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By R. E. Heithecker, D. B. Taliaferro

"INTRODUCTION Recovery of core specimens from subsurface formations and their subsequent analysis are important aids in efficient development and operation of oil and gas fields. Gore specimens first were obtained mainly for the geologic information they revealed; now they are analyzed to determine many of the physical characteristics and conditions of the subsurface formations as well. Cores recovered from the producing formations may be analyzed for porosity, permeability, oil content, ""connate"" water content, and other physical and chemical properties of the formation, all to the end of furnishing enough data for making reliable estimates of the quantity and avail¬ability of oil and as within a reservoir and in devising efficient means for their withdrawal.Examination of bottom-hole samples of oil gives valuable information concerning the amount of gas in solution in the oil within the reservoir and the resultant shrinkage of the oil when the gas is released. Producing characteristics of reservoirs nay be determined by means of subsurface pressure and temperature gages and measurements male at the wellhead; however, unless reliable core analyses are available, these data have only limited use in any quantitative study of reserves. In such a study the quantity of oil, gas, and water contained in a unit volume of the reservoir formation is extremely important. Although reliable methods of analyzing cores have been developed and the data thus obtained are valuable, their applications become more limited or reservoirs at higher temperatures and pressures are discovered. This condition results almost entirely from the fact that in recovering a core from a formation of high pressure and temperature by present methods a large part of the fluid content of the core is lost or contaminated to an unknown extent. For a number of years most petroleum engineers have held that if this loss and contamination of the fluid content of a core were eliminated, the value of core analyses would be increased greatly."

Nov 1, 1939

By C. P. Bowie

For years many oil producers have believed that often low-pressure oil- and gas-bearing strata have been over coked in fields where the rotary system of drilling has been used. Collom3/ gave as a reason for this con¬dition that because the mud fluid was thick, the oil or gas stratum was plastered and sealed as the tools passed through it and no oil showed at the surface. Although this observation was made 15 years ago, it may often still be true notwithstanding modern developments in coring and electrical logging. Operators have believed, also, that mud fluid does not solidify behind the casing. Lewis and McMurray4/ stated: "All the evidence obtainable from practical experience points to the fact that the mud fluid properly mixed and employed does not solidify behind the casing, even in deer wells and after long periods."

Jan 1, 1937

By G. R. Smith

This report describes research carried out by the Bureau of Mines to develop new technology for electrorefining metals at much higher current densities than those normally used in commercial practice, preliminary studies using rotating-ring and cylinder electrodes to increase the mass transport of copper are discussed. Following this work, single- and multichannel cells were developed that utilized a high electrolyte flow in the channels formed by the anode-cathode pairs. Using these cells, copper was successfully refined at current densities in the range of 70 to 300 amp/ft2. The effects of flow rate, electrolyte composition, and grain-refining and leveling agents on the morphology and purity of electrodeposited copper were determined.

Jan 1, 1979

By Irven A. Jacobson

This literature survey consists of references dealing with gaseous state thermal decomposition reactions of organic nitrogen and sulfur compounds. The reference source for the survey was the Chemical Abstracts from 1930 to 1956, inclusive. Original articles were not studied. The starting date was set at 1930 because previous to this time much of the work is questionable. This report is in three parts: Part I lists nitrogen compounds; Part II, sulfur compounds; and Part III, compounds containing both nitrogen and sulfur. The organization of the classes of compounds is alphabetical: Part I - amides, amines, amino acids, ammonia, azides, azines, azo compounds, heterocyclic nltrogen compounds, hydrazine, nitrates, nitriles, nitrites, nitro compounds and miscellaneous nitrogen compounds; Part II - disulfides, sulfides (including double and triple sulfides), thiols, thiophenes and xanthates; Part III - thioacid amides, thiazoles, thiocyanates and thiuram disulfides. A class formula is included with each class name. The R's used in these class formulas may refer to hydrogen or to the same or different radicals when more than one R appears.

Jan 1, 1960

By ARCH L. FOSTER

The rapid increase in the mmber of automobiles during the last 25 years has resulted in the insistent and growing demand for better roads of more permanent construction. Some form of State license for the operation of automobiles has been in effect almost from the time of the first "self-propelled" vehicle, and some part of the revenue derived from the sale of these licenses has been applied to the maintenance and construction of roads. However, to obtain funds with which to build their present highway systems, the individual States have resorted to the taxation of gasoline. The first State to adopt a gasoline tax was Oregon, the law becoming effective February 25, 1919. By 1928, all of the States except two had levied taxes on gasoline at rates varying from 2 to 5 cents per gallon. New York and Massachusetts passed gasoline tax laws which became effective in 1929. Regulations governing the quality and the methods of handling gasoline and other petroleum products sold in the States have also been adopted by 29 States; many of these laws antedate the adoption of a gasoline tax. The variations in motor fuel speci- fications and methods of test have been pronounced in the several States. The Bureau of Mines, in making certain technical studies of the rasolines marketed throughout the United States, the results of which are reported in its semiannual motor gasoline surveys and other reports, has had occasion to obtain and compile all of the present (April 1, 1931) tax and pection laws of the several States which relate to motor fuel and other petroleum products. To facilitate the use of this material and to obviate the need in most cases of reading the complete text of the laws as published by the States, the pertinent information was arranged in tabular form for cly reference. 3 Although digests of States gasoline tax laws' are available and copies of the complete laws can be obtained from the State agancies in charge of the enforcement of gasoline tax and inspection laws, it is believed that

Jan 1, 1932

By Will H. Coghill, C. O. Anderson

In July 1921 , we were assigned by the U. S. Bureau of Mines to an investigation of milling methods in the Tri - State zinc district ( Missouri -Kaneas- Oklahoma district ) . The work has progressed without interruption , and about onehalf of the funds allotted for it has been expended . This preliminary statement abcut the nature of the work and the results so far obtained , has been prepared for the information of the operators , and through their assistance to insure the greatest possible progress during the remainder of the work . A general survey of the district was made , and many of the mining companies cordially offered the facilities of their plants for the investigation . The work was finally centralized at the plant of the 0. M. Bilharz Mining Co. Its manager , F. H. Gartung, and his successor , O. W. Bilharz , have been especially helpful , also the millmen at this plant and elsewhere have rendered assistance without which the work could not have advanced . The Missouri School of Mines and Metallurgy , Rolla, Mo. , and the Miami School of Mines , Miami , Okla . , have given hearty cooperation . The Webb City Iron Works and the Joplin Supply Co. donated some necessary apparatus .

Jan 1, 1922

By Oliver Bowles

In its geologic sense the term marble is applied to rocks consisting of crystallized grains of calcite or dolomite or a mixture of the two. Although limestone has the same chemical composition as marble it differs in that the component particles of calcium or magnesium car- bonates are granular and noncrystalline. In marble the crystals may be intimately intergrown, whereas limestone is an aggregation of unrelated particles cemented together into a solid mass. In its commercial sense the term marble has a much wider applica- tion. As susceptibility to polish is one of its chief commercial assets, all calcareous rocks capable of polish are classed as marbles. Lime- stones that show little crystalline structure may, if they take a good polish, be classed as marbles. Furthermore, serpentine rocks, even if they contain little calcium or magnesium carbonate, are classed as marbles, as they are commercial substitutes of true marbles.

Jan 1, 1916

By Rustu S. Kalyoncu

A major goal of the Bureau of Mines is to conserve the Nation's mineral resources by developing improved performance materials. In support of this mission, a survey of the state of the art of chemically bonded refractories has been made, covering the scientific literature, government reports, and patents. This review includes research and development results for phosphate, silicate, oxychloride, oxysulfate, and other bonding agents used in refractories manufacture. A significant finding of the review was that references on bonding mechanisms, bond formation kinetics, and other important process parameters and conditions were few and universally vague. As a result, recommendations are made to expand research efforts to investigate the kinetics and mechanisms of reactions in chemically bonded refractories.

Jan 1, 1982

By G. E. McElroy

Tae purpose of this paper is to present types of charts adapted to aid in the graphic solution of fan-performance problems of selection and operation, and to urge the adoption of similar charts by the National Association of Fan Manufacturers as standard forms for presenting fan-performance data. As matters now stand, it is difficult for the average engineer to solve such problems because a laree number of variables are involved, and performance data are not presented in a manner that permits their direct application to many problems encountered in practice. The performance of any centrifugal machine is determined not only by the machine itself but also by the fluid-flow system on which it operates. Actual performance of centrifugal fans is therefore e matter of the type, size, and speed of fan, on the one hand, and of the relation of pressure to quantity of flow, as determined by the physical condition of the airway system, on the other.

Jan 1, 1936

By G. E. McElroy

[The purpose of this paper is to present type: of charts adapted to aid in the graphic solution of fan-performance problems of selection and operation, and to urge the adoption of similar charts by the National Association of Fan Manufactures as standard forms for presenting fan-performance data. As matters now stand, it is difficult for the average engineer to solve such problems because a large number of variables are involved, and performance data are not presented in a manner that permits their direct application to many problems encountered in practice. The performance of any centrifugal machine is determined not only by the machine itself but also by the fluid-flow system on which it operates. Actual performance of centrifugal fans is therefore a matter of the type, size, and speed of fan, on the one hand, anti of the relation of pressure to quantity of flow, as determined by the physical condition of the airway s: stem, on the other.]

Jan 1, 1936

By William F. Hahn

The Bureau of Mines recognized the problems encountered in low seam mining illumination systems. It was determined that the best way of implementing an illumination system is to integrate the design during the design and fabrication of new machinery at the factory. The purpose of this program was to integrate an approved lighting system in a low seam battery powered scoop and evaluate its performance. This report documents the work performed on this program and the results obtained.

Jan 1, 1980

By E. H. Crabtree

This paper, describing the milling practices at the White Bird concentrator, Picher, Okla., is one of a series on milling practices being published by the Bureau of Mines. The concentrator of the White Bird mine, Canam Metals Corporation, is located in almost the geographical center of the present Picher mining cam' in the Tri-State district, one-half mile east of the town of Picher, 1 mile south of the Kansas State line, and about 18 miles west of the Missouri State line.

Jan 1, 1930

By Allan M. Johnson

Case histories were used to document and evaluate deficiencies in underground mine closures which have resulted in post-operation problems such as subsidence shaft failures, acid or toxic water drainage and others. Three different underground mining districts in the United States were investigated; 1) an iron mining district in Michigan 2) coal mining districts in eastern Ohio and southern Illinois and 3) three metal mining districts in central Colorado. Previous work in the Michigan district on problems with subsidence and acid water drainage provided the background from which the concept for this project was developed Student investigators working towards their MS degrees in Mining Engineering did the work on the eastern coal and western metal districts. The combined studies show that problems from acid water drainage, subsidence and inadequately protected mine shafts are the most severe and widespread. Suggestions of a technical nature are presented as partial solutions to some of these problems. It was determined that pre-closure evaluations could result in the identification of some potential problems that may occur after the mine is closed. Early recognition of these problems would be an advantage for at this time more options are available to the mine operator to either prevent them or to plan for their occurrence. Mine closure and reclamation should be considered as a part of mining and be incorporated in the mining plan. This would result in reduced environmental impact and would be achieved at a lower overall cost to the mining companies and to society. The role of water in the occurrence of several types of subsidence during mine flooding was significant at some mines in the Michigan district. These mechanisms which involve, friction reduction, gravity loading, overburden transport and hydraulic forces in a flooded mine probably have a broader effect than is currently recognized. Control of these processes may offer some interesting options during mine closure. It is recognized that technical solutions alone cannot provide all of the answers to problems associated with underground mines. Education, modified attitudes on the part of regulators and operators, and a more realistic perception of the importance and value of mining by the general public are also needed.

Jan 1, 1983

By Harold M. Smith

Natural gas has been used as a fuel and source of energy almost from its discovery, but its use as a chemical raw material may be said to have begun in 1918, when Brooks and Humphrey3/ showed. presence of alcohols in the diluted acid oil obtained by the sulfuric acid-treatment of cracked petroleum distillates. However, development of the utilization of natural gas for chemical syntheses was slow, partly because erroneous ideas existed regarding the nonreactivity of tine hydrocarbons composing natural gas. Data accumulated by petroleum chemists throughout the world, particularly since about 1930, have shown that these hydrocarbons will react when activated by the effects of heat, pressure, chemical reagents, and light; also that the reactions can be made to proceed of practicable speeds and to provide good yields of useful products with moderate operating conditions, especially if catalysts are employed. As those results became known, the possibility of a synthetic organic chemical industry based upon these reactions became apparent, and today this industry is large and growing rapidly in importance. In this paper the story of the manufacture of chemical products from natural gas is told simply in graphic form. The industry is developing so rapidly that soma products may have been omitted, but every effort has been made to include all that are important or likely to become so. The difficulty of keeping information of this tape up to date is shown by reference to an information circular4/ or, the sore subject published by the Bureau of Mines in 1930, in which the important products are shown on a single chart, where as five charts are employed for the cane purpose at present.

Jan 1, 1940

By Anil Mahyera

This report present the results of a laboratory and field research program aimed at design and development of a torque-thrust controlled bolter with the capability to (1) predict the "quality of anchorage" attained while installing mechanical anchor roofbolts, and (2) improve the uniformity and tension levels achieved among a group of roofbolts. The prediction accuracy of the anchorage quality algorithm ranged from low to moderate because of the complexity and variability of the phenomena involved. The best roof support with mechanical anchor bolts was found to be achieved by simply installing them under ? proper torque-thrust control, and with ? a hardened washer under the bolthead. This procedure resulted in an improvement in uniformity of 3 times, along with an increase in mean tension levels of 75% over conventionally installed roofbolts.

Jan 1, 1983

By S. H. Ash

A CLAY, sand, and gravel deposit known as the "buried valley" of the Susquehanna River is situated in the Northern field of the anthracite region of Pennsylvania near Wilkes-Barre. The presence of this buried valley and the uncertainty regarding the extent and physical condition of the water-bearing valley-fill deposits have made great care necessary in mining operations to avoid breaking the strata between the mine workings and the valley-fill deposits to the extent that inundation of the mine workings would follow. The principal factor that threatens to cut short the life of the anthracite industry, to curtail production, and to affect the economic structure of the people and business dependent on anthracite for their livelihood is inundation of anthracite mines (6,7).3

Jan 1, 1950

By H. J. Kelly

[This investigation of the refractory properties of seven Pacific Northwest chrome ores and concentrates has shown that five of the ores and one of the concentrates are suitable for making refractories and that all may be used in combination with high-grade chromite. The specific objectives of the investigation were to determine the inherent physic al and chemical characteristics, to shapes using each of the chrome ores and concentrates, to compare the refractory qualities of the laboratory-prepared with commercial chrome refractories. As far as possible, standard tests were used as criteria.]

Jan 1, 1952

By Thomas A. Davidson

The Bureau of Mines Helium Field Operations has developed a simple and accurate method for calculating the viscosity of gas mixtures. Only the composition of the mixture and the molecular weights and viscosities of the pure components in the mixture are required. The momentum fraction of a mixture is calculated from the composition. The fluidity is calculated as a quadratic function of the momentum fractions. The efficiency factor for transfer of momentum in collisions between bodies of different masses is derived and used with one empirical constant. The viscosity is the reciprocal of the fluidity. Results of the method are compared with 752 reported viscosities for 40 dilute binary systems at temperatures from -78 to 276.9°C. Using this method the average absolute deviation is 1.29%, the root-mean-square deviation is 1.99%, and the average deviation is -0.84%.

Jan 1, 2010

By B. W. Gandrud

To say that the treatment and handling of the "fines" is the most difficult phase of coal preparation is probably an understatement of facts. It is the fine sizes from about 1/16-inch to 0 that are mainly responsible for the inescapable sludge and slurry problems at plants using wet methods of preparation. Sludge and slurry are a problem from the standpoints of both cleaning and dewatering. They cannot be cleaned satisfactorily by "gravity" methods, which are used so extensively on coarser Sizes, due to the fact that fine sizes, particularly from 65-mesh to 0, do not follow the same laws of settling as do the coarser sizes. Although fine sizes are cleaned more successfully on wet-wash tables than in jigs, even tables as usually operated in coal-preparation plants fail on sizes below 100-mesh. As to other phases of the, sludge and slurry problem, wet coal preparation plants are almost universally beset with troubles in connection with the recovery and dewatering of the fine sizes from about 14-or 20-mesh to 0. The sizes finer than 100-mesh further complicate the problems in a wet preparation plant by their tendency to stay in suspension and build up a troublesome load of solids in the circulating water. In order to prevent too much trouble from this source, it is, customary at most plants to bleed a fair-sized stream out of the circulating system continuously and replace it by addition of fresh make-up water. The slurry water withdrawn from the circuit is usually run to waste, in which case it carries with it a considerable amount of fine coal, thus increasing the "washer loss." Another evil results from wasted slurry water in that quite often it finds its way into creeks and larger streams, creating stream-pollution problems.

Jan 1, 1948

By John C. Gagliardi

The U.S. Bureau of Mines, in cooperation with Carter Mining Co., conducted vibration tests of four off-road vehicle seats. The purpose of the tests was to determine which seat provided the best vibration attenuation under laboratory conditions. Laboratory tests were constructed to simulate the mining vibration environment within the limitations of the test equipment. The acceleration test levels and corresponding response of the seats were low compared to ISO 2631's fatigue-decreased-proficiency time limits. Two of the seats employed mechanical suspensions and two seats employed air suspensions. The seats were tested using a 22,241-N (5,000-lbf) electrodynamic shaker. Mechanical suspension seats were tested with various preload-to-mass ratios (PMR's) and cushion densities. Air suspension seats were tested with various air pressure levels and seat cushion densities. Air suspension seats provided good vibration attenuation if pressurized greater than 552 kPa (80 psi). Mechanical suspension seats' attenuation performance decreased if the PMR exceeded 9.8. Seat cushions of lower density provided less vibration damping.

Jan 1, 2010