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By E. R. Palowitch

This report stems from a study by the Bureau of Mines of the possibility of reducing coal filter-cake moisture by applying radiant heat directly to the filter cake while under vacuum during the drying phase of the filter cycle. One disk of a 4-foot-diameter vacuum filter was equipped with gas-fired radiant-heat generators and the effect of radiant heating on the moisture content of a variety of filter cakes was studied. The results of this investigation show that this process can best be described as a filter aid capable of increasing the effectiveness of conventional filtration approximately 6 percentage points of moisture. The operating cost of removing water by this method is somewhat lower than the average operating cost of thermal drying and is considerably cheaper when the total cost is considered. Removal of water from coal that has been wet-cleaned is an important part of the overall coal preparation process. Water is a contaminant, and it is foolish to wash coal to reduce its ash content and add inert water in the process. In some instances the removal of water is actually more important than the removal of ash-forming minerals; its weight adds to the cost of transportation, and its evaporation during burning or carbonizing absorbs useful heat. Fine coal that contains more than about 10 percent moisture is notoriously difficult to handle. A problem thus exists for which there are sound practical and economic reasons to seek a solution.

Jan 1, 1961

By C. M. McKinney

This report presents analyses of crude oil from most of the fields in the United States producing 2,500 barrels per day or more. The purpose of the report is threefold : 1) To present detailed analyses of crude-oil samples from as many al possible of the important fields in the United States. On January 1, 1947, there were 340 fields producing 2,500 barrels & day or more. Analyses for 283 of these fie1ds are presented. Fifty-seven fields have been omitted because the Bureau of Mines did not have analyses or the crude oils being produced. As one sample was not representative of the promotion from several of the fields, two analyses are given for each field of this kind. (2) To compile these analyses, many of which have not been published previously in a single report. Since the publication of Bulletin 291 in 1928, there has been no report showing analyses of crude petroleum from fields throughout the United states, but a number of separate reports according to area or state have been issued. Many of these are out of print. (3) To provide a means of ready comparison of the properties of crude oils from different areas of the United states.

Jan 1, 1948

By H. H. Dewing

The U.S. Bureau of Mines characterized Hg-containing wastes and used a thermal-desorption process to remove and recover the contained Hg. The wastes were generated by an electrical-parts plant engaged in the assembly of Hg-containing switches and contained phenolic resins and paper insulating materials mixed with soil. The average Hg content was 396 ppm. Numerous characterization tests showed the Hg was tightly absorbed and could not be removed or concentrated by leaching or gravity separation techniques. Laboratory retort tests showed the Hg content reduced to < 16 ppm in 2 h at 400 °C; rotary-kiln, thermal-desorption tests required 4 h at 450 °C. Airflow through the retort im¬proved thermal-desorption efficiency, but vacuum operation only slightly reduced the temperature needed for thermal desorption. Offgases from decomposition of organic materials were burned in a high-temperature afterburner and subsequently cooled in a heat exchanger to condense water vapor. Finally, the Hg vapor was condensed and absorbed from the offgas by activated charcoal. Mercury recovery was over 99.99 pct of the desorbed Hg. Thermal-desorption processes have had wide application to many Hg-containing wastes, and historical experience in Hg mining has demonstrated its potential cost effectiveness.

Jan 1, 2010

By Raghoottma S. Pandurangi, Mohindar S. Seehra, Pedro Bolsait, Bronwyn L. Razzaboni

"Surface IR (infrared) modes of crystalline and fumed (amorphous) silica particles, calcined at temperatures up to 1095°C, have been studied by Fourier transform infrared spectroscopy. The ability of these same particles to lyse cells has been measured by a hemolysis protocol. The untreated crystalline and amorphous materials differ by a factor of 40 in specific surface area, and the intensity per unit mass of the sharp surface silanol band near 3745 cm-1 in the amorphous material is an order of magnitude larger than in the crystalline material. A similar difference is observed in the lysing potential of the two materials. The intensity of the silanol band increases after calcination for both materials, reaching peak values near 500°C, followed by a dramatic drop at higher calcination temperatures, and reaching negligible values for materials calcined near 1100°C. The lysing potential data follow essentially the same pattern for both crystalline and fumed silica. These results are consistent with the hypothesis that the surface silanol groups are involved in cell lysis. Further experiments are suggested to evaluate the relationship between the surface structure of ailica particles and their potential cytotoxicity. IntroductionThe characterization of the surface structure of various allotropic forms of silica is of interest because the cytotoxicity of silica particles of respirable size has been commonly related to the chemical interaction of functional groups on the surface of such particles with the lipoproteins contained in cell membranes (1-3). It has been found that the cytotoxic potential of silica particles varies greatly with their crystalline structure (4,5), particle size (6-8), surface composition (9), and molecular surface configuration (1,10). Studies of the infrared (IR) modes of various forms of silica have been reported by a number of researchers (3 ,11-19). Several books and reviews (20-24) have dealt with the identification of functional groups on silica surfaces and the effect of heat treatment on the surface structure. The nature of the surface is said to be critical in determining the biological activity of silica dusts (3).Fourier transform infrared (FTIR) spectroscopy is a highly sensitive ·technique for identifying IR surface modes of tine particulates, and it was deemed of interest to examine the surface structure and its relation to lysing potential of two widely different types of respirable silica dust. The lysing potential of respirable dust particles has been considered a first-level test for potential cytotoxicity."

Jan 1, 1990

By M. H. Kline, Wing G. Agnew

"INTRODUCTION The Yancey-Crawford tract, located 1-1/2 nines east of Yancey station on the Norfolk & Western Railway in Rockingham County, Va. was from 1917 to 1941 considered an unusually promising manganese prospect. Because of the favorable geologic formations and because of the common occurrence of manganese in the district and Virginia's large production of these minerals from this area, geological report 3/ have listed this tract as the No. 1 prospect in the State. During World War I, extensive geologic studies were made to locate manganese deposits similar to those exploited at the Crimera mine near Waynesboro to alleviate this mineral shortage during the existing emergency.In September 1941 the Bureau of Mines started exploratory drilling on the tract in an effort to discover and block out reserves of manganese minerals as authorized by the 76th Congress under the Strategic Materials Act. After five drill holes wore sunk, the project was terminated October 1941."

Apr 1, 1948

By W. K. Sawyer

Resistivity, porosity, permeability, and saturation data were obtained on core samples from the Big Injun, Clinton, Gordon, Bradford Second and Third, and Venango Second oil sands and formation factor-porosity relationships were derived using the general form of Archie&apos;s equation F = aø-m, where F is the formation factor, ø is the porosity, and a and m are constants that depend on characteristics of the rock. It was found that a and m varied significantly between sands, as did the exponent in the Archie relation I = Sw-n, where I is the resistivity index and S, is the water saturation. The average exponent, n, determined from all data was 50 percent greater at residual oil saturation than at residual water saturation. Samples from each sand exhibited differences in directional resistivity and/or permeability. The Bradford Third sand data showed correlation between resistivity and permeability anisotropy.

Jan 1, 1971

By James P. Ulery, Frank E. Chase

Clay veins found in coal mines have caused numerous injuries and fatalities. These structures plague all phases of mining, including entry development, pillar recovery, and panel extraction. Clay veins also increase production costs and may disrupt or halt mining. These detrimental aspects have prompted the Bureau of Mines to investigate the physical characteristics of and roof instability problems associated with clay veins. This was accomplished by observing and mapping clay veins in surface and underground mines. The occurrence and origins of clay veins were also investigated to determine predictive capabilities. The investigators found that clay veins normally occur in more stable, less rapidly subsiding coal basins. Clay veins result when tensile stresses develop fissures which are later infilled. These fissures can be propagated by compactional processes and/or tectonic stresses active during and subsequent to coalification. The Bureau also found that associated faults, fractures, and slicken-side planes commonly parallel clay veins and disrupt the lateral continuity of the immediate and, sometimes, main roof. When clay veins parallel or subparallel the direction of face advance, the roof is segmented into cantilever beams, causing unstable conditions. Consequently, the strata on either side of the clay veins should be bolted and strapped together to form a beam.

Jan 1, 1987

By Jack I. Paige

The Bureau of Mines conducted studies to provide data on the room temperature mechanical properties of Ti-6Al-4V alloy cast in waterglass-bonded zircon sand and to determine the effect of hot iso-static pressing (HIP) on these properties. Data on the cast and annealed Ti-6Al-4V alloy were compared with published data for forged and investment-cast Ti-6Al-4V alloy. The average Charpy V-notch impact strength compared favorably with the typical values of 17 ft?lbf for wrought material and 19.2 ft?lbf for investment-cast material. The room temperature mechanical proper-ties of cast and annealed material compared favorably with published values for investment-cast Ti-6Al-4V alloy and exceeded the specifications for (1) titanium and titanium alloy castings, grade C-5 according to ASTM B367-69, and (2) titanium alloy bars and forgings as specified in AMS4928H, except for the AMS4928H minimum requirement for reduction in area (25 pct). The minimum requirements are: tensile strength, 130 ksi; yield strength, 120 ksi (0.2 pct); and elongation, 6 pct. None of the specimens tested met the AMS4928H minimum requirement for reduction in area. The HIP process healed the internal casting porosity in the test specimens, but the fatigue strength was not significantly improved. The fatigue properties of both the cast and cast plus hot isostatically pressed castings were significantly lower than those of wrought products.

Jan 1, 1984

By Charles Janin, HENNEN JENNINGS

Many articles have been written on the general principles and details of gold dredging, a but it is not possible within the limits of this paper to recapitulate them, and it is thus necessary to assume some knowledge of this literature by the readers of this paper. Although the purpose of this paper is to describe gold dredging in Montana, a brief mention of some early appliances used in New Zealand, Australia, and California may serve as a world-connecting link in our consideration of the development of gold dredging. DREDGES EARLY USED IN NEW ZEALAND, AUSTRALIA, AND CALIFORNIA. Spoon dredges operated by hand were tried in New Zealand on rich spots in the Clutha River with some success as early as 1865. A dredge of this kind is shown in Plate I, A. In 1870 a modification of the spoon, operated by steam and being thus a primitive steamshovel dredge, was worked in New Zealand. Steam-shovel dredging was attempted in California as early as 1888 and 1893, and with some success in later years. The elevator gold dredge with endless bucket chain was put into operation in New Zealand in 1882. Plate I, B, illustrates a type of this dredge operated by current wheels. Plate II, A, shows a steam-operated dredge of this class, also started in 1882. In 1897 R. H. Postlethwaite, connected with the Risdon Iron Works, San Francisco, introduced the dredging practice of New Zealand into California. The first dredge built sank in the turbulent current of the Yuba. The second at Oroville, owned and operated by W. P. Hammon, proved effective and was the start in California of successful gold dredging. Since then the growth of the golddredging industry in California has been so rapid that the gold output from dredges in that State exceeds that of all other States in the Union, and, in fact, of any other country of the world, the value of the gold produced in California by dredging from 1897 to the end of 1914 having been about $71,000,000.

Jan 1, 1916

By Martin Hertzberg

A comprehensive study of the flammability behavior of air-dispersed coal dust was made using an 8-liter Bureau of Mines system which included the following: (1) An optical probe to continuously monitor the dust concentration; (2) measurements of ignition energy requirements; (3) the use of several narrow size distributions ranging from 3 to 65 µm in average diameter; (4) measurements of the extent of flame propagation based on pressure attained at constant volume, residual O2 content after combustion, and flame and dust surface temperatures. The measured lean limit for near-horizontal propagation of Pittsburgh coal dust was about 135 mg/l (milligrams per liter), virtually independent of particle size. Required ignition energies were hundreds of joules and measured limit flame temperatures were 1,450 to 1,600° K. Data on inerting? requirements with KHC03, rock dust, and NaC1 gave approximately the same results as full-scale explosion tests. The good agreement suggests that the cause of earlier discrepancies between small-scale laboratory data and full-scale mine experiments may not have been the difference in size, but were rather a problem of proper care in isolating and controlling the significant experimental variables and in consistently defining the extent of flame propagation at the limits.

Jan 1, 1979

By Irving Hartmann

In recent years various modifications in the methods of blasting have been tried as a means of increasing the production of cod and of reducing mining costs. Following an investigation by the Bureau or Mines, authorization was granted to increase the charger limit for permissible explosives par shot hole from 1.5 to 3 pounds under contain conditions; this greatly facilitates the blasting of coal in some cool fields the practice has gradually evolved of simultaneously charging several shot holes in a face and then firing the charges singly without inspecting for gas after each blast. This practice is disapproved by the Bureau of Mines. In other coal mines the explosive chews in several adjacent shot holes are fired simultaneously. This form of shooting is claimed to increase the rate of production, generate smaller volumes of noxious gases, promote the health and safety of workers by eliminating the need of inspection of the face after each charge is fired, produce less float dust, and require less explosive than single shooting. However, simultaneous blasting may have a more harmful effect on the immediate roof strata; in some instances it leads to wedging of the broken coal, thereby making the coal more difficult to load out; it makes misfired shots more difficult to detect and possibly increases the chances of misfires. This lacy be duo to variations in the characteristics of detonators, because of more stringent requirements for adequate firing current, to the need for better electrical connections in the shot-firing circuit, and partly to the inadequacy of present permissible multiple blasting devices.

Jan 1, 1952

By M. J. Kirwan

[There have been large increases in the oil production and casing-head gas production of certain wells on the Quinn dome (northern part of the Lyons-Quinn field of Oklahoma) caused by large volumes of gas under high pressure entering Vie productive oil sand, The oil production of sore of the leases in this part of the field temporarily increased over 100 per cent within a few days after gas entered the oil sand among the leases that had the greatest increases in oil production wore those on which no gas wells were drilled but which were located up-elope on the structure in reference to gas wells on adjoining properties. It is conservatively estimated that 1,444,000,000, cubic feet of gas entered the productive oil sand and, up to January 1, 1924, caused an increase of about 950,000 barrels of oil from this sand. The casing-held gas volumes of a number of wells producing between 25,000 and 75,000 cubic feet of gas per day increased to several hundred thousand cubic feet and a few walls increased to nearly two million cubic feet per day after extraneous gas entered the oil sand from which the wells were producing.]

Jan 1, 1924

"INTRODUCTION These inspection standards have been prepared for use as a guide for the Federal inspection of anthracite mines. They are a revision of ""Tentative Inspection Standards for Anthracite Mines,"" published as Bureau of Mines Information Circular 7231 in January 1943 and used as a guide for Federal inspections. Numerous changes in the original standards have been made, due in part to recognition of shortages of some types of safety equipment due to the war, in part to need of additional standards to cover certain mine conditions and practices, and in part to conditions not foreseen when the original standards were prepared.Throughout these standards reference is made to determining the methane content of the mine air by using a permissible flame safety lamp. The Bureau has approved various electrical devices for the detection of methane, but it is recognized that new devices for determining the percentage of combustible gases as well as the percentage of oxygen, might be perfected for general use in mines, and therefore it may be necessary to revise certain standards to include the use of such equipment if and when the device is accepted as being permissible.About one-fourth of these standards are marked with an asterisk (*) as being of particular importance in preventing accidents in many coal mines; however, failure to carry out the suggestions made in such of the other standards as are applicable may also lead to loss of life.With continuing change in mining methods, some of these standards may become inapplicable, and further revision will be advisable. Therefore, question regarding these standards and suggestions regarding new standards should be brought to the attention of the Bureau, so that changes may be made from time to time. Numerous changes proposed by mine operators and by State mining departments have been incorporated in these standards."

May 1, 1944

By H. R. Appell

The Bureau of Mines studied the conversion of a variety of cellulosic wastes, for example, sawdust, bovine manure, sewage sludge, urban refuse (free of metal and ceramics), etc., to heavy oils. The objective of the investigation was to determine the scope of the reaction and elucidate the chemistry involved. The reactions took place in the presence of synthesis gas and water or carbon monoxide and water under conditions of elevated temperatures and pressures. Waste conversions above 90 pct, often near 99 pct, with oil yields in the range of 40 to 60 pct, were obtained in the temperature range of 250° to 425° C and pressure range of 1,500 to 4,000 psig. Because mild conditions were sought, most of the experiments were conducted at temperatures of 250° to 350° C and pressures of 1,500 to 3,000 psig. In general, lower viscosity products were obtained at higher reaction temperatures. Conversions and oil yields were significantly increased by operating in the presence of a high-boiling oil; either anthracene oil or oil recycled from the process was satisfactory. Synthesis gas containing 50 pct carbon monoxide gave satisfactory results as a replacement for carbon monoxide. Cobalt molybdate on alumina catalyst, used with sodium carbonate, gave a product of lower viscosity and lower oxygen content than sodium carbonate used as the sole catalyst. The waste-to-oil process has been successfully investigated in continuous flow equipment as well as in batch autoclaves.

Jan 1, 1975

By W. A. Selvig

"The purpose of the investigation described herein was to determine how closely different laboratories can check one another in making determinations of fusibility of coal ash with the De Graaf electric coal-ash fusion furnace: how well duplicate determinations by the same laboratory will check, and how the results with the De Graaf furnace compare with those of the standard gas-furnace method of the American Society for Testing Materials.4Thanks are due the following laboratories who cooperated in this study by making fusibility tests with the Do Graaf electric coal-ash fusion apparatus: J. J. Brennan, testing engineer, Northern States Power Co.; R. E. Gilmore, superintendent, Fuel Research Laboratories, Canadian Department of Mines A. T. Leavitt, president, and W. Mueller, chief chemist, Hamilton By-product Coke Ovens. Ltd.; Edgar Stansfield, chief chemical engineer, Scientific and Industrial Research Council of Alberta. Canada; and H. S. Vassar, laboratory engineer, Public Service Electric and Gas Co.The ash-fusibility determinations by the standard gas-furnace method were made in the Coal Analysis Laboratory of the Bureau of Mines at Pittsburgh under the direction of H. M. Cooper, associate chemist. The investigation was made at the suggestion of A. C. Fieldner, chief engineer, Experiment Stations Division of the Bureau of Mines.Routine determinations of the fusibility of coal ash are made in the laboratories of the United States Bureau of Mines by the gas-furnace method. This method was standardized after considerable experimentation5 on the nature of the fusion of coal ash and the various factors which affect its determination. The method was subsequently adopted by the American Society for Testing Materials as one of its standard tests."

Jun 1, 1930

By J. W. Griflith, P. A. Mack, C. M. Lang, S. Riling

"N-acetyl-beta(B)-D-glucosaminidase is a N-acetyl-beta((B)-D-glucosaminidase enzyme se¬creted by alveolar macrophages in response to phagocytosis of particulate material. Alveolar macrophages participate in the degradation and fibrosis of pulmonary tissue that results in pneumoconiosis. Known quantities of four characterized respirable dusts were bronchoscopically placed into the right caudal lung lobe of macaque monkeys. Bronchoalveolar lavage (BAL) samples were collected from dust-exposed right lung and unexposed left lung of the same individuals at 2-week intervals for 12 weeks after dust instillation. The samples were tested for N-acetyl-B-D-glucosaminidase activity to determine if the enzyme levels could serve as an indicator of pulmonary injury induced by generic coal dusts when compared to known fibrogenic and nuisance dusts. Installation of generic quartz, anthracite, or TiO2 dusts produced significant elevations of enzyme activity and increased numbers of macrophages in the dust-exposed lobes. Elevations in enzymatic activity and macrophage numbers were greatest in response to generic quartz dust. These results suggest that quantitative levels of N-acetyl-B-D-glucosaminidase activity may be a useful indicator of acute and chronic lung injury following exposure to fibrogenic and nonfibrogenic dusts.IntroductionCoal workers pneumoconiosis (CWP) is an occupational pulmonary disease associated with the inhalation of coal mine dust. An important external factor in the development of CWP is the composition of the respirable coal mine dust. A cause-and-effect relationship exists between coal mine dust and CWP, but it has not been shown that exposure to generic coal dusts will cause CWP [12]. Numerous immunological, biochemical, and cellular changes occur in CWP; however, in this study, only N-acetyl-beta(B)-D-glucosaminidase (NAGase), protein, and alveolar macrophages (AM) will be examined [7, 32, 33]."

Dec 1, 1996

By John W. Cole

As part of a general preliminary investigation of lead-zinc deposits in Stevens County, Wash., the Electric Point and Gladstone mines on Gladstone Mountain, in the Northport Mining District, were examined by R. M. Gammell, an engineer of the Bureau of Mines, in June 1946. A trenching and sampling program was executed later the same year under&apos; the supervision of Miro Mihelich and the author. This report presents the factual data obtained from the trenching and sampling operations.

Jan 1, 1949

Case 1: A driller-helper was pulling a winch cable toward a stack of drill steel when the cable contacted a 12,000-volt power line. The helper was killed, and the driller at the rig controls was severely injured. [ ] Case 2: A crew was preparing to remove a pump from a well when the hoist boom contacted a 4160-volt power line. The hoist operator was electrocuted. [ ]

Jan 1, 2005

By A. C. Fieldner, W. A. Selvig

Information concerning the fusibility of coal ash has become of considerable value to the consumer of coal, mainly in connection with the troublesome formation of clinker resulting from the melting of the ash constituents of the burning coal. The growing interest in such data has led the Bureau of Mines to make a general survey of the "fusing" or "softening" temperatures of the ash from coals of the United States. It is hoped that this information when used together with the large number of coal analyses published 1 by the bureau will assist the consumer of coal in comparing different coals, and in selecting the coal best adapted for his purpose.

Jan 1, 1922

By S. E. Khalafallo

The Bureau of Mines investigated the kinetics of reduction of wustite and magnetite with carbon monoxide. A mechanism was postulated wherein the interaction between gaseous and absorbed carbon monoxide appears to be the rate-determining process. This mechanism fully accounts for the experimental rate equation JL.h relates th velocity of reduction to the pressure of the reducing gas at constant temperature. It also explains the variability of the heat of activation of the reduction process with the state of aggregation of the oxide material. The integrated rate equation is in perfect agreement with the experimental reduction-time curves.

Jan 1, 1966