Search Documents

By Farzad Mohammadi, David Kratochvil, Patrick Littlejohn

"With more rigorous regulations being enacted in the mining industry, a need exists for cost effective and environmentally compliant technologies to remove selenium from mine impacted waters to ultra-low concentrations. Existing selenium treatment methods have high life cycle costs, introduce risks of acute fish toxicity, and produce biological waste residues that represent future liabilities. Furthermore, achieving selenium discharge limits of less than 4 ppb is a challenge for existing technologies. Selen-IX™ is a technology developed by BioteQ that selectively removes selenium from mine impacted waters to less than 1 ppb. The technology is purely physico-chemical and takes advantage of the basic principles of ion exchange and electrochemistry. Unlike conventional electrocoagulation that removes suspended solids and breaks emulsions or oxidizes heavy metals, the electrochemical process employed by Selen-IX™ relies on creating conditions where iron acts as a highly effective reducing reagent transforming selenium from a dissolved species into elemental selenium bound in a solid phase. The iron-selenium by-product of Selen-IX™ is an inorganic, non-hazardous and chemically stable solid. Due to their high iron content, the solids produced by Selen-IX™ are of interest to the steel making industry as a low cost feedstock. This offtake potential can not only reduce the life cycle cost of selenium removal by reducing disposal costs but more importantly, eliminate the risk of future environmental liabilities. In this paper, the basics of Selen-IX™ technology are presented along with results of successful piloting on streams from coal and copper-gold deposits.INTRODUCTIONVarious contaminants are released into mining wastewater during the extraction and processing of metals. One such contaminant is selenium. A naturally occurring element found in rocks and minerals, mining activities accelerate its release into the environment. Selenium in trace quantities is essential to all life forms but at higher concentrations it can be harmful, especially to aquatic life where selenium bioaccumulation can lead to reproductive deficiencies."

Jan 1, 2016

By J. Mirza, E. Nicol, J. Lipkowski

Gold passivation in thiosulfate leaching media is a major barrier to its implementation. Addition of Cu (II) into the leaching solution has shown to aid in gold dissolution, but the mechanism by which it acts, and its role in the passive layer, remains unknown. Surface Enhanced Raman Spectroscopy (SERS), in tandem with linear sweep voltammetry, were employed to determine the dependence of leaching currents on mass transport and for fingerprint identification of sulfur species on the surface of gold. SERS leaching experiments were performed using gold nanorod electrodes that showed increased stability compared to other SERS active surfaces.

Jan 1, 2011

By Jeffrey D. Oke

While significant progress in underground construction engineering has occurred in the past few decades, a number of fundamental deficiencies persist regarding the recognition, prediction, and mitigation of underground construction hazards associated with complex geological conditions in rock and soil works, such as tunnelling. Many of these shortcomings could be addressed by improving geomechanical models which, in turn, would provide more realistic frameworks for determining input parameters for design analysis. This would improve predictions of construction efficiency for tunnelling and the formulation of more accurate modelling techniques (2D, 3D and 4D) required to optimize the design of engineered rock structures. This research focuses primarily on the issues related to forepole temporary tunnel support within weak rock masses. This research attempts to determine how best to numerically model forepole support. The behaviour and mechanics of forepole support has not been quantified and/or optimized. As well, there is a lack of in-situ and/or laboratory forepole and weak rockmass interaction parameters available. In terms of numerical modelling, there is a lack of understanding of the use of proper interaction parameters associated with the forepole and the rockmass. The parametric study that has been conducted by the authors demonstrates the influence of each of the forepole-rockmass interaction parameters and their sensitivity. Introduction

Jun 1, 2012

By F. McIntosh Galbraith

EMPLOYING geophysics to find ore was for a long time considered by the Canadian mining fraternity to be a performance of dubious value: in a category somewhere between the practice of sorcery, and using a divining rod to locate underground water. With increasing knowledge, however, and with constantly improving instruments, a solid speaking acquaintance with this adolescent science is becoming an integral part of the mining geologist's stock in trade. And quite properly so: for, in the established mining districts, the ore deposits which could be easily found, by ordinary prospecting methods, have already been located. There remain; however, in almost all of the principal mining camps, areas which are covered to varying depths by glacial debris; and it is here that the obvious opportunities exist for the successful application of geophysical methods. Geophysical results must always be considered in the closest possible relation to the local geology; and, in reality, the 'doodle-bugs' are simply additional tools for the geologist (in the same category with a plane table or a microscope). The Sudbury Basin is a shining example of precisely this state of affairs. Detailed geological mapping has not significantly altered the position of the outer norite contact as placed on Dr. Coleman's original map of the district. What detailed examination has done, of course, has been to reveal the accuracy with which the contact can be placed in different parts of the district, and to show up, in consequence, areas in which further work might reasonably be expected to disclose hitherto unknown or unsuspected ore. Viewed in this light, the proportion of the norite contact which is covered by substantial quantities of overburden is astonishingly large.

Jan 1, 1939

By T. M. Ahmed

Sherritt International Corporation experienced corrosion failures with the 316L stainless steel tubing in a high-pressure still condenser employed for ammonia recovery. A detailed failure analysis was conducted on the condenser tubing to determine the mode and the root cause of the failure. The analysis included both optical and scanning electron microscopy (SEM) of the inner and outer surfaces of the tube as well as characterization of the corrosion products using energy-dispersive X-ray spectroscopy (EDX). Results revealed that the corrosion attack was confined to the first ?100 mm of the tubing at the inlet where the tube was connected to the top tubesheet. The tube suffered both external stress-corrosion cracking (SCC) and crevice corrosion from the shell side (water side), and wall thinning of the inner surface (the tube side) due to erosion corrosion. It was evident that failure of one of the tubes occurred due to SCC that penetrated the whole wall thickness and resulted in a leak failure. Some prevention measures are proposed to avoid this type of corrosion attack in the future.

Jan 1, 2005

By J. B. Mitchell

Using digital image correlation the evolution of strain and strain at the onset of localisation resulting in a hot tear has been determined for alloys AA6111 and Al¬0.5wt% Cu during solidification. High resolution images of hot tear formation and growth were captured during a constrained bar test that incorporated a glass window above a central hot spot region. The images were analysed using digital image correlation software to measure the evolution of displacement and strain based on tracking the motion of discrete features on the as-cast surface of the sample. Temperature data was also acquired with a thermocouple cast into the sample in close proximity to the hot tear. The interval starting from the point immediately after solidification shrinkage ends (the metal pulls away from the glass) and finishing when the first sign of a crack or hot tear is visible to the eye was used to determine strain data. The minimum strain at which strain localisation occurs was found to be 0.0069 in AA6111 and 0.0021 for A1-0.5%Cu.

Jan 1, 2007

By M-A. Thibault, C. Gauthierand, J-P. Gagné, J-Y. Carrier, P. Rochette, G. Dufour

"Anodes consumed in the electrolytic process for the production of primary aluminium are considered consumables. They need to be replaced at regular intervals of approximately one month. The so-called anode butts which are removed from the cells contain the metal supports (rods), cast iron thimbles, crust and residual carbon material. Cleaning is required to remove the waste material before the rods are fitted with new anodes. An inspection is required to ascertain if repairs to the rods are necessary. Presently, this inspection is carried out visually. ST AS, in 2004 in collaboration with Alcoa Deschambault, initiated a project to develop an automated inspection system. The objectives were to find a technical solution to perform these functions with a very simple system. Such a system was designed around ""artificial vision"". The inspection system developed uses only one fixed camera and does not require a separate step in the process for the anode rod assembly to perform the inspection. This paper presents the initial steps of the work performed to develop the equipment and software as well as a summary of the results obtained."

Jan 1, 2006

By Eiichiro Mizushima

Catalyst systems comprising (Ph3P)AuCH3 and acid co-catalysts were found to be highly efficient for hydration of alkynes to give ketones. Methanol was the best choice of solvents. Introduction Hydration of carbon-carbon unsaturated bonds is one of the environmentally benign routes to the carbon-oxygen bond formation. Hydration of alkynes forming carbonyl compounds, an important variation in this category, is a well known reaction which has been extensively studied. The reaction by acid-catalysis is the most conventional method, while it is applicable only to electron rich acetylenes to obtain satisfactory yields (1,2). The hydration of simple alkynes usually requires another catalyst (co-catalyst), typically a mercury(II) salt (3), which is inconsistent with the guiding principle of Green Chemistry (4).

Oct 1, 2003

By R. D. Brown

In view of the many changes which have taken place since 1950 in the rules of the Income Tax Act concerning the deduction of exploration and development expenses, many corporate taxpayers each year face the tedious task of determining which particular rules their unclaimed exploration and development expenses are subject to and in what sequence these expenses are to be claimed. Recent amendments to the Act have cleared up some of the mystery of the "ordering" of these deductions. This article examines the sequence in which various categories of exploration and development expenses are to be deducted in accordance with the terms of the Act as amended by Bill C-11.

Jan 1, 1978

By M. Tanaka, Y. Sato, H. Narita, S. Alam, T. Ogata

To ensure a stable supply of rare earth elements (REEs), it is highly necessary to establish the corresponding recycling technologies for RE magnets and phosphors in inplant wastes and endoflife products. Solvent extraction using 2ethylhexylphosphonic acid mono2ethylhexyl ester (EHPNA) is often applied in the separation and purification of REEs. In this study, the equilibrium distribution ratios of neodymium and dysprosium between 1 mol/L nitrate solution and the EHPNA in an alkane diluent were measured at 298K. The experimental data were analyzed by correcting the nonideal behavior of the organic phase using the Alstad empirical equation under the assumption that a complex with a molar ratio of 1:6 (REE:extractant monomer) was formed. The model correlated well with the experimental data and the extraction equilibrium constants were obtained. The extractant equilibrium constants obtained by this methodology would be useful in the design of REE recycling processes using solvent extraction.

Jan 1, 2014

"NI 43-101 is a rule that governs how issuers disclose scientific and technical information about mineral projects to the public in Canada. The disclosure standards apply to oral statements as well as written documents and websites. NI 43-101 does not apply to disclosure concerning petroleum, natural gas, bituminous sands or shales, groundwater, or coal be methane. NI 43-101 first came into force on Feb. 1, 2001 and was revised in December 30, 2005. As a “National Instrument”, the law has been passed in each provincial and territorial legislature across Canada.“PART 1 DEFINITIONS AND INTERPRETATION 1.1 Definitions - In this Instrument “adjacent property” means a property(a) in which the issuer does not have an interest;(b) that has a boundary reasonablyproximate to the propertybeing reported on; and (c) that has geological characteristics similar to those of the property being reported on; “data verification” means the process of confirming that data has been generated withproper procedures, has been accurately transcribed from the original source and is suitable to be used; “development property” means a property that is being prepared for mineral production and for which economic viability has been demonstrated by a feasibility study; “disclosure” means any oralstatement orwritten disclosure made by oron behalf of an issuer and intended to be, orreasonablylikely to be, made available to the public in a jurisdiction of Canada, whether or not filed under securitieslegislation, but does not include written disclosure that is made available to the public only by reason of having been filed with a government or agencyof government pursuant to a requirement of lawother than securities legislation; “early stage exploration property” means a property that has(a) no current mineral resources or mineral reserves defined; and (b) no drilling or trenching proposed; in a technical report being filed in a local jurisdiction; “exploration information” means geological, geophysical, geochemical, sampling, drilling, trenching, analytical testing,assaying, mineralogical, metallurgical and other similar information concerning a particular property that is derived fromactivities undertaken to locate, investigate, define or delineate a mineral prospect or mineral deposit; “feasibility study” means a comprehensive studyof a mineral deposit in which all geological, engineering, legal,operating, economic, social, environmental and other relevant factors are considered in sufficient detail that it could reasonably serve as the basis for a final decision by a financial institution to finance the development of the deposit for mineral production; “historical estimate” means an estimate of mineral resources or mineral reserves prepared prior to February 1, 2001;“IMMM Reporting Code” means the classification system and definitions of mineral resources and mineral reservesapproved by The Institution of Materials, Minerals, and Mining in the United Kingdom, as amended; “JORC Code”means the Australasian Code for Reporting of Mineral Resources and Ore Reserves prepared by the Joint Ore Reserves Committee of the Australasian Institute of Mining and Metallurgy, Australian Institute ofGeoscientists and Mineral Council of Australia, as amended; “mineral project” means any exploration, development or production activity, including a royalty interest or similarinterest in these activities, in respect of diamonds, natural solid inorganic material, or natural solid fossilized organic material including base and precious metals, coal, and industrial minerals;"

Jan 1, 2003

By Hal. Oliver

MR.]. G. TRAILL: My only excuse for contributing to the discussion on Mr. Hall's interesting paper is that I had the good fortune to be employed at Noranda during those romantic years, 1927 and 1928, when construction was at its height. The mine was in course of being rapidly prepared and brought into production, and the initial difficulties in crushing-plant and smelter were being met and overcome. They were stirring days, and perhaps those members who were with the second Empire Mining and Metallurgical Congress in 1927 sensed the atmosphere of excitement and activity that prevailed. Early History. Noranda must surely possess some of the most remarkable ore-bodies known to mining men, and the story of their development is pure romance. Ed. Horne's faith in the property, and the persistence of Thomson and Chadbourne, were richly rewarded in the end, but only after some very thin times had been experienced. In those early days access to the district was by the Kenojevis river and various portages to Osisko lake, on the shores of which the mine and smelter and the town of Noranda now stand. But all the early work was done on the Chadbourne claims, more than a mile to the west; through the b~sh. I have read a log of the events of that period, and through the whole tale of hard work, discouraging developments, occasional shortages of food, and constant danger from forest fires, can be read the faith and persistence of the men in charge. The Chadbourne ore was of that well-known type which, though just too low-grade to pay (with gold at $20 per ounce), is yet sufficiently encouraging to lead one on in the hope of striking something better. It was only as a last resort that work on the Chadbourne claims was suspended and a diamond drill brought to the gossan-covered hill beside the lake. The diamond-driller told me his version (it may be exaggerated) of how the position and direction of the first hole were decided on. He was told, "You might as well set up your drill here, and drill in, say, that direction". I believe that the first hole went through the richest ore ever found at Noranda. After the drill had gone through about 150 feet of solid sulphide ore running 17 per cent copper and 4 dwt. of gold per ton, it passed into barren rock, but the diamond-driller expressed the opinion (I wonder how he knew)) that the hole would come into ore again before long.

Jan 1, 1937

By Mohammad. M. Khajeh

Rock mechanical properties are important parameters in geomechanical simulation. Considering stochastic heterogeneous models rather than conventional homogeneous layer cake models leads to more realistic simulation results and uncertainty assessment. These heterogeneous models are usually fine scale models generated by geostatistical techniques. Although considering high resolution property models is desirable, geomechanical simulation with a fine scale model is not computationally feasible for full?field, coupled geomechanical-flow simulation. Upscaling of property models is necessary to move from fine scale/high resolution property models to coarser scale/low resolution models appropriate for simulation. Local numerical upscaling was proposed by Khajeh et al. (2012) to describe the macroscopic elastic behavior of complex heterogeneous media and is expanded upon in this work. This numerical technique is not restricted to specific geologies as typical analytical techniques are. Moreover, transversely isotropic deformation is considered rather than the usual assumption of isotropic deformation. To compare the accuracy of the upscaling methodology, in this study shear strain is considered as the geomechanical response of a synthetic facies model and the response of the coarse scale model is compared to other conventional analytical averaging techniques. It is found that the numerical upscaling technique better approximates the geomechanical response of the fine scale model.

Jun 1, 2012

By Jr. Wilkinson

Suncor Energy currently mines approximately nine hundred thousand tonnes of ore and waste per day at its open pit operations in the Athabasca Oilsands near Fort McMurray, Alberta. Modeling these deposits for planning purposes is particularly challenging given the characteristics associated with the deposit - stratigraphic deposition coupled with gradational grade distribution. The identification of ore and waste is a combination of bitumen cutoff grade, minimum mining thickness and separable waste thickness subject to criteria established by provincial regulatory agencies. Suncor along with Mincom Inc. have collaborated on this project to derive a methodology, automated by computer software, to streamline the ore and waste identification process. This paper explains the methodology and programs created to identify ore and waste in use at Suncor Energy and how this identification is used to categorize reserves and to generate mine design surfaces.

Apr 1, 2005

By Sandra L. Mesa-Espitia, Gretchen T. Lapidus

Gold present in arsenopyrite matrices is refractory and requires highly oxidative pretreatments in order to obtain acceptable degrees of extraction. However, these release many byproducts that are harmful to the environment. In the present work, a high-grade arsenopyritic ore was pretreated with different solutions, containing hydroxide ion, EDTA, oxalic, tartaric, or citric acids, to improve gold extractions in a posterior leaching step. The pretreatments were carried out at room temperature for 24 hours with a respective ligand concentration of 0.25 M. Once completed, the residue was leached in a thiosulfate solution to quantify the effect of the pretreatment on gold extraction. Only 29% of the gold content was leached, with very slow kinetics, in the untreated mineral. However, after pretreatment with tartaric or citric acid, the kinetics improved, although the percentage of gold extraction only reached 42-45%. The highest gold recovery, with very rapid kinetics, was found with the oxalic acid or the hydroxyl ion pretreatment (70 and 62%), respectively, but also corresponded to the most arsenic co-dissolution.

Jan 1, 2014

By G. T. Lapidus, O. J. Solis-Marcial

Currently, ores with high-grades of copper oxides and secondary sulfides have become increasingly scarce, which has encouraged industry to look for alternative raw materials to obtain copper. The problem is that primary sulfides are difficult to dissolve at near ambient conditions. Proposed hydrometallurgical processes have not been implemented beyond a pilot or demonstration scale. One of the principal disadvantages is that the majority of these processes are not viable with ores that contain less than 4% copper. One of the more recently proposed techniques involves the use of organic solvents in the dissolution of copper concentrates with a chalcopyrite content of between 20 and 30%, which has shown high efficiency. The present research explores the ability of this process to leach copper from low grade chalcopyritic ores (<4% Cu) at different temperatures ranging from 20 to 50°C. It was found that depending on the temperature, high percentages of copper were extracted in 40 to 100 minutes, using different oxidants. Additionally, distinct leaching behavior was observed with each oxidizing agent. In some cases, the extraction kinetics adjusted to the diffusion controlled shrinking core model.

Jan 1, 2014

By D. P. Wilkinson

Flow field design is critical to determining fuel cell performance with respect to operating conditions. Flow fields are normally designed around their maximum power operating point with the goals of maximizing performance and minimizing pressure drop between the inlet and outlet of the flow field. At lower power pressure drop is reduced, and water management and reactant distribution issues can occur over the active area as well as issues with cell to cell reactant distribution in the fuel cell stack. Flow fields have fixed flow channel geometries and fixed active areas which determine the reactant flow characteristics over the operational range of the fuel cell. In this paper we discuss some of the benefits of a new approach of changing the flow field active area with changing operating conditions. Such benefits for future fuel cell designs could include improved cell performance and stability, improved cell to cell reactant distribution, reduced low current density failure modes, and overall system advantages.

Jan 1, 2005

By G. Diaz

Técnicas Reunidas (TR) has been involved for over 30 years in the development of process technologies for the recovery of zinc from different primary and secondary feed materials, such as the ZINCEXTM process. Because of the complexity of the feed mineral resources, solvent extraction (SX) is an invaluable technique to concentrate and purify zinc solutions. When applied to a pregnant leach solution, solvent extraction can produce an extremely high quality zinc electrolyte, suitable for obtaining SHG zinc ingots, after electrowinning and melting and casting processes. However, the high affinity of most organic extractants for Fe(III) poses a serious problem, which may adversely affect the zinc extraction process. Different methods may be applied to deal with the negative effect caused by Fe(III). An acid regeneration step and electro-reduction stripping have been considered as the most viable techniques to remove the iron from the organic phase. This paper describes some findings of Técnicas Reunidas in the area of zinc solvent extraction, especially on removing Fe(III) from the organic phase.

Jan 1, 2006

By Zhang. L.

Ordered intermetallic PtSb had been synthesized by arc-melted and then sintering treatment. The electro-oxidation of formic acid on PtSb was investigated at room temperature by cyclic voltammetry and chronoamperometry. The results are compared to those at a polycrystalline platinum electrode surface. It was found that PtSb intermetallic was catalytically more active than pure platinum according to the onset potential and current density. XRD and XPS technologies had been used to investigate the crystal structure and electron effect. We think formic acid decomposition on PtSb favors the reactive intermediate route and is not very much affected by the CO intermediate as compared to Pt.

Jan 1, 2005

By Ming’an Wei, Qifu Duan, Chengtie Wang, Jianmin Wu, Erdenet Mining Corporation, Lusheng Zhou, Wenjian Wu

"The development and industrial applications of magnetic liners have been around for decades. A Swedish company SKEGA first introduced the rubber magnetic liner, and then followed by the Chinese metal magnetic liners. Traditionally, both liners were used in secondary and regrind ball mills, especially for ores containing magnetic materials. Mostly steel balls or equivalent forged balls, usually below 60 mm in diameter, were used as grinding media. With the development of mineral resources over the years, SAG mills and larger ball mills have become the dominating components for comminution circuit design globally. Due to the larger ball mills and thus larger grinding balls (up to 80 mm) especially in non-ferrous metal industry, the application of magnetic liners has been very limited. Based on the new development of materials, the HMR Group Limited has been exploring new designs of magnetic liners which led to the invention of the Nano Steel Magnetic Liner (NSML). Recently, NSML had a successful application in a 5.5m x 6.5m ball mill with 80 mm balls at the Erdenet Copper Mine in Mongolia. Although the first set of liner had a service life of 12 months, the design of the second set was modified and improved to accommodate the operating conditions, which is expected to reach least 24 months service life. The original manganese steel liner only had about 8 months liner life.1. IntroductionMineral processing is an essential operation for the development and utilization of mineral resources. The effective concentration of various useful minerals depends on sufficient liberation of the mineral particles in the ore. The crushing and grinding process such as ball milling are the most common way to achieve proper liberation size. Mill liner is an eternal topic for the operations, not only because it protects the equipment, but also affects the mill grinding efficiency and availability. In recent years, magnetic mill liners have been developed that can easily meet the production targets with numerous benefits, such as zero maintenance, reducing specific energy consumption and improving grinding efficiency."

Jan 1, 2016