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By Y. Tang

"Rare earth elements (REEs) have many key applications in traditional and advanced technologies. A shortage of several critical REEs is expected due to the discrepancy between the availability of REEs from REE deposits and the REE demand from the market. REE recovery and separation from secondary resources such as uranium wastes and recycled materials might help balance the shortfall in a cost-effective way. This paper presents data concerning the recovery of heavy REEs (HREEs) from uranium raffinate. It also discusses the design, commissioning, and operation of a solvent extraction pilot plant for the separation of REEs.RÉSUMÉ Les éléments des terres rares (ÉTR) trouvent de nombreuses applications importantes dans les technologies classiques et de pointe. On prévoit une pénurie de plusieurs ÉTR critiques en raison des divergences constatées entre la disponibilité des ÉTR provenant de gisement d’éléments des terres rares, et la demande d’ÉTR sur le marché. La récupération et la séparation des ÉTR à partir de ressources secondaires telles que les déchets générés par le traitement du minerai d’uranium et les matériaux recyclés pourraient contribuer à équilibrer cette pénurie de manière rentable. Cet article présente des données relatives à la récupération des ÉTR lourds (HREE, de l’anglais heavy REEs) à partir de raffinat d’uranium. Il aborde également la question de la conception, de la mise en service et de l’exploitation d’une usine pilote d’extraction par solvants pour la séparation des ÉTR INTRODUCTIONSignificant amounts of strategic specialty heavy rare earth elements (HREEs) are present in waste streams in Saskatchewan uranium operations. Selective precipitation including neutralization, oxalate, and double-salt precipitation, as well as sulfide precipitation, ion exchange (IX), and solvent extraction (SX) are commonly used technologies for the recovery and purification of rare earth element (REE) solutions. REE oxalate precipitation can effectively remove Fe, Al, Ca, Si, and other impurities by taking advantage of the solubility difference between REE oxalates and impurities in the acidic solution (Xu, 2005)."

Jan 1, 2018

By J. E. Dutrizac

"The end of an era in zinc metallurgy took place on July 31, 1976 when the horizontal retort furnaces of the National Zinc Company in Bartlesville, Oklahoma were permanently shut down (1) . For more than a century, horizontal retorting had been the most common method of producing zinc in the United States; it was a thriving industry in many parts of that country, especially in the natural gas belts of Oklahoma and Texas. With the Bartlesville closure, yet another metallurgical process has become an object of historical interest for North American metallurgists. Although shrouded in controversy, the origins of zinc metallurgy seem to date back at least 2000 years. Pyrometallurgical methods with carbon reductants are capable of producing zinc from oxidic zinc ores, but only above the boiling point of the metal. Although slow cooling results in re-oxidation of the zinc vapour by air or carbon monoxide, quenching yields liquid zinc; some form of rapid cooling, either accidental or intentional, was likely used by ancient metallurgists to liquify the metal. Zinc metal found in Athenian objects of the Roman era was likely of accidental origin. The Romans employed brass extensively for coins and ornaments(2) , and this was intentionally produced by the calamine process whereby oxidic zinc ores were added to molten copper under strongly reducing conditions. Zinc appears to have been known in China and India as early as 1000-1300 A.D., and was probably smelted commercially in those countries from the 14th century. Although the early metallurgical procedures were probably inefficient, they were able to produce zinc metal in significant amounts. The large heaps of zinc residues with clay retorts bear testimony to an early smelting industry of impressive magnitude. It is estimated that the heaps at Zawar, India alone represent the extraction of 100 000 tons of metallic zinc(2) In the 1730s the smelting of oxidic zinc ores was developed in England using a vertical retort method. In 1788 a British patent was granted for making zinc from zinc blends (ZnS) by roasting the ore in a coalfired reverberatory furnace, mixing the calcine with charcoal and smelting the mixture with suitable zinc condensation. The English process was very energy intensive, however, and early in the 19th century the Belgians developed a horizontal retort process for the reductiondistillation of zinc that was more fuel efficient. This technique was gradually developed into what came to be known as the Belgian process, the forerunner of the ""modern"" horizontal retort furnace."

Jan 1, 1999

By F. K. McKean

Abstract A discussion of the difficulties involved in the production of a clean molybdenite concentrate introduces the paper. There is a brief description of the various methods for producing molybdenite that will fit marketing specifications, and it is shown how these methods are nor suited to the milling of ores containing small quantities of bismuth and copper. A process that was developed in the ore testing laboratories of the Bureau of Mines at Ottawa for the La Corne mill of the Molybdenite Corporation of Canada is described in derail and some results from pilot plant operation of this milling scheme are tabulated. A description of the La Corne mill, where the writer supervised the introduction of the process on a commercial scale, adds to the interest of the paper. In conclusion, there is a review of the conditions necessary for proper operation of the flowsheet. An attempt is made to show how the process might be satisfactory in other problems similar to that at the La Corne mill. Introduction The production of a molybdenite concentrate, free from impurities and high in grade, has been a difficult task when milling some types of ore. Whereas ordinary flotation techniques will produce acceptable concentrates of the baser sulphides, in many cases they will not serve in the treatment of molybdenite, for this mineral must be of optimum grade and purity to bring the best prices, or to find a market at all . Faced with the necessity of meeting stringent specifications, the mill operator has been forced to employ expensive processing methods, and to be satisfied with low recoveries, in order to make grade with his product. The most objectionable and common impurities found with molybdenite are: (a) gangue minerals and iron sulphides, which lower the grade; and (b) copper, bismuth, or antimony, which are deleterious in the final uses of the molybdenite products. It is difficult, and sometimes impossible, to market a concentrate with over 0.5 per cent of any of the latter impurities, or with a grade much below 90 per cent MoS2. Various methods, which have been highly successful in specific applications, have been developed to meet the problem of producing a suitable concentrate. All of them, however, have certain defects precluding their use when treating ores of a nature different from the one for which they ? were designed. The writer has developed a process for molybdenite ores having an objectionable impurity content. A description of the procedure involved, and of the La Corne mill of the Molybdenite Corporation of Canada, where the process has been adopted, should be of interest to flotation operators.

Jan 1, 1947

By D. Laguitton

The basic chemistry of a1•senic related to its dissolution and subsequent precipitation in gold-mine waste waters is discussed. The lime addition methods provides the most economic treatment of arsenical slurries, but requires a careful control of the oxidation of Asm into Asv, of the pH (>12) and the filtration of the precipitate. If arsenic levels below 0.5 mg/ l are required, a modification of the method by phosphate addition must be considered.

Jan 1, 1976

By Engineering Staff

In 1958, the Iron Ore Company of Canada decided to proceed with the Carol Project. The ore deposits in the area are part of the highly metamorphosed southern zone of the Labrador Trough. They lie along the shore of W a bush lake, in the western part of Newfoundland-Labrador, 190 miles north of Sept-Iles. The project is designed to mine, by open-pit methods, 17,200,000 long tons of crude ore, grading 37 per cent iron, per year. This ore will be beneficiated to produce 7,000,000 long tons of concentrate, grading 66 per cent iron, of which 5,500,000 long tons will be pelletized. Production is scheduled to commence this summer. Initially, ore will be taken from 45-foot benches in the Smallwood mine, using jet-piercing production drills and large-scale blasting with "slurry" explosives. Four 13-yard electric shovels will muck the broken ore into 100-ton trailer trucks. The trailers will be hauled to two 2,000-ton loading pockets, which feed the ore into 100-ton railcars. Four ore trains, each comprised

Jan 1, 1962

By N. I. Basuki, E. T. C. Spooner

"Abstract - More than 2800 published fluid inclusion data (primary inclusions) from eighteen typical Mississippi Valley-type (MVT) Zn-Pb deposits and districts were examined to study possible relationships between MVT fluid properties and metal tonnages and ore grades. The mean Th and salinity values for fifteen MVT deposits and districts are 122°C ± 21°C and 20.7 ± 2.6 wt% CaCl2 equivalent, respectively. In general, temperatures increase from pre-ore to ore stages, and salinities decrease from ore to post-ore stages. From post-ore to late calcite stages, salinity and temperature decrease with various trends within specific districts.Several conclusions are drawn: first, results show that Hanor’s (1996) salinity threshold for metalrich basinal fluids applies to typical MVT ore fluids (~16 wt% CaCl2 equivalent). Second, the lower limit of mean Th values of measured MVT deposits and districts (n = 15) of ~75°C is similar to Hanor’s (1996) observed temperature threshold for metal-rich basinal brines of ~60°C (n = 224). Third, there is no statistically significant relationship between fluid inclusion homogenization temperatures (Th) and metal tonnages or ore grades. Fourth, there seems to be a tendency for large tonnage districts/deposits to be associated with mean fluid salinities that are relatively low (~16 to 21 wt% CaCl2 equivalent) within the overall range of salinity means (~16 to 26 wt% CaCl2 equivalent). There is also a correlation between higher ore grades and higher salinities. Finally, comparison with other sedimentary rock-hosted Zn-Pb deposit types shows a trend of salinity decrease and temperature increase from MVT, sandstone-hosted and diapir-related Pb-Zn deposits, to vein-type and Irishtype Pb-Zn deposits, and then to sedex deposits. However, more data are needed for sedex deposits. The salinity threshold for significant Zn-Pb transport decreases to =~10 wt% CaCl2 equivalent at ~250°C. This study suggests that fluid inclusion analysis during exploration may be useful in assessing ore-forming potential (threshold salinity) and possible ore grades (salinity)."

Jan 1, 2002

By M. F. Goudge

BRUCITE associated with highly metamorphosed Precambrian limestone was discovered in the vicinity of Rutherglen in northern Ontario by the writer during field work on the limestones of that district in 1937, and later was identified in similar limestone at Bryson and Wakefield, Quebec. The brucite occurs as granules disseminated through the limestone (Figure 1) and comprises from 20 to 35 per cent of the rock. Such rocks may be referred to as predazzites or pencatites, depending on the proportions of the constituent minerals. In this paper, however, the general term brucitic limestone is used to designate limestone containing brucite. In none of the deposits does the magnesia content of the rock approach that of magnesite, and in the deposits near Bryson and Wakefield the magnesia content is only that of dolomite. Therefore, without some method of concentrating the brucite, the deposits would be of little or no more value as a source of magnesia than is ordinary pure dolomite, which is abundant in many parts of Canada. Investigations in the laboratories of the Bureau of Mines have, however, resulted in the development of a method whereby, from certain of the deposits, pure calcined brucite, or magnesia, in granular form can be obtained, apparently at a cost that will enable it to compete in eastern Canada with imported magnesia. The granular magnesia so obtained appears to be highly suitable for use in basic refractories, for making magnesium metal, and for various other purposes for which magnesia is commonly used. Prospecting in the neighbourhoods of the original discoveries has resulted in a number of other deposits being found in each of the three areas, and there is now apparently available s1.dficient brucitic limestone of a grade that will lend itself to commercial exploitation to supply for many years a large part of the present and prospective Canadian market for magnesia and its products. Furthermore, it is expected that additional deposits will be discovered as prospectors and others become more familiar with the appearance of brucitic limestone.

Jan 1, 1940

By Craig M. Sams

"Variable speed mill popularity has grown during the last 10 years with almost every SAG mill fitted with a variable speed drive. In addition, many of today’s larger ball mills are running a variable speed drive for various reasons. In the past, motor suppliers, especially gearless drive suppliers, have considered mills as being an overpriced rotor. This has lead to mills demanding more torque than what a motor can generate. This paper identifies the reasoning of what has happened and how to mitigate the mismatch in the future. Technical and economical issues are discussed, allowing mill operators to make an informed decision of which path to take in deciding what motor to put on a mill.INTRODUCTIONIt has been generally accepted in the past that motor suppliers and specialists in engineering companies understand the workings of a SAG mill or a ball mill and although there is a fair knowledge within the industry, in regards to mill torque requirements, the advent of variable speed drives in ball mills has shown the writer that a complete understanding of the mill torque requirements are not fully understood.This paper will discuss two aspects of mill torque requirements, (operating torque at various charge levels and start up torque), and how it relates to specifying the proper motor torque requirements.MILL OPERATING TORQUEMill operating torque at a given charge level and density in a mill is essentially constant throughout the entire speed range. For the purpose of this paper, we will take a 38’x 22.5’, 20’ EGL, SAG mill and provide the power draw at variable speeds but fixed loading conditions.The power draw and mill torque of this mill at 8% ball charge and 28% total loading (Highlighted) is shown below as Figure 1, at variable speeds."

Jan 1, 2007

By M. E. D. Raymont

"During the history of the sulphur industry there have been three distinct phases of production. Factors controlling supplies during these periods have shifted from demand for sulphur to demand for energy and a cleaner environment. The pattern of brimstone production is t raced through these phases and includes estimates of future supply; these indicate an involuntary excess production of some 20 million plus tons per year by 1980 unless some large-scale new uses are found. Traditional uses for sulphur, including fertilizer, chemicals, fibers, etc., are generally expanding slowly; how• ever, supply in ""by-product"" form alone will soon outstrip demand. The predicted oversupply situation can be corrected by the development of novel potential markets. Promising areas include construction materials, insulation and plastics, among others."

Jan 1, 1972

By Terry Braden

"Meeting probable world mineral demand in the years ahead will almost certainly require an ability to economically treat lower grade and more complex ores. Achieving this will require extensive research and technical development across the full spectrum of mineral processing.For mid-sized or smaller companies the most effective way to participate in such extensive programs - and gain access to the technology required to stay competitive - may be through collaborative research.This paper explores the recent history of collaborative research in mineral processing and in particular its ability to attract world-class multi-institutional research teams with sufficient resources to make step-change advances. It chronicles the advances achieved, but also explores the research architecture and administrative structures required to deliver research outcomes and technology transfer mechanisms to a range of often disparate sponsoring companies.INTRODUCTIONIn medieval times the dream of alchemists was to turn base metals into gold. We modern alchemists, of course, don’t waste our time on that sort of foolishness: we turn base metals into dollars. When I see the profit reports filed by some companies recently, I can only conclude that a lot of those present today must be pretty good at this.But the fact that we are here at this conference reminds us that an alchemist’s work is never done; turning base metals into dollars is not a one-trick wonder but an art that we must extensively refine year after year if we are to survive in a competitive marketplace.It is not that demand for metals is likely to slow; most people seem to think that China, India, Brazil and other emerging economies are still at the lower end of their demand curve. They will need significantly larger volumes of metals in the years ahead. The challenge for us as processors is that to supply increasing tonnages of those metals profitably we will almost certainly need to process more complex or lower grade ores and probably to do so with reduced energy inputs."

Jan 1, 2009

The #3 Shaft at Brunswick Mine, Bathurst, New Brunswick, Canada, intersects a soft graphite zone just below the 3400 Level. Ground movement within this zone causes the concrete liner of the shaft to be deflected towards the shaft?s interior, affecting the steel framework of the conveyance. In some areas, the clearance between the cage and the liner has been reduced to less than 2 cm, which is a concern. An innovative surface-mounted extensometer was designed in 2008 to monitor potential movements of the shaft?s liner. Four such novel extensometers were installed in the shaft for the surveillance of a particularly critical 3.0m by 5.5m area. This article describes the approach taken to instrument the shaft, the principle of the new extensometer, as well as the performance of the instrumentation following its installation.

May 1, 2009

By Claude Bourgoin

"The Copra massive sulphide deposit occurs as a continuous slab of ore dipping at approximately 40 degrees within a sericite schist formation. The orebody has been delineated over a distance of more than 5,000 feet down dip. This paper is mainly concerned with the mining procedure, and particular reference will be made to the use of steel mill holes and hydraulic roof supports. The gravel backfill line, which is operated both by gravity and hydraulically, is described. The paper mentions some of the operational problems, discusses the feasibility of longwall mining and presents the information obtained from stope testing."

Jan 1, 1966

By D. W. Euler, D. G. Brophey

"In an attempt to address the issue of rising labour costs, and to improve productivity, a laser-based system to guide underground LHDs and trucks has been developed. This comprehensive system is known as the Opti-Trak system.Essentially, the vehicle is equipped with front and rear-mounted lasers which scan a reference strip mounted on the drift back. The vehicle follows this reference strip and in addition, based on reflective bar codes mounted beside the reference strip, initiates certain functions (i.e. dump cycle, speed change, brake check, etc.). Any programming that is drift-specific is handled by the positioning of the reference strips and bar codes. Consequently, the vehicle can easily travel to many different haulageways or branches, providing the reference strip and bar codes are in place.The advantages of this system are an immediate elimination of haulage operator costs and an increase in available hauling time to 7 hours out of an 8-hour shift as compared to the typical 5Y2 out of 8 hours that a manned haulage system offers.This paper describes the Opti-Trak system and the benefits to be realized from automation of mine haulage requirements."

Jan 1, 1994

By Leslie McHattie

?Intelligent mine? conjures up a futuristic image of unmanned extractors and loaders working in harsh conditions in a remote lunar landscape. The promise of increasing mine fleet productivity and solving the problem labor shortages in mining regions can certainly be achieved today through remote controlled extraction and automated hauling. The technology is available and it doesn?t seem to be so much science fiction when Google?s self-driving cars hurtle down the freeway. ?Intelligent mining,? on the other hand, implies the application of information technology at every phase of the mining value chain, from exploration and geological modeling to equipment, operations and maintenance, and logistics and transportation. These are really industry-specific, enterprise-class software solutions focused on using information technology to support the business processes of mining and make them more efficient and effective. Overlaying the physical world with the digital or virtual world enables us to model and simulate our assets, giving us the ability to effectively design, build, and ultimately optimize the performance and reliability of our assets throughout the lifecycle. The digital asset, often a 3D model, is created initially during the engineering and construction phase, and is handed over to the operator before the mine goes into operation. Combined with geospatial or geographic information systems, the operator has a complete digital representation of the physical world, which forms the foundation for risk and performance management, along with compliance and regulatory reporting. Laser scanning and positioning technology can be used to create point clouds ? information models consisting of millions of data points ? which enable the visualization and representation of the ?as-operated? reality. But consider that once the mine is in operation, it throws off an endless stream of data in the form of performance and condition data from sensors and monitoring devices on fixed and mobile assets through networks, servers, and services. This ?big data? can be processed and analyzed to spot trends, help predict events, and formulate reliability strategies as early as the design stage (e.g., reliability-centered design). ?Intelligent mining? implies that massive amounts of data augment the reality of the physical mine, plant, and equipment. This embedded intelligence can be used to optimize operational efficiency, increase asset availability and utilization, improve safety and environmental integrity, and maximize return on investment. Lastly, the sweet spot for intelligent mining is seen in the convergence of consumerization and industrialization. The application of ?consumer? technologies that we use every day on our iPhones and Android devices, such as cameras, motion sensors, and positioning in an industrial context, are producing ?immersive? experiences. Overlaying the digital world on the physical world and connecting them accurately through intelligent positioning results in ?intelligent infrastructure,? which is safer and more sustainable. Bentley Systems works with many mining companies and engineering, procurement and construction companies involved in all aspects of mining infrastructure development. In fact, 10 of the top 20 mining companies ranked by market capitalization are users of Bentley software, including all of the top five. In addition, Bentley provides software solutions to the world?s leading engineering, procurement, and construction companies, as well as owner-operators, who design, build and operate the world?s infrastructure. Bentley?s solutions for mining and resource extraction industries help increase the efficiency of capital projects associated with the design, procurement, and construction of mines and processing plants, as well as the operation and maintenance of mining fleet and equipment.

Aug 1, 2013

By I. S. Thompson

"Exploration properties form a continuum from grass roots to those with favourable geology, geochemical and/or geophysical anomalies, mineralization, showings (prospects), and finally to those with defined mineral deposits. Often, properties exhibit a composite of these categories.The most problematic to value are properties or deposits that are not economically exploitable at the time of the valuation due to a lack of exploration, insufficient grade or tonnage, poor mining conditions, or the imposition of socio-economic, environmental, or legal constraints.Various acceptable methods of valuing the range of all such mineral properties or deposits are reviewed. Some less appropriate methods are also discussed."

Jan 1, 2002

By The Mine Staff

THE PROPERTY of the Lamaque Mining Company, Limited, ?is located in the Town of Bourlamaque, seventy miles east of Noranda, in Bourlamaque township, Abitrbi county, north western Quebec. Gold production commenced at Lamaque in April, 1935, with an initial mill capacity of 250 tons per day. The capacity was doubled in November of the same year, and in December, 1937, it further increased to 1,200 tons per day. During the war years the mill operated at a reduced tonnage, but in 1951 milling units were added along with complementary crushing and shop facilities to bring the capacity to 1,500 tons per day. Finally, in 1953, the capacity was raised to 2,000 tons per day, which rate is being maintained at the present time. The total production at Lamaque from April 2nd, 1935, to December 31st, 1956, has been 9,168,901 tons of ore from which 2,208,168 ounces of gold was recovered. The total value of this production , excluding E.G. M.À.*, was $77,869,653.

Jan 1, 1957

By G. F. Carr

"IntroductionFLUORSPAR has been found at several •localities in Newfoundland, but all the commercial deposits discovered to date are in the vicinity of St. Lawrence, a town on the southeast coast. Most of the veins are within six miles of St. Lawrence harbour, and between sea-level and an altitude of 400 feet. The St. Lawrence Corporation of Newfoundland, Limited, and Newfoundland Fluorspar, Limited, a subsidiary of the Aluminum Company of Canada. Limited. are the two producers.With the arrival of 1953, the St. Lawrence area entered upon its twenty-second •consecutive year as a producer of fluorspar. Production has increased more or less steadily during this period, as is shown by the fact that approximately one-half of the total shipments to date have been made during the past six years. Between four and five hundred men are employed by the industry, and more than $1,250,000 was paid out in wages and salaries during 1952. Shipments during that year reached an all-time high of 81,283 tons valued at $2,484,943, compared with 67,925 tons valued at $1,966,477 in 1951 (1).As a result of an agreement made in July, 1952, with the United States Defence Materials Procurement Agency, production of the St. Lawrence Corporation, Limited, and St. Lawrence Fluorspar, Incorporated, an affiliated company, will •be increased by .approximately 50,000 tons of acid-grade fluorspar per year. The contract extends over a period of four years, or until 150,000 tons of acid-grade concentrates have been produced."

Jan 1, 1954

"This generic study has been developed in response to the frequently asked question, ""That is the best treatment route for refractory gold ore?"". The study has developed operating and capital costs for many potential treatment routes and they are presented here in a generic form. All costs are in relation to the value of 1.00 given to the base case, a 1000 mtpd bio-oxidation plant, operating at 25% solids and 72 hours residence time.There is unfortunately no simple answer to the above quest ions. The treatment of refractory ores is a complex subject, with many variables, such as mineralogy, chemistry, environment and tonnage. However this study does offer information and relative numbers that we believe will be of assistance to gold metallurgists in obtaining a ""first shot"" at estimating costs.Equally, this technology is a rapidly evolving one. As more plants are commissioned, and test programs completed, better data is constantly being generated. For a generic study of this type to remain useful it will need regular updating and adjustment."

Jan 1, 1989

By G. Auld

"A simple method is presented whereby the additional quantity and static pressure necessary to compensate for ventilation duct leakage may be estimated using the circular reference functions of modern spreadsheets. Favourable comparisons have been made to the National Coal Board (United Kingdom) design charts and to a case study analysis. IntroductionIn mining, most ducted systems are applied to the development of access tunnels, and most of these systems leak to some extent. When the ventilation duct fails to deliver the required quantity of air to the work place, there is a significant contribution to the development costs, either directly or indirectly.Directly — More air and more pressure are required to compensate for the leakage, more capital development (ventilation shafts, parallel drives) are required because ventilation systems cannot push the fresh air far enough, and longer re-entry times to ensure toxic blast fumes to be diluted.Indirectly — There is a reduction in productivity because of the inclement atmospheric conditions, and/or closure of development ends because of unacceptable atmospheric conditions at the working place. This has been exacerbated over the last few decades because of the increased use of diesel equipment of ever increasing power, and the more stringent Occupational Health and Safety requirements demanding more air flow per kilowatt of diesel power.The leakage from a duct must, therefore, be reliably estimated in order to assess the effectiveness and construction of the system; assess the effectiveness of the maintenance or repair of the duct; appreciate the cost of the leakage, and therefore apply effective maintenance and installation procedures; and engineer safer, healthier and more cost-effective ventilation systems."

Jan 1, 2002

By J. U. MacEwan

Introduction The equilibrium between copper, zinc, and chlorine may be considered as the simultaneous equilibrium of the two separate chemical reactions of formation of the stable chlorides of copper and zinc at the temperature of the reaction i.e., l440°K. (1,167°C., 2,133°?F.)§ [Zn(g) +Ciz(g) ZnCl2z(g). ... (1) ] [2Cu(l)+Cbi'g) Cu2Cl2(l 1 ....... (21 ] Subtracting, [Zn(g) +Cu2(Clz(l i ZnClz(g) +2Cu!l) ... . (3) ] If this reaction is carried out with a copper-zinc alloy at some constant temperature above the melting point of brass, and at a total pressure of one atmosphere, the equilibrium concentrations obtained will depend on the free energy decrease .of the reaction as written in (3) and on the activities of the various components in. the reaction mixture. If the equilibrium is examined from the point of view of the phase rule, it is a three-component system, and if it exists in two phases (liquid and gas) it will have three degrees of freedom. If the restrictions of constant temperature and pressure are imposed, the degrees of freedom are reduced to one. This means that, in a two-phase system under these conditions, each different alloy phase will be associated with a gas phase of constant composition.

Jan 1, 1951