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By J. L. Jambor, E. J. Reardon, E. C. Appleyard, J. A. Cherry

Abstract- Since the 1957 initiation of deposition of mill tailings at the Heath Steele mine, New Brunswick, periodic detailed studies of the tailings geochemistry and mineralogy have been con­ ducted, thereby providing a unique opportunity to examine the geochernical evolution of a sulfide- rich mine-tailings impoundment. When deposited, the tailings contained about 85 wt% sulfide minerals, 1 wt% to 3 wt% carbonate minerals, and 12 wt% to 14 wt% aluminosilicate minerals. Mineralogical examination of samples of the tailings from deep in the impoundment indicates that little oxidation occurred prior to tailings deposition. The mill process-water deposited with the tailings was neutral to slightly basic and contained low concentrations of Cu, Pb, Zn and As. Sampling of the tailings five years after deposition indicated that sulfide-oxidation reactions, occurring near the tailings surface, had decreased the tailings-water pH and increased the concentrations of Fe, SOi-, Cu, Zn and Pb (up to 10 000 mg/L, 25 000 mg/L, 2.5 mg/L, 200 mg/L, and 4.5 mg/L, respectively) . In 1975, ten years after decommissioning, the tailings could be divided into three zones: an upper oxidation zone in which sulfide oxidation is actively occurring, a hardpan layer, 15 cm to 20 cm thick, composed of tailings cemented by secondary Fe minerals, and an underlying reduction zone in which the tailings are relatively tinoxidized (Boorman and Watson, 1976). Chemical analyses indicated the presence of low-pH waters containing very high concentrations of SO42- , Fe, and other metals (up to 63 600 mg/L SO42-, 28 600 mg/L Fe, 10 mg/L Pb, 600 mg/L Cu and 4000 mg/L Zn), suggesting that there was a period of intense sulfide oxidation between five and ten years after tailings deposition. More recent sampling, conducted some 20 years after the end of tailings deposition, indicates that relatively little change has occurred in the last ten years, thereby suggesting that the hardpan layer has provided an impediment to the downward movement of dissolved constituents . Analyses of the tailings solids show increased accumulations of many metals at or near the depth of the hardpan layer. Evaluations of the long-term evolution of the tailings can be enhanced by comparison of descriptions of the tailings with descriptions of the gossan that overlay the massive­ sulfide orebody prior to mining. At Heath Steele, this comparison suggests that many of the mechanisms controlling the distribution of metals in the tailings will probably persist over geologic time.

Jan 1, 1992

By R. Blosser

Phelps Dodge introduced a process improvement model known as Quest for Zero in 2001. In 2004, the focus of Quest for Zero shifted from corporate-led initiatives to projects led by site personnel. The Hydrometallurgical Division at Morenci focused on two (2) significant process improvements: reducing electrolyte bleed and organic losses. In September 2004, Morenci kicked off a bleed reduction project to reduce electrolyte bleed by 45%. By the end 2005, electrolyte bleed was reduced by 55% through understanding and reduction of variance. Significant process changes made during this time period include changes in acid-addition strategy, reduction of uncontrolled bleed, and optimization of bleed placement. In April 2005, the organic reduction project began with the goal of reducing losses by 15%. Operational improvements during this project included improved organic recovery systems, mixer speed optimization, and picket fence installation. By the end 2005, this project reduced organic losses by 35% and current losses are 48% lower than at the start of the project. These projects and smaller Questfor Zero projects have resulted in sustainable annualized savings of $13 million in Morenci hydrometallurgical operations. Through the use of Six Sigma tools, process variances can be controlled and reduced.

Jan 1, 2007

By M. Palfreyman

"Most of the minerals employed in Canadian refractory production are imported; in fact, most of the refractories consumed in Canada are imported. Whereas this situation is partly due to a definite shortage of suitable raw materials, e.g., fire clays, it is possible that the potential of certain mineral deposits which could be usefully exploited has not been recognized. There are exceptions, notably magnesite and dolomite, from which refractories are produced in Canada.In many cases, known mineral deposits are located either in inaccessible areas or in areas where transportation would be a major economic factor. This paper lists some minerals and their respective known deposits which could be employed in the production of refractories, irrespective of economics."

Jan 1, 1973

By Javier Linares García

At then end of this year will be 10 years of producing concentrate for Antamina. This is a summary of what occurred over the last decade to increase production and tonnage above the design tonnage of 70,000 tonnes per day, up to an average of 100,018 tonnes per day in 2010, an increase in production of 42.9%. Equipment currently in use is the originally installed equipment, signifying a meaningful increase in capacity without capital. In this paper, the different phases of improvements and the realization of their impacts in chronological order will be outlined. Figure 1 below shows the average daily tonnage processed each year (tonnage throughput each year/calendar days), as well as the percentage increase over the tonnage of design.

Jan 1, 2012

By A. Sokolov, E. Hasikova, V. Gostilo, V. Titov

Introducing online X-ray fluorescence (XRF) analyzers in the mining and processing industries can lower costs and improve the representativeness and speed of analysis. The applicability of the CON-XTM industrial conveyor XRF analyzer for continuous measurement of potassium content in process materials was demonstrated at various stages of potassium muriate (MOP) production. The CON-X analyzer produced reliable and accurate results for sylvinite ore (27–36% KCl), MOP cake after flotation (88–97% KCl), and NaCl residue (1.5–5% KCl). Tests of the analyzer at an MOP-producing plant showed a < 0.5% difference between online and laboratory results.

Jan 1, 2014

By S. Ianos, C. Vibert

Type and shape of large dams founded on rock depend upon the expected deformation of their foundation. Their design consequently requires the assessment of the deformability of the rock mass at large scale. Seismic refraction, laboratory tests on rock samples and empirical formulas can provide an order of magnitude of the deformation modulus, with a limited degree of reliability. Direct in-situ measurement of the deformability of a volume of rock is therefore preferred, which integrate the effect of discontinuities, such as plate loading tests, dilatometric tests, etc. The authors have been compiling results obtained by in-situ deformability tests on a number of dam sites, including the Scarabée (“Petite Sismique”) method. This last method consists in thoroughly analysing the shape of seismic wave forms transmitted through the rock mass. It has been used since now more than 40 years over a large number of dam foundations, and has proved to provide a satisfactory assessment of the static deformation modulus. After comparing the results obtained from different methods on six dam sites, the Authors conclude that their reliability closely depends upon the size of the loading device in relation to the spacing of the discontinuities. Attempts to correlate results from different types of in-situ loading tests reveal difficult, because closely depending upon local geotechnical conditions at test location. Plate jacking tests appear to be the most reliable, because involving a relatively large volume of rock. On the other hand, the Scarabée method (“Petite Sismique”) allows a rapid assessment of the deformation characteristics of the rock mass at large scale, and has been found to provide values generally in agreement with those from plate loading tests, while dilatometric or flat-jack tests were found too dependent upon local conditions. The Authors conclude that preference should be given first to the Scarabée method, which uses light equipment and is quickly performed, together with an accurate geological and geotechnical assessment for interpretation. In a second stage, Scarabée shall be complemented by adequately performed plate jacking tests in selected locations, in order to cross-check results and refine the assessment. The general accordance between the results of the two methods, which both can integrate anisotropy of rock masses, justifies this statement.

Jan 1, 2015

By Jiuhua Xu, Yuling Xie, Fenglei Bie, Neng Jiang

"Abstract - The Xiaoqingling Mt. area is one of the most productive gold districts in China. The gold-bearing quartz veins are controlled by a series of east-west shear zones within the Archean Taihua Group, and related to the late Yanshanian (Cretaceous) granite. The major metallic minerals are native gold, electrum, pyrite, galena, chalcopyrite and sphalerite, with gangue minerals dominated by quartz, sericite, ankerite, and calcite. The host rocks are mainly amphibolite, plagioclase gneiss, and migmatites. Principal alteration is sericitization, silicification, pyritization, and carbonization.There are four generations of hydrothermal quartz in altered rocks of gold deposits. The earliest generation of quartz, (Q1), occurs in altered amphibolite gneiss and migmatite, and typically contains fluid inclusions with halite crystals (type A) and two phases, (L+V), of fluid inclusions (type B). The salinities of type A inclusions are 32 wt% to 52 wt%, with dissolution temperatures of halite crystals being from 155°C to 465°C. The second generation of quartz, (Q2), occurs as a fine-grained aggregate associated with sericite, and has small (less than 3 µm) type B inclusions. The third generation of quartz, (Q3), occurs in mylonitic, intensively altered rocks and specially beresite (a type of rock composed of quartz, sericite, and pyrite) near the veins, and contains large amounts of CO2-rich fluid inclusions (type C-fluid inclusions with liquid CO2 and type D-fluid inclusion with high density CO2). The CO2 contents of type C range from 72.6 to 87.4 mol% in gas phases, and 35.7 to 68.3 mol% in liquid phases, based on Laser Raman analysis. The homogenization temperatures of fluid inclusion type A and C are from 215°C to 380°C, and from 210°C to 325°C, respectively. The minimum trapping pressure of fluid inclusions is estimated as 80 MPa to 170 MPa for type A, and from 57 MPa to 190 MPa for type C, which approximate to those of fluid inclusions in vein quartz.The ?18O of quartz are from 10.4‰ to 11.0‰ for Q3 of altered rocks, and from 10.7‰ to 12.8‰ for stage I quartz. The calculated ?18O of fluid inclusions varies from -1.3‰ to 6.0‰. The ?D of fluid inclusions ranges from -67‰ to -59‰ and from -81‰ to -48 ‰, respectively. It is concluded that the water in the hydrothermal fluids both reacting with wallrocks and precipitating orebodies could have been mainly of magmatic and/or metamorphic nature. However, local meteoric water might have been important in late mineralization, because of a distinct oxygen-shift toward the meteoric water. The ?34S values for pyrite of the ores range from -7.1‰ to +7.1‰, with an average of +2.9‰. Those of other sulfides (chalcopyrite, galena, and sphalerite, range from -12.5‰ to 8.3‰. The ratios of lead isotopes for galena of the ores are: 17.06 to 17.31 (206Pb/204Pb), 15.43 to 15.74 (207Pb/204Pb) and 37.58 to 38.45 (208Pb/204Pb). In summary, ore-forming fluids in the Wenyu-Dongchuang gold deposits may have originated from a mantle and/or lower crust source, and ore materials were derived from the Precambrian basement, the Taihua Group."

Jan 1, 1998

By T. Takayama Filho

Votorantim Metais Zinco is a smelting facility which produces SHG zinc, zinc alloys, sulfuric acid, liquid SO2, copper sulfate, cadmium metal and silver concentrate. It is located at Juiz de Fora, Minas Gerais State, Brazil. This facility has been operating since 1980 and its current capacity is 95,000 tonnes of zinc per year, using mostly imported sulfide concentrates.The plant uses the conventional roast-leach electrowinning (RLE) process, in which iron is removed from the circuit as jarosite. The residues generated by the RLE process, which amount to about 200 t/day (dry weight), were until 10 years ago, deposited in tailing ponds having no impervious lining. More recently, jarosite and other wastes have been deposited in a properly built reservoir, but this is reaching its maximum capacity. In order to decommission these disposal operations and to reclaim the sites in an environmentally acceptable manner, Votorantim Metais concluded in 2004 a rehabilitation project for the old tailings pond and prepared detailed plans for managing the current and future disposal of jarosite-bearing residues. This paper describes the procedure for removing iron from the hydrometallurgical circuit and discusses the past and current status of the residue disposal sites, as well as the future challenges related to the environmentally acceptable handling of iron residues.

Jan 1, 2006

By Henrik Saxén, Mikko Helle, Hamid Ghanbari

In this study, a process integration approach in a primary steelmaking is investigated to evaluate future operation concepts of a steelmaking site considering sustainability issues. Mathematical programming is used to study the integration of the steel plant with chemical units for utilization of available off-gases in the system, and carbon capturing and sequestration unit. Different industrial carbon utilization options are considered to find the best route of development. A multi-period optimization model is developed based on site-wide mass and energy balances by considering the availability of the fuels and by-product gases and their consumption in the production system and a conceptual polygeneration system. The objective is to reach maximum economic profit while environmental aspects of integrated system are considered for different fuel systems, alternative blast furnace reductants and implementation of new process technologies. The model can provide useful information concerning techno-environmental and economic aspects for decision-making and can estimate optimal operational condition of current and future primary steelmaking under alternative scenarios. The results of the work illustrate the potential to develop steelmaking towards more sustainable operation in the future.

Jan 1, 2015

By I. Vazaios, M. S. Diederichs, N. Vlachopoulos

"As rock engineering moves from continuum to more discontinuum approaches for modeling, the engineer must make decisions regarding the degree of complexity to simulate for a given application, balancing the level of structural detail within the rockmass model with computational cost and result accuracy. It is important to consider that model does not need to include all the existent fractures and that representative geometrical properties for a given rock mass volume can be defined including only major structural entities.Within this paper, the scale-dependency associated with the geometrical properties of fractured rock is investigated utilizing a Synthetic Rockmass (SRM) approach with a view to characterize such ground to aid in the design of geotechnical works. In terms of process, the concept of the Representative Elementary Volume (REV) is used to determine the equivalent structural properties of the rockmass in order to justify the applicability of far-field behaviour of such ground. A large size Discrete Fracture Network (DFN) measuring 60m x 60m x 60m has been generated using the structural data obtained from LiDAR scanning of the Brockville Tunnel, Ontario, Canada. A number of DFN samples of varying sizes are extracted from the master network, generated using MoFrac, in order to be used as a the basis of the structural analysis of the rockmass. Volumetric measurements for the density and the intensity of jointing are employed in order to approximate the geometrical REV for the networks.In this paper a complete methodology of how to generate a DFN from LiDAR data and its analysis in order to determine the size of a geometrical REV is demonstrated. For the specific rockmass found in the area of the Brockville Tunnel, a geometrical REV measuring 3.5m x 3.5m x 7m is established. The results are generally in good agreement with the in-situ observations."

Jan 1, 2015

By S. Kline

The compositions of metamorphic minerals of the south limb of the Dore Lake Complex have been determined by microprobe techniques. Mineral assemblages typical of the greenschist facies occur in Mg-rich bulk compositions, but in Fe-rich rocks albite-epidote amphiboli te facies assemblages occur. Low oxygen fugaci ties and a general paucity of metamorphic fluids prevailed in most of the complex, but a higher oxygen fugacity is indicated near the Chibougamau Pluton, and a local abundance of C0z and Cl in fluids near the pluton is suggested by the presence of scapoli te. The metamorphic gradient overprinted on the complex near the Grenville Front is apparent in mineral chemistries as well as by the appearance of garnet. Chlorite becomes richer in Mg, and iron is fractionated more strongly into hornblende. The amphibole also increases in Alz03.

Jan 1, 1984

By X. (Mike) Yao

Rock mechanics engineers must provide ground support designs that ensure a safe underground working environment. Unexpected falls of ground are unacceptable while ground support systems must be adequate. Ground support must be economic for the area supported and the time frame the opening is in use. While numerical modeling can be used for ground support design, empirical models are still the common useful design tools. Empirical models are best developed and improved from local experiences although some models, such as Stability Graph (Potvin et al, 1992), are in extensive use by the Canadian mining industry. To determine the adequacy of ground support practices at HBMS, a database of 50 fall of ground case histories between 1985 and 2001 was compiled. For each failure, the recorded data included: location, rock type, rock mass conditions, opening and failure geometry, installed ground support and failure mechanism. An analysis of the database was done to obtain an understanding of failure frequency association with rock types, stope geometry and installed ground support, and to assess what support design changes were necessary. The paper describes changes made to ground support and mining practices during the last five years, and the formation of new ground support standards and practices which have been successful in reducing ground falls while providing improved, efficient and economical ground support.

May 1, 2002

By M. Kumral, E. Dilhuydy, B. Ozdemir

"In-pit crushing and conveyor (IPCC) systems have become increasingly popular in the mining industry as an alternative to truck-and-shovel systems. Deciding whether to haul waste rock by truck or IPCC represents an important gap to be investigated in semi-mobile IPCC systems. A cost analysis is presented to evaluate the feasibility of crushing and conveying waste material in IPCC systems, along with sensitivity and risk assessments through Monte Carlo simulation. Although the capital expenditure is higher, results showed waste crushing will be feasible in deep pits and over long mine life and haul distances.RÉSUMÉ La popularité des systèmes de concassage et de transport dans la fosse minière (IPCC, de l’anglais In-pit crushing and conveyor) n’a cessé de croître dans l’industrie minière ; ils constituent en effet une option intéressante de remplacement des systèmes par camions et pelles mécaniques. Le choix entre le transport des stériles par camions ou par IPCC est encore difficile à faire et devra faire l’objet d’une étude approfondie au niveau des systèmes d’IPCC semi-mobiles. Une analyse des coûts est présentée pour évaluer la faisabilité du concassage et du transport des stériles par les systèmes d’IPCC, de même que des évaluations de la sensibilité et des risques par le biais de la simulation de Monte Carlo. Si les dépenses en immobilisations s’avèrent être plus élevées, les résultats ont cependant montré que le concassage des stériles sera envisageable dans des fosses profondes ainsi que sur une longue durée de vie et de longues distances de transport. INTRODUCTIONThe mining industry is currently facing many challenges such as low commodity prices, increasing environmental concerns and regulations, lower grades, deeper mines, and greater waste-rock quantities. As a result, the profitability of mining operations has decreased, with many mines stopping or suspending operations, and many new projects being postponed. Mining companies have therefore focused on improvements and innovations to increase the cost effectiveness of operations, for example, increasing production capacity to take advantage of the economies of scale (Crowson, 2003) and decreasing the unit operation cost. Changes in production capacity force mining companies to evaluate alternative material handling systems.During the past few decades and within material handling systems, significant improvements have been made to truck performance and capacity. Consequently, operating expenditures (OPEX) associated with fuel and maintenance have risen swiftly. In a mining operation, truck hauling systems now represent 40–50% of the capital cost and approximately 45% of the OPEX (Tutton & Streck, 2009). Additionally, material transportation costs are expected to increase due to longer haul distances arising from deeper and larger mines (Fleet et al., 2015). Finally, large fluctuations in fuel prices result in high risks associated with truck OPEX. According to the United States Energy Information Administration (2015), the cost of crude oil—the largest component of the retail price of diesel fuel—increased from US$24.31/barrel in 1986 to US$46.92/barrel in 2016, peaking at US$151.72/barrel in 2008 (Macrotrends, 2016)."

Jan 1, 2017

By J. T. Sims, C. E. Karayannopoulos

Today&apos;s rare earth industry is undergoing significant and rapid evolutionary change toward greater reliability and diversity of supply, increased security of supply chains, and better price forecasting. Technology innovation is reducing rare earth production costs while decreasing the impact of producers on the environment. Advances in rare earth material science are reducing the need for relatively scarce heavy rare earths (HREEs) in high-performance neodymium-iron-boron (NdFeB) permanent rare earth magnets and opening the NdFeB magnetic market space for a broader range of downstream applications. Rare earth producers such as Molycorp are increasingly able to offer long-term supply agreements with forward price predictability, something that has not been the case for many years. All of these trends are helping to restore the confidence of customers and other stakeholders in the rare earth space. That increased confidence is likely to bolster global demand for rare earth materials and expand innovative utilization of these remarkable materials.

Jan 1, 2014

By J. Postle, Deborah McCombe

"This is the third in a series of articles about the Committee for Mineral Reserves International Reporting Standards (CRIRSCO). The first article was an interview with Niall Weatherstone, Chairman of CRIRSCO (CIM Magazine, February 2008) the second described the background and goals of CRIRSCO (CIM Magazine, March/April 2008). In 2007, CRIRSCO was adopted as the Reserves and Resources Task Force of the International Council on Mining and Metals. This decision by ICMM has resulted in an increased level of funding for CRIRSCO and the ability to advance its objectives. In mid-October 2007, CRIRSCO members met in London England to discuss the status of each of the member countries’ reporting codes and the progress of various CRIRSCO projects. Update on national reporting codes Australia: The last update of the Australian JORC Code was in 2004. While there are ongoing discussions about issues that arise from the application of the latest version of the Code, there are no plans to update JORC in the near future. Canada: The Canadian Securities Administrators revised National Instrument 43-101 in December 2005. At the same time, the Canadian Institute of Mining, Metallurgy and Petroleum published updated Resource and Reserve Definitions that are incorporated by reference in NI 43-101. CIM is continuing work on developing Best Practice Guidelines to assist practitioners in the estimation of Mineral Resources and Reserves. South Africa: The South African Mineral Reserve Committee is currently awaiting an update of the Johannesburg Stock Exchange Limited Listing Rules, which will incorporate both SAMREC and SAMVAL (South African valuation guidelines). The official launch of both codes is expected in 2008. Europe: The Pan-European Reserves Reporting Committee expects to release a consultation draft in 2008. Emphasis is being placed on industrial minerals and aggregates, which constitute a very large industry in Europe. Chile: The Chilean Certification Code was approved in early 2008. As part of the Code, a National Commission is being established to screen and review reports on a random or specific basis. United States: The Society of Mining Engineers updated the SME Reporting Guidelines in 2007. The Securities and Exchange Commission has not accepted these more up-to-date definitions and guidelines. The SME committee will continue to discuss the incorporation of these Reporting Guidelines with SEC. SME has also established a class of membership, a Registered Member, which includes disciplinary measures for non-compliance with the SME guidelines."

Jan 1, 2003

By M. Courtin, D. Berthelot, M. Haggis, D. McClarty, R. Payne

Over forty years of uranium mining in the Elliot Lake region of Ontario (1956–1996) has resulted in the production of over 300 million pounds of uranium. With the completion of mining activity, Rio Algom Limited and Denison Mines Limited are utilizing progressive environmental technologies and management systems to reduce and manage the environmental risks associated with the 150 million tonnes of potentially acid-generating tailings in nine regional waste management areas. Water covers designed to reduce oxygen entry and, thereby, significantly inhibit acid generation, have been applied at six of the sites with the Quirke site serving as a demonstration site for the Mine Environmental Neutral Drainage program. All five of Rio Algom Limited’s effluent treatment plants are monitored and controlled from a central control station utilizing a Supervisory Control and Data Acquisition (SCADA) system based on “Fix Dmacs” technology. Scheduling, auditing and reporting of plant operating and environmental monitoring programs for the entire watershed are controlled utilizing the Regional Environmental Information Management System (REIMS). Proper application of these technologies and management systems facilitates delivery of cost-effective environmental monitoring, care and maintenance programs at these sites and provides tools to demonstrate compliance with all environmental performance criteria.

Jan 1, 1999

By Waldemar W. Koczkodaj, William O. MacKasey

Abstract - A consistency-driven pairwise comparisons method for mineral potential assessment is presented, using a simplified case of volcanic-associated massive sulfide type deposits as an example. Geological, geochemical, and geophysical criteria are considered on two levels: local and regional. The local geological criteria are subdivided into stratigraphy, lithology, alteration and/or mineralization, and structure. The concept of geomerit index and a procedure for computing this index are introduced. The method of consistency-driven pairwise comparisons can be combined with other quantitative and qualitative assessment methods, enhancing them by incorporation of nonmeasurable geological criteria (e.g., stratigraphy or lithology) and by computation of weights. The consistency-driven approach allows experts to refine at-times subjective judgments concerning exploration and land-use planning, and contributes to the improvement of mineral-potential assessments.

Jan 1, 1997

By Waldemar W. Koczkodaj, William O. MacKasey

A consistency-driven pairwise comparisons method for mineral potential assessment is presented, using a simpli?ed case of volcanic-associated massive sul?de type deposits as an example. Geological, geochemical, and geophysical criteria are considered on two levels: local and regional. The local geological criteria are subdivided into stratigraphy, lithology, alteration and/or mineralization, and structure. The concept of geomerit index and a procedure for computing this index are introduced. The method of consistency-driven pairwise comparisons can be combined with other quantitative and qualitative assessment methods, enhancing them by incorporation of non-measurable geological criteria (e.g., stratigraphy or lithology) and by computation of weights. The consistency-driven approach allows experts to re?ne at-times subjective judgments concerning exploration and land-use planning, and contributes to the improvement of mineral-potential assessments.

Jan 1, 1997

By F. McCarthy, R. McDonald, G. Woodbridge, G. Brock, D. Robinson

"The Direct Nickel process is a hydrometallurgical technology being developed to treat nickel laterite ores by leaching at atmospheric pressure. The leaching process uses nitric acid in a relatively large excess, is thus non-selective, and much of the soluble iron goes into solution. The first stage of solution purification is iron hydrolysis and the Direct Nickel process utilises the colligative properties of the pregnant leach solution (PLS) to enable the removal nitric acid of varying concentrations via distillation. Once sufficient acid has been removed, the boiling point of the solution is increased allowing high temperatures (up to ~170°C) to be achieved under atmospheric pressure. The higher temperatures initiate the precipitation of the iron primarily as hematite and allow the removal of the acid generated by the hydrolysis reaction. The rejection of the iron is near complete with solution tenors typically falling from 65 g/L Fe, or more, to less than 50 mg/L Fe. The separation of clean nitric acid from the PLS at this stage allows for relatively simple acid recycling. A hematite product with iron content above 60% could also provide an extra revenue stream.INTRODUCTION The Direct Nickel (DNi) Process is a novel hydrometallurgical processing route designed to treat all types of nickel laterite ores in a single flow sheet using nitric acid under atmospheric conditions. A simplified flow sheet is shown in Figure 1.Between 2007 and 2012 the process was developed and refined at Direct Nickel’s laboratory within the CSIRO Minerals’ facilities in Perth, Australia, and in 2013 a series of pilot plant trials were run under continuous operating conditions. The process is designed to treat both limonite and saprolite in the same flow sheet, and after comminution, the blended ore is mixed with nitric acid and leached just below boiling point in agitated atmospheric leach tanks. The acid is added in excess, so typically for a blend of limonite and saprolite the acid addition can be in the order of 1.8-2.0 t acid/t dry ore. After a residence time of between 4-6 hours the majority of the soluble metals have leached into solution and the insoluble leach residue is separated from the pregnant leach solution (PLS) via counter-current decantation."

Jan 1, 2016

By A. H. Onur, S. Ural

"The Afsin-Elbistan coal deposit with its 3.4 billion metric tons of reserve is the biggest coal basin and one of the most important resources for electrical energy production in Turkey. The coal deposit is located north of Elbistan, Kahramanmaras Province, in southeast Turkey (Fig. 1).The Kislakoy sub-basin of the Afsin-Elbistan basin was selected as the first open cast mine to feed four power station blocks of 340 MW each. The mine is equipped with six identical bucket wheel excavators of the type Sch Rs (2300/5) 32. The annual coal demand of the power station is 18.5 million metric tons. The Elbistan basin encompasses an area of 900 km2, and its centre lies about 1150 m above mean sea level. The sedimentation took place mainly in the upper Pliocene period. The thickness of the coal bed varies from 20 m to 60 m, respectively. The basal part of the coal beds consists of clay, marl and sandy clay. These formations are overlain by gyttja, which may also occur in the form of calcareous ooze, enveloping coal beds. The thickness of the gyttja is up to 35 m (Otto-Gold, 1969). The coal of Afsin-Elbistan is soft coal and the quality has been found to vary considerably throughout the deposit. The thicknesses of the sterile intercalations vary from 0.50 m to 2.2 m and average 1 m in thickness. From the quality control point of view, the coal seam is regarded as upper seam where the gyttja formation occurs as sterile intercalations, and lower seam where the clay formation occurs instead of the gyttja (Fig. 2). The CaO content of upper Kislakoy coal is very high, grinding resistance is low and base to acid ratio of ash, that is, the ratio of acid oxides of metals to base, is greater than one (Ural and Onur, 2001). Contrary to upper Kislakoy coal, CaO content of lower Kislakoy coal is very low, grinding resistance is high and base:acid ratio of ash is smaller than one. Modified Impact Strength Index (MISI) tests are used to determine the grindability of the Elbistan coals (Ural, 1999)."

Jan 1, 2003