determinations as to the margin between success and failure were made; hence, in attempting to answer inquiries concerning the reported explosions it was found desirable to be able to give actual gauze temperatures as a measure of the comparative safety of lamps under various conditions. The previous laboratory tests of flame lamps in still mixtures were made in a chamber or ""gallery"" of relatively small volume where the lamps might have been subject more or less to the smothering effect of the combustion products. It was therefore decided to make a special series of tests to obtain the gauze temperatures of both bonneted and unbonneted lamps in still and low velocity mixtures, using a larger gallery to offset any smothering effect.These tests are believed to represent the first attempt at measuring gauze temperatures by means of themocouples. The results will not only be of interest but will also be helpful to many in determining the status of flame safety lamps relative to gas ignitions in mines."

Feb 1, 1929

By Timothy A. Clancy

In support of research on forming ceramics from mining and processing wastes, the Bureau of Mines tested various commercial refractories to evaluate their resistance to melts of these wastes. Sixteen refractories of various types were exposed in slag erosion tests to two siliceous waste melts with Si02/CaO ratios of 4.0 and 2.2, The extent and nature of slag attack were then determined for each refractory. The nature of slag attack was investigated through scanning electron micrographs and microprobe elemental distributions. The refractories that performed best in resisting attack by the melts were high-alumina types, and of the refractories tested, the most resistant was a 90-pct-Al203, 10-pct-Cr203 refractory.

Jan 1, 1983

The performance of two large-capacity ventilation systems was compared through tests conducted in a large dead-end heading at a pilot oil shale mine in Colorado. Sulfur hexafluoride (SF6) tracer gas was used to measure the performance of the two systems: a free-standing jet fan and a reversible fan with rigid duct. The tracer gas was used to simulate the production of mine air pollut-ants, including blasting pollutants, hot diesel emissions, free methane from surrounding strata, and methane desorbing from muck piles. The test room was 55 ft wide, 30 ft high, and 320 ft long. The performance of the two fans was similar, but the jet fan used less power. The tests showed that either system could provide effective ventilation during oil shale mining.

Jan 1, 1986

By Dale E. Wittmer

Nonoxide ceramic materials could substitute for high-temperature alloy steels containing imported critical and strategic materials such as cobalt, chromium, and nickel if their high-temperature properties can be improved. An important result of this substitution would be a reduction of the Nation&apos;s need for imports of critical and strategic materials. In this Bureau of Mines investigation, the primary objective was to produce high-purity u1trafine (particles <5 ~m equivalent spherical diameter (ESD)) alpha-silicon carbide (a-SiC) powders with improved high-temperature properties using the Bureau&apos;s patented turbo-milling process. A secondary objective was to determine the feasibility of using polymer mill construction materials as a means of eliminating metal contamination from the turbomill. U1trafine a-SiC powders with BET (Brunauer-Emmett-Te11er) surface areas from 30 to 35 m2/g (~0.06 ~m particle ESD) were produced in an all-polymer turbomi11. These high-purity powders (with I-pct Band I-pct C additions) hot-pressed to greater than 99 pct of their optimal density and exhibited properties commensurate with those of commercially available a-SiC. The most promising of the construction materials tested for the major wear surfaces of the turbomi11 was u1trahigh-mo1ecu1ar-weight (UHMW) polyethylene, a polymer thermoplastic.

Jan 1, 1984

By W. H. Lewis

This Bureau of Mines report and its companion report (Information Circular 9074) have been prepared as a complete reference on underground coal mine lighting. This report discusses the fundamentals of light and its interrelationship with the visual process. The purpose of the report is to insure an understanding of the numerous complex and interrelated factors that must be considered to design and implement a mine lighting system that will satisfy human needs for good vision and comfort. Topics include history, objectives, and technical considerations of coal mine lighting; light physics; light and vision relationships; and disability and discomfort glare.

Jan 1, 1986

Table 1.-Salient aluminum statistics (Thousand short tons and thousand dollars) [ ]

Jan 1, 1967

By C. F. Wingquist

As part of an ongoing study to determine how the wear of mining tools affects dust generation, the Bureau of Mines has measured bit tempera-ture rise during cutting of abrasive rock. Radial bit wear-flat tem-peratures generated by linear cutting in Berea Sandstone were measured as a function of cutting depth and speed. Depths of cut (DOC) were 1/8, 1/4, and 1/2 in, and cutting speeds were 10, 40, and 80 in/s, respectively. Temperature sensing was accomplished by emplacement of a miniature thermocouple into the center of the wear flat. Temperatures observed ranged from 2000 to 5000 C. Correlation between depth and temperature was weak. Temperature increased linearly with speed at 1/2-in DOC, but data taken at 1/8-and 1/4-in DOC produced inconclusive results. The results indicated that at least for deeper cuts (1/2 in), bit temperature, and therefore wear, can be reduced by lowering the cutting speed.

Jan 1, 1987

By F. R. Cattoir, R. E. Cumings

Columbium metal was electrorefined in a fused - salt electrolyte . Excellent results were obtained in lowering the impurity content in a 94 - percent columbium anode feed material to produce a 99.8- percent - pure metal . The reductions of the major impurities follow : Oxygen from 19,800 to 500 ppm , carbon from 9,700 to 25 ppm , iron from 9,200 to 630 ppm , nitrogen from 2,100 to 90 ppm , and silicon from 750 ppm to not detected . Columbium with a purity of 99.9 percent was produced from 99.5- and 99.8 - percent grades of columbium. The investigation was devoted to the evaluation of a fused - fluoride - salt electrolyte ( KF - NaF- K₂ CbF, ) for electrorefining columbium. The effects of the columbium concentration and the voltage upon the product's purity were investigated . The effect on the cathode current efficiency of ampere - hours of deposition and the formation of a dual valence state of the columbium was also investigated .

Jan 1, 1964

Treat contaminated coal mine drainage to meet EPA and State water quality requirements. Approach A model (fig. 1) is presented for selecting, designing, and sizing one or several passive mine drainage treatment systems that can be used in remediation of abandoned mine lands (AML). The three principal types of passive mine drainage technologies for the treatment of coal mine drainage are an aerobic system, a compost wetland, and an anoxic limestone drain. The multistep approach presented here provides a simplified method to characterize the type and magnitude of the water quality problem and then to select either a single treatment system or a combination of treatment systems to address the specific site situation. How It Works Step 1. Discharge Characterization. Characterization of the discharge consists of measuring the discharge flow rate and collecting water samples at the point of discharge for chemical analysis. Both the flow rate and chemistry of a discharge can vary seasonally and in response to storm events. It is important to account for this variability by determining flow rates and water chemistry under various conditions.

Jan 1, 1992

By Rex D. Thomas

Concentration of the kerogen (organic material) in oil shale was accomplished by centrifuging after pretreating the oil shale with carbonic acid to remove the carbonates and pretreatment with sodium hydroxide (pH 11.5) to remove the claylike minerals. Analysis of the materials obtained showed that the concentrations of organic sulfur and organic nitrogen compounds were not affected by centrifuging. These compounds are evenly distributed in the kerogen and are not strongly bound to the mineral constituents. Organic oxygen compounds, however, were concentrated in the light fraction. These compounds are more closely associated with the kerogen and are not bound to the mineral constituents. Iron compounds other than pyrite apparently are closely associated with the organic material.

Jan 1, 1970

By R. V. Ramani

"The importance of adequate mine ventilation for good health and safety conditions has been recognized since miners first ventured underground. All over the world, governmental actions on mine health and safety arc directly connected with mine atmospheric environments their assessment and control. These governmental actions have been, and continue to be, motivated by the repeated experience that potential threats from inadequate control can evolve, either suddenly or in the long-term, into unpleasant reality, with catastrophic health and safety consequences. These governmental actions arc also an indication of the remarkable professional progress being made in the field of mine ventilation.Surely, no developed country allows underground mines to operate without strong measures for the control of ventilation under legislation specific to the mining industry. In the United States, the federal government's responsibility for mine safety has evolved over the years through a series of legislative actions beginning in 1865 and continuing through 1910, 1941, 1947 and 1952.The passage of the Federal Metal and Nonmetallic Mine Safety Act of 1966 (the 1966 Metal Act), the Federal Coal Mine Health and Safety Act of 1969 (the 1969 Coal Act) and the Federal Mine Safety and Health Amendments Act of 1977 (the 1977 Mine Act) arc the most important milestones in this long legislative history. The 1977 Mine Act adopted many of the stronger features of the Occupational Health and Safety Act of 1970, perhaps the most significant piece of legislation on workers' occupational health and safety in US history.It is worthwhile to ask, ""How far has the United States come in mine ventilation since the enactment of the 1969 Coal Mine Health and Safety Act?"" This Act and its associated regulations defined in great specificity many standards for healthful and safe operation of a mine and. in some cases, what constitutes good ventilation practice."

Nov 1, 1995

By S. J. Broderick

[The term "nonmetallic minerals? as commonly used is the mining industry, refers to those minerals of industrial importance that are mined essentially for uses other than for the metals contained. The field comprises several hundred rod minerals of industrial importance, of which 70 have can adequately described in the textbook Industrial Minerals and Rocks. A few o f the more important nonmetallic products are sand and gravel, salt, phosphates, clays, refractories, limestone, and cement materials. Some of the minerals, such as bauxite and pyrolusive, have both metallic and nonmetallic applications, but in this report only the nonmetallic mineral phases are considered. In the organic field of nonmetallics only coal is considered, as, the others - petroleum, natural gas, natural bitumens, and hydrocarbons - are of no importance in water softening.]

Jan 1, 1941

By C. B. Daellenbach

A prototype particulate size analyzer system was developed that would rapidly determine size distributions of homogeneous and two-mineral materials in the 74-micrometer (200-mesh) to 7-micrometer size range. The system sizes particles in a series of hydrocyclone elutriation steps and senses the weight of the five sized fractions by nuclear attenuation techniques. Size distribution of materials was determined from experimentally developed mathematical relationships that existed between particulate weight and the measured transmittance of gamma rays from an Americium-241 source. In the developmental phases, size distributions of three minerals (quartz, magnetite, and hematite) and a laboratory prepared two-mineral mixture of quartz and magnetite were accurately determined by the prototype system. In later stages of the investigation, semiconcentrates, an intermediate magnetic product from a taconite plant, were evaluated. Using 25-gram feed samples of this industrial material, the analyzer system was found to predict weight percentages for individual size fractions with an accuracy of ±0.85 percent or better at a 95-percent confidence level.

Jan 1, 1974