Search Documents

By M. Naymanbayev

The characteristics of the mineral composition of ores and valuable set of components: the technology of processing depending on the type of mineralization, the nature of the impregnation of ore minerals and their composition have been considered. There have been given technological schemes for processing concrete objects. The analysis of fitness fields for industrial development (degree of scrutiny, the effectiveness of developed enrichment and hydrometallurgy technology) has been provided.

Sep 1, 2012

By S. P. Das

Tumbling mill is an important unit operation in a mineral processing industry whose operation needs to be understood to make it an energy efficient unit. One of the important mill parameters is the impact spectra generated by collision of the moving charge mass on the mill shell. This process also generates mechanical vibration on the mill shell and propagates to the plumber block of the mill. In this work, we tried to understand the impact spectra by using different minerals such as Banded Hematite Quartzite (BHQ), Hematite and Quartz as mill feed of a semi-autogenous (SAG) mill. The said mill is of 1000 mm diameter and fitted with a force sensor on the mill shell and a vibration sensor on the plumber block. The analysis of the impact spectra was done by taking into consideration the peak impact force above a certain threshold value. It clearly shows that the impact force decreases as the particle size become finer irrespective of the mill feed material. This can be used as an effective tool by the mill operators to have an understanding of the mill product size reduction. The mechanical vibration tapped by a tri-axial accelerometer was analyzed by power spectral density analysis. The vibration signal analysis shows the variation in the power spectrum magnitude both at lower and higher frequency. It also shows inconsistency in case of BHQ where it shows a significant decrease in vibration at lower frequency and increase in vibration at higher frequency. Therefore, the impact spectra analysis is a better method compared to vibration analysis in understanding the mill product size reduction.

Sep 1, 2012

By G. V. S. Murthy

Beach Placer Ilmenite is an important source for production of titanium metal, titania slag and pigment grade titanium dioxide. Besides, these well known applications for which Ilmenite is mined and processed, there are other emerging processes that are being tried for obtaining highvalue products. Synthesis of Ilmenite based materials for varistor applications and direct electrochemical reduction of Ilmenite to produce ferrotitanium are two such attempts being discussed in this work. In this paper, recent efforts undertaken to study the electrical and magnetic characteristics are discussed. Ilmenite, FeTiO3, is one of the mixed-valence transition metalbearing minerals, inwhich Fe can be in two different oxidation states, Fe2+ and Fe3+.. Similarly, Ti can be in Ti3+ and Ti4+.Ilmenite is inherently suitable for making Varistors, which are devices, used for limiting the transient voltage surges in a circuit. Varistors produced from Ilmenite can withstand harsh environments seen in nuclear reactors and outerspace. Electrochemical reduction of Ilmenite can be used to prepare ferrotitanium directly without any reductant. The process essentially involves removal of oxygen from the mineral through electrolytic action using calcium chloride as electrolyte and graphite as anode. At a temperature of 950°C, it is shown to be possible that all the oxygen can be removed from the Ilmenite sample, which passes through the electrolyte, to form CO/CO2 at the anode. The process has immense potential for cost effective production of titanium metal as well. Results of the above developmental works are presented in this paper. Keywords: beach placer ileminite, varistor applications

Sep 1, 2012

By Edson Charikinya, Pierre-Henri Koch

"The extraction of mineral values from ore requires liberation followed by separation steps. Liberation is achieved by size reduction operations which are energy inefficient processes typically dominating the energy consumption in a mineral concentrator. As the grade of ore reserves declines, future viability of mineral operations will be determined by energy costs of comminution. The application of high power microwave energy to secondary crusher products has been suggested as a possible commercially viable thermal treatment method for reducing comminution energy and improving value mineral liberation. Recent studies have shown that microwave pre-treatment of coarse sphalerite ore particles (> 5mm) at specific microwave heating energies (1-3 kWh/t), induces microfractures and creates new crack surfaces. This suggests that subsequent crushing of these microwave treated particles could yield enhanced liberation. However, limited studies have been carried out investigating the mode of breakage and the extent of enhanced liberation in that case. The objective of this study is to develop numerical methods for quantifying the extent of enhanced liberation and mode of breakage in crushed microwave treated and untreated particles. Sphalerite ore particles representing small (-5+4.75) mm, medium (-16+9.5) mm, and large (-25+19) mm HPGR and cone crushed particles were microwave treated at specific energies between 1-3 kWh/t. Cracks in the ore particles before and after microwave treatment were analysed with QEMSCAN and numerical models of the measured particles (before and after microwave treatment) were developed in MATLAB. The propagation of random and non-random cracks was investigated by simulating comminution of the modelled treated and untreated particles. Results of this study demonstrate that the breakage mechanism and the liberation of valuable minerals from gangue in microwave treated and untreated particles is significantly different. This study contributes to the development of numerical tools to quantify crack propagation in heterogeneous ore particles."

Jan 1, 2018

By Pamela Castillo, Marcia Muñoz, Rodrigo Luca, Brian Townley, Fernando López

In the present study we discuss the value of multi-element geochemistry as a tool for semi-quantitative to quantitative bulk mineral characterization in geological and geo-metallurgical modeling of porphyry copper type deposits, with an emphasis on hydrothermal alteration associations, types and intensities. In mine production of porphyry copper deposits much effort is placed on ore grade and geological modeling, applied for predictive mineral processing behavior, from blasting, grinding, leaching or flotation, down to waste disposal and environmental management. High confidence geological models are commonly based on geological mapping of drill core and surface/ underground exposures, combined with discrete mineral characterization (e.g., petrography, QEMSCAN®, spectroscopy, etc.). Unfortunately these are expensive and applied to limited numbers of samples, thus lacking sufficient representation and not suitable for geo-statistical modeling. In addition, geological mapping always presents uncertainty, based mostly on qualitative estimates. The combination of information usually provides geological models that are hard to combine with geo-metallurgical data, much less with mineral processing predictive behavior models. The advent of multi-element geochemistry, at low cost, has allowed employment of such tools massively, yet little use is given to the data, usually focused on elements of economic interest (main ore and credits) and elements of negative impact to concentrates and/or process. Geochemistry reflects the mineral composition of rocks, thus allowing characterization of lithology, alteration types and intensities, and mineralization. As examples of such applications we present generic classification techniques which were developed on various porphyry copper deposits of northern Chile, these based on multi-element geochemistry, allowing for semi-quantitative to quantitative high resolution modeling of key aspects of lithology, hydrothermal alteration and mineralization, and which may be cross-referenced to metallurgical test samples and by that, to geo-metallurgical properties of rocks and modeling. In addition, as data is quantitative and continuous, modelling of gangue can benefit from geo-statistical modeling.

Jan 1, 2018

By Shankar Narasimhan

Data Reconciliation is a technique that has been developed more than fifty years ago and has been refined over the past few decades and is now being deployed routinely in several process industries such as refining, petrochemicals, mineral processing and hydro-metallurgy. The main aim of data reconciliation is to obtain accurate estimates of all process variables and parameters using plant measurements that are invariably corrupted by random errors and may also contain biases and other gross errors. These reconciled estimates are subsequently used either in offline exercises such as simulation, retrofitting, and de-bottlenecking or in online optimization and control applications. In this presentation, a brief history of data reconciliation, its assumptions, and uses are reviewed. New developments in this area are highlighted such as robust data reconciliation to handle model uncertainties, and reconciliation using identified models derived purely from operating data. Several case studies in the mineral processing industries reported in the literature are also highlighted to indicate the potential benefits of this technique.

Sep 1, 2012

By S. Schade-Dannewitz

In terms of a sustainable waste management, high recycling rates and purities of the different collected waste components are very important. Especially the recycling of used packaging materials with valuable components like plastics, ferrous and non-ferrous metals and liquid cartons (light weight packaging) requires a complex technology. In plants to recycle those light weight packaging materials films cause problems and often manual sorting is necessary to remove them. The Nordhausen University of Applied Sciences together with the company Schulz & Berger from Altenburg tries to replace manual sorting with fully automated technologies. The objective is a technology that can enable a high recovery of recyclable film and satisfy the maximum purity requirements for the film fraction. For that purpose, a new machine called Low-pressure Separator was developed. The test materials used consist of separately collected recyclables from the yellow recycling bins or bags in Germany?s Dual System (Duales System Deutschland ? DSD), the recyclable waste collection system. First tests show that high purities of the film-fraction, for example the required 92% or higher, can be realized. Next to the film-purity, furthermore the mass yield and the recyclable yield are discussed because they play an important role to evaluate the efficiency of the recycling process. Further activities to improve and establish the developed technology are mentioned.

Sep 1, 2012

By A. Morrison, P. Brito-Parada

"The separation of valuable and gangue minerals according to their surface hydrophobicity in a froth flotation tank occurs in both its pulp and froth phases. In the pulp phase, hydrophobic particles must be brought into contact with rising bubbles introduced at or near the bottom of the tank. In a mechanical froth flotation tank, this is primarily achieved through the agitation of the pulp by an impeller or by a rotor-stator system. However, the turbulent and mixing effects of such an impeller or rotor-stator system, necessary to promote bubble-particle interactions in the pulp, are not confined to the pulp zone, but are transmitted into the froth zone at the pulp-froth interface. This impeller-induced turbulence at the pulp-froth interface is compounded by the impulse of buoyant bubbles entering the base of the froth phase, reducing the stability, and thus separation performance, of the resulting froth. Hence, turbulence improves separation performance if it occurs deep in the pulp phase, but diminishes it if it occurs close to the pulp-froth interface. For this work, a performance-enhancing pulp phase insert was designed to isolate the impeller-induced turbulence from the pulp-froth interface in a laboratory-scale, continuously-operated froth flotation tank. The result was a shifted grade-recovery curve that allows the insert to be designed to maximize the recovery from the system without sacrificing the grade of the concentrate, or vice versa, along a spectrum of improved performance. This paper will present the insert design and development process that resulted in this improved grade-recovery curve, as well as a set of heuristics that could be used to design a similar insert for pilotand industrial-scale validation and deployment.INTRODUCTIONAn almost ubiquitous design feature of commercial flotation tanks is the enclosure of the impeller to create a concentrated turbulent zone (Mavros, 1992). These turbulent zone enclosures are varied-- from the rotor-stator design of, for instance, Outotec cells, to the air disperser design of Wemco cells-- but all share the same rationale: that turbulence is desirable to promote bubble-particle interactions (Ralston, 1999), and to produce smaller bubbles (Wills, 2006), but also undesirable because it promotes the detachment of valuable mineral particles from bubbles, and exacerbates entrainment-inducing mixing at the pulp-froth interface (Jameson, 2010)."

Jan 1, 2018

By I. Gombköto

To sustain the growth of industrial production necessitates the increasing of the amount of processed mined raw and secondary materials. As a side effect of raw material production, the amount of tailings material, - coming from mineral processing operations ? increases as well. Using wet technology, these tailing materials are generally transported and stored with the water used for previous operations. This habit could lead to dangerous situations. Enough to remember the disasters had happened to the last decade, safe tailings operations need to remove as much water from the solid as possible. Environmental, technical and economical needs should meet, therefore using a technology combining these specific needs could be necessary. Paste technology was introduced generally into tailings operations at the last ten years, as an answer to the call of the above mentioned challenges, however there are still many questions to answer within the frame of using it. The Institute of Raw Materials Processing and Environmental Process Engineering of the University of Miskolc has been dealing with mechanical process engineering, especially by the support of the EU project TAILSAFE Contract nº EVG1-CT-2002-0066 and the NKFP 3A/068/2004 Hungarian fund extensive research has been carried out about paste technology. Different test methods and materials were applied. Tested tailings materials were as follows: different fly ashes from coal power plants from Pécs ? Hungary, Gyöngyös ? Hungary, Neyvil ? India, different Croatian ashes, hazardous waste incineration plant ashes from Dorog ? Hungary, different kind of sands from Hungary, fine glass sand from Fehérvárcsúrgó ? Hungary, flotation ore processing tailing from Gyöngyösoroszi ? Hungary. Different additives, as gypsum, bentonite and cement were tested as well. The applied test methods were as follows: physical material testing (laser sizer, piknometer, different microscopes), X-ray diffraction analysis, settling columns, the three measuring pipes tube viscometer (16~27 mm pipe diameter), a hydraulic test loop with different pumps (40~53 mm pipe diameter, 0.2~4 m/s average slurry velocity range, 0%~52 % volumetric concentration range), rotational viscometer, Cassagrande yield locus tester and the slump cone test. This paper summarizes and systematizes the results of the aforementioned research as well as reports about the developed paste pipe transport design method based on the fine suspension ? coarse mixture model. The paper also reports about a systematic experimental series with different materials to establish criteria when high concentration suspensions behave like paste.

Jan 1, 2014

By Luís Marcelo Tavares, Daniel Francioli, Malcolm Powell, Mohsen Yahyaei

"Mathematical modeling of the comminution process requires understanding of all breakage mechanisms occurring in this mechanical environment. Modeling of high energy impact breakage is well established, however, modeling low energy breakage including incremental damage breakage, attrition and abrasion is still under development. Free fall incremental impact tests were carried out to investigate the surface fragmentation of a copper-gold ore. This process was achieved by dropping particles individually from a height of four meters onto a metallic plate. The impact specific energy was 0.01KWh/t. The setting of the metallic plate was changed to test the impact angles of 0°, 45°, and 60°. Tests were carried out using fresh angular rocks as well as smoothed particles. Changes to the plate angle and particle shape enabled the study of the influence of the tangential component of the impact energy along with particle shape on superficial breakage. By studying the fractional mass loss variation in each impact, two distinct stages of surface fragmentation were clearly determined: high fractional mass loss dominated in the first 10 impacts and was attributed to chipping, whereas low fractional mass loss occurred for the remainder of the impacts and was attributed to abrasion. Smoothed particles demonstrated higher resistantance to breakage and their surface fragmentation behavior indicated a closer relationship to abrasion, especially when lower impact angles were used."

Jan 1, 2014

By Hans-Åke Häggblad, Bertil I. Pålsson, Jan Stener, Kent Tano, Andreas Berggren, Pär Jonsén

Numerical modelling of grinding in tumbling mills is traditionally done with the discrete element method (DEM). The grinding balls are then represented by DEM particles and the mill structure is considered rigid. To include more physical phenomena several numerical methods can be combined. One important improvement is to include the mill structure response, using the finite element method (FEM). The interaction between charge and lining can then be studied in detail. The pulp can also be included using a particle-based continuum method e.g. smoothed particle method (SPH). The strength of SPH lies in modelling of free surface flows and very large deformations and it is suited to model simultaneous fluid and granular flow. Still, the coarse particles (grinding balls) in the charge are suitable to be model using DEM. Each of these methods has their strength and weaknesses, but combined they can successfully mimic the main features of the charge movement. With these numerical tools the complex interaction between the different components of the grinding process; pulp, charge, lining and the mechanical behaviour of the mill, can be studied together. This work will present novel numerical approaches to model, simulate and validate charge behaviour in tumbling mills. These numerical models give possibilities to better understand the physical and mechanical behaviour of particulate material systems during grinding in a tumbling mill. This is important in order to develop and optimise future high-capacity grinding circuits and save energy.

Jan 1, 2014

By P. Somasundaran

Gangue minerals can often have severe adverse effects on selective value mineral separation. Such effects can be mediated through a variety of pathways or mechanisms. One popular mechanism is that of ?slime coating? or heterocoagulation, wherein the gangue mineral fines are believed to coat the value mineral surfaces and thereby reduce selectivity and floatability. Another pathway that has received relatively little attention is that mediated through the effect of gangue minerals on pulp rheology, and consequently selective separation. Our recent work in developing a scientific understanding of these effects has highlighted the prevalence and importance of this pathway. In this study, the impact of shape and morphology of serpentine gangue minerals on suspension rheology and selective Ni flotation from ultramafic ores was investigated. We found strong evidence for micro- and macro-network formation in the presence of acicular (needle-shaped) or fibrous minerals, which impacted pulp rheological properties. Results also supported the hypothesis that morphology has a greater role to play than mere shape. The size of the network ranged from 5 microns to 2 cm depending upon the amount and aspect ratio of fibrous minerals. These networks impede many flotation sub-processes, such as gas dispersion and bubble-particle interactions. Additionally, the small pore size of the networks prevents bubble penetration leading to a large transport of the gangue minerals to the concentrate via lifting of the entire network by bubble flux, which resulted in a significant grade dilution. Based on the scientific insights generated in this study various techniques have been developed to improve selective value mineral separation. Keywords: fibers, aspect ratio, microstructures, networks, pulp viscosity, gangue transport

Sep 1, 2012

By Robinson Irarrazabal, Edison Collinao, Rodrigo de Carvalho, Patricio Davila, Marcelo Tavares

"In recent years, DEM (discrete element method) softwares, along with 3D laser measuring equipment, have become powerful tools to describe mill charge behavior, as well as forces acting on the liners of SAG mills. With the aim of contributing to streamline this application of the advanced technologies ME Elecmetal and Universidade Federal do Rio de Janeiro, UFRJ, proposed a new approach to improve the design of mill liners using elements from mechanistic modeling of grinding. The paper presents a methodology for continuous improvement of liner design, which uses information from the DEM collision energy spectra in the mill discriminated for the different components (ore and steel balls), as well as information on the breakage properties of the ore being ground. From these it proposes the concept of "effective collisions", which corresponds to the collisions that are of sufficient magnitude to cause breakage, thus allowing to discriminate from impacts that do not cause breakage either in a first impact or after repeated loading. It also tracks the collision of steel balls against the shell in order to assess their potential damage to the liners. An industrial case study is presented of a 38’ diameter SAG mill, which was experiencing challenges associated to liner breakage and low efficiency with the old liner design. Through a modification of the liner design, simulations demonstrated the potential benefit associated to reduction in ultraprojection and improvement in mill capacity. Implementation of the new design in the SAG mill was carried out, resulting in increase in daily throughput from 6 to 12%. Further, the time spent in liner change was reduced by 47% given the reduction in the numbers of parts. This operation also benefited from having no stops due to unplanned shutdowns to replace broken tiles. These demonstrate the benefit of coupling advanced computational tools to sound engineering principles in continuous improvement of liners."

Jan 1, 2014

By Wenying Liu, Marek Pawlik

Long-chain ionic surfactants, with fatty acids and amines as the most important representatives, are widely used as collectors in froth flotation. These surfactants, generally referred to as weak electrolyte collectors, frequently form solid insoluble precipitates within a certain pH range. However, the action and behavior of these colloidal precipitates in froth flotation systems are not well understood and has not been well decoupled from those of dissolved forms. The objective of this study was to understand and compare the role of colloidal precipitates with that of the dissolved forms at gas-liquid and gas-liquid-solid interfaces. Using primary amine as the model surfactant, experiments were carried out to measure: the maximum volume of bubbles generated in the presence of dissolved and precipitated forms of the surfactant; surface tension for both forms of the surfactant using the drop shape and maximum bubble pressure methods; and contact angle using the sessile drop method. The experimental results showed that: in the presence of the precipitate, bubble volume was smaller, which was correlated with the lower surface tension and higher contact angle measured; the surface tension of solutions containing surfactant precipitate was affected by the surface age of liquid droplets. This study enhances understanding of the interfacial behavior of long-chain ionic surfactants under different conditions, which would help improve the efficiency of reagent utilization in froth flotation.

Jan 1, 2014

By E. Lee

Cone crushers are widely used within the mining and aggregate industries for the size reduction of minerals, ores, and rock materials. In mining applications for example, the product from cone crushers is often fed to HPGRs or directly to mills in the subsequent grinding circuit. An improved cone crusher performance can therefore result in an overall improved and more efficient comminution process. The objective of this paper is to systematically study a number of different ways of applying compressive crushing. By mathematically modelling these different crushing concepts and then theoretically optimizing crushing sequences accordingly, each concept can be studied and evaluated. In addition, aspects concerning whether or not the results are mechanically or practically achievable are considered. This study thus explores the advantages and disadvantages of different crushing concepts. In this paper, four different theoretical crushing concepts are presented and studied. The results show that in terms of interparticle crushing, optimal crushing sequences with varying compression ratios can be replaced by easier implemented series of constant compressions without significant deterioration. It is also shown that that considerably better performance is obtained for crushing sequences with both breakage modes. The subsequent comparison between such concepts indicates that different approaches can achieve the same results, and that the different concepts are comparable. It is further concluded that interparticle crushing should be kept to a minimum if fines generation or energy consumption is to be minimized, and that each of the studied concepts presents different challenges for implementation. Keywords: compressive crushing, cone crusher, optimization, modeling, crushing concept

Sep 1, 2012

Spent automobile catalyst is an important secondary resource of PGMs (platinum group metals) and the recovery is significant. Various methods of recovery technology have been reported and applied in practical production, including pyro- and hydrometallurgical processes. Since the grade of PGMs in the catalysts is so low, approximately 0.5 wt. %, the present recycling technologies require high energy-consumption, it is of great significance to enrich the PGMs with some energy saving physical separation methods as a pretreatment. Automobile catalyst is usually composed of cordierite phase as a substrate and alumina phase, with PGMs, which covers the cordierite phase. We adopted the quenching pretreatment, one method of thermal shock, to generate micro-cracks between the two phases and separate the alumina phase from cordierite. Quenching was carried out by heating the catalysts in an electric furnace of different temperatures followed by rapid soaking into cold water. It was found that the phase boundary between alumina and cordierite was broken in the quenching and selective separation (detachment) of alumina from the cordierite could be achieved in the following surface grinding. The effect of quenching was checked by microscopic observation, hardness measurement, and chemical analysis. This paper figures out the stress formula of the quenching process, which is largely connected with layer thickness and temperature gradient by using an FEM (Finite Element Method) simulation and clarifies the mechanism of crack generation in the quenching process. Keywords: automobile catalyst, PGM, quenching process, FEM

Sep 1, 2012

By A. Oberrauner

Electrostatic separation is a dry separation technique usable for many applications in the mining- and recycling industries. At the Chair of Mineral Processing intensified research has been done on this topic during the last years. One challenge was to measure the triboelectric charging of fine mineral particles in a triboelectric charging device consisting of an electrically insulated polyethylene rotor/stator assembly. These tests, performed on monomineralic samples, were accomplished in a climate chamber. It was shown that charging of minerals not only depends on rotor speed, feed rate and atmospheric circumstances but also on the properties of the applied electrostatic field. Tests on pure calcite in contact with the polyethylene rotor/stator system resulted in specific triboelectric charges up to +10 nC/g at low relative humidity. With more water present in the surrounding atmosphere, these charging values decreased significantly. However, at higher relative humidity, triboelectric charge values could be maintained after an electrostatic field of positive polarity was applied. Similarly, charging behavior was found with other hydrophilic minerals. The idea behind all these tests was to find the largest charging difference between minerals occurring together in a deposit and to be able to charge them oppositely, assuming that this means good sort ability in an electrostatic separator. The results gained from these investigations are shown. After having obtained many results on charging pure minerals, it became interesting to test the applicability of the charging tendencies on electrostatic separation of fines <100 µm. In order to do so, a separator for fine polymineralic powders was developed, constructed and combined with the triboelectric charging device, all being set up in a climate chamber. This new so-called coax-separator is presented along with first test-results.

Sep 1, 2012

By Graeme J. Jameson

"When mineral particles are floated in a mechanical flotation cell, it is found that the rate constant, after reaching a maximum value, starts to decline as particle size increases. It had been thought that the reduction in rate constant had been due to the increased prevalence of composite particles in natural ores, for larger particles. However, Jameson (2012) showed that the rate constant for composites is certainly a function of the surface liberation, but the reduction in flotation rate is independent of particle size. Thus all particles are equally affected by reduced surface liberation, independently of their size. He further argued that the classical peak observed in the rate constant with increasing particle size, is a function of machine hydrodynamics. Thus in mechanical cells, the peak may be due to the high energy dissipation rate and its effects on the detachment of particles from bubbles (Goel and Jameson, 2012). Consequently, in a different flotation environment, it may be possible to float large composite particles that cannot be floated in mechanical cells. This paper describes the flotation of large composite particles in a fluidized bed flotation cell. The particles to be floated are fed to a column in which there is a continuous upflow of liquid. A conventional froth layer of controlled depth is formed at the top of the vessel. A fluidized bed of particles is established which provides a gentle environment for the contacting of large particles with bubbles. An example is given where a porphyry copper ore was prepared at a top size of 710 µm, and floated with conventional collector (PAX) and frother (MIBC). The concentrate was separated into size fractions and examined by photography. Composites were observed at all size fractions, but above 400 µm, all particles were composites. The implications for future flotation circuits will be described."

Jan 1, 2014

By M. Alvarez-Silva

The control of the amount of chromite reporting to the concentrate during the flotation of UG2 ore is of critical importance since its presence affects the downstream smelting process. It is generally reported that the main mechanism responsible for chromite recovery is through entrainment. This is reflected in analyzing the solids and water recoveries. These in turn are strongly dependent on the froth phase. In the present investigation a laboratory scale column flotation cell was used to investigate the role of the froth phase in the flotation of UG2 ore. Such a device is superior to a standard batch cell since it operates at steady state in open circuit and also allows for a greater degree of flexibility in terms of froth heights. The mass of solids and water recovered in the concentrate as well as chromite (Cr2O3) recovery by size class was determined as a function of froth height, superficial gas velocity and depressant dosage. The results showed that depressants had little effect on chromite recovery but increased the grade due to the depression of gangue minerals. A 60cm froth height always resulted in slightly lower solids, water and chromite recovery than for 30cm. Typically only 20-25 % of solids reaching the pulp-froth interface reached the launder. The relationship between solids and water recovery for a wide range of conditions indicated that chromite is mostly recovered by entrainment. Keywords: UG2 ore, column flotation cell

Sep 1, 2012

By John Ralston

"Interfacial chemistry plays a pivotal role in bubble-particle capture, for it controls whether or not attachment occurs. Surface heterogeneity, degree of surface hydrophobicity, bubble nucleation and related phenomena influence the stability of the aqueous wetting film between a particle and an approaching bubble. The latter must be unstable if capture is to occur. Various techniques that may be used to quantify this interfacial, chemistry-dominated behaviour, are described.The efficient capture of specific particles by rising bubbles and the delicate control of interfacial chemistry that leads to selective capture are central issues in froth flotation. For efficient capture to occur between a particle and a bubble, they must undergo a close encounter, a collision process dominated by hydrodynamics. Should this encounter bring the particle and bubble within the range of attractive forces, the intervening liquid film between the bubble and the particle will drain, leading to a critical thickness at which rupture occurs. The liquid-vapour interface then retreats over the solid particle surface until a stable wetting perimeter is established. The particle and bubble are then joined after this attachment process. The particle may only be dislodged from this state if it is supplied with sufficient kinetic energy to exceed the detachment energy in this detachment process. These various events are now well documented and may be followed using high-speed videomicroscopy (Schulze, 1984; Nguyen et al., 2001).The process of collision can now be described quantitatively for single bubbles colliding with bubbles under various flow regimes (Dai et al., 1998) and appropriate scale up is possible for multiple bubble particle collisions occurring under turbulent conditions (Pyke et al., 2002). In this paper we will be concerned with the role of interfacial chemistry and how this influences the attachment process."

Jan 1, 2003