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By P. Somasundaran, Bruno Lartiges

Two different groups of mechanisms have been considered in the past to explain the effects of chemical additives on grinding. While one group of explanations is based upon alterations of surface and mechanical properties of the individual particles, the other group depends mainly on the arrangement of particles and their flow in suspensions. In this paper some of the past work on grinding aids is reviewed and attrition grinding of a commercially important ceramic material, zirconia (stabilized with yttria) with polyaaylic acid as grinding aid, is studied in order to determine the effect of the aid on the ground product itself. It was observed that even though polyaaylic acid did cause a drastic decrease in the viscosity of the pulp, it did not have any major effect on the grinding of zirconia at least up to 2000 ppm and only minor detrimental effect above it. Importantly, complexation by the polymer was found to cause extraction of yttrium into solution with possibly significant changes in the surface chemical composition of the product.

Jan 1, 1992

By Y. C. Kim, F. Szidarovsky

The technique of linear kriging as a grade estimation method of mining blocks is reason¬ably established in the mining industry. During the kriging process, negative kriging weights ([]i) are sometimes encountered. Due to negative kriging weights, negative block grades may be obtained in some extreme situations, which makes no practical sense. To guarantee nonnegative weights, an additional constraint is required in the kriging system of equations. Unfortunately, the nonnegative weight constraint results in a set of nonlinear system of equations. In this paper, a derivation of the resulting set of nonlinear equations is presented and a numerical algorithm is developed for the solution of the equations. Because the algorithm developed does not remove negative weights arbitrarily, optimal nonnegative weights are always guaranteed. Results obtained using the developed algorithm were compared with those using the standard linear kriging, in terms of computer, time and the estimation results. Both the computer time and the kriging variance were found to be higher with nonnegative constraint, as expected. However, some systematic pattern was observed in the kriged values (i.e., over-or underestimation) with or without the nonnegative constraint. The study also demonstrated when one should generally expect negative kriging weights in practice, and what practical impact the negative weights can have on the kriging estimates.

Jan 1, 1987

By Hassan El-Shall, El-Sayed A. Abdel Aal

The major goal of this study is to decrease iron content in wet-process phosphoric acid. Reducing the amount of post-precipitated sludge in the acid is another important objective in this investigation. In order to achieve these goals, research efforts have focused on bench scale testing of an iron-chelating reagent to remove iron from phosphoric acid produced from South Florida high-iron and -magnesium phosphate concentrate, and plant testing using freshly produced concentrated acids for reducing the post- precipitated sludge. The data obtained in the above studies suggest that the addition point of the precipitating reagent is very important, as the precipitated iron compound has higher solubility at higher P2O5 concentrations. Up to 60% Fe2O3 removal efficiency is achieved depending on the amount of the reagent, concentration of acid used, and operating conditions. The addition of precipitating reagents to freshly concentrated phosphoric acid leads to a decrease of up to 84% in sludge volume percentage depending on acid type and clarification conditions. Decreasing the volume percentage of the sludge facilitates acid handling as well as decreases the adherent water- soluble P205 leading to lower total P2O losses.

Jan 1, 2002

By E. M. J. A. Pallone, F. N. Cunha, W. S. Resende, R. M. Stoll, R. C. Bradt

Utilization of the magnesium aluminate spinel in refractor' applications is briefly reviewed. The synthesis of a magnesia aluminate spinet aggregate from natural raw materials is considered in terms of the crystal chemistry of the spinet structure and expected impurities. Principles for the formation of this spinet refractory aggregate from different natural raw materials are presented. The basic concepts were then applied to the reaction of a bauxitic clay with a natural magnesite. This combination of raw materials has the potential to produce a low-cost refractor' aggregate that is a composite of spinel and forsterite. Experimental results are reported to produce a spinel refractor.' aggregate containing a small amount of forsterite. It possesses low apparent porosity and high bulk density suitable for industrial refractor' applications, including steelmaking, aluminum and copper foundries and cement production.

Jan 1, 2002

By Judith M. Ballantyne

Carlin-type. disseminated, sediment-hosted gold deposits can be better described as hydrocarbon-associated gold deposits. A new genetic model for these deposits involves the intrusion of one or more small bodies of magma into a shallow hydrocarbon reservoir or ma of hydrocarbonenriched rocks, imposing a convecting geothermal system on the local groundwater. Pyrite, commonly associated with the organic material, provides a substrate for deposition of gold and other trace elements in an environment rich in dissolved sulfide. Both diagenetic and hydrothermal pyrite may act as gold depositional sites. Thermal cracking of hydrocarbons, catalyzed by illite, subsequently generates an oxidizing environment by depleting hydrogen. As oxidation increases, arsenic sulfide minerals and barite m stabiied at first. Increasing hydrogen depletion converts sulfide to sulfate, generating acid oxidizing conditions which: alter pyrite to hematite; continue the deposition of sulfates; and ultimately develop late stage acid-sulfate assemblages containing minerals such as kaolinite. alunite. and jarosite. Gold released from the oxidizing pyrite is redeposited as free gold, and pehaps remobilized.

Jan 1, 1988

By R. Pazhianur

Many investigators conducted surface force measurements between hydrophobic surfaces in water, and observed attractive force that was substantially stronger than the van der Waals attractive force. The excess force was appropriately referred to as “hydrophobic force”, for which many different theories have been put forth by numerous investigators. In an earlier publication (Yoon and Ravishankar, 1996), it was suggested that the hydrophobic force maybe due to the interaction between the large dipoles created by the surfactants adsorbing on solid surfaces in patches (or domains). In the present work, a mathematical model has been developed to further elaborate the theory.

Jan 1, 2003

By S. Chander

A comparison of gold, platinum and sulfide ion selective electrodes was made for determination of Eh in solutions containing hydrosulfide ions as a model system. The comparison was made in terms of the accuracy of the measured response, response time, pH dependence, and reproducibility of measurement. The sensitivity of each electrode towards changes in hydrosulfide ion concentration was measured in terms of the change in measured Eh per decade change in concentration. On the basis of a detailed investigation of the electrode processes occurring at the surface of gold and platinum electrodes, it was postulated that within the pH range investigated these electrodes respond to changes in the hydrosulfide ion concentration in solution. In comparison, the sulfide ion selective electrode is known to respond to changes in the sulfide ion activity in solution. Although the potentials measured with gold and platinum electrodes were mixed potentials, pretreatment procedures can be used to obtain a signal suitable for process control. For control of hydrosulfide ions in flotation pulps, the use of a gold electrode pretreated at 1.0 V with respect to a standard hydrogen electrode is recommended.

Jan 1, 1992

By S. P. Banerjee

Injection of inert gases to combat mine fires has been practiced in various parts of the world for a long time. Of late, nitrogen has become the preferred inert gas for control of mine fires and safe salvage of longwall equipment as compared to carbon dioxide or fuel gases produced from burning of fuel. In India, carbon dioxide has been used for fire fighting in a number of mines during the 1960s and 1970s. More recently inert gas produced from burning of fuel oil in surface plants has been used in controlling the atmosphere in fire areas in two mines. In yet other cases, liquid nitrogen has either been poured directly into fire areas in liquid form or injected in gaseous form to keep the fire in check. Nitrogen produced in liquid form in an oxygen plant is more costly than nitrogen produced from PSA (pressure swing adsorption) based plants. A PSA-based plant has been installed in one of the Indian mines in 1986 and more are in the offing. This paper reviews the application of various inert gases in Indian mines and discusses the likely trend of inert gas application in Indian mines in the future.

Jan 1, 1987

By F. D. Mendes, A. H. Martins

The high copper grade in the Igarapé Bahia (Brazil) gold-copper ore restricts the direct application of the classical cyanidation process. Copper oxide and sulfide minerals react with cyanides in solution, causing high leach-reagent consumption, raising processing costs and decreasing gold recovery. According to studies, a feasible solution would be to pretreat the ore to remove copper minerals prior to cyanidation. The goal of this experimental work was to study the conditions for the removal of copper from the Igarapé Bahia gold-copper ore by sulfuric acid leaching, applying a statistical approach to the experimental design. By using the Plackett Burman method, it was possible to select the variables that exhibited the largest influence on copper extraction at the sulfuric acid leaching stage. These variables were leach solution temperature, stirring speed, sulfuric acid concentration in the leach solution and ore particle size. The individual effect of these variables and their interaction influences on the experimental response were analyzed by applying the replicated full-factorial design method. Finally, the selected variables were optimized by the ascending-path statistical method, which determined the best leach experimental conditions for maximum copper extraction. The optimized leaching conditions resulted in a copper extraction of 75.5%. Keywords: Copper, Gold, Extraction, Sulfuric leaching, Optimization

Jan 1, 2003

By E. H. Cho, Q. Luo

Pittsburgh No. 8 coal, cleaned by conventional froth flotation, was oxidized in a 2-L Parr stirred bench-top autoclave. Autoclave tests were carried out for up to 5 hrs under the following conditions: 150 to 225ºC, 60 to 500 psi 02 and 15 to 60 g of coal per 600 mL of distilled water. The oxidation of coal was evaluated by measuring the total acidic group formed on the surface of the coal and by measuring the adsorption (under standard conditions) of calcium ion from a solution. The degree of oxidation of the coal increased continuously, without much leveling off, with increasing oxygen pressure. With increasing temperature, the oxidation of the coal increased sharply between 150 to 175ºC and then leveled off above 175 °C. The adsorption of calcium was >3% on coal oxidized under the most favorable conditions. The adsorption of calcium on coal increased sharply with increasing equilibrium pH. The loss in Btu was found to be sensitive to oxidation temperature. This study concluded that the optimum oxidation of coal is achieved over 3 hrs at high oxygen pressures (e.g., 500 psi) at ~170ºC. This study also concluded that, when measured in terms of calcium adsorption, Btu loss and reaction time, the oxidation achieved in an autoclave is far superior to that achieved in a fluidized bed.

Jan 1, 1996

By Van Zyl Brink

A longwall-based coal mine in Australia, referred to in this paper as AusMine Colliery, experienced windblasts resulting from goaf falls. Windblasts were the cause of serious injuries and threatened the continued operation of the mine. A microseismic early warning system was installed and a significant success rate in providing early warning of large roof instability resulting in high velocity windblasts, has been achieved. Early warning of goafing is accepted as an operational tool on the mine. Severe demands are placed on the operator in terms of 'real time' interpretation. The development of an expert system allowed for a probabilistic approach to achieve automatic alarms. This paper will quantify the success, failure and false alarm rates achieved by manual operation and automatic expert system-based decisions making, respectively.

Jan 1, 2002

By K. M. Belingheri, M. E. Smith

Pinson Mining Co. operates a conventional mill and two heap leach operations in north-central Nevada. The latest of these heap leach operations, the Preble project, is a low-grade, low-tonnage property made profitable through several innovative capital reduction techniques. Rapid return on investment was a prime factor in design. To facilitate this, fast-track design and construction techniques were employed. The project is a seasonal 1.5 kt/d (1 700 stpd) crush/agglomerate heap leach plant using both clay and plastic leach pads. Construction and startup were achieved through cooperative arrangements between local contractors and in-house construction personnel, with few items put out to bid. An interactive approach to design minimized lost time and construction costs.

Jan 1, 1987

By Richard Meriwether Smith

Mining-related earthy bodies in contact with the atmosphere are now counted, generally, as minesoils. Because soils within this broad category are extremely young the influence of parent material is stronger than in older soils, where climate, organisms, and topography have had time to interact with near-surface rocks to form more distinctly differentiated profiles. Understanding of minesoil properties and processes is aided by definitions of rock types in terms of chemical, physical, and mineralogical characteristics that are, with some degree of consistency, translatable into soils. Geological correlations based on age or sedimentary sequences are helpful if they assure details of mineralogy and lithology, but our pedologic objectives demand that any conflicts involving rock types must be resolved in favor of distinctions having strongest implications for soil properties after mining. Chemically this approach emphasizes accounting of potential acid-base status, plant nutrient availability by adapted and calibrated extraction procedures, and absence of biotoxins. Physically it anticipates particle sizes, shapes, and arrangements in readily pervious soil profiles that will favor plant growth with desired levels of moisture and oxygen. Concurrently we are considering soil property suitability for uses other than growth of plants. Above all we need to be able to predict pedogenic processes in the particular environment, including rate as well as direction of chemical and physical change.

Jan 1, 1974

By R. L. Garrett

The quality of mineral additives used in a drilling fluid (mud) can dramatically affect the fluid's properties and the overall cost of drilling an oil or gas well. The principally wed minerals are bentonite, barite, barite/hematite blends, and hematite alone. The high specific gravity minerals, barite and hematite, are used to increase drilling fluid density. Bentonite clay is used to increase drilling fluid viscosity and gel strength and to provide a low permeability filter cake. A multimillion dollar investment in a well and the safety of the personnel on the drilling rig can depend on how effectively these mud additives perform with other constituents in the mud. This paper points out effects caused by small amounts of certain carbonate and sulfide mineral impurities in barite or hematite and how polymeric extender additives in bentonites contribute to unpredictable behavior of a mud. Effects like these are the reason oil companies using these materials sometimes set their own quality standards beyond those already specified in APZ Spec. 13A. Also discussed in this paper are the current standardization activities of API Committee 13 on these minerals.

Jan 1, 1988

By L. G. Austin

Using an instrumented laboratory high-pressure grinding rolls mill, the grinding force, gap dimension, mass flow rate and net mill power were measured for six coals and a crystalline quartz. A technique was developed to estimate the compressive stress-strain curves for compression of the materials in the mill plus the effects of elastic decompression. To reconcile the mill power and grinding pressure results, it was necessary to allow for the energy recovery on decompression. No clear correlation was obtained between the form of the stress-strain curves or the variation of specific mill power factor with the Hardgrove grindability index (HGI), although coals with the lowest and highest HGIs (i.e., 44 and 106) gave results significantly different from the other coals. Feeds below 140 mesh (105 µm) flowed more rapidly than coarser feeds and would not build up high grinding pressures. This indicated shearing and fluidlike properties rather than compression as a locked bed.

Jan 1, 1998

By A. J. Monhemius, S. Raghavan, G. W. Warren, E. Peters, D. W. Furerstenau

A lyometallurgical process for extracting copper from an ore containing chrysocolla by leaching it with a kerosene solution containing LM 63 in the presence of small amounts of aqueous ammonia is described. The experimental results indicate that 70 to 75 percent of the copper can be extracted from the ore using an ammonia content that is about one-fourth the stoichiomeaic quantity required to leach copper in an aqueous leaching system. The rate of copper extraction was found to be a function of particle size, ammonia concentration and temperature. The large quantity of physically adsorbed water together with ammonia in the pores of chrysocolla provides a mechanism for the transport of copper to the external surface of the particles where it is complexed by the LM molecules and transferred into the organic phase. When size reduction accompanies leaching, the extraction process was found to proceed when only "trace" quantities of ammonia are present in the system. The kinetics of the extraction process appear to be controlled by a mixed (reaction and diffusion) mechanism.

Jan 1, 1993

By J. L. Hoover, P. W. Conrad, J. Downey, S. Parrow, S. Rosenthal

The goal of the drill bit consumption study was to develop an equation(s) based on various components that affect drill bit wear and use that equation(s) to estimate the consumption of bits during production drilling. Drill bit data from various geographic locations were compiled and used to develop linear regression equations using the Microsoft Excel software package. Multiple drill bit consumption equations were developed and statistical analysis was used to verify the accuracy of those equations. The equations will allow mining companies to more accurately forecast drill bit consumption when evaluating new mine properties. This capability becomes increasingly beneficial to forecasting as the cost of consumables increases.

Jan 1, 2012

By M. J. Gula

In the solvent extraction -electrowinning recovery of copper from oxide or sulfide ores there is a continuous transfer of iron and other impurities from the primary leach solution to the copper electrowinning electrolyte via chemical transfer or mechanical entrainment. Iron is the principal impurity that has to be controlled in the electrolyte by a "bleeding" of the electrowinning solution. This bleeding transfers copper and sulfuric acid back to the primary leach circuit along with the iron. Copper is recovered via the solvent extraction process and generally the sulfuric acid is used as a reagent in leaching. Unfortunately, cobalt, which is added to the electrowinning solution to modify the anodic process, is irreversibly lost through the bleeding operation. This cobalt loss represents a significant operating cost to SX-EW copper producers. DiphonixTM ion exchange resin contains diphosphonic acid and sulfonic acid functional groups on a polystyrene-divinyl benzene matrix. This resin has been found to strongly and selectively extract ferric ion from copper sulfate -sulfuric acid solutions containing cobalt. Thus, an ion exchange process using DiphonixTM resin for the control of iron has been developed to replace the conventional bleed stream process. The new process minimizes the loss of cobalt from the electrowinning circuit and strips the iron into a sulfate based solution suitable for leach solution makeup. In addition, this process can effect a lowering of the total iron concentration in the electrolyte circuit with an associated increase in current efficiency. In this paper, data on the loading and elution of iron are presented. Laboratory and pilot scale data will be discussed along with information on process design and comparative economics.

Jan 1, 1996

By Jurgens PE Hamman, Faisal Putra, Hadnaltias Alpeki, Willem de Beer

The Deep Ore Zone mine is the third lift of caving at PT Freeport Indonesia’s East Ertsberg Skarn System. An increasing trend in seismicity along the northern boundary of the DOZ cave, as well as the northern fringes of the DOZ production and infrastructure levels, was taken as indicative of an interaction between the approaching DMLZ cave and the DOZ subsidence zone. Seismicity trends and locations indicated a reducing crown pillar and an associated stress increase along these DOZ excavations, as well as the regional area along the DOZ cave boundaries. Although rockbursts were not identified as an immediate hazard, seismic shakedown was a highly probable hazard in the case of remote large (≥3.0) seismic events. An evaluation process, as described in the Canadian Rockburst Support Handbook (1996), was followed to identify and quantify the various parameters that could contribute to a shakedown evaluation. A shakedown assessment, based on the Peak Particle Velocities scaling relation, was conducted to assess the current installed ground support systems along the northern fringes and the fixed facilities of the DOZ mine. The range in ground support systems were mostly due to different geotechnical environments. The load–deformation characteristics of these support systems were evaluated to determine the support capacity and compared to the potential support demand under varying shakedown conditions. Shakedown hazard maps were compiled to indicate the installed ground support system’s vulnerability to seismic shaking. Based on this information, areas were divided into zones indicating whether they were sufficiently supported, additional support was required, access was to be restricted, and / or they were to be abandoned. Mine management utilised these hazard maps to strategize actions for the various operational zones within the DOZ, including the fixed facilities. This paper briefly describes the derivation of the PPV scaling relationship. Seismic and geological data for the DMLZ – DOZ interaction areas were evaluated to determine the likely source of large events. Subsequent larger events and their effects are shown to assess the veracity of the magnitude and PPV estimates, as well as the effectiveness and appropriateness of the ground support systems.

Apr 26, 2022

By J. E. Gebhardt, S. Chander

Significant advances have occurred in the use of electrochemical techniques for sulfide mineral flotation research. The techniques have been used singly or jointly with other characterization methods. When used in combination with other methods, the electrochemical methods provide a means to control the state of oxidation of the surface. Various analytical methods are employed for characterization. The methods that have been used include wetting, x-ray photoelectron and fourier transform infrared spectroscopies. The electrochemical methods include voltammetry and transient electrochemical techniques of galvanostatic polarization and AC impedance spectroscopy. The challenge for the future lies in the utilization of this knowledge in plant operations so as to increase the overall efficiency of flotation separations.

Jan 1, 1989