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By D. E. Banks, J. K. H. Ma, Y. Rojanasakul, J. Y. C. Ma, C. J. Malanga

There is evidence to suggest that cell injury induced in alveolar macrophages (AM) following phagocytic activation by silica particles may be mediated through changes in intracellular free calcium [Ca 2+}. However, the mechanism of silicainduced cytotoxicity relative to [Ca2+], overloading is not yet clear. To provide a better insight into this mechanism, isolated rat AMs were exposed to varying concentrations of crystalline silica (particle size< 5 µm in diameter) and the fluctuation in their [Ca2+]; and cell integrity were quantitatively monitored with the fluorescent calcium probe, Fura-2 AM, and the membrane integrity indicator, propidium iodide (Pl). Results from this study indicate that silica can rapidly increase [Ca2+]; in a dose-dependent manner with a characteristic transient calcium rise at low doses (<0.1 mg/ml) and an elevated and sustained rise at high doses (>0.1 mg/ml). Depletion of extracellular calcium [Ca 2+]0 markedly inhibited the [Ca2+]; rise (˜90%), suggesting that Ca2+ influx from extracellular source is a major mechanism for silica-induced [Ca2+]; rise. When used at low doses but sufficient to cause a transient [Ca2+]; rise, silica did not cause significant increase in cellular Pl uptake during the time of study, suggesting the presevation of membrane integrity of AMs under these conditions. At high doses of silica, however, a marked increase in Pl nuclear fluorescence was observed. Depletion of [Ca 2+] 0 greatly inhibited cellular Pl uptake, induced by 0. 1 mg/ml or higher doses of silica. This suggests that Ca 2 + influx, as a result of silica activation, is associated with cell injury. Indeed, our results further demonstrated that the low dose effect of silica on Ca 2+ influx is inhibited by the Ca2+ channel blocker nifedipine. At high doses of silica (>0.1 mg/ml), cell injury was not prevented by nifedipine or extracellular Ca2+ depletion, suggesting that other cytotoxic mechanisms, i.e., nonspecific membrane damage due to lipid peroxidation, are also responsible for the silica-induced cell injury. Silica had no significant effect on cellular ATP content during the time course of the study, indicating that the observed silicainduced (Ca2 ... ); rise was not due to the impairment of Ca2 + -ATPase pumps, which restricts Ca2+ efflux. Pretreatment of the cells with cytochalasin B to block phagocytosis failed to prevent the effect of silica on [Ca2+]; rise. Taken together, these results suggest that the elevation of [Ca2+]; caused by silica is due mainly to Ca2+ influx through plasma membrane Ca2+,channels and nonspecific membrane damage (at high doses). Neither ATP depletion nor Ca2+ leakage during phagocytosis was attributed to the silica-induced [Ca2+]; rise.

Nov 1, 1995

By Joseph L. Condon

High-speed movies were taken of crater experiments in two-dimensional plates of Tennessee marble to study craters being formed primarily by stress-wave action. The contribution of gas action to the cratering process was minimized because the two-dimensional models did not contain the expanding gases from the explosive. Four burdens were studied for solid plates and one burden for a segmented plate. After cratering, the plates were reassembled for dye penetrant studies of fracturing. Flyrock velocities were calculated and related to the degree of fracturing, and compared with those from quarry shots. In general, the smallest burdens produced the highest flyrock velocities and the least amount of fracturing. Flyrock velocities compared favorably with initial flyrock velocities in quarry blasts, but did not show step accelerations due to gas effects as did the quarry blasts. The test with a segmented plate was used to simulate cratering in a jointed material and showed that stress-wave effects can be important for crater formation in jointed rocks.

Jan 1, 1972

By Henry M. Harris

The Bureau of Mines investigated a glass containing approximately 17 percent lithia and 83 percent silica to establish a method of devitrifying cast and rolled shapes. Glass shapes with high strength were made by melting, forming, and rapid cooling of the composition, and the shapes subsequently were converted to a crystalline condition by heat treatment. The best devitrification schedule included rapid cooling of the glass to below 300° C, followed by reheating at a rate of 50° to 400° C per hour, depending on the size of the shape, followed by a of 60 to 70 hours at 500° C and another period of 15 hours at 800° C. attempts to use faster heating rates or slow cooling to accomplish devitrification in deformation of the shapes. The crystalline shapes had flexural strengths that averaged over 33,000 psi, achieved with an annealing time of 60 to 70 hours at 500° C.

Jan 1, 1965

By B. D. Sartwell

Multiple-charged beams originating from a 300-kv ion accelerator are important tools in the study of metal surfaces and thin films. A knowledge of the particle range is necessary for an understanding of the interaction processes of the ions with the targets. Utilizing a theory developed by Lindhard for determining the range of low-energy ions in solids, the ranges of H, He, C, N, 0, and Ar ions in A1203, Al, Fe203, Fe304, CuO, Cu20, Fe, Cu, Sn, and W were calculated for the energy range 60 to 400 kev using a computer program written in BASIC. The range, presented in graphical form, is given in both µg/cm2 and angstroms. In addition, heavy ion ranges were calculated for comparison with published experimental values. For ions with Z > 5, the discrepancy between the calculated values and published experimental values generally ranged from 2 to 40 percent; the largest deviations were probably due to experimental error.

Jan 1, 1970

Eliminate the need for roof bolter operators and their helpers to work under unsupported roof while setting or removing temporary supports before or during the roof bolting cycle-a task that annually accounts for approximately 20 percent of all roof fall fatalities. Approach The Bureau of Mines designed, built, and field tested an auto-mated temporary roof support (ATRS) that can be carried from place to place on the drill head of a single, fixed-head roof bolting machine (squirmer) used in low coal seams (less than 42 inches thick). How It Works The ATRS is designed for installation on any streamlined squirmer. It consists of a ten? foot-long, steel, wide-flange beam supported by two double-acting, telescoping hydraulic cylinders. A steel sleeve, mounted on the bottom center of the beam, is designed to fit over top of the

Jan 1, 1983

By T. T. Read

"Education is the one thing which is unanimously regarded as valuable. The growing complexity of modern life, with its intricate organization, the manifold kinds of mechanical equipment that are used, and the constantly growing, necessity for the speedy and accurate interchange of information and ideas, make education an asset that constantly increases in value. The number of things that may profitably be known has grown so large that the field of education has been divided, and attention is often directed to only those things that are most immediately valuable. Modern educational facilities are often directed to what may be called corrective, work; the, providing of people with information that they teed in the conduct of their daily lives, but which for various reasons they have not previously had facilities for acquiring. The value of special education in the industrial world has been so thoroughly demonstrated that far-seeing managers of mining enterprises are always interested in the educational facilities existing in the community where their work is carried on.The educational facilities of a modern community may be classified in several ways. They may be divided into;1. Facilities for general education, for the purpose of increasing the whole field of knowledge of the student.2. Facilities for special education, which are intended to remedy a specific defect, or to give proficiency in some special field. This may be divided as follows;a. Training for work, intended to fit an employee to adequately perform the task assigned to him, this ranges from brief instruction by a foreman or fellow-worker up to definite training courses in which the employee dose nothing but study for a period of several weeks or months, being paid during this period a wage that may range from a nominal amount up to practically full time salary. The student's educational preparation may already be fairly advanced. Some of the manufacturers of electric machinery maintain, a school similar to that just described for graduates of engineering colleges. In other cases the only pre-requisite may be a common school education, as in the schools for operators, maintained by the telephone companies."

Apr 1, 1920

By B. R. Mohal, F. F. Aplan, S. Chander

"Dust abatement by water sprays involves the subprocesses of 1) collision between dust particles and water droplets, 2) adhesion of particles to droplets, and 3) engulfment of particles by the droplets. A review of the fundamental aspects of these subprocesses shows that collisions between particles and droplets are determined by aerodynamics and the size and surface charge of the particles and of the droplets. However, the adhesion and engulfment subprocesses depend upon the wetting characteristics of the particles. Although wetting agents (also known as surfactants) have been used as dust suppressants in several investigations, conflicting results are available regarding their effectiveness. In this paper, we show that these results can be explained if the effects of coal rank on surfactant adsorption and wetting characteristics are taken into account.The influence of several nonionic surfactants containing polyethoxy adducts on the wetting behavior of coal is presented. The wetting was determined by a modified Walker Test method, and contact angle measurements. The results show that the wettability of coal depends upon coal rank, structure of the hydrocarbon chain of the surfactant, and the number of ethoxy groups in the molecule.IntroductionDue to the inherent nature of the mining process, a large number of particles are generated, a portion of which becomes airborne to create dust. Dust can be aesthetically and environmentally unacceptable and it can also be explosive. Fine particles in the respirable size range ( < 5 urn) are con-sidered to cause lung diseases, namely, silicosis, pneumoconiosis, etc.(1) Several approaches to reduce dust in mine environments are practiced throughout the mining industry. These include decrease in generation of dust through improvements in mine machinery, ventilation (in which lower dust levels are achieved by dilution of contaminated air with clean air), and dust removal methods. Water sprays are most commonly used to remove dust par-ticles. Recently, scrubbers are reported to have been installed on mining machines to remove dust,(2,3) which also make use of water sprays to reduce dust."

Mar 1, 1989

By W. K. Sawyer

In this Bureau of Mines investigation, one-and two-dimensional gas reservoir simulators were combined in such a manner that pressure distributions both in an induced vertical fracture and in the surrounding formation, could be determined as a function of time for any specified well production rate. The technique used consisted basically of the alternate ust of one-and two-dimensional algorithms for obtaining new pressure distributions in the fracture and in the reservoir, respectively. The pressures at adjacent reservoir and fracture nodes were used to calculate flow rates from the formation into the fracture, which provided source terms for both algorithms. The combination model developed provides the only known means of simultaneously simulating transient gas flow in a vertical fracture and the surrounding formation. Thus, the technique developed would be useful in locating wells in a gas storage field in that the effects of both fracture length and conductivity could be considered prior to drilling and fracturing operations. In addition, it will be helpful in analyzing pressure drawdown tests in a vertically fractured gas well since the entire test can be readily simulated for a wide range of reservoir and fracture properties.

Jan 1, 1974

By Harold F. Unger

The Bureau of Mines conducted drilling experiments in the laboratory with a commercially available percussive drill that has an independent rotational system. Eight rock types with a wide range of physical properties were drilled under several combinations of rotational speed, drilling thrust, and operating pressure. Penetration rates and energy per unit volume correlated well with the coefficient of rock strength as shown graphically. Size-distribution analyses of some of the drill cuttings show how particle size varies with rotation speed and rock hardness. In general, changing the rotational speed has a greater influence on the penetration rate in softer rocks, with penetration rate increasing with increasing rotational speed.

Jan 1, 1972

By L. B. Pankratz

Low-temperature heat capacities, high-temperature enthalpy increments, and the enthalpy of formation at 298° K were determined calorimetrically for vanadium subnitride (VN0.465). The low-temperature investigation gave S°298.15 = 6.379 ±0.005 cal/deg mole, and a combustion calorimeter investiga¬tion provided ?Hf°298.15 = -31.80 ±0.60 kcal/mole. The two quantities were combined with the high-temperature data to give standard values of enthalpies of formation and free energies of formation above 298° K. These and related thermodynamic functions were tabulated to 1,800° K. Similar data are included in the range of 298° to 1,600° K for the mononitride, VN.

Jan 1, 1971

By C. H. Elder, M. C. Irani

Two degasification test boreholes were drilled to depths of 1,238 and 1,212 feet on Bureau of Mines property at Bruceton, Pa., as part of the Bureau&apos;s long-range coal degasification program. The holes provided detailed geologic information and geologic sections, which were correlated with regional stratigraphic cross sections prepared by the Pennsylvania Geological Survey. Gas content determinations and coal analyses were made on the Upper Freeport, Middle Kittanning, Clarion, Brookville, and Mercer coalbeds; gas content of the coalbeds ranged from 53 to 165 cubic feet per ton. Formation pressure and gas flow tests were conducted on selected coalbed intervals in borehole 1; formation pressures ranged from 292 to 473 psig. The middle Kittanning coalbed was hydraulically stimulated using very heavy gelled water, but gas production remained low because gel residue and formation water inhibited the flow of gas. Gas contents in the Clarion, Upper Brookville, and Mercer coalbeds were anomalously low owing to the proximity of porous sand- stones which act as reservoirs for gas migrating from coalbeds.

Jan 1, 1977

By S. D. Maksirnovic, Fred N. Kissell

The use of vertical surface degasification boreholes with bleeder systems and the use of a timbered bleeder system to degasify gob areas were studied by (the Bureau of Mines. This report describes three gob degasification studies ,conducted in the Pittsburgh coalbed. One study was conducted to determine the number of panels degasified with one large borehole . The study showed that the borehole provided degasification for three panels. Another study was conducted during the retreat of a 35-acre panel with a single-entry and a two-entry bleeder system and a large surface borehole. A major portion of methane emitted from the panel was carried away by the bore- hole, leaving the bleeder entries relatively free of methane. The last study was made to determine the effectiveness of a timbered bleeder system. The bleeder entries successfully degasified the gob area when enough entries were available and adequate pressure was available to force the air through roof falls.

Jan 1, 1980

By R. P. Beyer

[The Bureau of Mines has measured the low-temperature heat capacities and high-temperature enthalpies of crystalline K2Si2O5 as part of a program for advancing mineral resources technology with energy economy. High-temperature enthalpies of glassy and liquid K2Si2O5 and crystalline K2SiO3 were also mea¬sured. An adiabatic calorimeter operating over the range 5 to 308 K was used for the heat capacity measurements for K2Si2O5 from which the standard entropy at 298.15 K, S°298 = 45.55 ±0.05 cal/deg-mole, was calculated. Tabulated values of Cp°, S°, -(G° -HO°)/T, and H°-HO° from 5 to 300 K are given for K2Si2O5. A copper-block drop calorimeter was used in the enthalpy measurements, operating from 298.15 to 1,198 K for K2SiO3 and from 298.15 to 1,453.8 K for K2Si2O5. No transitions were found for K2SiO3. The KI2Si2O5 showed two reversible first order transitions, one at 510 K with a heat of transition of 0.29 kcal/mole and one at 867 K with a heat of transition of 0.38 kcal/mole. The heat of fusion for K2Si2O5 20 5 was calculated to be 8.42 kcal/mole. Relative enthalpies are given in equation form, and high-temperature values are tabulated for Cp°, S°, - (G°-H°298 )/T, and H°-H°298 . Also tabulated are ?H°, ?G°, and log K for formation of K2SiO3 and K2Si2O5 from both the elements and the oxides.]

Jan 1, 1979

By J. L. Konchesky

The Bureau of Mines investigated the main reactions of coal gasification by steam. Coal (minus 70 mesh)-water slurry was fed into a laboratory-scale tube-coil gasifier to show the effects of residence time (0.6 to 1.1 sec), steam-coal ratio (2 to 11 lb/lb), and temperature (1,600° to 1,900° F), at about 1-1/2 atm. Devolatilization was very rapid: about 70 pet of the coal&apos;s volatile matter evolved within 0.6 sec at about 1,600° F; temperature increase released more volatile matter until about 95 pct was driven off at 1,900° F. Devolatilization was not increased by raising steam concentrations and was only slightly increased by extending residence time. Below 1,600° F, there was no evidence of the steam-carbon reaction, but at 1,900° F more than 80 pct of the coal&apos;s fixed carbon was converted to gas; the conversion was increased Significantly by increased residence time and steam concentration. The water-gas shift reaction occurred simultaneously with devolatilization, and the steam-carbon reaction, approaching equilibrium with increased residence time and temperature and decreased steam concentration.

Jan 1, 1969

By D. H. Baker

This report, one of a series prepared by the Federal Bureau of Mines on the technology of titanium, describes the development of an electrorefining cell from which cathode deposits up to 30 inches long can be produced. Data show individual deposits to be homogeneous, comparable from top to bottom, and not varied in quantity or quality of metal over the entire length of the deposit. Investigations concerned with various diameter cathodes showed that cathode current efficiencies were materially reduced with cathodes less than 2 inches in diameter. Deposits produced on 1/2-inch-diameter cathodes showed cathode current efficiencies of 19 percent and on 1-inch cathodes, just over 22 percent, whereas deposits produced on 2- and 4-inch-diameter cathodes showed about 70-percent current efficiencies. A series of 20 deposits on 4-inch-diameter cathodes was produced under simulated production operation. The average current efficiency, based upon a divalent ion, was 72 percent with 11 1/2 pounds of metal produced per cycle of operation - 98.8 percent of which had a Brinell hardness number (B.h.n.) of 80 or less.

Jan 1, 1959

By H. G. Iverson

An investigation was conducted on the conditions affecting the precipitation of aluminum by autoclaving synthetic solutions containing Na2SO4, Al2(SO4)3, H2SO4, and H2O. Virtually all of the alumina could be precipitated as natroalunite (NaAl3(SO4)2 (OH)6). This product could be readily filtered and dried. Results are reported in terms of alumina precipitated in this compound and not in terms of alumina itself. Solutions of ~ 0.30, ~ 0.60, and ~ 0.80 mole/liter A1203 and various concentrations of H2SO4 and Na2S04 were investigated. The optimum time and temperature for autoclaving were 20 to 30 minutes at 200° C. The highest yields of natroalunite were obtained from solutions containing little H2SO4 and ~ 2 moles Na2SO4 per mole A1202. Acid in quantities of 0.3 to 0.5 mole/mole of alumina in solution depressed the yield to 90 percent or less. In differential thermal analysis, at 1,000° C the natroalunite precipitate decomposed without melting to yield SO, and SO2 gases, a solid composed of Na2SO4, and gamma and alpha Al203. Continued heating to 1,200° C produced No SO, and alpha A1303. Water-leaching of this product removed the Na2S04 and left a final residue of alpha A1203.

Jan 1, 1968

By Launa G. Mallett, Dana Reinke, Charles Vaught, Michael J. Brnich

As mines become safer and major disasters fewer, the number of experienced emergency responders is decreasing. This decrease will create a gap in response expertise which could have serious ramifications during future mine disasters. While working toward safety goals which may make emergency response obsolete, it would be reckless not to acknowledge that the potential for disaster still exists and that the protection of miners in such circumstances must remain a priority. The Mine Emergency Response Interactive Training Simulation (MERITS) is a computerized mine emergency simulation that meets a variety of needs. It allows personnel in leadership positions to test their knowledge and skill. Groups of individuals composed of representatives from mining companies, labor, and government agencies can practice working together during the simulated mine emergency much in the same way an actual emergency would require. An individual could also run the program to enhance his or her response skills. With this training tool, responders will be able to learn from their mistakes before facing situations with potentially catastrophic consequences. This paper discusses MERITS and its use in providing command center training.

By G. T. Brow

An experimental method is described for testing diffusion of gases in crude oils at pressures and temperatures up to 3,000 psia and 200° F. A sampling technique was developed to withdraw by constant-pressure mercury displacement about 60 µl of oil from the diffusion cell through any of several 1/2-in vertically spaced capillary tubes and to trap about 4 µl of the oil in a specially designed microsampler. Oil trapped in the microsampler can be completely inserted in the sample inlet of a chromatograph. From analysis in a three-stage chromatograph (GLC), gas concentration in a sample is determined from the ratio of gas peak heights to area of peaks of reference components (hexanes or heptanes) in the oil. A diffusion coefficient is calculated from measured concentration profiles with known equations for diffusion in finite or semi-infinite systems, depending on whether the gas has or has not reached the end of the oil column. Results are given for a test of methane diffusing at 2,560 psia and 160° F in crude oil from the Weber Sandstone reservoir in the Rangely field, Colorado. A constant diffusion coefficient of 3.34 X 10-5 cm2 per sec was obtained which gives a good fit between calculated and experimental profiles determined at six times after start of diffusion. The maximum standard error of gas concentration determinations experienced with this method was ±0.88 ml per ml of gas-free oil.

Jan 1, 1970

By J. R. Welty

High-temperature thermodynamic data have, in recent years, become increasingly important for the extractive metallurgist. The extraction of metals from their ores previously was based on trial and error methods, involving hours of testing and often costly equipment fabrication. Using thermodynamic data it is frequently possible to predict the feasibility of a proposed metallurgical process as well as the optimum operating conditions for the process with reasonable accuracy. Such predictions can save consider-able tim~ and expense. Widespread use of thermodynamic analyses has been handicapped by lack of dependable experimental data. Investigators, notably K. K. Kelley (4)4. have devoted many years to determining and compiling such data. These investigators, although prolific in their production of thermodynamic values, have been unable to meet all the needs of industry and other branches of science. This becomes obvious when one considers the aeronautical and nuclear fields, in which previously unimportant, therefore uninvestigated, substances have become of prime importance.

Jan 1, 1962

By A. R. Rule

Research was conducted by the Bureau of Mines to develop a process for utilization of Idaho kyanite. A continuous gravity-flotation separation process was applied successfully to recover kyanite-group minerals from an Idaho ore containing about 21 percent combined kyanite, andalusite, and sillimanite. Dry magnetic separation of the concentrate resulted in a product containing about 90 percent kyanite at a recovery of 63 percent of the kyanite-group minerals in the ore, Alumina and silica analyses were within the range generally accepted for conversion to mullite, and the finished products had a pyrometric cone equivalent of more than 38. A recovered garnet coproduct may be of commercial value.

Jan 1, 1973