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By T Belligoi

Diamond cores and drill chips provide the only direct physical evidence for ore containing rocks. Early characterisation of cores and drill chips is important as it provides critical information for downstream processing. Traditional characterisation techniques include visual logging by a geologist or analytic and spectroscopic methods but they are time consuming and can miss some important textural or geomechanical features.The goal of this work is to evaluate the application of image analysis to iron ore cores and drill chips and to suggest improvements to existing core-scanning and chip monitoring systems. Two samples of massive ore differing by their mineralogy and texture, as well as two different batches of drill chips, have been imaged and analysed. Results are compared in function of the imaging system and the classification algorithms.As a conclusion, despite the necessity for more testing and improvements in calibration and lighting, it is obvious that image analysis technologies can bring a lot of useful information in the perspective of a geometallurgical mapping of the deposit.

Jul 11, 2011

By B Jones, M Chappell

Permanent rock bolts used to support rock tunnels are required to perform for the design life of the structure as a minimum. Quality of installation is critical to the performance over the life of the rock bolt.This paper will present the findings from an in investigation into the integrity of rock bolts installed in an underground hydroelectric power station cavern and access tunnel. The 25?mm diameter rock bolts were installed 50 years ago, tensioned and post cement grouted. Due to a major machine upgrade the whole facility was subject to an asset survey. The owners are responsible for managing the risks associated with the failure of these rock bolts and ensuring the structural integrity of the tunnels and caverns is maintained to continue operations, protect machinery, assure production and more importantly maintain a safe working environment for all employees and visitors.To help manage risk a proactive approach is desired. To this end a test schedule using a non-destructive testing (NDT) system was carried out by Independent Integrity Testing Pty Ltd (i2t). The system used in this application was RokTel™. The system operates by applying a small axial impact to the rock bolt end and measuring the resultant acceleration response. The rock bolt characteristics affect the acceleration response.The data output from the system is analysed principally using Fourier Analysis (FFT) and sinusoidal waves. The energy generated in the bar, the rate of damping and changes in frequency are all assessed. Testing was carried out on 70 rock bolts within the tunnel and cavern. A selection were then over cored, photographed and documented. The data gathered from the testing is then correlated with physical evidence to establish a calibration for the remainder of the rock bolts and assess if this is a viable method for identifying defective elements, and what degree of accuracy can be achieved. The findings will assist with the future assessment of similar hard rock underground?facilities.CITATION:Jones, B and Chappell, M, 2014. The use of non-destructive testing to identify defective rock bolts – a case study, in Proceedings 15th Australasian Tunnelling Conference 2014 , pp 275–280 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

By R Morrison, P Walters, B Adair, V Jokovic

‘Grade Engineering<sub>®</sub> is an integrated approach to coarse rejection that matches a suite of separation technologies to ore specific characteristics and compares the net value of rejecting low value components in current feed streams to existing mine plans as part of a system-view’ (Walters, 2017). Two of these technologies are directly recoverable through screening stages: Natural Deportment and Induced Deportment. The potential for taking advantage of “Natural Deportment” by size following blasting and crushing has been demonstrated for a range of ore types. Simple and low cost screening can in some cases generate a fine product with improved grade and a lower grade oversize which can be directed to leach or to waste. Where an ore body consists of many different ore types, the traditional approach of blending to metal grade will often add to complexity of treatment, which will reduce the effect of “natural deportment” by size.CITATION: Jokovic, V, Walters, P, Adair, B and Morrison, R, 2018. Applying enhanced grade engineering to complex ore bodies, in Proceedings Complex Orebodies Conference 2018, pp 21–23 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 21, 2018

By B Dodd

This paper details how the Australian Securities and Investments Commission (ASIC), as a disclosure and conduct regulator, approaches regulation of continuous disclosure, capital raising and control transactions in the mining and resources sector, and the reasons for the approach. In examining this topic the paper considers the Joint Ore Reserves Committee (JORC) Code (JORC, 2004), the VALMIN Code (VALMIN Committee, 2005), the relevant ASX Listing Rules and the relevant provisions of the Corporations Act 2001 (Corporations Act). This paper discusses ASICÆs approach to expert reports and disclosure with reference to Regulatory Guides 111 Content of expert reports and 170 Prospective financial information.CITATION:Dodd, B, 2012. Issues in capital raisings and disclosure, in Proceedings International Mine Management 2012, pp 3-14 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 20, 2012

By D MacKay

The Mt Wright Project is located near the town of Ravenswood in North Queensland and is operated by Carpentaria Gold – a wholly owned subsidiary of Resolute Mining Limited. Underground Development of the current Mt Wright orebody commenced in June 2006 and the first production ore was brought to surface in June 2007. The orebody is a rhyolite pipe containing fine-grained disseminated gold in a granite host rock. Ground conditions tend to be good to excellent throughout development, with some minor deformation experienced when stope-sized excavations are formed. The mine commenced as a sublevel open stoping (SLOS) operation with the intent to utilise development waste to back fill isolated upper level stopes while developing to the bottom of the known orebody. The mine plan intended to commence production with a bottom-up primary/secondary stoping retreat through the main orebody utilising cemented fill. Some challenges were faced during the initial production phase that included:•Ongoing underground diamond drilling and updating of the block model resulted in some issues reconciling the grade control results to the resource model. This was primarily due to the high variability of grade which in turn caused difficulties in accurately identifying areas of low and high-grade.•The cost of establishing and operating a cemented fill plant to achieve the planned extraction sequence of the orebody had increased significantly beyond initial estimations.•Geotechnical conditions such as stress orientations, ground behavior and response to the forming of excavations learned through the mining of the upper level stopes were different to the assumptions made during the initial design.A number of in-house and external reviews of the mining method were completed which has resulted in a revised mining plan. This paper will summarise the challenges faced and the implementation of the mine plan to date.

Mar 21, 2011

Gold mine production in South America was 247.3 tonnes in 1995 up from 156.4 tonnes ten years earlier in 1986. This represents a 58 per cent increase and amounted to 11 per cent of total world gold mine production. The major countries involved in order of production, were: Brazil (67.4 tonnes), Peru (51.5 tonnes),. Chile (48.5 tonnes), Colombia (24.1 tonnes), Venezuela (17.1 tonnes), Bolivia (16.0 tonnes), Ecuador (9.6 tonnes), Guyana (8.8 tonnes), French Guiana (3.3 tonnes) and Argentina (one tonne). The most dramatic increase was reported in Peru where production increased from 10.9 tonnes in 1986 to 51.5 tonnes in 1995, heavily influenced by the production from Minera Yanacocha which began operations in 1993 and produced 17.2 tonnes in 1995.With the reformation of the mining laws and the introduction of investment incentives in all the South American countries in recent years, dozens of major and junior mining companies began flocking into the area in the early-1990s to conduct exploration. A recent study undertaken in Brazil shows that an average of $240 million per year will be expended in this country during the period 1993 - 2010. Twenty-five per cent of this expenditure is expected to be made on gold exploration. Similar figures for Peru are $220 million total per year with 50 per cent for gold; $170 million per year in Argentina with 25 per cent for gold and $120 million ner year in Chile also with 25 Der cent for gold.

Jan 1, 1997

By T J. Grandfield

Paste fill has been used successfully at Henty Gold Mine for the past five years. It has allowed 100 per cent extraction of the orebody, stabilised poor ground and enabled wide sections and offsets to be mined safely. However, there are a number of inefficiencies in the current paste fill system. These include the low output from the drum filter, the addition of aggregate to the paste to compensate and the trucking of paste from the plant to the portal. These inefficiencies have increased the operating cost of the paste fill system and caused a number of operational challenges such as blockages and increased pipe wear. These challenges have been partly overcome by taking ownership of the paste fill process, improved quality control and better communication. Henty is currently developing two new orebodies, the Mt Julia and the Darwin and has an opportunity to build an efficient paste fill operation. This is likely to be a high density paste system without aggregate, either located above the new orebodies or located at the plant and pumped to the new site.

Jan 1, 2002

By D Yan, D Connelly

Beneficiation of magnetite is an integral part of the future of iron ore processing. Historically, the focus of Western Australian producers has been on exporting direct shipping ore (DSO) namely haematite. The future for new DSO resources is limited so companies are changing their emphasis into processing the very large, undeveloped magnetite ores in Western Australia (WA), using beneficiation to produce shippable magnetite concentrates. These magnetite resources require higher cost processing techniques such as fine grinding and beneficiation to produce saleable concentrates. This distinct difference, from the DSO ores, has led to the development of a number of new technologies. This paper reviews: the different techniques used for magnetite beneficiation and provides some case studies in the WA industry; the use of mineral liberation analysis (MLA) to describe the nature, grain size, occurrence and associations of the mineralisation;the consideration of coarse cobbing as a critical upgrading; the application of high pressure grinding rolls (HPGR) to save energy; how the field of magnetic separation has resulted in new machines with higher field strength (SLon Separators); ultra fine grinding requirements of magnetite concentrates; andthe application of reverse flotation to reduce silica in the concentrates.

Jan 1, 2009

By C Rule

In 2003, Anglo Platinum, in a joint development with Xstrata Technology, installed the world’s first 10 000 litre IsaMillTM in a concentrate regrind duty at the Western Limb Tailings Re-treatment Plant. The success of that installation was the enabling event for Anglo Platinum to proceed with a substantial investment in horizontal stirred milling technology. Since 2006 an additional three IsaMillsTM in concentrate regrind duties and a further 18 IsaMillsTM in the more technically challenging coarse grinding mainstream applications, have been commissioned in group Concentrator operations - bringing the total number of IsaMillsTM installed in Anglo Platinum plants to 22.A collaborative approach between Anglo Platinum and Xstrata Technology towards improving milling efficiency and reducing operating costs, through internal mill component wear optimization and operating recipe development, has resulted in further improvements in the overall success of IsaMillsTM in the flow sheets of many Anglo Platinum operations. The addition of IsaMillsTM in the Anglo Platinum flow sheets has improved plant PGM recoveries by as much as 5%.This paper explores the improvements made to the IsaMillsTM flow sheet and mill internal design and shares some of the operating experience with IsaMillsTM technology in Anglo Platinum

Aug 8, 2011

By C A. Cooper, G A. Suter

The sizing of a starter dam for a Tailings Storage Facility (TSF) involves balancing many competing demands. It should cost as little as possible, be high enough to store tailings until the first raise can be constructed, it must be able to contain water safely, and it must be designed in such a way that the long-term integrity of the higher raises are not compromised, among other things. In addition to these demands there is the complication of the behaviour of the process plant, and the tailings during commissioning. Variations in slurry density, excess water in the TSF, initial settled density of the tailings, reliability issues, and beach slopes above and below water can all impact the way the tailings beaches are developed and ultimately impact the ability of the starter dyke to contain the required volume of tailings and water.The conventional approach to the design of a TSF starter dyke is to begin looking at the elevation required for a set of deterministic design parameters, find ways to reduce the size or volume of it as much as possible to reduce cost, and then possibly look at the sensitivity of some of the input parameters. This paper discusses a stochastic modelling approach for starter dykes that allows a wide range of design inputs to be simulated quickly, with an envelope of possible results produced. The sensitivity to different parameters can also be examined to understand which design inputs have the biggest impact on the required dyke sizing. By integrating the 3D TSF modelling tool Muk3D with GoldSim, it will be demonstrated how a wide range of scenarios can be evaluated and how that information can be used to make better decisions about the selection of design options.CITATION:Cooper, C A and Suter, G A, 2018. Starter dyke optimisation with Muk3D and GoldSim, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 466–475 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

The Mt Newman Beneficiation Plant uses a combination of heavy media deans, heavy medium cyclones and Reichert cones to produce saleable iron ore concentrates from low grade iron ores. The aim of this paper is to discuss score of the changes that have been made to improve the operation of the heavy medium circuits.

Jan 1, 1987

By M Noakes

EcoTechnology refers to a series of potential metallurgical processes for complex ores, concentrates, tailings and slags that are all based on an initial chlorination step at low to moderate temperatures probably in a fluid bed chlorinator (FBC). Examples of the research and development (R&D) results are provided in this paper for a high grade Au/Sb Leach Tailings (EcoGold<sub>®</sub> Process), a very refractory sulphide Au concentrate, a refractory gold calcine tailings, a Cu/Au tailings (EcoCopper<sub>®</sub> Process), bulk polymetallic sulphide concentrates and polymetallic sulphide/oxide complex ores (EcoZinc<sub>®</sub> Process and EcoLead<sub>®</sub> Process). R&D on over thirty different ore types has been conducted at a bench scale as discussed. Latterly a dedicated pilot plant was designed and constructed by EcoTech Mining Pty Ltd (EML) and several of the different feed stock results have been confirmed by pilot plant testing. It is planned to scale up to a commercial demonstration plant. To demonstrate the versatility of EcoTechnology, bench and pilot plant test results on five of the projects are used as case studies as follows: Fosterville ‘leach tailing’, VIC; Wiluna flotation concentrate – BIOX Feed, WA; Wiluna calcine facility tailings, WA; Mt Morgan Cu/Au tailings, QLD; Polymetallic sulphide concentrates from Pegmont Deposit, QLD and Polymetallic sulphide/oxide ores from Commonwealth Mine Project, NSW. CITATION: Noakes, M, 2018. Improved recoveries and environmental outcomes from complex ores utilising EcoTechnology, in Proceedings Complex Orebodies Conference 2018, pp 122–123 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 21, 2018

By A Roshal

It is anticipated that many future uranium mines in Australia will be using the in situ leaching mining process. It is fair to say that close to one third of uranium production will be generated by this method, whilst the other two thirds will fall on the uranium generated from hard rock mining and other mining methods, such as traditional open cut mining. For other types of deposits the in situ leaching mining method will remain the best technological, commercial and environmental alternative. It is important to identify and prevent all risks involved in uranium mining. The expertise in this subject is limited. Over the years there was only one mine using the in situ leaching process for uranium extraction in Australia. Computer simulation of propagation of leachate during and after the uranium in situ leaching is a crucial factor, not only for addressing the environmental concerns, but also for the most efficient recovery of the deposit. The decontamination can be modelled for a period of up to 100 years, with the acid neutralisation forecast for a period of up to 400 years. The results of the modelling are paramount for definition of the reserves, efficiency of the mining method and the environmental impact statement. The accuracy of the hydrogeological modelling and carefully selected environmental management program enables a mining company to quantify and minimise the impact of the mining activities on the regional aquifer and to prevent environmental disasters. In the study, the completed hydrogeological model allowed the client, the authorities and the community to make an informed decision about the environmental impact of the in situ leaching of uranium. In particular, the model proved that neither during the mining, nor during the neutralisation the toxic elements would interact with the local catchment area.

Jan 1, 2008

By B Waldon, M Valastro

A coal dust explosion is one of the most significant risks in the harsh and complex environment of an Underground Coal Mine (UCM). Reviewing literature, regulations and existing systems surrounding explosive dust management shows that there have been few advancements in managing this risk over the past 90 years. Legislation has remained relatively stagnant and minimal systems are implemented in the real world that can simplify, standardise and improve the effectiveness of UCM explosive dust management. To help bridge this gap, Corehesion, in collaboration with an UCM has designed, developed and implement an Explosive Dust Risk Mitigation System (EDRMS) utilising components of Business Intelligence (BI) that is capable of real-world use in industry. To do this the existing explosive dust management process at the associated research mine was evaluated to form high-level and detailed design requirements, focusing on digitally simplifying the procedure, not replicating it. The system was then iteratively and incrementally developed and implemented at the research mine to commence real-world use. The developed BI platform is compared with the existing process to highlight the advancements in performance transparency, efficiency and optimisation of UCM explosion mitigation. This comparison and evaluation of the real-world system implementation at the research mine demonstrate its success in automating procedure steps, providing a readily accessible source of data and enabling a proactive approach to planning and managing explosion risk mitigation. In addition to improvements just for the research mine, this EDRMS created directly address many Queensland regulatory audit findings. By finalising the total system and making the highlighted changes for standardisation, this BI system will have the adaptable capabilities for implementation across the UCM industry. As accurate data availability improves at UCMs, further work can be done to improve the systems’ optimisation techniques and integration of other risks.

Apr 16, 2024

By C Simpson, J M. F Clout, G Plummer

Detrital iron deposits (‘DID’) in the Hamersley Province of Western Australia have been successfully mined and processed as small quantities of saleable standalone or blended lump and fine ore products over many decades. Despite their past, present, and potential future exploitation, they have received far less geological attention than the economically more significant higher grade bedded iron deposits (BID) or channel iron deposits (CID). DID are composed of Pliocene to Quaternary unconsolidated colluvial/alluvial hematite gravels with minor sand, silt, and ferruginous clay, as well as minor iron rich hematite clast conglomerates. DID mineralisation at Solomon has been subdivided into six distinct stratigraphic units, DID-5 (lowermost) to DID-0 (uppermost) based on differences in clast and matrix textures and mineralogy, degree of consolidation/lithification, particle size distribution and replacement textures. The most significant accumulations of DID-1 to DID-5 are in tributary valleys that have been cut through the Joffre Member of the Brockman Iron Formation on either side of the main Kings-Queens valley which contains the CID. DID-5 and DID-4 are ferruginous conglomerate, referred to as canga, with four subtypes recognised. DID-4 is composed of BID hematite clasts cemented by hematite or goethite. DID-5 is characterised by partial to complete replacement of BID hematite clasts and matrix by the yellow ochreous and brown to black vitreous forms of goethite. DID-3 to DID-0 are unconsolidated hematite detritals composed of largely (>80 weight per cent) fine to coarse gravel, minor sand and little silt or clay. The gravel clasts are largely composed of hematite and hydrohematite that replace BID, micro-nanoplaty hematite-martite-ochreous goethite (m-nplH-M-oG) BID, reworked canga, hematite pisoids, siliceous hematite BID (micro-nanoplaty hematite-martite-quartz, m-nplH-M-quartz), chert (~10–20 per cent) and minor (<5 per cent) Banded Iron Formation (BIF). Hematite abundance decreases from DID-3 to DID-0 whilst siliceous hematite BID is highest in abundance in DID-0 and lowest in DID-3. A key finding of the study is that >90 per cent of mineralised detrital clasts are derived from hypogene altered BID micro-nanoplaty hematite-martite with subsequent later supergene ochreous goethite mineralisation hosted by the Joffre Member. The DID genesis model entails interpreted Palaeoproterozoic siliceous hematite hypogene microplaty BID mineralisation of the Joffre Member undergoing Cenozoic supergene leaching of quartz and replacement by ochreous goethite to form low phosphorous BID micro-nanoplaty hematite-martite-ochreous goethite clasts. BID martitenanoplaty hematite-martite-ochreous goethite clasts and detritus eroded from hill slopes were deposited in the valleys as an initial single DID-5-DID-4 unit over a weathered pre-CID basal conglomerate. DID-5 and DID-4 underwent goethite cementation of the matrix followed by replacement by hydrohematite, hematite, and maghemite. DID-3 formed during subsequent periods of erosion of largely DID-4 hematite clasts and pisoids. Groundwater flow-through hematite canga resulted in partial to complete hydration replacement of DID-4 hematite clasts and matrix by ochreous and vitreous goethite to form DID-5. Deposition of DID-2 to DID-0 was via reworking and deposition of DID-5 to DID-4 canga and DID-3 as clasts and pisoids/ooids, as well as siliceous hematite and BIF sourced from the Joffre Member in the hill slopes.

Nov 8, 2021

By T Arena

To maintain copper recoveries and maximise production at the Sepon Copper Operation it is crucial to control the amount of copper entering the leaching circuit. This requires close control of blending of the multiple ROM stockpiles to achieve the desired head grade. Grade variability in the ROM stockpiles can lead to significant variation in the processing plant copper feed grade.Head grade sampling from the milling circuit at Sepon is complicated due to milling in leach solution to preserve the water balance. Copper is present in both liquid and solid forms and copper in the added milling solution has to be accounted for. This leads to difficulties in manual head sampling which also introduces delays due to sample preparation and assay turnaround. On-stream analysis is complex because of the solution and solid copper and the need to account for recycled copper solution.This paper describes the complexity of feed grade management at Sepon and the application of on-belt analyser technology to assist in the control of copper metal throughput.

Aug 8, 2011

By L O’Connor, S C. Dominy

"Geometallurgy is an important addition to any evaluation project or mining operation. As a discipline, it seeks to maximise the net present value (NPV) of an orebody while minimising technical and operational risk. It also aims to promote sustainable development and initiatives by ensuring that all stages of extraction are performed in an optimal manner from a technical, environmental and social perspective. To achieve these goals, development of innovative technologies and approaches along the entire commodity value chain are being established (Glass, 2016). Geometallurgy has been shown to increase operational stakeholder collaboration, creating an environment for knowledge sharing and improved data acquisition and interrogation, with the end result being the integration of such data into mine planning and scheduling. All of these aspects create better business optimisation, utilisation of staff and targeted and realistic key performance indicators.The mining industry faces numerous challenges including, but not limited to:declining ore gradesgeometrically and/or internally more complex depositsdeep-seated deposits, with potentially high in situ stress regimesincreasing quantities of mine waste that needs to be managed appropriatelyhigher energy, water and chemical costsprocessing of more challenging and refractory ores – textural complexitiesstricter environmental/permitting conditions – so-called ‘licence to mine’increasing demand for specialist metals (eg rare earth elements, In, Ge, Te, Rh, Se, Ga and Li)commodity market volatilitya difficult funding environment.Given these challenges, geometallurgy provides the opportunity to control or at least manage some of them.CITATION:Dominy, S C and O’Connor, L, 2016. Geometallurgy – Beyond Conception, in Proceedings The Third AusIMM International Geometallurgy Conference (GeoMet) 2016, pp 3–10 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jun 15, 2016

By Konishi Y, Morioka Y, Okabe K

A part of the results of dissection survey of Chiba No.1 blast furnace, Kawasaki Steel Corporat- ion, is presented. Distributions of coke size and of slag and metal holdup are shown in the region of the dropping zone. A similar relation to the irri- gated packed bed is obtained. The distribution of coke size, coke temperature and liquid holdup are measured in and around the raceway. The shape of raceway in the horizontal and vertical sections indicates that each raceway worked individually. Liquid flow in the dropping zone and around the raceway on the basis of holdup measurements is Discussed.

Jan 1, 1981

By P Moarefvand, M Osanloo

The anticipated economic life of the mine, which defines the rate of mine production, is dictated initially by the design capacity of the mill/concentrator and the production capacity of the mine relative to the grade and tonnage of ore that can be encompassed by the pit design. A small pit will result in smaller investment and cash flow; in contrast, a larger size of pit will increase capital investment and annual revenue. Since open pit mine design and long-term production sequencing are essentially based on three-dimensional block models, changes in block dimensions leads to different mine sizes, and therefore changes in the mine life. The physical characteristics of the deposit, such as reserve tonnage and ore grade, affect the expected future revenues from the mining project, and consequently they affect the life of the mine. Large blocks will increase the recoverable ore reserves and production rates and hence increase the mine life. This paper discusses the effects of the block dimension on the commercial ore reserve, grade-tonnage curve and its effect on the production rate, ultimate pit size, mining cost and consequently the mine life. The result shows that block height is the most effective parameter governing the economical life of the mine.

Sep 26, 2011

By S Kakara, A Kamaraj, S S. Varanasi, B V. R Mandalika, M B. Shaik

The properties of top slags play a very important role in secondary steelmaking. Fluxes should be chosen based on the ladle furnace (LF) slag requirements like viscosity, melting temperature, sulfide capacity, etc. CaF2 and CaO-Al2O3-based synthetic slags are the most used fluxes in secondary steelmaking to improve slag fluidity and interfacial chemical reactions. CaF2 is obsolete due to fluorine pollution and CaO-Al2O3 based slags have 40–50 wt per cent Al2O3 and 30–40 per cent CaO which is not beneficial for desulfurisation. Yet another drawback is that LF slag disintegrates into fine powder during cooling due to phase transformation C2S (2CaO.SiO2). Hence, there is a need for the development of low melting fluxes with high CaO content and the capability to prevent slag disintegration. The current work studied the effect of 0–9 wt per cent B2O3 on physico-chemical properties and characterisation of LF slags. X-ray diffraction (XRD) analyses were carried out to identify mineralogical phases present in slag and Fourier-transform infrared spectroscopy (FT-IR) analysis was done to understand the changes in bonds of B2O3 added LF slag. The characteristic temperature of slag was determined by a hemispherical method using high-temperature microscopy. Empirical models were used to calculate viscosity, break temperature, and sulfide capacity. FactSage™, ver 8.2 (by GTT-Technologies) simulations were carried out to find the equilibrium phase fractions and percentage of liquid slag at different temperatures. New phases such as Ca11B2Si4O22 and Ca2B3O5 were formed in LF slag with B2O3 addition. Based on the results, 0.5–1.0 wt per cent B2O3 was found to be sufficient to prevent C2S-driven disintegration of LF slag. Also, the melting temperature and viscosity of LF slag were reduced by adding 3–8 wt per cent B2O3 due to the formation of BO3 planar triangular structure and low melting eutectics in slag. Liquid slag started forming at a temperature as low as 800°C when B2O3 is >6 wt per cent. It was found that the sulfide capacity, viscosity, and break temperature of the slag decreased with increasing wt per cent B2O3. Based on the analysis carried out, B2O3 can be a promising fluxing material in secondary steelmaking, for improving the desulfurisation kinetics and valourisation potential of LF slag.

Aug 21, 2024