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By A. M. Ozbayoglu

Gross calorific value (GCV) of coals was estimated using artificial neural networks, linear and non-linear regression techniques. Proximate and ultimate analysis results were collected for 187 different coal samples. Different input data sets were compared, such as both proximate and ultimate analysis data, and only proximate analysis data and only ultimate analysis data. It was observed that the best results were obtained when both proximate analysis and ultimate analysis results were used for estimating the gross calorific value. When the performance of artificial neural networks and regression analysis techniques were compared, it was observed that both artificial neural networks and regression techniques were promisingly accurate in estimating gross calorific values. In general, most of the models estimated the gross calorific value within ±3% of the expected value.

Sep 1, 2012

By Y. Foucaud, C. Eswaraiah, L. Filippov

Enhanced gravity separators such as Falcon concentrator which uses additional centrifugal force, are the most common gravity concentration techniques used for fine particles processing. Hence, understanding the kinetics and separation mechanisms within these separators is of paramount interest. Recent research yielded a predictive physical model for the Falcon Ultra Fine (UF) which however does not explain some results obtained with industrial ores. This study aims to identify the mechanisms involved in Falcon UF separation with the objective of confirming or rejecting the hypotheses on which the current model is built and suggesting potential points of improvement. The Falcon UF kinetics is investigated through the processing of complex low-grade and fine-grained ores from the Altenberg tin deposit (Germany), the Tabuaço tungsten deposit (Portugal) as well as a synthetic iron ore. Saturation tests are performed on the Falcon UF by controlling the separation efficiency in terms of recovery and enrichment ratio with time or feed mass. Results show an evolution of Falcon UF performance with time in contradiction with the stationary separation hypothesis on which the physical model is based. Observation of the concentrate bed suggests the presence of erosion figures in furrows which may play locally an active role in the separation. In terms of Falcon UF separation timing, three phases can be distinguished. First, upon initial feeding of the bowl, a bed quickly grows unselectively and ultra-fine particles are ejected from the bowl until the bed reaches its final profile. Next, actual separation occurs with selective concentration of dense particles. Finally, capture sites saturate and recovery drops. The evolution of partition curves over time confirms the existence of two separation mechanisms. First, differential particles settling within the flowing film responsible for the ejection of small size particles during the whole separation cycle which is already accounted for in the physical model. The second mechanism involved may be explained by the action of lift force, neglected in the physical model, which acts preferentially on coarse particles deposited at the surface of the bed resulting in coarser particles being rejected in the tailings. Hence, the addition of a lift force component to the existing model is suggested to account for this second separation mechanism.

Jan 1, 2018

By Osvaldo A. Bascur

One of the most vigorous of the continuous improvement methodologies is Six Sigma. While usually associated with improving manufacturing and product quality, leading manufacturers are using it to improve their extended supply chain and logistics capabilities. At the same time they are improving reliability, some companies have cut hundreds of millions of dollars of fat out of their supply chain. Mine to Mill optimization is a transformation of culture from processing tons to processing a quality feed size distribution which reduces the overall operational costs and add the highest value to the mine. This is not a constant endeavor. As such, a dynamic performance monitoring and diagnosis is necessary. We will review a systemic way to performance improvements and avoiding metal losses from the blast to the metals. We show the requirements of using raw data to analysis the data to define operational maps which provide assistance to run the mine and mill. A case study is provided with the mine and mill data was integrated combining process control and quality information resulting in reduction of water and energy consumption while improving the overall value of the mine. The results of reengineering the current system with this SIX SIGMA Strategy had the following results: an increase of ore milling: 4.6% decrease of mil power: 3.9%, decrease of fresh water consumption: 6.8%, with a total of net profits: US$ 31.8 million, the PI System infrastructure contribution: US$ 7.95 million. These estimates were for the period 2009/04/04 to 2009/12/31.

Sep 1, 2012

By Z. M. Wang

A large scale a polymetallic mine in north China is a refractory ore containing many useful com-ponents: W, Mo, Cu and Fe. Mineralogical investigation shows that the deposit is a quite complex one due to fine disseminated size and unevenly distribution of valuable, intergroth of sulphide and tungsten minerals, concurrence of scheelite and calcium minerals. Based on ore characteristic, a flowsheet is used by the floatation processing of sulfide minerals superior to scheelite. Bulk sulphide flotation is used in sulphides. Mo and Cu are floated in sequence after sulphides regrinded. Tungsten mineral is floated using combined depressant that is an effective depressant to gangue, and can improve the grade of rough tungsten concentrate. Compound depressant has high effective in removal of collector in gangue and sulphide, and tungsten is activated also. High quality of tungsten concentrate is obtained at satisfactory recovery. The test production obtains Mo concentrate with grade of 48.16%, recovery of 81.43%; W concentrate with grade of 66.47%, recovery of 78.19%; Cu concentrate with grade of 23.14%, recovery of 56.6%; Fe concentrate with grade of 67.33%. The valuable metals are recovered comprehensively and well techno-economic index is obtained. The mine enterprise profit is increased greatly.

Jan 1, 2014

By Ingvar Ymén, Anders Sandc, Jan Rosenkranzc, Lisa Malma, Ann-Sofi Kindstedt Danielssonb

The understanding of particle surface properties is essential for the study and evaluation of froth flotation phenomena, particularly in the investigation of various chemical or reagent effects. Dynamic Vapor Sorption (DVS) is a method used for the analysis of surface properties of powders for instance in the pharmaceutical industry. To the knowledge of the authors, it has however not been used before in applications related to mineral processing. The DVS technique involves measurement of the water uptake of a relatively small amount of sample as a function of the relative humidity (% RH) in a temperature-controlled environment. The purpose of this work was to evaluate the method and investigate how it can complement existing techniques for surface characterization in mineral processing. Four samples (feed, CuPb concentrate, Cu concentrate and Pb concentrate) from the Cu – Pb flotation process in the Garpenberg concentrator, Sweden, were analyzed by DVS and the traditional capillary absorption technique (Washburn capillary rise). This enabled comparison between the two methods and evaluation of their respective advantages and disadvantages. Both methods give the expected ranking of the hydrophobicity for CuPb concentrate, Cu concentrate and Pb concentrate, but a discrepancy was observed for the feed. Washburn gave a value for the contact angle which was in the same range as for the CuPb concentrate, whereas DVS gave a value for the moisture uptake which was much higher than for the CuPb concentrate. Thus, DVS ranks all samples correctly, but with an unexpectedly high value for the feed whereas Washburn gives good ranking for three samples out of four. Potential reasons for the discrepancies are discussed.

Jan 1, 2018

By E. Yigit

In the flotation process the physical factors such as agitation intensity air flow rate and pulp solid concentration are very important parameters affecting grades and recoveries of the products. The flotation tests were performed on the samples of Bigadic colemanite ore to investigate these factors at different agitation intensities ranging from 1000 rpm to 1400 rpm and air flow rates from 1000 cm3 ? min-1 to 2000 cm3 ? min-1 with 2 L and 4 L cells using Denver laboratory flotation machine. The tested collectors were Cytec Aero 825, Aero 848N and their mixtures. Agitation intensity and air flow rises resulted in more floated material although sometimes being not selective. These effects can be attributed to powerful collisions between air bubbles and mineral particles. The first observation was the effect of pulp solid concentration on the floatability of minerals, while the flotation in 2 L cell (0.125 g.L-1 solid concentration) at 1000 rpm (0.176 wattcm-3), and with 1000 cm3.min-1 air flow rate was possible, the flotation in 4 L cell (0.0625 g.L-1 solid concentration at 1000 rpm. (0.176 wattcm-3) and with 1000 cm3 ? min-1 air flow rate was not possible. However at 4 L cell after increasing agitation intensity to 1200 rpm (0.201 wattcm-3) keeping 1000 cm3 ? min-1 air flow rate, flotation was possible again. This shows that these factors such as agitation intensity have some critical role on flotation. Another interesting observation was on the selective effect of pulp solid concentration. In the flotation with 1 L cell at different agitation intensities, collector Aero 848N was selective against calcite, while in the flotation with 2 L cell at different agitation intensities the same collector Aero 848N was selective against colemanite.

Jan 1, 2014

By Kym Runge, Wei Huang, Fengnian Shi, Christian Antonio

"This paper presents an emerging High Voltage Pulse (HVP) technology for ore pre-treatment. Unlike previous studies where HVP was utilized as a crusher to pulverize ore particles to micron size ranges for downstream processing, the researchers at the Julius Kruttschnitt Mineral Research Centre (JKMRC) use HVP to enhance ore processability. Application of relatively low levels of HVP energy to selectively break mineralized particles from barren rocks, followed by size-based screening separation enables the feed ore to be split into high grade and low grade products. During HVP treatment, cracks/micro-cracks are generated which results in pre-weakening of the treated ore particles, which ultimately results in energy savings in the downstream comminution processes. HVP treatment followed by conventional grinding also results in improved liberation of the valuable minerals in comparison to that achieved with traditional conventional comminution, subsequently improving downstream separation efficiencies. The three major improvements in ore processability through HVP pre-treatment have the potential to facilitate rejection of low grade ore prior to processing, increase production rates, reduce the energy required for comminution and improve flotation separation recoveries. This paper summarizes the major research outcomes of HVP pre-treatment demonstrated using ores from various mining operations conducted by the JKMRC. It also discusses the barriers that must be overcome before it can be adopted by industry with confidence in a continuous high tonnage rate application.INTRODUCTIONThe challenges of declining ore grades and increased plant throughput rates, resulting in higher energy consumption and operational costs, require the mining industry to adopt new technologies to make future ore treatment economically viable. Over the past 50 years, many researchers have engaged in investigating novel comminution techniques. Since Yutkin (1955) first demonstrated the potential to generate shock waves with pressures exceeding 103 MPa via electrical breakdown of water, several applications of electrohydraulic crushing by shock waves have been reported (Curley-Macauly, 1968). Interest in this technique was bolstered when Andres (1977) demonstrated that electrodynamic fragmentation results in superior liberation of mineral grains as compared with conventional grinding techniques. Despite mounting laboratory-scale evidence of the efficacy of electrodynamic fragmentation for mineral liberation, development of the technology for full-scale operation has stalled, primarily because the energy required to achieve desirable mineral liberation is approximately two to three times that of mechanical comminution, amounting to approximately 100 kWh/t for typical mineral ores (Andres et al., 2002)."

Jan 1, 2018

By L. Q. Luo

SHP-F3200 wet high-intensity magnetic separator (HIMS) was successfully used to separate the complex and weakly magnetic iron ores being composed of specularite, limonite and siderite in Ji-uquan Iron and Steel (Group) Co Ltd (JISCO). It is more and more difficult to separate iron ores from gangues, such as quartz, jasperite and phyllite, as the properties of iron ores gradually become more complicated and refractory. Some technologies have been used to improve SHP-F3200 HIMS, including modifying angle of magnetic polar from 90°to 83°, cooling exciting coils by oil instead of air, adding reverse-washing device to wash off magnetic particles, adjusting the tooth-space of matrix from 5.0 mm to 3.5 mm or 2.5 mm, so as to enhance the recovery of fine iron ore particles. It is still difficult to meet the requirement for recovering more difficultly-separated iron and the demands for high-grade concentrate of iron. In this paper, after analyzing magnetic force exerting on iron ore particles within different separating sections of SHP HIMS, it is proposed to apply the flowing-film technique into the HIMS. Thus a new-type LY matrix is designed to form magnetic gradient vertically, combined with a special flowing-film feeder to improve the existing SHP HIMS. The moving pattern of magnetic particles in pulp in HIMS separation district also has been analyzed in this paper. And the test on the SHP-F700 HIMS shows, under the condition of iron ore containing 30.52% Fe, with particle size of ?0.074 mm accounting for around 75%, if applied with flow-film technique, the iron recovery will be up from 69.45% to 76.07%, by 6.62 percent, with the same grade of concentrates of iron. The calculation of iron yield of every size fraction and the tests showed that film magnetic separation (Film-MS) could promote the iron yield of each size fraction, denoting an excellent result of application of the film technique to SHP HIMS. The mechanism of the film magnetic separation technique is to convert the turbulent flow and disordered movement of dynamic mass particles in the pulp into a directional and ordered laminar flow along the surface of tooth plate so as to strengthen the separation effects.

Jan 1, 2014

By C. G. Anderson

Industrially proven and applied nitrogen species catalyzed (i.e. NSC) acidic pressure leaching has been utilized to treat a number of ores, concentrates and recycled materials. This versatile technology offers many advantages including low temperatures, low pressures, low capital costs, low operating costs, faster throughput and less costly materials of construction than conventional pressure oxidation. This paper will elucidate the application of this technology for production of gold, silver, palladium, rhodium, zinc, germanium, gallium, cobalt, copper, molybdenum, rhenium and nickel. Recycled material applications will also be elucidated. In addition, details of an application for treatment of a refractory chalcopyrite copper and gold bearing ore will be presented and pertinent economics discussed.

Jan 1, 2014

By D. R. Nagaraj, Raymond Farinato

Water constitutes one of the most valuable resources employed in mineral recovery and processing. Identifying potential problems encountered in mineral processing in waters unusable for drinking or agriculture (including seawater and even hypersaline waters), understanding chemical factor interactions, and optimization of flotation reagents will greatly expand our ability to create more sustainable beneficiation technologies. The current paucity of our knowledgebase regarding high salinity effects on flotation clearly signals a need for a significant research effort. We report here results of a study designed to probe effects of pulp chemistry on metallurgical performance in the flotation of Cu and Cu-Mo ores in saline waters. The results clearly demonstrate that pH (more correctly dosage of pH modifier to target a pH set point) has the most significant effect on Mo recovery when using seawater. This is linked to the formation/precipitation of Mg(OH)2 when pH = 10.3 (in seawater). The type of pH modifier used, NaOH or Ca(OH)2, had no impact on Cu or Mo recovery, indicating that Ca2+ ions were not involved in any reduction in Mo recovery in the pH range of 9-11. Our results in tap water spiked with either Ca2+ or Mg2+ ions in the same pH range (controlled by NaOH), confirmed that Ca2+ ions had no effect on Cu or Mo recovery, but that addition of Mg2+ ions had a severe adverse effect on Mo recovery at pH = 9.5, and to a lesser extent on Cu recovery. The onset of Mg(OH)2 precipitation occurred at a higher pH, and the adverse impact of Mg(OH)2 on Cu recovery (and perhaps Mo recovery as well) was less, in sea water than in tap water spiked with Mg2+. These effects are attributed to the mitigating role of the high electrolyte concentration, notably NaCl.

Jan 1, 2014

By S. Patra, R. Venugopal

"The quality of pellets produced is affected by quality anssastd quantity of green pellets, amount of addition of binders, type of binders added, amount of moisture added along with the other variables like rotation, inclination and fineness of feed. The green pellet quality depends upon chemistry, mineralogy and granulometry of fines used for pellet making, the feed size, its moisture content and porosity. During firing of green pellets ingredients present within reacts to form different phases and microstructure. So in turn physical and metallurgical properties of pellets are influenced by amount and type of binder and flux addition, induration time and temperature. During iron making process, the metallurgical properties of fired pellets are decided by the type and amount of these phases and their chemistry. Green pelletizing and induration studies have been already carried out with hematite ore fines. Indian iron ores of high alumina content showing different pelletizing characters, these studies can’t be directly interpreted. The main objective of proposed research work is to understand the green pelletizing process and determine the water bentonite interaction at different levels. Detailed investigation on swelling behavior of bentonite and microstructure of the green pellets of iron ore fines from SAIL captive iron ore fines from the Barsua in the state of Odisha. To convert these ore fines into pellets, the key raw material, additives and process variables that influence the pellet quality needs to be identified.INTRODUCTION Pelletization is the unit operation of agglomerating iron bearing fines (generally below 150µ with 65-80% passing 40µ) by tumbling in horizontal rotating drums or inclined discs, (Sivrikaya and Arol, 2013; Bhuiyan et al., 2011; Forsmo et al., 2006; Sastry et al., 2003) and the pellets are approximately spherical lumps formed by this process in presence of water and binder, on subsequent induration at 1300°c (Sivrikaya and Arol, 2014; Sivrikaya and Arol, 2013; Sivrikaya and Arol, 2012; Sivrikaya and Arol, 2010; Sastry et al., 2003; Kawatra and Ripke, 2003; Iveson, 2001a; Iveson, 2001b)."

Jan 1, 2018

In many base metal sulphide concentrators reagents such as collector and cyanide are often added to the grinding mill as well as to the flotation circuit. Whilst good reasons can be cited for splitting the reagent addition in this way, the benefits of such are rarely quantified and the complex reagent-mineral-media interactions occurring during milling are often poorly understood in terms of pulp chemistry. A new laboratory batch grinding mill designed by Magotteaux allows the user to measure, monitor, and control the pulp chemical conditions during grinding when testing different ores and media. Some of these parameters include pulp pH, pulp Eh, temperature, gaseous atmosphere, and dissolved oxygen concentration. In a recent development, the mill has been coupled with a simple on-line reagent monitoring system, designed by CSIRO, which allows the levels of species such as xanthate and cyanide in the grinding pulp to also be measured continuously during milling using a robust UV detection system. In this way the uptake of collector during grinding and the rate and ex-tent of cyanide interaction with the minerals and media can be determined as a function of grinding time. A series of grinding tests using an Australian nickel sulphide ore was conducted with the coupled system in which the cyanide dose, xanthate dose, and media type were systematically varied. The xanthate and cyanide levels were monitored as a function of grinding time and the data collected are discussed in terms of the pulp chemistry of the system and implications for plant reagent dosing strategies.

Jan 1, 2014

By Y. M. Zhao

Reutilization of waste printed circuit boards (PCB) can not only prevent potential environmental pollution, but also achieve recycling of secondary resources. Study on recycling of discarded PCB belongs to the front edge of environmental pollution prevention and resource recycling. In order to effectively crushing waste PCB, and solve the problem of secondary pollution of fugitive odor and dust during the crushing process, a wet impacting crusher was adopted to achieve comminution liberation of PCB in water medium. 96.79% of the crushed yield was distributed in ?2mm, and metal took 97.18% in this grade of production. Size distribution of PCB particles was characterized double peaks at the sizes of ?1+0.5mm and ?0.074mm. A double Rosin-Rammler function, is called DRR function, is put forward to describe the size distribution of PCB particles. The DRR function of cumulative weight percentage oversize of PCB was non-liner fitted by self-defining DRR function of the Origin 7.0. The evaluation indexes of the fitting results are the correlation coefficients R2 of 0.9994 and residual E of 0.18671, those show that DRR function is perfectly accurate. Based on the research the mechanical separation and material properties of PCB, a wet process of reclaiming metals from PCB using a new style separator ? tapered diameter separation bed (TDSB) in water medium was designed, and the related separation mechanism was studied. The fluid field of the tapered diameter separation equipment was simulated by the Ansys Flotran software, the variation laws of the velocity in each position in the fluid field as well as the equation of axial distribution sectional max velocity were analysed according to the simulation result, the stress change and motion trajectory of the pellet in the certain fluid field were analysed. The results show that the expanding tubular structure of the varied diameter separation bed indicates gradually decreasing velocity of water flow along the axis, assuming a certain angle in the bed, as a result of the gravity?s influence, and there was corresponding change to the distribution of the flow velocity, thus the whole formed a special fluid field where velocity variations exist in different positions. When the material passed through the fluid field along with the water flow, as a result of the difference to the particle density, the granularity and the shape, there would appear the difference to the motion trajectory as well as the movement distance under the action of the fluid: The lower density materials discharge along with water flow, but the higher density materials would be kept in bottom of the bed and discharge through material mouth. Therefore, light and heavy products were separated effectively according to the density. Using tapered diameter separation bed to process the ?1mm size crushed material of waste printed circuit boards, with the discharge of water 5.5m3/h, feed-rate of the material 250g/min and with an obliquity 35°, product with 93.92% in integration efficiency and 93.73% in recovery ratio of the metal were obtained by the primary separation. Compared with other mechanical methods, the range of particle size was broaden using the TDSB to recovery metals from PCB, and lower limit size of separation almost approach to 0. An innovative process of ?wet impact crushing+ classifying+ tapered diameter separation? recycling metals from waste PCB was developed.

Jan 1, 2014

By Y. F. Hou

This paper reports the results of the study of the influences of concentration and modulus of sodium potassium silicate solution (Na-K activator) and curing mode on the phase composition, mi-crostructure and strength development in the geopolymers prepared using Class F fly ash. X-ray dif-fraction (XRD), Fourier transform infrared spectroscopy (FTIR) and MAS NMR are utilized in this study. It shows that the compressive strength increases while sodium potassium silicate solution modulus increases, but when modulus exceeds 1.7, the compressive strength decreases, and it decreases markedly while modulus is greater than 2.0. The compressive strength improves with increase of sodium potassium silicate solution concentration. When the concentration is 36%, the compressive strength reaches the maximum. Elevated temperature can increase the strength of samples synthesized using sodium potassium silicate solution with 32% concentration and modulus 1.2. Compared to the strength of the sample cured at 50?, the strength of the samples cured at 65? and 80? are higher at 1 day and 3 days, but when cured at 80?, strength is smaller than that cured at 50? for 7 days. When temperature is too high, too long curing time will decrease the strength. Long precuring at room temperature before application of heat is beneficial for strength development, and there is about 10%~50% increase in strength of the samples cured at 1 day precuring and 2 days elevated temperature as compared to the strengths of the samples cured for 3 days at elevated temperature or cured for 28 days at room temperature. The main product of reaction in the geopolymeric material is amorphous alkali aluminosilicate gel.

Jan 1, 2014

By Ofra Damm, v du Preez, D. van Vuuren, L. Simpson, H. Chikwanda

"South Africa is the world?s second largest producer of titanium bearing minerals, but apart from producing titanium mineral concentrate to form TiO2 slag, little further value is added in South Africa to mined minerals. Various studies were undertaken by both government and the private sector in an un-coordinated manner until 2007 when the South African Department of Science and Technology (DST) planned and adopted a national strategy to establish a local titanium metal industry through the research and development of key technologies that would provide a competitive advantage to such a local industry. The strategy entailed a two-pronged approach in the development of this capability, viz. simultaneous investments in the development of high-level human capital and technology in the fields of titanium metal powder production and downstream titanium metal powder processing technologies. To date significant progress has been made to establish research and/or pilot scale facilities in the following technical areas: TiCl4 production technology, titanium powder production technology, high energy milling of titanium powder, metal injection moulding facilities, rapid production of large components using laser additive manufacturing technology, investment casting of titanium, resource efficient machining of titanium and friction stir welding of titanium. Supporting technologies are also at an advanced stage through investments in titanium powder spheroidization and direct rolling of titanium powder. The intent with investment in some of these areas is not to develop new technology per se, but rather to establish local capability that will position South Africa to collaborate with other organisations in the world so that technologies can be acquired and transferred when needed in the future."

Jan 1, 2014

By D. DePaoli, P. Zhang

"Phosphate ore is one of the most significant secondary resources for rare earth elements (REEs), and Florida phosphate is of particular interest due to its much higher ratio of heavy REEs, especially yttrium. Analyses of numerous samples from different phosphate processing streams in Florida showed that heavy REEs account for about 50% of the total REEs in Florida phosphate with yttrium accounting for approximately 30%. It was estimated that the amount of yttrium from US phosphate processing could meet the world demand for this critical element. This research aimed at recovering both REEs and phosphorus from a phosphate flotation tails. This tails is composed of mainly silica and phosphate with a small fraction of heavy minerals including monazite and xenotime. Since the specific gravity of silica is 2.6 versus 3.2 for phosphate and 4.5-5 for rare earth minerals, pre-concentration of the minerals of interest by gravity separation was investigated first. A pilot scale shaking table was used in this study. One pass gravity concentration achieved a shaking table concentrate analyzing over 600 ppm REEs at about 40% recovery. Flotation of the shaking table concentrate resulted in a product containing 1809 ppm REEs and 26.37% P2O5 with corresponding recoveries of 73% and 82%. Sulfuric acid leaching at 75oC could recover over 60% REE and nearly all the P2O5. Higher REEs (>90%) recovery was achieved by conducting leaching at higher temperature with concentrated sulfuric acid. The phosphoric acid from leaching of the flotation concentrate is of superior quality compared with that generated from regular phosphate rock.INTRODUCTION Rare earths are a group of 17 elements including those of the lanthanum series, as well as the non-lanthanides, yttrium and scandium. These elements have very specific critical uses in a multitude of markets. For example, lanthanum is used as a catalyst in breaking down crude oil to produce gasoline, diesel and jet fuel and neodymium is the core magnetic component in high-strength magnets for electric car batteries, wind turbines and hard disk drives. Rare earths are also essential for many military applications. Many of these applications have no substitute materials and the move to green technologies has dramatically increased their demand."

Jan 1, 2018

By N. V. Ramana Murthy

Utilisation of Low-Grade Iron Ore Fines after concentration not only helps in conservation of the mineral wealth, but also substantialsly improves the economics of iron ore mining. There has been need to develop suitable beneficiation process for upgradation of low-grade iron ores towards their rational utilisation. Presently the circuit adopted for processing iron ores has limitations in reduction of alumina. The depletion of high-grade reserves, utilisation of low-grade reserves coupled with in-creasing market pressure for improved product quality necessitates re-examination of the process flow sheets and evaluate alternative or supplemental processing routes. The main objective of the Process amenability studies for utilisation of Low-Grade Iron Ore Fines (-10mm) is to get Pellet grade concentrate with +65% Fe (min), SiO2 1.8% (max), Al2O3 1.8% (max) and other proportionate constituents by adopting suitable beneficiation techniques and to collect the relevant data (Quality and Quantity of the Products) for the process development. In an effort to formulate a conceptual process flow sheet, the Process amenability studies for utilisation of Low-Grade Iron Ore Fines (-10mm), which is lying at a mine site in India, samples were collected and taken up for the study. The efforts of R & D of NMDC are discussed in this paper. Low-Grade Iron Ore Fines (-10mm) sample assayed 60.10% Fe with 3.48% SiO2 Aland 4.48% 2O3from 40 microns to 300 microns. The sample consists of hematite as the chief ore mineral followed by minor amounts of maghemite. The gangue minerals include quartz and ferruginous clay in which quartz occurs as medium grained where as ferruginous clay occurs as fine to sub microscopic size mineral. The economical processing route evolved out of the studies finally could yield a final concentrate constituting 58.63% by weight along with Iron unit?s recovery of 63.51% assaying 65.10% Fe with 1.48% SiO2 and 1.85% Al2O3route that adopted comprises the following operations. Making slurry in a sump pump followed by grinding in close circuit with 48mesh size Screen. The -48 mesh size product was subjected o the Cycloning to remove slimes. The Cyclone Underflow product was subjected to Floatex Density Separation (FDS) to separate fine heavy minerals from the gangue minerals. The FDS Underflow was collected as concentrate. The FDS Overflow product was further subjected with Wet High Intensity Magnetic Separation (WHIMS) to recover more Iron units as magnetics. A conceptual process flow sheet was evolved, which may become the prelude to the subsequent finalisation of the process flow sheet for commercialisation.

Jan 1, 2014

By T. Moloane, C. Bergman, Heloise Thiele

"A pilot test campaign was undertaken to evaluate dense medium cyclone separation efficiencies on samples of iron ore fines (-1mm +300µm). Evaluations were done using both gas and water atomised FeSi types across a range of operating conditions in the presence of slimes build-up. A Mineral Liberation Analyser (MLA) was used to measure size, density, shape and liberation data of DMS feed and products. The results of the test work were used to obtain parameters for modelling of the partition size/density response. The findings indicated that accurate density characterisation of the feed ore is essential in understanding product quality and recovery, particularly due to the effect of porosity and micro-inclusions. A significant off-set between cyclone underflow density and separation cut-point (D50) was found indicating that relatively low feed media densities (about 3.4g/cm3) are required to achieve high density cutpoints of over 4.0g/cm3. In agreement with CFD modelling, the separation quality is dominated by viscous effects, hence FeSi type and slimes content will need to be carefully controlled to ensure efficient separation.INTRODUCTION In the South African context, future resources of hematite are expected to be both of lower head grade and will contain a higher content of banded iron formation (BIF) (1). These ores may require finer crushing in order to liberate the high-grade fractions and will thus increase the amount of -1mm material to be processed. In order to efficiently upgrade these materials, it becomes necessary to re-examine both traditional and novel processes to treat material finer than 1mm in size. These include spiral and up-current classifiers, wet high intensity magnetic separation processes, Reflux classification and potentially includes dense medium separation (DMS). This study presents a technical evaluation of fines DMS using a mineralogically-based particle tracking analysis method (PTA) to calculate efficiencies of separation."

Jan 1, 2018

By Sarra Scherbakova, Alexander Kurkov, Andrey Egorov

"Deep concentration of iron ores involves extraction, in addition to magnetite concentrate, of hematite and martite concentrates and recovery of other valuable components. A flotation technology was designed specifically for finely disseminated hematite ore, allowing producing saleable hematite concentrate containing 64-66% Fe. The main process challenge is caused by the presence of other ferruginous minerals such as carbonates, silicates, and phosphates, and fine hematite and martite mostly concentrated in the -0.044 mm fraction. Main operations of the processing circuit are removal of slime, flotation to remove impurities (carbonates, phosphates etc.) with an anionic phosphorous collector in an alkaline environment, hematite and martite flotation using same collector in a slightly acidic environment to produce commercial iron concentrate. Tailings of wet magnetic separation of magnetite containing 24.5% Fe and finely disseminated hematite ore containing 51% Fe were processed to produce iron concentrates with a yield of 15% and 50%, respectively, containing approximately 65% Fe and 5% of silica. Hematite flotation tailings had the highest content of gold (up to 0.09 - 0.11 g/t), while in other products it never exceeded 0.02 g/t. Using a Knelson concentrator was able to recover 40 to 45% of the gold into 3.31 g/t Au gravity concentrate. The success of gravity concentration is due to high gravitational contrast of gold to mostly quartz and aluminosilicates in the hematite flotation tailings. In general, the proposed process can be used as a solution to the challenge of selective concentration of finely disseminated iron minerals."

Jan 1, 2014

By Wei Sun, Chengwei Li, Zhiyong Gao, Yuehua Hu

"Grinding for mineral liberation is a prerequisite for a successful flotation separation. Different grinding media produce mineral particles with different morphologies and surface properties. In this study, the surface physicochemical properties of fluorite particles produced by ball and rod mills were systematically investigated through single mineral flotation experiment, wettability measurement, X-ray diffraction (XRD) test and scanning electron microscopy (SEM) observations. The XRD observations reveal that the surface exposure degree for both mill particles follows the order {111} > {110} > {100}. The difference lies in that the rod mill ones have a higher exposure of more reactive {110} and {100} surfaces, leading to a stronger interaction with the collector. The difference also leads to their higher elongation and lower roundness values of rod mill particles which are beneficial for the particle-bubble attachment by shorting the induction time. The wettability and flotation results show that the rod mill ones have a lower critical surface tension and a greater hydrophobicity when treated with the collector solution and accordingly perform a higher flotation recovery. This work, for the first time, revealed the importance of the exposure of crystal surfaces in determine the shape factors and reactivity of the mineral particles and will help provide guidance for optimizing flotation separation and particle surface modification. INTRODUCTIONFluorite (CaF2) is the most important source mineral for producing F-based chemicals and materials which are widely used in industrial, environmental, and medical fields [1, 2]. In ore deposit, there are two kinds of occurrence forms of fluorite mineral. Firstly, the fluorite mainly coexisted with the gangue minerals like calcite (CaCO3) and quartz (SiO2). Because of their similar density and fine-grained dissemination in ore deposit, ball mill grinding before flotation separation has been widely applied to produce relatively fine particles [3]. Secondly, the fluorite is often associated with other valuable minerals with higher relative density such as scheelite (CaWO4) and cassiterite (SnO2). Due to their obvious density differences and coarsely grained distribution in ore deposit, rod mill grinding before gravity separation has been usually used to produce more uniform particles and avoid over-grinding [4-6]. After the gravity separation, a flotation separation is also employed to beneficiate the fluorite [7]."

Jan 1, 2018