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By W. H. Tomlinson

Although the thoughts and efforts of the great majority of people in many parts of the world are today directed toward killing each other, the purpose of this paper is to discuss means of conserving human life. In a world of turmoil and strife, we find time to discuss and make plans to achieve our objective -prevention of the "sacrifice" of life through avoidable accidents. The word" sacrifice" is used here advisedly, as one meaning of the word given in the 1942 edition of Funk and Wagnalls New Dictionary of the English Language is "the act of giving up some desired or valued object for the sake of *** future good." As everyone agrees that life is man's most priceless possession, one wonders if past sacrifices have been in vain. It appears that life is cheap in America; it is cheap because some of the industrialists are too much concerned with making a profit to devote much time and thought to conserving human life; it is cheap because some labor leaders apparently are interested solely in personal power and prestige; it is cheap because a great many workmen fail or refuse to cooperate energetically with the various organizations interested ill; their safety and welfare; it is of little value because, individually and collectively, we are indifferent to our responsibilities toward our fellow men.

Jan 1, 1944

By Nabil A. Bibawy

An improved method for preparing gravimetric standard gas mixtures of helium-4 in nitrogen has been developed by the U.S. Bureau of Mines. A single-pan 12-kg analytical balance that has a sensitivity of 3 mg is used to prepare the mixture. The balance will accommodate a cylinder having a volume of approximately 4 L that weighs approximately 5 kg. The method has been improved to a precision of ±O.04 pct by performing four successive dilutions, by improved handling of gases in the manifold, and by using an improved analytical method to select high-purity gases.

Jan 1, 1990

By Arne Landsberg

The Bureau of Mines has undertaken research to elucidate the chemistry involved in the efficient recovery and control of minor elements in base metal smelting operations. These elements should be effectively recovered not only because they have commercial value, but also because of their potential hazard to workers' health and the environment, if they are not controlled during processing. Cadmium, a minor metal in zinc ores, is the subject of this report. The roasting step of the complex zinc-smelting process was chosen for investigation because of the high potential for removing cadmium by volatilization during this primary stage. Commercial roaster feed materials were used to determine the sequence of reactions and the effect of these reactions on the volatilization of cadmium. Electron microprobe examination of both the commercial roaster product and oxidized sulfide solid solutions prepared in the laboratory showed that oxidized iron was of prime importance in preventing cadmium volatilization. The mechanism by which iron prevents cadmium volatilization is proposed, and a preheating technique is recommended for more effectively recovering cadmium prior to roasting.

Jan 1, 1981

By W. E. Wallace, P. S. Raghootama, M. S. Seehra, C. A. Hill, M. J. Keane, P. Mike

"Dipalmitoyl glycerophosphorylcholine (lecithin) dispersed in physiologic saline, a model of the primary component of pulmonary surfactant, is adsorbed by respirable quartz and aluminosilicate dusts. Dust cytotoxicity as measured by erythrocyte hemolysis and pulmonary macrophage enzyme release is suppressed by this adsorption. The degree of suppression of hemolytic potential versus specific adsorption of lecithin from dispersion in saline by respirable quartz, kaolin, and alumina dusts are compared with dusts' BET specific surface areas to interpret the prophylactic effect cf lecithin adsorption. Dust hemolytic potential versus media pH are presented. Fourier transform infrared spectroscopy and photoacoustic spectroscopy of lecithin on quartz and of lecithin on kaolin are presented and reviewed with results of studies of the time course of removal of lecithin adsorbed on mineral surfaces by digestion by phospholipase enzyme. Results are discussed in terms of a model of prompt neutralization of respired mineral dusts by pulmonary surfactant, and a gradual re-toxification by digestive processes acting on the adsorbed prophylactic surfactant coating following phagocytosis.Introduction Quarts dust of respirable size is well known to cause fibrotic lung disease, but numerous questions persist in the understanding of the initiation and' progression of this disease. Our approach concentrates on physical and chemical aspects of mineral dusts early-on in their interactions with living organisms, and we have chosen simplified models to investigate that interaction. In the alveolar spaces of the lung, tissue is coated with a surface-active material (pulmonary surfactant), which, sagas other functions, mechanically stabilises the lung from collapse by reducing the surface tension of water in the alveolar sacs.(1) This surfactant is also the material that is first contacted by a mineral particle that is transported to an alveolus and is impacted there. This surfactant material has been studied extensively. The primary components are known to be proteins (about 11% in dog lavage fluid). and phospholipids (about 88%).(2) Fhosphatidyl cholines constitute roughly 80% of the phospholipid fraction; about 70% of the phosphatidyl choline fraction is dipalaitoyl lecithin (DPL).(2) Respirable aluminosilicate particles are capable of adsorbing dipalmitoyl lecithin from dispersion in physiologic saline, a model for a possible initial event occuring upon deposition of a particle in a pulmonary alveolus.(3)"

Jan 1, 1988

By Charles W. Huggins

DEVELOPMENT of the electron microscope has permitted man to examine many small objects that could not be resolved by the light micro-scope. Diffraction, spherical aberration, and chromatic aberration are the main factors that limit resolution to about two-tenths micron with the light microscope. No matter how perfectly a light microscope is constructed and operated, it cannot possibly resolve points separated by less than two-tenths micron. Rapid development following World War II has produced many electron microscopes capable of 20 A resolution. Fibrous inorganic minerals are well suited for electron microscopic study. Many micrographs of chrysotile have been published, but electron microscopic study of the amphiboles has been somewhat neglected. New techniques in sample preparation have simplified the study of fibrous material. Ultrasonic energy has been very helpful in sample dispersion. This publication contains a representative group of electron micrographs of natural inorganic fibers that have industrial value. These fibers commonly are referred to as the asbestiform minerals. The Bureau hopes that the knowledge gained through electron microscopy and other scientific study of the natural inorganic crystalline fibers eventually will lead to the production of synthetic fibers that will satisfy the requirements of industry.

Jan 1, 1959

By C. T. Baroch

This report summarizes cost data accumulated during 15 months of sustained operation of the Bureau of Mines Boulder City (Nev.) titanium plant, which had a capacity of about 1,350 pounds of titanium sponge per day. The plant was constructed during the 1952 fiscal year with funds supplied by the Ordnance Corps, Department of the Army. Its original purpose was to engage in process development work as a continuing phase of the Bureau of Mines policy to seek improvements in producing titanium metal. In early 1953 the Defense Materials Procurement Agency contracted with the Bureau of Mines for producing approximately one-half million pounds of usable ductile titanium sponge. Production began in May 1953, ended in September 1954, and yielded 492,503 pounds of acceptable metal. Operating costs covering this period of operation, with suggested depreciation and administrative costs, are given, as well as outlines of building and equipment capital costs. In addition, miscellaneous economic considerations are discussed, including labor and operating-time schedules.

Jan 1, 1956

By E. L. Rawlins

A previous report4 has explained that pipe lines for the transmission of natural gas should be buried to minimize temperature fluctuations because when excessive the latter decrease accuracy in measuring gas volume and increase leakage of gas due to expansion and contraction in the pipe joints. These effects are governed by the rapidity of the temperature fluctuations and by the total variation over a period of time. The temperature of gas flowing through a pipe line depends to a large extent, upon the temperature of the ground adjacent to the pipe; hence, fluctuation of the ground temperatures at various depths determines the economic depth at which pipe lines should be buried. Scope and Purpose of Report This report covers a record of the daily atmospheric temperature fluctuations at Bartlesville, Okla., for 12 months and a-similar concurrent record of the temperature variation 1, 2, 3, and 4 feet below the surface of the ground.

Jan 1, 1928

By Martin J. Gavin

During the recent study of lubricating oils carried on in the San Francisco laboratory of the United States Bureau of Mines, it became desirable to distill the oils used in the experimental work at pressures as low as 10 millimeters (mercury column) absolute. In the effort to Overcome difficulties and eliminate sources of error, certain changes were made in the apparatus for vacuum distillation used by the Bureau of Mines for crude petroleum.4 These changes were described in R.I. 2819, issued in July, 1927. Subsequent to the publication of R.I. 2819 several other changes have been made, and the present form of the apparatus for vacuum distillation of lubricating oils is described in this revision of R.I. 2819. These changes were found to give more accurate checks on duplicate distillations. The major part of the credit for the laboratory work which developed the changes in the apparatus and method revised herein is due to Boyd Guthrie, assistant petroleum chemist, and R. V. Higgins, junior chemist, o the San Francisco laboratory, United States Bureau of Mines. DESCRIPTION OF APPARATUS The distilling flask employed is essentially the Hempel flask as used by the United States Bureau of Mines for the analytical distillation of petroleum.5 he complete apparatus is shown in Figure 1. The fractionating column and exposed portion of the flask is wrapped with 4 inch asbestos rope and then surrounded by a cylindrical hood of 1/8 inch pliable asbestos sheet with a narrow air space between the wrapping and the cylindrical hood. This was found necessary to prevent any radiation or convection heat losses from the column, and resulted in obtaining a more even and constant fractionation by eliminating any dephlegmating action caused by temperature changes around the column.

Jan 1, 1930

By Leonard Obert

THE CRACKING AND POPPING of rock, often heard by men working underground, for years has been interpreted as a warning of danger and unstable ground. However, not until 1939 was it discovered that rock under stress generates subaudible and sometimes audible seismic disturbances (referred to as "micro-seismims" 4), which can be detected with the use of a suitable seismic apparatus. Since that date laboratory and field investigations have been in progress to ascertain to what extent this phenomenon can be utilized to detect, localize, and determine the magnitude of areas of instability in and around mine openings and to predict if and when failure will occur. These investigations have included a determination of the types of problems to which the method is applicable and the effect of rock type, geological defects, such as joints, fractures, faults, and other uncontrollable factors, on the reliability of results. Six reports have been prepared covering the investigations conducted between 1940 and 1952 (4-9). 5 These reports describe some of the characteristics of micro-seismims, as determined from both laboratory and field tests; the equipment used to pick up and record micro-seismims; the general test procedure and method of analyzing results; and applications of the method to specific mining problems.

Jan 1, 1957

By James S. Browning

Heavy liquids have been used to separate minerals of different specific gravities for many years.4 5 6 7 8 9/ The method permits substantially quantitative evaluation of a variety of minerals and requires much less time than the usual methods of chemical analysis. This Bureau of Mines investigation was conducted to determine the applicability of heavy liquid mineral separation to the evaluation of certain spodumene and kyanite ores, prepared mixtures, and plant products. After careful standardization of the particular mineral and associated gangue, estimates of chemical analyses could be obtained from results of heavy liquid separations.

Jan 1, 1960

By John H. Soule

Appreciable quantities of sine and lead orus have been produced from the West. Pinos Altos district of Grant County, N. sex. This area was visited many times by engineers of the Bureau of ines. D. H. Johnson and 4. R. Storms visited the district in haren 1943 in connection with an acrenu road to toe wines. M. H. Storma again visited the area in July 1943 in connection with a hetals Feserve Corporation loan on the Routen-Thomas

Apr 1, 1948

By Will H. Coghill

[The supply of gravel spar and of acid spar is not well balanced. Gravel spar -- 85 per cent flourspar, 5 per cent silica -- gluts the market, whereas acid spar -- 98 per cent fluorspar, 1 per cent silica -- is somewhat scarce. Hence it is desirable to convert some of the gravel spar into acid spar. Knowledge of this condition prompted the Franklin. Fluorsrar Co. at Paducah. Ky., to enter into cooperation with the U. S. Bureau of Mines and the Missouri School of Mines and Metallurgy to improve the methods of fluorspar, milling so that morn acid spar would be available. The fluorspar company detailed Mr. Omar Greeman for the work. During the course of the investigation, while Mr. Greeman was also doing work for a master's degree in the School of Mines? an extensive study was made of gravity concentration of fluorspar ores. Decrepitation by heat treatment was also given a laboratory try-out. A part of tie time was spent on flotation; these notes relate only to the flotation. The results of one of the flotation runs is appended. The test was made in a 500-gram mechanical-agitation machine. The sample was ground to 100-mesh in a pebble mill.]

Jan 1, 1928

By B. R. Mohal, S. Chander

"The adsorption and wetting behavior of freshly ground and aged coals has been determined in the presence of a nonionic surfactant. The amount of surfactant adsorption changes with the concentration and ""age"" of the coal. The freshly ground coal has smaller amounts of adsorption at lower surfactant concentrations than the ""aged"" coal whereas at large surfactant concentrations, the order is reversed . In the latter case, more surfactant is adsorbed on fresh coal than on the ""aged"" coal . . It is proposed that at low concentrations, the surfactant adsorbs through both hydrophobic and hydrophilic interactions with the molecule lying parallel to the· surface, whereas at higher concentrations surface micelles form at the hydrophobic sites. The wetting behavior correlates well with the adsorption behavior.INTRODUCTIONNonionic surfactants have many applications in the coal and mineral processing industry. They can be used as dispersing agents to modulate flotation, flocculation and filtration of particulates (1). They can also be used to increase the wettability of hydrophobic solids such as coal and can hence be used as dust suppressants (2,3). Although the adsorption of representative nonionic surfactants such as Triton N-101 (an ethoxylated nonylphenol with 9.5 moles of ~thylene oxide and HLB equal to 13.4) have been studied extensively on substrates such as calcium carbonate (4), silica (5) carbon black (6) and graphite (7), very few studies are available for coals. Coals differ from other substrates with respect to two important characteristics: 1) coal are porous and 2) coals consist of a patchwork of hydrophobic and hydrophilic sites (8). Since the adsorption characteristics of a surfactant are influenced significantly by the nature of the substrate the characteristics of the coals must be taken into consideration."

Jan 1, 1989

By W. F. Faragher

The principal equipment in the catalyst plants at Ludwigshafen-Oppau was inspected and is presented in the form of flow sheets for the manufacture of four of the principal catalysts. The equipment is in many cases of special design rather than stock items that was built by the company and modified in the coarse of the growth of the high-pressure synthesis of hydrocarbons in Germany. It is believed that if the manufacture of catalysts were to be undertaken elsewhere, the selection of equipment for the operations involved could be made successfully from the guidance furnished by this rather general report. Five additional catalysts are described, also. II. CATALYST 5058 FROM FRESH TUNGSTIC ACID In a supply tank of about 2,000 liters capacity, 500 kg. of tungstic acid (W03.H2O) that contains about 92-93 percent of W03 is dissolved at 60-70° C. in 1,500 liters of mother liquor. The solution is-effected by stirring for about 1-1/2 hours. The mother liquor is obtained from a previous, lot of catalyst and is first adjusted to a concentration of 13 percent 1H3 by passing in gaseous ammonia. The solution is allowed to stand without stirring for 1 hour, then is pumped into the saturating vessel through a cloth filter (three-quarters hr. to one hr.). The saturator is purged with H2S and thereafter the solution, which has been cooled to about 75° C., is heated in an atmosphere of hydrogen sulfide with stirring to about 70° C. This charge is slowly cooled to 50°, and then more rapidly to about 20° C. (time of cooling 6-7 hours).

Jan 1, 1946

Provide reasonably priced, reliable fire protection for front-end loaders. Approach Automatic fire sensing and suppression systems were developed and ruggedized for use on front-end loaders operating in harsh mine environments. How It Works Temperature sensors mounted in the loader's engine, transmission, and articulation areas detect the heat from a fire while it is still small and controllable. This triggers the release of the ABC class dry chemical extinguishing agent through a fixed piping system onto the fire. The system can also be manually activated from either the cab or ground level. Locations of the principal components of the system are shown in the drawing. Two control subsystems were designed to respond to varying fire protection needs and mine conditions. One subsystem only initiates discharge of the extinguishing agent. The other subsystem initiates visual and audible operator alarms if there is a fire sensed or if there is a fault in the control circuit.

Jan 1, 1979

By R. N. Roby

In the course of the Bureau of Mines investigations for suitable sources of high-aluminum clay for the production of alumina, the Whiteware clay deposit was examined in August 1942 by G.N. Bennett, mining engineer, Bureau of Mines, Montana District Office. This report presents the factual data obtained by the investigation, which also includes data on trenching and drilling, and the results of some refractory tests and chemical analyses of representative samples of the clay later taken from some of the best trench exposures and from adit dumps.

Jan 1, 1949

By John C. Franklin

A radon survey was made at five different locations in the Twilight mine near Uravan, Colo., to determine chances in radon concentrations in an inactive mine. Data were taken with a continuous monitor set for 1-minute count periods and readings were taken 24 hours a day for 9 days. The 12 readings per station each hour accurately showed how t w radon concentration varied during the day. From the data collected from the intake portal to station 4, the average radon emanation rate was estimated at 18 picocuries per second per square foot (pCi/sec/ft3). A daily cycle in radon concentration was detected that apparently was related to barometric pressure change.

Jan 1, 1976

By A. S. Prokopovitsh

A spectrophotometric method for the determination of small amounts of copper in tungsten metal powder using the principle of solvent extraction has been developed by the Federal Bureau of Mines. The metallic sample is dissolved in hydrogen peroxide, tartaric acid added, the pH adjusted, and the excess peroxide destroyed by boiling. Copper is reduced to the cuprous state, and the reagent neocuproine (2,9-dimethy1-1,10-phenanthroline) is added to form a colored complex with the copper. This colored complex is then extracted into chloroform and the absorbance of the separated chloroform layer measured on a spectrophotometer. Copper contents as low as 1 p.p.m. (parts per million) can be determined. The method is limited to finely divided tungsten powder. The interest of the Bureau of Mines in developing more sensitive methods for the determination of trace impurities in high-purity tungsten prompted an investigation of the possibility of using solvent extraction-colorimetric methods. The organic reagents now commercially available make possible many extremely sensitive colorimetric methods for the determination of metallic ions. Extraction of the colored complex into a small volume of organic phase can be used to further increase sensitivity (4) .4/ This general approach has the added advantage that no special equipment beyond that normally found in an analytical laboratory is required.

Jan 1, 1961

By A. C. Johnson

This report is one of a series being prepared by the Bureau of Mines on exploration, development, mining methods, and costs at various mines in the United States. It describes operations at the Black Rock mine, Wah Chang Mining Corp., Mono County, Calif. The purpose of these reports is to promote development and conservation of our mineral resources by disseminating technologic information on mining methods, practices, and costs. The Black Rock tungsten mine of the Wah Chang Mining Corp. is 33 miles north of Bishop, Calif., in the Benton Range, Mono County, Calif. The property was acquired in August 1950 and a well-planned program of exploration, development, and exploitation resulted in a good production record with low costs. Operations were halted in July 1957, about 6 months after suspension of the tungsten purchase program by the Federal Government.

Jan 1, 1960

By B. J. Scheiner

Extraction of molybdenum from molybdenite ore by an electrolytic oxidation procedure was investigated by the Bureau o f Mines. Various parameters affecting molybdenum extraction, such as salt concentration, temperature, treatment rate, current density, and particle size, were studied. Molybdenum extraction of 95.2 percent was achieved on a laboratory scale from an ore containing 0.35 percent molybdenite. Corresponding power consumption was 24 kwhr per pound of molybdenum extracted with a base consumption of 4.5 pounds of sodium carbonate. Laboratory and pilot plant experiments are in progress on low-grade molybdenum concentrates containing rhenium and copper. Preliminary results indicate that molybdenum extractions in the 90- to 99-percent range and rhenium extractions of 93 to 99 percent can he obtained without appreciable oxidation of associated copper minerals.

Jan 1, 1972