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By John Kosek

The electrochemistry of carbon monoxide, nitric oxide and nitrogen dioxide was investigated at a variety of electrode materials in different supporting electrolytes. A portable detector for carbon monoxide was developed using a porous gold anode in perchloric acid supporting electrolyte. This detector has two full scale ranges, 0-100 ppm and 0-500 ppm. A portable detector for mixtures of nitric oxide and nitrogen dioxide was developed using a porous silver cathode in sulfuric acid supporting electrolyte. Nitrogen dioxide was determined in the gas stream by electroreduction. The nitric oxide in the gas stream was oxidized to nitrogen dioxide by passing it over Cr(VI) on firebrick. Electroreduction gave the sum of NO + N02. Analog circuitry was used to display the amounts of NO and N02 separately. Two ranges were available for each gas. They were 0-10 and 0-50 ppm for NO and 0-2 and 0-10 ppm for N02.

Jan 1, 1979

By M. Copeland

Phase relations of gadolinium alloyed, up to 40 weight-percent (wt pct), with AISI 304-type stainless steel were established. Body-and face-centered cubic iron-rich solid solution phases and several intermetallic gadolinium-containing compounds of variable composition that approximated the formulas Fe9Gd, Ni7Gd2, Ni3Gd, Fe2Gd, NiGd, and NiGd3 were identified. The intermetallic phases Fe9Gd and Ni7Gd2 were noted to melt at about 1,080° C at about 0 to 2 wt pct gadolinium. The melting temperature of Fe9Gd increased with increas-ing gadolinium content to a plateau at about 1,230°C and 30 wt pct gadolinium, and the melting point of Ni7Gd2 decreased to a plateau at 900° C and 30 wt pct gadolinium where Ni3Gd, NiGd, and Fe2Gd coexist. Body-centered cubic iron solid solution was stable from 1 to 2 wt pct gadolinium to higher contents, 30 wt pct gadolinium or possibly more, and face-centered cubic iron up to 12 wt pct gadolinium below 1,200° C. The stability of these phases above 1,200° C was not resolved except for the mel points. A limited number of fabrication variables as well as mechanical and corrosion properties of alloys containing up to 5 wt pct gadolinium were studied. Equilibrating and forming operations were best conducted at about 940° to 1,080° C. Some variability in the yield and tensile strengths of alloys was noted; however, there was a continual decrease in ductility and impact resistance with increasing gadolinium contents. The resistance of gadolinium alloys to corrosion in water at 354° C was about the same as stainless steel.

Jan 1, 1965

By R. V. Ramani

This report is volume 2 of an eleven-volume final report for a Grant completed by The Pennsylvania State University for the Bureau of Mines to develop a dynamic general purpose computer simulation model for underground coal mining. The simulator developed under the Grant has a wide range of possible applications in the design and evaluation of underground coal mining systems from the standpoints of health and safety, productivity, and mine environment. The Master Design Simulator consists of nine free-standing function-oriented subsystem models linked together into an integrated, comprehensive model of an entire mining system. The subsystems comprising the Master Design Simulator include geology and reserves, methane generation, roof support, subsidence, production, rail haulage, cost, water generation, and ventilation. This volume of the final report describes the Geology and Reserves subsystem of the Master Design Simulator. The two functions of this subsystem are: 1) the design of a geological data library to provide input to the other subsystems of the simulator; and 2) the calculation of coal reserves and associated values and grades under various user-specified conditions. The subsystem uses a weighted moving average method to interpolate between the borehole values, and provides output in report format, graphical plots and/or storage on magnetic tape or other storage devices for later retrieval. The application of the subsystem as an independent model with test results and comparisons with other methods of computing reserves is also presented. The appendix comprises a users manual for the model, and includes a program listing.

Jan 1, 1974

By E. G. Noble

The effects of hydrogen chloride (HCI) concentration and temperature on the solubility and hydration state of the alkali chlorides LiCI, NaCI, and KCI and the alkaline-earth chlorides, MgCI2, and CaCl2 were investigated by the Bureau of Mines. Saturated aqueous solutions of the chlorides were sparged with HCI gas at temperatures of 20°, 40°, and 60° C. Increased HCI concentration caused decreased salt solubility be-cause of the common ion effect. Aqueous solubilities for the chlorides of Ca, Li, Mg, K, and Na ranged from 42.6, 45.2, 35.2, 25.5, and 26.1 pct, respectively, at 20° C to 56.9, 49.4, 37.6, 31.0, and 27.0 pct, re-spectively, at 60° C. In solutions sparged to HCI saturation, solubili-ties for these chlorides ranged from 22.4, 26.5, 3.0, 1.3, and 0.05 pct, respectively, at 20° C to 53.2, 48.8, 28.3, 2.6, and 0.8 pct, respec-tively, at 60° C. The solubilities of LiCI and CaCl2 in HCI solution were high because HCI solubility is low in these solutions. The chlo-ride salts of Ca, Li, and Mg formed hydrates, which depended on tempera-ture and HCI concentration. Monohydrates for LiCI, tetrahydrates and hexahydrates for MgCI2, and dihydrates, tetrahydrates, and hexahydrates for CaCl2 were obtained.

Jan 1, 1985

By Shirley F. Colby

The past 40 years have seen the sand and gravel industry grow from small roadside pits and holes in farmers' back yards to giant corporations selling millions of tons of sand and gravel each year and owning plants representing huge capital investments in land and equipment. The days hen a man could "work out" his taxes by providing the materials for nearby roads are gone forever. In addition to the hundreds of privately owned and operated plants, Government agencies operate sand and gravel pits and plants to supply aggregates for the tremendous road-building and public-works programs in progress during the past few years. EXPANDING PRODUCTION In 1940 the send and gravel industry produced almost a quarter of a billion short tons valued at more than 110 million dollars. This compares with less than 2 million short tons worth 1 1/2 million dollars produced in 1902. The practice of screening sand and throwing away the gravel in the early days of the industry's growth has stopped, and in 1940 gravel constituted two-thirds of the total production. In 1906, the first year in which sand and gravel were reported separately gravel accounted for only one-

Jan 1, 1942

By R. R. Sayers

"The number of investigations reported during the past year indicates that control of the health hazard due to abnormal air conditions is still a matter of serious consideration in the mining, metallurgical, and allied industries.Australia. - In an investigation into the health and working conditions of employees in the mining industry of Tasmania and Victoria3, it was found that although pulmonary tuberculosis may occur early in life, silicosis is e disease of slow evolution and does not appear frequently under the ace of 40. A period of at least ten years in the industry was found necessary to produce silicosis, and in no case was the disease found in those who had not worked underground. A very high incidence of silicosis was found in all fields among those who had worked underground 20 years and longer. There was some evidence that silicosis complicated by tuberculosis may occur earlier than uncomplicated silicosis.England. - In a paper presented before the Section on Occupational Diseases of the British Medical Association, Dr. E. L. Middleton, the medical inspector of factories, called attention4 to the occurrence of silicosis in various industries throughout the country.punitive on some quite harmless industries. Thus Middleton says: ""Where the amount of dust is small the action of the phagocytes is likely to be effective, but where it is great . . ."" What dosage is indicated by ""small"" and ""great"" in this connexion? If the meaning of ""small"" were known, would it be correct to go on to say, as he does, ""each successive dose of silica produces a summation of effects""? Then, again, would it be fair to say ""a comparatively brief period of exposure may be the only determining factor""? What, in minutes, hours, or days per week, per month,' or year, is intended by ""a comparatively brief period""? ""Intermittency of the process"" is another expression used in summing up the reasons for and against a standardization of air purity by a gravimetric process or enumeration of the particles; the arguments against such a standardization are, by Middleton, considered strong, but they are by no means convincing to us. A standard has been accepted in respect of the amount of lead in milligrams per 10 cubic metres of air; Dr. Ronald Lane showed in another paper read that adherence to this makes the occurrence of poisoning highly improbable. Mavrogordato has placed on record figures of silica dust at different stages of the improvements in the workings of the Rand mines, and such a control is in constant operation in them today.We emphasize these points because apparently the Government has taken the unusual course of legislating first and postponing inquiry to a later date, as in the ""Various Industries (Silicosis) Scheme, 1939."" The insurance companies also have a considerable interest in the matter of compensation for the silicosis risk. Where exposure - as in the refractories industries, the grinding industries, sandstone industry, and pottery industry - is day in and day out, they rightly demand a premium far higher than for any other disease scheduled under the Workmen's Compensation Act - 5 per cent on the wages bill. row every industrial employer, such as the paint and varnish manufacturer, who has a sack of crushed silica in his store .room, from which he extracts once a week enough to make a paste With spirit and add to his other ingredients in order to give them the necessary ""bite,"" becomes involved, and may have to abandon the use of the material or pay 8 per cent on his wages bill for an absolutely negligible risk.. For meting out justice standardization seems urgently called for."

Feb 1, 1930

By David A. Summers

The use of high pressure fluid cavitation is investigated as a means of breaking an ore into its constituent grains. This Cavitational Rock Dissagregation (CRD) is found to be possible and effective in breaking down galena ore, both in sandstone and dolomite host material. The technique did not work as well in comminuting and cleaning oil shale, because the cavitation drove the oil into emulsion with the water. The presence of dominant bedding in the rock also caused preferential breakage to these lines, rather than to the individual grain boundaries. This problem was also encountered in tests on igneous ore where weakness plants of the overall ore proved weaker than the boundaries of the individual grains. It was found that the prevailing expression of cavitation erosion dependence on pressure was not absolutely valid. In contrast it was found that CRD is much more sensitive to jet flow diameter, and when this was recognized it was found possible to erode rock with compressive strength of up to 350 MPa with operating jet pressures of 10 MPa.

Jan 1, 1982

By Charles E. Larson

Square Butte has no history of mineral development or production. Surface mapping, radiometric surveys and chemical analyses of rock samples reveal no mineral potential. The area has a speculative potential for petroleum and natural gas. INTRODUCTION The Square Butte Instant Wilderness Study Area, in Chouteau County, Montana, consists of 1,946 acres (788 ha) about 35 miles (56 km) southeast of Fort Benton and 50 miles (80 km) northwest of Lewistown (fig. 1). This study was performed under provisions of the Federal Land Policy and Management Act (Public Law 94-579, October 21, 1976), in conjunction with the U.S. Geological Survey, which is responsible for regional geological, geochemical, and geophysical investigations, and the U.S. Bureau of Mines, which determines the mineral potential of existing mines, prospects, or mineralized areas.

Jan 1, 1982

By Sidney Katell

This Bureau of Mines study estimates capital investment, operating costs, and selling prices for three underground bituminous mines producing coal with annual production ranging from 1.03 to 3.09 million tons. It is assumed that the mines have a 20-year life. Wages and union welfare payments are considered as of December 6, 1974, under the Bituminous Wage Agreement of 1974, and costs for material and equipment are based on 1975 indexes Initial capital investment ranges from $26,498,500 for the 1.03- million-ton-per-year (MM tpy) mine to $67,173,300 for the 3.09-MM-tpy mine. Total capital investment ranges from $37,437,500 to $92,984,300 for the same mines. Corresponding selling prices for the coal range from $14.83 to $13.26 per ton, assuming a 15-percent discounted cash flow rate of return after Federal income taxes.

Jan 1, 1975

By Thomas M. Barczak

Wood cribs are used extensively to stabilize openings in underground coal mines. This U.S. Bureau of Mines report describes the results of full-scale testing of several multitimbered wood crib configurations. Multitimbered configurations are wood cribs that are constructed with two or more timbers per layer. Nine different crib configurations were evaluated. Configuration parameters under study included the aspect ratio (height-to-width relationship) and the percentage of solid rr:aterial used in crib construction. Test results and generalized wood crib behavior are discussed and recommendations are made concerning crib constructions to maximize strength and stability. Crib performance is enhanced by reducing buckling effects by decreasing the aspect ratio and geometry considerations that increase the moment of inertia. A cost benefit analysis of multitimbered wood crib configurations is made. Generally, increasing the percentage of solid provides more resistance at less unit construction cost. A comparison of laboratory results and underground observations of several wood pack wall supports suggest in situ load capacity is less than that measured in laboratory testing. Reasons for the apparent decrease of in situ load-bearing capability include load rate effects, stiffness of reaction surfaces, and varying boundary conditions that alter the load transfer mechanics of the crib structure.

Jan 1, 1991

By J. Shawn Peterson, David S. Yantek, Adam K. Smith

Occupational noise-induced hearing loss continues to be one of the most pervasive health problems in the mining industry, despite over 25 years of regulation. One of the loudest pieces of equipment used in underground mining is the continuous mining machine. Noise sample data collected by the Mine Safety and Health Administration indicate that 42% of noise overexposures between 2000 and 2005 involved continuous mining machine operators. Previously conducted field and laboratory tests have determined that the continuous mining machine conveyor system is a dominant noise source. Loud impacts occur as the conveyor chain flight bars, used to move the mined aggregate, traverse their path from the top to the underside of the conveyor deck. Various noise control treatments have been applied to abate noise caused by the conveyor system. A durable polyurethane coating has been developed for the conveyor flight bars, resulting in a time-weighted average reduction of 3 dB(A) for an eight-hour work shift. In an attempt to further reduce continuous mining machine operator overexposures, a similar urethane coating has been applied to the tail roller component of the conveyor system. Laboratory results showed a 2 dB(A) reduction in sound power levels, but the component failed during underground durability testing. An outer steel sleeve has been added to the urethane coating of the tail roller to enhance wear resistance during mining. The urethane jacketed tail roller is the latest effort, combined with previous noise treatments, to bring the continuous mining machine into compliance with federal noise regulations.

By Edwin S. Secor

The Federal Bureau of Mines conducted a field survey of 153 bituminous coal strip and auger mines to estimate coal recovery from surface mines in the Eastern United States. Recovery was calculated from field data by measuring coal losses resulting from mining coal and leaving barriers. Mean total recovery for strip mining in States east of the Mississippi River was 83.0 percent and ranged from 72.3 percent for Tennessee to 91.3 percent for Maryland. Mining losses and barrier losses were 10.1 and 7.7 percent, with standard deviations of 4.8 and 10.4 percent, respectively, indicating that barrier losses, although less than mining losses, were more variable. Mean total coal recovery varied only slightly for the two regions studied; 82.7 percent for Appalachia and 84.3 for the Midwest. Total recovery grouped by mining method--contour, area, and mountaintop removal--was 79.8,84.7, and 85.3 percent, respectively. Mean auger recovery was 35.9 percent; of the total average loss of 64.1 percent, over one-half resulted from design limitations while the remainder was attributed to operating losses. The wide recovery range at individual mines indicates the variability of the eastern surface coal mining industry. Because of this, care should be exercised in applying the results of this report to reserve estimates other than those of a general nature.

Jan 1, 1977

By D. V. Keller

Black lung disease, or paeumocomosis, is a serious health hazard for workers working in a coal mine. Though the exact cause of black lung disease is not known, it is certain that prolonged inhalation of fine coal particles, ever present in the mines, does give rise to black lung disease. For a long time, it also has been known that limestone applied to coal dust mine surfaces tends to hold down coal dust thus preventing it from refloating in the air of the coal mines. Since the humidity in the mines may be generally high, this also might be an important factor in the particular substrate system behavior. Fine solid particles stick to other particles and surfaces very indiscriminately. The term adhesion is used for the phenomenon of attachment of particles to surfaces whereas cohesion is used for the phenomenon of attachment of particles to each other. The measurement of the force of adhesion of coal particles to coal substrates presents a great problem, especially in the case of particles in the size range of a few microns. These micron sized particles are at the limit of the resolution of the optical microscope and therefore an electron microscope has to be used for this purpose. The forces of adhesion between these particles and substrate may be very strong and can exceed the weight of the particle by four to five orders of magnitude.

Jan 1, 1973

By Ren G. Dong, Thomas W. McDowell, John Z. Wu, Chris Warren, Dan E. Welcome, Chun L. Dong

Hand forces are important factors for risk assessment of hand-arm vibration syndrome (HAVS).1 Grip force is one of the most important force components in the operation of powered hand tools. A considerable number of studies on grip force have been reported. It is well known that the grip force applied on a cylindrical handle is not uniformly distributed on each axis across the center of the handle cross-section.2 Therefore, maximum and minimum orientations of grip force exist around the handle. Such orientations have not been clearly identified. In a recently proposed international standard (ISO/CD 15230, 2005),3 it is stated that “the direction of the main gripping force is generally parallel to the z-axis defined in ISO 8727.” 4 This assertion is questionable, and further examinations are required. The objective of this study was to establish a fundamental theory on the distribution of the grip force around cylindrical handles. Methods As shown in Fig. 1, the grip force is defined as a vector composed of normal and shear components (FN & FT) in this study. Fig. 2 shows the hand coordinate system defined in this study, together with the ISO systems.1,4 Based on this novel grip force definition, we derived four fundamental properties and a theorem. More significantly, we formulated a novel hypothesis: similar to Mohr’s circle of stress, the normal and shear components can be represented approximately using an ellipse on the plane of the two force coordinates, as shown in Fig. 3. The maximum and minimum grip normal forces are termed as the first principal grip force (F1) and the second principal grip normal force (F2), respectively. Their corresponding orientations are termed as the first principal grip angle (a1) and the second principal grip angle (a2). A series of experiments were conducted to test this hypothesis. Twelve

Jan 6, 2006

By Roy L. Wilfong

The thermal decomposition of the ammonium sulfate, carbonate, nitrate, oxalate, and sulfate salts of praseodymium, neodymium, and samarium was investigated thermogravimetrically in the temperature range 25° to 1,500° C. Each salt was decomposed at a heating rate of 2.5° C, per minute. The pyrolytic sequences have been identified and the temperatures of formation of inter-mediates, the minimum oxide formation temperatures, and values for loss on ignition have been determined. The nonstoichiometric ranges between Pr6011 and Pr203 and the extent of these ranges have been determined for oxides derived from the carbonate, nitrate, and oxalate salts of praseodymium. The alum and sulfate salts of praseodymium produced the sesquioxide without forming the intermediate non-stoichiometric oxides. The temperature limits of formation and regions of stability for the alums and sulfates were better defined than were those for the carbonates, nitrates, and oxalates. The minimum oxide formation temperature increased in the order of samarium, neodymium, and praseodymium irrespective of the anion.

Jan 1, 1962

By Thomas M. Barczak

The initial Support Technology Optimization Program (STOP),Version 1.0, was released at the 19th Ground Control Conference. This original program has since been updated to Version 2.3 which was released in May, 2001. This paper describes the additional features of Version 2.3, focusing primarily on the following three aspects: (1) including uncontrolled convergence into the design requirements for standing roof supports, (2) the addition of design procedures for cable bolts as an alternative secondary roof support, and (3) the addition of new standing roof support technologies. Another new feature which should facilitate the development of design criteria for standing roof support is the capability to define ground reaction curves through convergence measurements alone without having to make support loading measurements. There are several other new features provided in Version 2.3 which are only briefly addressed in the paper. These include: (1) additional graphics capabilities to facilitate rapid assessment of support comparisons, (2)an East-West designation for support selection to more accurately provide cost and support availability data, (3) additional safety measures including a safety factor to identify support design near the peak support capacity, checks to see if the support dimensions comply with aspect ratio requirements, and a measure of roof coverage for the design layout of the support system. These new features of STOP provide more capabilities to design and analyze secondary roof support systems for conditions which could not be fully analyzed in the original version of the program.

By Clyde L. Brown

The ignition source of fires and explosions in coal mines is sometimes difficult to explain because resulting widespread destruction often erases valuable evidence that might reveal the cause. However, through years of experience, investigators have been able to piece together enough evidence to establish the reasons and, thereby, have been equipped to recommend corrective or preventative measures. The pattern of hazards is not constant. It changes with the development of new practices and new equipment. Important among the new hazards to coal mining are those introduced by electricity. In addition to the dangers of electric shock, fires and explosions from heat and arcs, and premature blasts, certain others have developed as a result of stray electric currents from direct-current traction systems. The conventional direct-current power-distribution system in coal mines is conducive to electrolysis damage to mine tracks, metallic pipelines, grounded power conductors, and structures in a position to become conductors of stray currents. The voltage drop resulting from power demand on intentionally grounded power conductors and accidental grounds on insulated conductors are common sources of stray currents in coal mines. Uncontrolled electric cur-rents flowing through the earth and metallic structures can be a menace, and these contribute to the estimated $6,000,000,000 annual loss caused by corrosion. The purpose of this publication is to discuss some of the electrolysis hazards in the coal-mining industry and to outline corrective measures to alleviate them.

Jan 1, 1962

By J. A. Kost

The contract objective was to evaluate the effectiveness of available dust-control technology for double-drum shearers. Eight underground surveys were conducted to evaluate drum design, drum spray nozzle locations, ranging-arm sprays, water quantity, wetting agents, and cutting techniques. The final report is made up of eight dust-control technique reports, each discussing, details of the individual mine surveys.

Jan 1, 1985

By Eric S. Weiss, Deno M. Pappas, Timothy M. Barton

During the past few years, the Pittsburgh Research Laboratory of the National Institute for Occupational Safety and Health (NIOSH) has been evaluating developments with surface support liners which includes shotcrete and thin spray-on liners (also referred to as sealants, coatings and membranes) from a ground control perspective. The proper selection and use of a surface support material can significantly enhance ground control which may result in a decrease in worker related injuries due to ground falls. The purpose of this paper is to evaluate the preliminary findings of a long-term underground study of various types of surface support liners, and to examine installation practices that are critical for an effective liner material application. The underground study utilizes NIOSH’s Lake Lynn Laboratory Experimental Mine to evaluate the long-term performance of several types of shotcrete and thin spray-on liner materials. Liner material performance to date was evaluated on a regular basis over a three year period. Although the study is still ongoing, critical mining practices were identified that may seriously affect the bond of the liner material to the mine roof and rib.

By A. T. Sweet, G. Douglas Gardner

"INTRODUCTION In the ammonium sulfate process for the production of alumina from clay,,3/ the clay is baked with amonium sulfate at about 400ºC. to form anhydrous ammonium alum and free ammonia or ammonium carbonate. The alum is leached from the baked product with water and circulating liquors and is purified by recrystallization. Aluminum hydroxide is precipitated by treating thus alum the alum the ammonia or ammonium carbonate from the baking step. Ammonium sulfate is recovered from the filtrate for reuse, and the aluminum hydroxide precipitate is calcined to produce high-purity alumina. In this process, as in other acid processes for the production of alumina, 4/ a large part of the iron in the clay is extracted. The iron tends to build up in the leach liquors and contaminate the crystals, so that its elimination is one of the most important problems in the process. A number of large clay deposits occur in the Western States. Those that have boon explored most extensively 5/contain an average of 24 to 30 percent available A12O3 and 2 to 8 percent available Fe2O3. 6/ The available Fe2O3 content of various other clays ranges from less than I percent to more than 20 percent. The available Al2O3 or Fe2O3 is usually 90 to 98 percent of the total but may be much less. In generals the iron content bears no fixed relation to the alumina content and may vary widely within a given deposit."

Jan 1, 1948